Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Source rates and ion recycling rates for Na and K in Mercury's atmosphere     

R.M. Killen  M. Sarantos  P. Reiff 《Icarus》2004,171(1):1-19

The supply rates of Na and K to the atmosphere of Mercury by processes acting on the extreme surface—thermal vaporization, photon-stimulated desorption (PSD), and ion-sputtering—are limited by the rates at which atoms can be supplied to the extreme surface by diffusion from inside the regolith grains. Supply rates to the atmosphere are further regulated by ion retention and by gardening rates that supply new grains to the surface. We consider the limits on supply of sodium and potassium atoms to the atmosphere, and rates of photoion recycling to the surface. Thermal vaporization rates are severely limited by the ability of atoms to diffuse to the surface of the grain. Therefore, the diffusion-limited thermal vaporization rates on Mercury's surface are comparable to or less than the PSD rates. Ion sputtering is primarily due to highly ionized heavy ions, even though they represent a small fraction of the solar wind. We have shown that up to 60% of the Na photoions are deposited on the surface of Mercury. Ion recycling to the surface can have a long-term effect on the regolith abundance if an average recycling pattern persists such that more ions return to a particular area than are launched there. It is unknown whether the formation of latitude bands of >100% ion retention persist on average despite a rapidly changing magnetosphere. The total exospheric column of sodium observed at Mercury between 1997 to 2003 varied by a factor of 2-3 from perihelion to aphelion.  相似文献   

HCN fluorescence on Titan     

Roger V. Yelle  Caitlin A. Griffith 《Icarus》2003,166(1):107-115

The HCN emission features near 3 μm recently detected by Geballe et al. (2003, Astrophys. J. 583, L39) are analyzed with a model for fluorescence of sunlight in the ν₃ band of HCN. The emission spectrum is consistent with current knowledge of the atmospheric temperature profile and the HCN distribution inferred from millimeter-wave observations. The spectrum is insensitive to the abundance of HCN in the thermosphere and the thousand-fold enhancement relative to photochemical models suggested by Geballe et al. (2003, Astrophys. J. 583, L39) is not required to explain the observations. We find that the spectrum can be matched with temperatures from 130 to 200 K, with slightly better fits at high temperature, contrary to the temperature determination of 130±10 K of Geballe et al. (2003, Astrophys. J. 583, L39). The HCN emission spectrum is sensitive to the collisional de-excitation probability, P₁₀, for the ν₃ state and we determine a value of 10⁻⁵ with an accuracy of about a factor of two. Analysis of absorption lines in the C₂H₂ν₃ band near 3 μm, detected in the same spectrum, indicate a C₂H₂ mole fraction near 0.01 μbar of 10⁻⁵ for P₁₀=10⁻⁴. The derived mole fraction, however, is dependent upon the value adopted for P₁₀ and lower values are required if P₁₀ at Titan temperatures is less than its room temperature value.  相似文献   

The Roche Limit     

I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2003,87(1-2):13-25

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.  相似文献   

Mesoscale linear streaks on Mars: environments of dust entrainment     

P.C Thomas  P Gierasch  D.S Miller  B Cantor 《Icarus》2003,162(2):242-258

Variable surface albedo features on Mars are likely caused by the entrainment and deposition of dust by the wind. Most discrete markings are associated with topographic forms or with regional slopes that serve to alter the effective wind shear stress on the surface. Some of the largest variable features, here termed mesoscale linear streaks, are up to 400 km in length and repeatedly occur in one of the smoothest regions of Mars: Amazonis Planitia. Their orientations and apparent season of variability as observed by Viking and Mars Orbiter cameras indicate linear streak formation by enhanced surface wind stresses during regional or local dust storms and during the initial stages of global dust storms. They provide an example of the ability of large-scale winds, without significant local enhancement, to initiate dust motion on Mars. The sizes and spacing of the linear streaks may be controlled by boundary layer rolls. The repetitive formation of these streaks, over a span of more than 11 Mars years, gives one measure of the stability of Mars’ eolian processes.  相似文献   

板翅式换热器综合性能优化的设计方法     

高俊忠  陈维汉 《广东海洋大学学报》2003,23(6):45-49

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。  相似文献   

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨     

王毅志  梁超云 《青海国土经略》2001,(Z1)

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。  相似文献   

Wolf-Rayet stars     

K. A. van der Hucht 《Astronomy and Astrophysics Review》1992,4(2):123-159

Summary Recent literature on Population I Wolf-Rayet star research extending from the Milky Way to blue compact dwarf galaxies is reviewed, broken down into inventory, basic parameters and galactic distribution, atmospheres, binaries, intrinsic variability, mass loss, enrichment and evolution. Also the incidence of Wolf-Rayet stars with variable non-thermal radio emission, excess X-ray fluxes, and episodic/periodic IR excesses is reviewed. These phenomena appear to be associated with wind-wind interaction in wide long-period WR+OB binaries and with wind-compact object interaction in WR+c binaries, with orbit sizes of the order of magnitude of the WR radio photosphere sizes or larger.  相似文献   

Observations of hydrogen deficient binary Upsilon sagittarii     

N. Kameswara Rao  V. R. Venugopal 《Journal of Astrophysics and Astronomy》1985,6(2):101-112

The absolute magnitudeM _v of the hydrogen deficient binary υ Sgr has been estimated as -4.8 ± 1.0 from the distribution of the interstellar reddening, polarization and interstellar lines of the surrounding stars. From the ANS observations obtained at the time of the secondary eclipse, it appears that the hotter secondary is surrounded by a disc with colours of a B8-B9 star. The λ 1550 CIv absorption line arising in the stellar wind does not show any change in strength during the secondary minimum. The upper limit to the mass-loss rate from the high temperature wind is estimated as ≤ 5 × 10^-7 M⊙ yr^-1 from the 2 cm and 6 cm radio observations. Based on observations obtained with the Astronomical Netherlands Satellite and VLA. The National Radio Astronomy Observatory’s Very Large Array at Socorro, New Mexico is operated by Associated Universities Inc. under contract with the National Science Foundation.  相似文献   

Loss of water from Mars:: Implications for the oxidation of the soil     

H. Lammer  H.I.M. Lichtenegger  I. Ribas  E.F. Guinan  S.J. Bauer 《Icarus》2003,165(1):9-25

The evolution of the martian atmosphere with regard to its H₂O inventory is influenced by thermal loss processes of H, H₂, nonthermal atmospheric loss processes of H⁺, H₂⁺, O, O⁺, CO₂, and O₂⁺ into space, as well as by chemical weathering of the surface soil. The evolution of thermal and nonthermal escape processes depend on the history of the intensity of the solar XUV radiation and the solar wind density. Thus, we use actual data from the observation of solar proxies with different ages from the Sun in Time program for reconstructing the Sun's radiation and particle environment from the present to 3.5 Gyr ago. The correlation between mass loss and X-ray surface flux of solar proxies follows a power law relationship, which indicates a solar wind density up to 1000 times higher at the beginning of the Sun's main sequence lifetime. For the study of various atmospheric escape processes we used a gas dynamic test particle model for the estimation of the pick up ion loss rates and considered pick up ion sputtering, as well as dissociative recombination. The loss of H₂O from Mars over the last 3.5 Gyr was estimated to be equivalent to a global martian H₂O ocean with a depth of about 12 m, which is smaller than the values reported by previous studies. If ion momentum transport, a process studied in detail by Mars Express is significant on Mars, the water loss may be enhanced by a factor of about 2. In our investigation we found that the sum of thermal and nonthermal atmospheric loss rates of H and all nonthermal escape processes of O to space are not compatible with a ratio of 2:1, and is currently close to about 20:1. Escape to space cannot therefore be the only sink for oxygen on Mars. Our results suggest that the missing oxygen (needed for the validation of the 2:1 ratio between H and O) can be explained by the incorporation into the martian surface by chemical weathering processes since the onset of intense oxidation about 2 Gyr ago. Based on the evolution of the atmosphere-surface-interaction on Mars, an overall global surface sink of about 2×10⁴² oxygen particles in the regolith can be expected. Because of the intense oxidation of inorganic matter, this process may have led to the formation of considerable amounts of sulfates and ferric oxides on Mars. To model this effect we consider several factors: (1) the amount of incorporated oxygen, (2) the inorganic composition of the martian soil and (3) meteoritic gardening. We show that the oxygen incorporation has also implications for the oxidant extinction depth, which is an important parameter to determine required sampling depths on Mars aimed at finding putative organic material. We found that the oxidant extinction depth is expected to lie in a range between 2 and 5 m for global mean values.  相似文献