石墨炉原子吸收分光光度法测定土壤样品中痕量镉   总被引：2，自引：0，他引：2  

董丽  沈谷苗 《江苏地质》2004,28(1):42-44

研究了土壤样品中痕量镉的石墨炉原子吸收分光光度法测定最佳条件以及磷酸二氢铵与硝酸镁作基体改进剂对测定镉的基体改进效应，并比较了两种试样分解体系。方法检出限为0.01pg／L，精密度(RSD，n=8)为3．29％-7．69％，经国家一级标准物质分析验证，结果与标准值符合。  相似文献   

The main structure and tectonic features of the Chernorud-Mukhor site on the western shore of Lake Baikal from TEM and SP measurements     

Nikolai Kozhevnikov  Bülent Tezkan   《Journal of Applied Geophysics》1998,39(4):237-250

Transient electromagnetic (TEM), self-potential (SP) and geoelectrical mapping measurements were carried out at the Chernorud-Mukhor site in the Priolkhonje area on the western shore of the Lake Baikal. All measurements were made along several profiles across the main strike of the regional Primorsky fault. TEM measurements were carried out in a time range from a few tens of microseconds to several tens of milliseconds. The most important result of the 1D modelling of TEM soundings is the discovery of nearly horizontal boundaries that divide high resistive overlying and well conducting underlying rocks. The resistivity of the former is in the range from 100 Ωm to 1000 Ωm, while the resistivity of the latter varies from less than 1 Ωm to several tens of Ωm. This good conductive zone could also be verified by geoelectrical mapping using Schlumberger array (AB/2=100 m). Due to high conductivity of the underlying rocks only the upper boundary of the conductive layer could be determined by TEM soundings. A regional SP anomaly with amplitude of about −450 mV has also been observed above the low resistivity zone indicating the electron nature of its conductance. Geologically, the conductive zone is represented by a graphite-bearing layer within the region of archean rocks. Since that layer extends over a large area, it may be used as a key in studying structures and tectonics of the Priolkhonje area. A 1D TEM geoelectric section shows a wide, gently sloping syncline as a probable base structure of the Chernorud-Mukhor site. Neotectonic faults divide the syncline into vertically displaced blocks that form a wide complicated graben with a total amplitude of about 250 m.  相似文献   

萃取分离—石墨炉原子吸收光谱法测定铅锌矿中的铟     

赵星  张代云  刘锐 《云南地质》2014,33(3):417-420

样品经硝酸、氢氟酸分解除硅,加热硫酸冒烟除尽硝酸、氢氟酸,利用铟与氢溴酸能生成稳定的络合物并被乙酸丁酯萃取的性质,将铟与其它干扰离子分离并富集.使用MOLAARM6（Thermo Electron Corporation）石墨炉原子吸收分光光度计,以钒为机体改进剂,测定铅锌矿中的铟.方法检出限为LD=0.012ug/ml.实验结果令人满意.  相似文献   

河北省邢台县谈话石墨矿地质特征   总被引：1，自引：0，他引：1  

徐少康  张青松  焦学涛  康鹏跃  张慧敏  李洋  陈宇凯  宋世超 《化工矿产地质》2014,36(3):152-160

河北邢台谈话石墨矿含矿岩组大和庄组分为四个岩性段。石墨含矿(矿化)层位为大和庄组二段及四段下部和中部。石墨含矿(矿化)层(段)有7条,分属上述三个矿化层位。石墨矿体有两个,分属两个含矿层,均属大和庄组四段下部的含矿层位。1号矿体长约400m±,斜伸约55m±,均厚2.40m;2号矿体长约560m±,斜伸约55m±,均厚2.50m。矿石类型有两种:斜长石型块状矿石,属1号矿体,品位2.02%~2.93%;蓝晶石型片状矿石,属2号矿体,品位2.40%~5.46%。两个矿体中可综合利用成分均为金红石和蓝晶石。窑子沟村周边大和庄组三段中石榴石含量较高,推测有一定资源量。  相似文献   

激发极化法在新疆奇台县岩浆岩型石墨矿中的应用     

杨彦龙 《新疆地质》2019,(3):408-413

石墨矿相对于围岩物性特征更加独特,主要呈低阻高极化特征。依据石墨的独特物性条件,奇台黄羊山岩浆岩型石墨矿与围岩明显的物性差异,对黄羊山一带石墨矿勘查布设了激发极化法物探测量方法,通过与地质、槽探、钻探等方法的相互验证、补充,取得了重大勘探成果,突破了亿吨级资源储量类别。激发极化法在黄羊山石墨矿勘查边界圈定及深部资源推断中得到了很好的应用。通过对奇台黄羊山石墨矿激电测量的应用与研究,在大面积、埋藏较深的石墨矿勘查中,运用时间域激电及等距对称四极测深装置测得的视极化率(ηs)、通过反演计算取得的视电阻率(ρs)等主要参数,结合石墨矿体的实际产状确定矿体空间位置,以此准确判定矿体分布范围,为下一步地质工作、资源储量预测和工程布设指明方向。  相似文献   

全球石墨资源分布与供需格局变化分析     

刘艳飞  颜玲亚  高树学  欧阳友和  陈正国  陈军元 《地质论评》2020,66(S1):129-131

  相似文献   

Geological characteristics and analysis of known and undiscovered graphite resources of China     

《Ore Geology Reviews》2017

Graphite is one of the most essential non-metallic minerals with a wide variety of uses, and is an important commodity used in the emerging industry of China. Graphite is sourced from 170 mine areas in China from 25 provinces. This contribution is on a study of 15 regions in China with known graphite resources based on the spatial and temporal analyses of the regional metamorphic, contact metamorphic, and hydrothermal types of graphite. The knowledge gained on the metallogenesis of graphite in China is used to develop a model for choosing prospective regions for graphite, and to target areas for detailed exploration. It outlined 28 prediction areas with predicted graphite resources of about 1.63 billion tonnes to a maximum depth of 500 m in the Heilongjiang, Jilin, Liaoning, Shandong, Inner Mongolia and Hunan provinces. And of these, the predicted flake graphite resources in the Heilongjiang Province has been totalling almost a billion tonnes representing almost 60% of China’s graphite resource. As a result of this study, it is concluded that graphite has been formed during restricted periods of time, with the regional metamorphic type being the main style present in China.  相似文献   

原子吸收光谱法测定土壤和水系沉积物中的银   总被引：1，自引：1，他引：0  

王永鑫  李守权 《贵州地质》2009,26(1):73-74

样品经四酸分解,1％的硝酸提取,2％硫脲定溶。石墨炉原子吸收测定样品中的银,方法检出限0．014ug/g,精密度（RSD,n=6）4％～16％;回收率为96％～104％。方法经国家一级标准物质验证,测定结果与标准值相符。  相似文献   

新疆玉泉山石墨矿床地质特征及成因探讨   总被引：1，自引：0，他引：1  

陈刚  李凤鸣  彭湘萍 《新疆地质》2009,27(4)

新疆玉泉山石墨矿床赋存于塔里木古陆库鲁克塔格地块中下元古界兴地塔格群辛格尔组云母石英片岩中,经历了沉积-聚炭和区域变质-结晶2个主要成矿期.区域变质-结晶成矿期又分为与低角闪岩相、高绿片岩相和低绿片岩相对应的3个成矿阶段.地层岩石条件、区域变质条件、构造条件是最重要的控矿因素,矿床成因属区域变质型晶质石墨矿床.  相似文献   

氯化钯作基体改进剂石墨炉原子吸收光谱法测定土壤中的铍   总被引：1，自引：1，他引：0  

姚朝英  任兰 《岩矿测试》2012,31(6):975-979

铍是一种对人体有害的金属元素,土壤中铍的测定目前尚无国家标准方法.本文采用盐酸-硝酸-氢氟酸体系微波消解、石墨炉原子吸收光谱法测定土壤样品中的铍,实验了钯、硝酸铝、硝酸镁、钙盐的增敏效果.结果表明,以氯化钯为基体改进剂,灰化温度和原子化温度分别提高到1100℃和2650℃,原子化峰形尖锐,背景吸收很小,提高了测定灵敏度;其他三种基体改进剂虽然也能提高测定灵敏度,但背景吸收较大.采用优化的实验条件,Fe、Mg、K、Na、Ca、Ti、Cu、Ba、Mn、Zn、Pb、Sr等共存元素对测定不产生干扰.铍的浓度在0 ～4.00 μg/L范围内线性良好,方法检出限为0.01 μg/g,精密度(RSD,n=6)为3.5％ ～6.7％,实际土壤样品的加标回收率为84.0％ ～ 113.0％,土壤国家标准物质的测定值在标准值的误差范围内.本法与萃取光度法、电感耦合等离子体发射光谱/质谱法相比,操作简便,分析成本较低.  相似文献