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Salt-water inflows into the Baltic Sea are important events for renewing the deep and bottom waters of the deep basins of the Baltic Sea. These events occur only at irregular intervals. The last strong event was in January 1993 followed by minor inflows in winter 1993/1994. As a result of these inflows, the deep water of the central Baltic basins was completely renewed.Based on extensive observations of polycyclic aromatic hydrocarbons (PAHs) in water, fluffy layer material and surface sediments between 1992 and 1998, the transformation of PAHs and the modification of their distribution in the Baltic deep water is discussed in connection with the spreading of the inflowing highly saline and oxygen-rich water along its pathway from the sills into the central basins. In the course of the inflows in 1993/1994, the PAH concentration in the deep water of the different basins increased significantly. The concentrations were elevated, at least by a factor of 2 and as much as seven to eight times (for the four-ring PAHs) compared to the previous and the following years. Two hypotheses for the causes were discussed: the inflowing salt water may have entrained more highly polluted surface water in the western Baltic Sea, or it may have entrained contaminated fluffy layer material or sediment particles along the route of transport. 相似文献
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The tolerance of the oligochaete Monopylephorus rubroniveus and the polychaete Streblospio benedicti to sediment-associated fluoranthene was characterized under normoxic (>80% dissolved oxygen saturation) and moderately hypoxic ( approximately 50% dissolved oxygen saturation) conditions. Under both conditions, M. rubroniveus was highly tolerant of fluoranthene. Streblospio benedicti was considerably less tolerant of fluoranthene compared with M. rubroniveus. In addition, S. benedicti was less tolerant to fluoranthene under moderately hypoxic conditions, although no differences in sensitivity between the two oxygen conditions were observed based upon median lethal tissue residues. Bioaccumulation factors were higher for S. benedicti exposed to moderate hypoxia, suggesting that behavioral adaptations to compensate for the lower dissolved oxygen increased its bioaccumulation of fluoranthene. The results of the present laboratory study demonstrate that (1). changes in annelid tolerance to fluoranthene under varying oxygen conditions is a species-dependent phenomenon and (2). the differential tolerance of these two annelids to these combined stressors is consistent with their relative abundances in the field. 相似文献
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Polycyclic aromatic hydrocarbons in water, seston and copepods in a harbour area in the Western Mediterranean (Ligurian Sea) 总被引:2,自引:0,他引:2
Luigi Pane Simona Boccardo Fabio Bonfiglioli Gian Luigi Mariottini Francesca Priano & Osvaldo Conio 《Marine Ecology》2005,26(2):89-99
Polycyclic aromatic hydrocarbons (PAHs) are widespread carcinogenic, mutagenic and teratogenic pollutants that can significantly affect ecosystems and exert an influence on marine planktonic and benthic communities as well as on higher organisms such as fish and mammals, including humans. In this paper the concentrations of six PAHs in water, seston and copepods were examined in a harbour zone of the Genova Gulf (Ligurian Sea) from November 1997 to June 1998. The importance of freshwater inputs coming from a polluted stream and the influence of seasonal and atmospheric factors were also considered. Highest PAH values were recorded during spring. Fluoranthene, Benzo[b]fluoranthene and Benzo[k]fluoranthene were the most abundant PAHs either in water, seston or copepods. The concentration of total PAHs in seawater was often lower than the detection limit: recorded values ranged between 0.001 and 0.06 ppb. In seston, total PAHs ranged between 0.033 and 6.26 ng·g?1 and in copepods between 0.01 and 2.34 ng·g?1. With this study, PAH contamination in the harbour zone of Genova Sestri‐Ponente and the importance of inputs of organic pollutants coming from land and freshwaters have been emphasized. 相似文献
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Xinghui XIA 《中国地球化学学报》2006,25(B08):263-263
Photodegradation of chrysene, benzo (a) pyrene and benzo (g, h, i) perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. (1) The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. (2) The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo (a) pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo (g, h, i) perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. (3) The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. (4) Since the soluble humic substances in the suspended solids of the river have been dissolved in water, 相似文献
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1 INTRODUCTION Extensive literature (Brown et al., 1985; Sawhney et al., 1981; Bierman and Swain, 1982; Connolly, 1980; Lopez-Avila and Hites, 1980; O扖onnor, 1988) described lots of sorbed pollutants or toxic substances in bed sediments of rivers, even after the effluent was halted for a long time. This is particularly true for hydrophobic organic compounds that can be sorbed on the particles and accumulated in the river bed sediments (Karickhoff et al., 1979). Pollution events of… 相似文献
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污染土壤中多环芳烃的微生物降解及其机理研究进展 总被引:24,自引:1,他引:24
多环芳烃(PAHs)是一类普遍存在于环境中的难降解危险性“三致”有机污染物。微生物对多环芳烃的降解是去除土壤中多环芳烃的主要途径。研究表明,对于土壤中低分子量多环芳烃类化合物,微生物一般以唯一碳源方式代谢;而大多数细菌和真菌对四环或四环以上的多环芳烃的降解作用一般以共代谢方式开始。本文重点论述了高分子量多环芳烃:芘和苯并(a)芘的微生物降解及其机理。并介绍了多环芳烃污染的微生物—植物联合修复机制,最后展望了污染土壤中多环芳烃的研究趋势。 相似文献
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天津地区表土PAHs含量的多尺度空间相关性 总被引:1,自引:1,他引:1
本文应用因子克立格分析方法,分析了天津表土16种PAHs之间多尺度空间结构特征。分析结果显示,天津表土PAHs在空间上可以划分三种尺度:块金尺度(0~5km),小空间尺度(5~10km)和大空间尺度(10~50km)。在不同的空间尺度上,16种PAHs之间表现出不同的空间相关性,具有空间尺度相关性。这种空间尺度相关性,是由于不同的空间污染过程造成的,有助于下一步的多尺度空间污染源的判断和污染物迁移转化规律的识别。 相似文献