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1.
Roles of Biogeochemical Processes in the Oceanic Carbon Cycle Described with a Simple Coupled Physical-Biogeochemical Model 总被引:1,自引:0,他引:1
Masahiko?FujiiEmail author Motoyoshi?Ikeda Yasuhiro?Yamanaka 《Journal of Oceanography》2005,61(5):803-815
To evaluate the contribution of biogeochemical processes to the oceanic carbon cycle and to calculate the ratio of calcium
carbonate to organic carbon downward export, we have incorporated biological and alkalinity pumps in the yoked high-latitude
exchange/interior diffusion-advection (YOLDA) model. The biogeochemical processes are represented by four parameters. The
values of the parameters are tuned so that the model can reproduce the observed phosphate and alkalinity distributions in
each oceanic region. The sensitivity of the model to the biogeochemical parameters shows that biological production rates
in the euphotic zone and decomposition depths of particulate matters significantly influence horizontal and vertical distributions
of biogeochemical substances. The modeled vertical fluxes of particulate organic phosphorus and calcium carbonate are converted
to vertical carbon fluxes by the biological pump and the alkalinity pump, respectively. The downward carbon flux from the
surface layer to the deep layer in the entire region is estimated to be 3.36 PgC/yr, which consists of 2.93 PgC/yr from the
biological pump and 0.43 PgC/yr from the alkalinity pump, which is consistent with previous studies. The modeled rain ratio
is higher with depth and higher in the Pacific and Indian Oceans than in the Atlantic Ocean. The global rain ratio at the
surface layer is calculated to be 0.14 to 0.15. This value lies between the lower and higher ends of the previous estimates,
which range widely from 0.05 to 0.25. This study indicates that the rain ratio is unlikely to be higher than 0.15, at least
in the surface waters. 相似文献
2.
The interstitial water composition (
, alkalinity, Ca2+, Mg2+, Sr2+, Na+, K+) and the cation exchange capacity (CEC) were determined for the muddy sediments of the continental shelf off the Gironde Estuary (France), in the area where the sediment represents the deposit of the muddy suspension of the river. In comparison with seawater concentrations, the pore waters below 10 cm depth, show depletions of
and Ca2+ and below a 30 cm depth show depletions of Mg2+. Inversely, the upper 10 cm an enrichment of Ca2+ concentration, and an increase of K+ concentration to a 40 cm depth. High values of
are observed at the top 4 cm. Alkalinity enrichment is observed along the length of the core. Applying the alkalinity models for the sediment below a 10 cm depth demonstrates generally that calculated alkalinities are higher than the measured ones. Ca2+ dissolution occurs at the first 10 cm and authigenic carbonate precipitation starts beneath that level. Mg2+ depletion is accompanied by bicarbonate loss. This proves that Mg2+ depletion is due to a Mg-silicate reaction. The result of the CEC does not confirm the Mg2+ uptake by clay minerals in exchangeable site, under reducing conditions. Diffusion and bioturbation play an important role in the pore water concentration at the top of the core. 相似文献
3.
盐碱水NaCl浓度和碱度对银鲫(Carassius
auratus gibelio)幼鱼毒性的初步研究 总被引:2,自引:0,他引:2
通过对银鲫(Carassiusauratusgibelio)幼鱼(L=3.56±0.28cm)的NaCl浓度(pH=8.80±0.10)及碱度(pH=8.84±0.26)的急性毒性试验,用概率单位法求得其24,48,96h的半致死浓度(LC50值)NaCl浓度分别为11.53、10.77、8.58g/L;碱度分别为98.74、79.49、64.19mmol/L。在此基础上采用水生毒理联合效应相加指数法进行了氯化钠与碳酸氢钠浓度的联合毒性实验(浓度=11),结果在96h内二者的关系全部为协同作用,且其协同性逐渐减弱并趋向于相加作用。 相似文献
4.
A preliminary study of carbon system in the East China Sea 总被引:1,自引:0,他引:1
Shizuo Tsunogai Shuichi Watanabe Junya Nakamura Tsuneo Ono Tetsuro Sato 《Journal of Oceanography》1997,53(1):9-17
In the central part of the East China Sea, the activity of CO2 in the surface water and total carbonate, pH and alkalinity in the water column were determined in winter and autumn of 1993.
The activity of CO2 in the continental shelf water was about 50 ppm lower than that of surface air. This decrease corresponds to the absorption
of about 40 gC/m2/yr of atmospheric CO2 in the coastal zone or 1 GtC/yr in the global continental shelf, if this rate is applicable to entire coastal seas. The normalized
total carbonate contents were higher in the water near the coast and near the bottom. This increase toward the bottom may
be due to the organic matter deposited on the bottom. This conclusion is supported by the distribution of pH. The normalized
alkalinity distribution also showed higher values in the near-coast water, but in the surface water, indicating the supply
of bicarbonate from river water. The residence time of the East China Sea water, including the Yellow Sea water, has been
calculated to be about 0.8 yr from the excess alkalinity and the alkalinity input. Using this residence time and the excess
carbonate, we can estimate that the amount of dissolved carbonate transported from the coastal zone to the oceanic basin is
about 70 gC/m2/yr or 2 GtC/yr/area-of-global-continental-shelf. This also means that the rivers transport carbon to the oceans at a rate
of 30 gC/m2/yr of the coastal sea or 0.8 GtC/yr/ area-of-global shelf, the carbon consisting of dissolved inorganic carbonate and terrestrial
organic carbon decomposed on the continental shelf. 相似文献
5.
6.
硅酸盐细菌解钾作用机理的综合效应 总被引:44,自引:5,他引:44
硅酸盐细菌能释放土壤含钾硅酸盐矿物中的磷、钾、硅等元素,直接供给植物生长利用,同时亦具有固氮能力。这为挖掘土壤潜在肥力、发展可持续农业提供了一条新的思路。本文分析了硅酸盐细菌对钾长石、伊利石的解钾作用过程,细菌-矿物复合体的形成,细菌对矿物的溶蚀作用,矿物晶体结构与细菌的解钾作用关系,复合体微环境的变化对细菌解钾作用的影响以及细菌对K^ 的主动吸收等,从微生物矿物学的角度讨论了硅酸盐细菌对含钾硅酸盐矿物解钾作用的机理问题,提出了硅酸盐细菌解钾作用综合效应的看法,并就农业生产上的利用问题指出,应根据当地的土壤环境,选择适宜的生产菌种和吸附剂,并配合使用其它化学肥料和有机肥料。 相似文献
7.
8.
插层高岭石层间醋酸钾的作用和取向 总被引:9,自引:1,他引:9
利用X粉晶衍射和激光拉曼光谱实验分析高岭石及其醋酸钾插层物的结构。通过实验表明醋酸钾对结晶指数(HI)为0.9的高岭石进行插层.插层率为73%,使高岭石的d(001)由0.72075nm增加到1.42093nm。进入高岭石层间的醋酸根利用其羧基上的两个氧同时和高岭石的面内羟基形成氢键,在高岭石层间直立取向,而对其内羟基基本无影响。当温度升高时,与面内羟基伸缩振动有关的峰(3698cm^-1,3684cm^-1,3672cm^-1等)发生红移,且强度增加;而与内羟基伸缩振动有关的峰(3621cm^-1)则发生蓝移。温度升高到100C以上,开始发生去插层过程;直到250C,插层分子还不能完全从高岭石层间脱去。 相似文献
9.
10.
四川盆地西部富钾卤水水文地球化学特征及其成因意义探讨 总被引:6,自引:0,他引:6
四川盆地西部宫钾卤水以深层卤水形式赋存于地下4000余m的中三叠统雷口坡组四段(T2l4)盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比,其中含K+含量异常高,构成液态钾矿资源;Br-、I-、B(3+)、Li+等稀有组分也远超过综合利用工业品位,为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因,具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。 相似文献