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A.C. Fischer J.J. Kroon T.G. Verburg T. Teunissen H.Th. Wolterbeek 《Marine Chemistry》2007,107(4):533-546
Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron 55Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10− 9 mol/m2 or 1.7 × 10− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log KFe'W = 11.0 ± 0.3 m2/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 −4–10− 5 L/s and rate constants for association in the order of 108 L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry. 相似文献
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基于GOODALL相近指数的遥感图像和其它空间数据综合分类方法 总被引：2，自引：0，他引：2
介绍ＤａｖｉｄＷ．Ｇｏｏｄａｌｌ基于概率的相近指数理论,研究它被应用在遥感图像和其它空间数据综合分类中的可能性,并首次在ＧＲＡＳＳ环境下实现了基于ＤａｖｉｄＷ．Ｇｏｏｄａｌｌ的相近指数的遥感图像和其它空间数据综合分类算法,并对该算法进行了测试,将分类结果 与其它几种较流行的分类方法结果进行了比较。 相似文献
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本研究基于10′×10′空间分辨率运用GIS软件对中国植被分布地理配准数字化,提取获得196个优势植物的地理分布数据以及内插相关的气候因子,运用分位数函数计算获得各个植物地理分布的气候阈值; 在此基础上采用生物气候群组（BAGs）的分类方法,对196个优势植物气候因子数据进行聚类分析,同时结合中国植被的地理分布特征,最后划分出29个BAG组,包括13个乔木组(6个常绿阔叶和2个落叶阔叶群组,4个常绿针叶和1个落叶针叶群组)、10个灌木组(5个常绿灌木和5个落叶灌木群组)和6个草本组。本研究的BAGs划分是建立在较高空间分辨率和定量气候因子阈值的基础上,因此,通过计算获得BAGs气候阈值(包括每日温度变化幅度、地表霜冻频率、月均温度、月降雨量、相对湿度、日照时数和>5℃年积温等),运用生物圈碳循环CARAIB模型,模拟出中国19个生物群区的现代潜在分布。模拟结果较好地表达了中国植被类型的地理分布,尤其较详细地展示了热带、亚热带、温带和高原地区的不同植被类型地理分布格局,但由于东北地区、西部草原以及热带原生植被受人类活动严重干扰,使得模拟结果比该地区的原生植被地理分布的实际面积偏大。总体而言,本研究获得的29个生物气候群组对模拟现代生物群区分布提供了理想的分类依据,其气候阈值也是进行过去和未来生物群区模拟的重要参照数据。 相似文献
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Mukund Sharma Sanjay Mishra Suryendu Dutta Santanu Banerjee Yogmaya Shukla 《Precambrian Research》2009,173(1-4):123
In this study, biometric and structural engineering tool have been used to examine a possible relationship within Chuaria–Tawuia complex and micro-FTIR (Fourier Transform Infrared Spectroscopy) analyses to understand the biological affinity of Chuaria circularis Walcott, collected from the Mesoproterozoic Suket Shales of the Vindhyan Supergroup and the Neoproterozoic Halkal Shales of the Bhima Group of peninsular India. Biometric analyses of well preserved carbonized specimens show wide variation in morphology and uni-modal distribution. We believe and demonstrate to a reasonable extent that C. circularis most likely was a part of Tawuia-like cylindrical body of algal origin. Specimens with notch/cleft and overlapping preservation, mostly recorded in the size range of 3–5 mm, are of special interest. Five different models proposed earlier on the life cycle of C. circularis are discussed. A new model, termed as ‘Hybrid model’ based on present multidisciplinary study assessing cylindrical and spherical shapes suggesting variable cell wall strength and algal affinity is proposed. This model discusses and demonstrates varied geometrical morphologies assumed by Chuaria and Tawuia, and also shows the inter-relationship of Chuaria–Tawuia complex.Structural engineering tool (thin walled pressure vessel theory) was applied to investigate the implications of possible geometrical shapes (sphere and cylinder), membrane (cell wall) stresses and ambient pressure environment on morphologically similar C. circularis and Tawuia. The results suggest that membrane stresses developed on the structures similar to Chuaria–Tawuia complex were directly proportional to radius and inversely proportional to the thickness in both cases. In case of hollow cylindrical structure, the membrane stresses in circumferential direction (hoop stress) are twice of the longitudinal direction indicating that rupture or fragmentation in the body of Tawuia would have occurred due to hoop stress. It appears that notches and discontinuities seen in some of the specimens of Chuaria may be related to rupture suggesting their possible location in 3D Chuaria.The micro-FTIR spectra of C. circularis are characterized by both aliphatic and aromatic absorption bands. The aliphaticity is indicated by prominent alkyl group bands between 2800–3000 and 1300–1500 cm−1. The prominent absorption signals at 700–900 cm−1 (peaking at 875 and 860 cm−1) are due to aromatic CH out of plane deformation. A narrow, strong band is centred at 1540 cm−1 which could be COOH band. The presence of strong aliphatic bands in FTIR spectra suggests that the biogeopolymer of C. circularis is of aliphatic nature. The wall chemistry indicates the presence of ‘algaenan’—a biopolymer of algae. 相似文献
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基于岩浆铬矿床与超镁铁质岩石的关系,从元素亲合性和共生规律的角度揭示了铝对铬成矿制约的主导作用。分析了铝和铬亲石、亲氧的二重性及其晶体化学的依存关系。论证了超镁铁Ｓｉ－Ｏ体系中铝丰度过高或过低均不利于铬的成矿。揭示了制约因素分散富集的因素都是在一定条件下互为依存和转化的。是在动态中的矛盾的对立和统一。 相似文献
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嗜水气单胞菌是水产养殖中一种比较常见的致病病原菌。本研究以嗜水气单胞菌为研究对象,利用SELEX指数富集系统进化技术(Systematic Evolution of Ligands by Exponential Enrichment,SELEX),经过12轮的筛选,通过生物素-抗地高辛碱性磷酸酶显色系统检测DNA适配子与嗜水气单胞菌的亲和力,克隆、测序后,用DNAMAN软件分析其一级序列与二级结构。研究结果表明,通过12轮筛选后,亲和力由最初的0.32升到第9轮的0.72,亲和力提高了2.25倍。一级结构主要由GT组成,说明同源性适体有了一定程度的富集。二级结构模拟图以茎环状结构为主,说明这些茎环状结构可能是适体与靶分子进行结合作用的基础,也是其进一步形成三维空间结构的基础。 相似文献
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基于居民行为周期特征的城市空间研究 总被引：4，自引：1，他引：3
伴随着中国经济社会进入“新常态”的发展阶段,对城市存量空间的研究提出了更加精细化的要求,基于居民行为活动的周期规律对城市空间进行研究,进而提升城市空间的品质日益重要。随着信息通信技术的快速发展,使许多大数据的获取成为可能,并由于其低成本、即时、大样本等优势,在城市空间研究方面具有巨大的价值。以上海市中心城区为例,利用手机信令数据,探究居民活动的空间周期变化特征,并基于空间的周期特征曲线,采用相似性传播聚类算法进行空间分类。研究表明,居民活动有平日一日周期和平日加周末二日周期,与人的作息规律相符合。市核心区、城市副中心及主要就业中心,昼夜波动和平日周末活动强度的差异都较为明显。空间分类结果显示,城市活动空间的组织既体现出个体充分的空间能动性,也反映出对土地使用类型以及设施建设、投入程度的耦合性。上海市内环内核心区混合多样的用地模式使得活动区内居民活动内容丰富,周期特征功能区边界模糊。研究成果可为未来的城市空间规划提供指导,为城市空间结构、功能布置、设施布局等优化提供决策支撑和科学依据。 相似文献
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伴随着经济和社会的持续发展,我国的城市化进程正处于加速向前推进阶段,遗憾的是不少大城市,也包括一些中小城市在其发展的同时,却逐渐丧失了作为城市重要功能之一的亲和力。这其中既有城市发展途中固有的积弊,又有作为城市主导因素——人的原因。文中着重分析了我国城市的亲和力缺失的现状,同时就如何增强城市亲和力,使其发挥积极的作用进行了探讨。作为城市的管理者与被管理者,都应在城市的发展中树立和培养“以人为本”的思想与意识,在强调建设的同时加强引导,在注重权利的同时提倡奉献,这样才能避免城市亲和力的缺失。 相似文献
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