On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics     

A.C. Fischer  J.J. Kroon  T.G. Verburg  T. Teunissen  H.Th. Wolterbeek 《Marine Chemistry》2007,107(4):533-546

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.  相似文献   

“标贯”确定粘性土承载力标准值简易计算法     

汪国军  许洪亮 《云南地质》2008,27(2):257-259

标准贯人（“标贯”）试验锤击数,要确定粘性土地基承载力标准值简易计算公式。将经杆长修正的标准贯人击数N进行统计分析,再把修正击数平均值带人相关方程,计算粘性土的承载力标准值fk,从而简化了计算过程。  相似文献   

对天然地基承载力计算公式的理解和应用   总被引：1，自引：0，他引：1  

毛群芳  徐四一 《上海国土资源》2003,(3):26-29

文章就新老国标和上海标准对地基承载力的计算公式进行了分析比较,并认为在上海地区岩土工程勘察报告中提供天然地基承载力设计值fd更适合。  相似文献   

基于多源数据约束的成矿动力学模拟——以宁芜盆地钟姑矿田典型矿床为例   总被引：1，自引：0，他引：1       下载免费PDF全文

贾 蔡 袁 峰李晓晖  胡训宇廖宝胜孙维安  张明明沈 乐 《地质科学》2018,(4):1327-1346

数据驱动是大数据分析的特点之一。成矿过程的数值模拟即采用数据驱动方式,在基本的物理化学方程及地质模型基础上,通过定量的手段,模拟不同阶段、不同条件下成矿系统的演化过程,从而能够更深入、直观的讨论各种地质要素对成矿系统的影响,验证已有的成矿理论,获得新的认识。姑山铁矿床和杨庄铁矿床是宁芜火山岩盆地钟姑矿田内的典型矿床。前人研究显示,杨庄铁矿床为典型的充填-接触交代型热液矿床,而姑山铁矿床目前在成因上仍存在争议,存在岩浆成因和热液成因等多种观点。为了更好的对比和了解姑山铁矿床和杨庄铁矿床的成因及成矿过程,本文基于多源数据的综合解译剖面,采用力-热耦合数值模拟方法对与热液矿床密切相关的扩容空间的形成机制和特点开展研究。模拟结果显示,姑山铁矿床和杨庄铁矿床可能分属不同的成因类型;随着岩体的逐渐冷却,杨庄铁矿床内岩体和地层接触带会出现明显的扩容空间,可为成矿流体的汇聚及矿质的沉淀提供良好的条件,有利于热液矿床的形成;而姑山铁矿床内岩体和地层接触带只有局部区域出现扩容空间,同时体应变数值较小且形态变化大,并不利于大规模的流体汇聚及矿质的沉淀,姑山铁矿床可能主要为岩浆成因,并受少量热液的叠加改造。  相似文献   

An adaptive capacity spectrum method for assessment of bridges subjected to earthquake action     

Chiara Casarotti  Rui Pinho 《Bulletin of Earthquake Engineering》2007,5(3):377-390

Estimating seismic demands on structures, to predict their performance level with confidence, requires explicit consideration of the structural inelastic behaviour: to this end, the use of nonlinear static procedures is inevitably going to be favoured over complex nonlinear time-history methods. The currently available assessment procedures have been tested predominantly against building frames. A newly derived assessment procedure is proposed within the scope of bridge applications, based on an innovative displacement-based adaptive pushover technique. The procedure, which can be incorporated into a performance-based engineering philosophy, is applicable to MDOF continuous span bridges with flexible or rigid superstructures, and for varying degrees of abutment restraint. As a first application to determine the viability of the proposed procedure, a parametric study is conducted on a ensemble of bridges subjected to earthquake motion. It is shown that, compared to the seismic demand estimated by means of the more accurate nonlinear dynamic analysis tool, the novel static assessment method can lead to the attainment of satisfactory predictions, both in terms of displacement as well as moment demand on members.  相似文献   

城乡劳动力的转移与城市化   总被引：6，自引：1，他引：6  

孟晓晨 《地理学报》1992,47(5):441-450

本文从城市化基本定义出发,探讨了劳动力在农村与城市两大经济载体之间流动的机制,指出农业容纳力与排斥力、城市吸引力与吸收力是劳动力流动的决定因素,并在对四个因素进行相互关系分析的基础上,阐明了均衡与非均衡条件下劳动力转移的不同途径。  相似文献   

图们江地区水环境容量及其对区域开发的影响研究   总被引：10，自引：1，他引：9  

田卫  俞穆清 《地理科学》1998,18(2):169-175

以ＣＯＤ为控制指标,计算了图们江地区５条河流逐月环境容量以及污水达标排放时的允许污水排放量。结果表明,各月环境容量分配极不均匀,丰水期２个月约占５０％,而长达５个月的枯水期环境容量很小,不足全年的１０％;即使以１９９５年污水排放量衡量,污水达标排放时,枯水期图们江干流等５条河流控制断面水质也达不到指定功能水质标准,已无环境容量可利用。因此,河流水环境容量已成为制约图们江地区开发的主要因素,为了确保  相似文献   

论喀斯特环境的脆弱性   总被引：71，自引：0，他引：71  

杨明德 《云南地理环境研究》1990,2(1):21-29

占全球陆地面积15%,居住着近10亿人口的喀斯特区域,是一个特殊的自然环境。在环境科学和喀斯特学间的互相渗透和交叉,产生了喀斯特环境学这一边缘分支学科。本文从系统论的观点、人地关系角度简要地论述了喀斯特环境的结构、功能和特性,并以贵州为例,对喀斯特环境脆弱性问题进行了分析,笔者认为:环境生态系统变异敏感度高,环境容量低,灾变承受阈值弹性小,是喀斯特环境脆弱性的最本质特征。  相似文献   

From adoption to implementation? An academic perspective on Sustainable Fisheries Management in a developing country     

《Marine Policy》2015

Despite the fact that Sustainable Fisheries Management (SFM) has long been proposed internationally, it remains controversial. Practical and successful applications are scarce, especially in developing countries with a recent history of massive overfishing, such as Mexico. Although SFM has been adopted at the highest level of the Mexican legal framework during the last two decades, its successful implementation still faces a series of complex challenges. At present, important changes in the Mexican political regime are at a breaking point, motivating the academic discussion about the national implications of adopting SFM approaches. Through the analysis of a series of deep interviews of key actors, combined with published material, the article illustrates how the fast-track adoption of SFM approaches has fared in a national fisheries context, the current situation being largely dysfunctional with regard to the challenges of SFM. A complicated mixture between unbeaten management and academic vestiges caused the present circumstances of an enhanced but limited fisheries system. The article proposes academic initiatives required to improve the implementation of SFM in Mexico based on an enhanced understanding of domestic historic conditions and challenges.  相似文献   

The Coral Triangle Initiative and regional exchanges: Strengthening capacity through a regional learning network     

《Global Environmental Change》2015

Natural resource management and conservation programs that promote building capacity and social learning among participants often lead to the formation of learning networks: a type of social network where learning is both a goal and potential outcome of the network. Through forming relationships and sharing information, participants in a learning network build social capital that can help a network achieve social and environmental goals. In this study, we explored social capital in a learning network that emerged through a large-scale marine governance effort, the Coral Triangle Initiative on Coral Reefs, Fisheries, and Food Security. Through a mixture of social network analysis and key informant interviews, we examined the major patterns of information exchange among individuals who had participated in regional learning exchanges; evaluated whether the network's structure resulted in information sharing; and considered implications for strengthening network sustainability, capacity building, and learning. We found that the Regional Exchange network fostered information sharing among participants across national and organizational boundaries. While the network had individuals who were more central to information sharing, the network structure was generally decentralized, indicating potential resilience to changes in leadership and membership. Participants stressed the importance of the knowledge and connections they had acquired through the learning network; however, they expressed doubts regarding its sustainability and stressed the need for a strong coordinating entity. Our findings suggest that conservation learning networks have the ability to bridge cultural divides and promote social learning; however, a strong network coordinator and continuing efforts to support information sharing and learning are crucial to the network's strength and sustainability. The tangible learning and capacity development outcomes cultivated through Regional Exchange network underscore the value of and need to invest in conservation networks that support peer-to-peer learning.  相似文献