Intrinsic sample methods for mineral exploration and resource assessment     

DeVerle Harris  Guocheng Pan 《Natural Resources Research》1993,2(2):113-121

We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California.  相似文献   

Fluid sources for the La Guitarra epithermal deposit (Temascaltepec district, Mexico): Volatile and helium isotope analyses in fluid inclusions   总被引：1，自引：0，他引：1  

Antoni Camprubí  Beverly A. Chomiak  Ruth E. Villanueva-Estrada  David I. Norman  Martin Stute 《Chemical Geology》2006,231(3):252-284

The La Guitarra deposit (Temascaltepec district, South-Central Mexico), belongs to the low/intermediate sulfidation epithermal type, has a polymetallic character although it is currently being mined for Ag and Au. The mineralization shows a polyphasic character and formed through several stages and sub-stages (named I, IIA, IIB, IIC, IID, and III). The previous structural, mineralogical, fluid inclusion and stable isotope studies were used to constrain the selection of samples for volatile and helium isotope analyses portrayed in this study. The N₂/Ar overall range obtained from analytical runs on fluid inclusion volatiles, by means of Quadrupole Mass Spectrometry (QMS), is 0 to 2526, and it ranges 0 to 2526 for stage I, 0 to 1264 for stage IIA, 0 to 1369 for stage IIB, 11 to 2401 for stage IIC, 19 to 324 for stage IID, and 0 to 2526 for stage III. These values, combined with the CO₂/CH₄ ratios, and N₂-He-Ar and N₂-CH₄-Ar relationships, suggest the occurrence of fluids from magmatic, crustal, and shallow meteoric sources in the forming epithermal vein deposit. The helium isotope analyses, obtained by means of Noble Gas Mass Spectrometry, display R/Ra average values between 0.5 and 2, pointing to the occurrence of mantle-derived helium that was relatively diluted or “contaminated” by crustal helium. These volatile analyses, when correlated with the stable isotope data from previous works and He isotope data, show the same distribution of data concerning sources for mineralizing fluids, especially those corresponding to magmatic and crustal sources. Thus, the overall geochemical data from mineralizing fluids are revealed as intrinsically consistent when compared to each other.The three main sources for mineralizing fluids (magmatic, and both deep and shallow meteoric fluids) are accountable at any scale, from stages of mineralization down to specific mineral associations. The volatile and helium isotope data obtained in this paper suggest that the precious metal-bearing mineral associations formed after hydrothermal pulses of predominantly oxidized magmatic fluids, and thus it is likely that precious metals were carried by fluids with such origin. Minerals from base-metal sulfide associations record both crustal and magmatic sources for mineralizing fluids, thus suggesting that base metals could be derived from deep leaching of crustal rocks. At the La Guitarra epithermal deposit there is no evidence for an evolution of mineralizing fluids towards any dominant source. Rather than that, volatile analyses in fluid inclusions suggest that this deposit formed as a pulsing hydrothermal system where each pulse or set of pulses accounts for different compositions of mineralizing fluids.The positive correlation between the relative content of magmatic fluids (high N₂/Ar ratios) and H₂S suggests that the necessary sulfur to carry mostly gold as bisulfide complexes came essentially from magmatic sources. Chlorine necessary to carry silver and base metals was found to be abundant in inclusion fluids and although there is no evidence about its source, it is plausible that it may come from magmatic sources as well.  相似文献   

Constraints of stable isotopes on the origin of alunite from advanced argillic alteration systems in Bulgaria     

C. Lerouge  A. Kunov  C. Flhoc  S. Georgieva  A. Hikov  J.L. Lescuyer  R. Petrunov  N. Velinova 《Journal of Geochemical Exploration》2006,90(3):166-182

Voluminous areas of advanced argillic alteration (AAA) constitute major exploration targets for surficial Cu–Au epithermal and potentially underlying porphyry-type deposits. In Bulgaria, more than 30 alunite occurrences are recognised, few of them being associated with a mineralised system. A mineralogical study combined with a stable isotopic (O, H, S) study has been carried out on nine alunite occurrences of advanced argillic zones hosted by volcanic rocks of Late Cretaceous age in the Srednogorie belt and of Oligocene age in the Rhodopes belt. This work was realised in order to constrain the origin of alunite and to define criteria to discriminate alunite from ore deposits and alunite from large barren alteration systems.Mineralogy of the nine occurrences consists of alunite + quartz + minor alumino-phospho-sulphates, associated with more or less kaolinite, dickite, pyrophyllite, diaspore and zunyite, depending on formation temperature. Alunite generally occurs as tabular crystals but is also present as fine-crystalline pseudocubic phases at Boukovo and Sarnitsa, in Eastern Rhodopes. In the advanced argillic alterations associated with economic ore, the presence of zunyite in the deeper parts indicates acid–fluorine–sulphate hydrothermal systems, whereas it is absent in uneconomic and barren advanced argillic alteration. All occurrences are formed at temperatures between 200 and 300 °C.(H, O, S) isotopic signatures of alunite combined with mineralogical features from all the studied occurrences, whatever their type, show characteristics of magmatic-hydrothermal systems. Sulphur data indicate essentially a magmatic origin for sulphur. Oxygen and hydrogen data suggest that hydrothermal fluids result from a mixing between magmatic fluids and an external component, which is identified as seawater-derived fluids or meteoric water in the vicinity of a sea. In most of the alunite occurrences, magmatic fluids are dominant and H₂S/SO₄ ratios are estimated to be higher than 2. Two exceptions exist in the Rhodopes. At Boukovo and Sarnitsa, where the estimated formation temperatures of alunite are the lowest, the external fluids are dominant and H₂S/SO₄ratios are estimated to be lower than or close to 1.At this stage of the work, the mineralogical and isotopic criteria do not enable a clear distinction between economic and uneconomic systems. However, some features are common in the economic ore deposits: the presence of zunyite in the deeper part of the system, the relatively high temperatures suggested by the zunyite + pyrophyllite + alunite + diaspore assemblages, the (O, H, S) signature of alunite, which is characteristic of dominant magmatic–hydrothermal acid–sulphate–fluorine systems.  相似文献   

新疆准噶尔地区富硫型与贫硫型浅成低温热液金矿床成矿流体与碳、硫、铅同位素   总被引：1，自引：2，他引：1  

王莉娟  王京彬  王玉往  朱和平曲丽丽 《岩石学报》2005,21(5):1382-1388

对新疆准噶尔地区浅成低温热液型金矿床中富硫型的阔尔真阔腊金矿、贫硫型的石英滩金矿进行了流依包裹体的均一温度、爆裂温度、包裹体气液相成分、H、O 同位素、矿体围岩及脉石英包裹体 C 同位素、矿体中黄铁矿等 S、Ph 同位素等系统地进行了研究,综合研究表明,本区该类型金矿成矿流体一般温度低、盐度低,来源主要为循环的大气水、矿石中黄铁矿的 S、Pb 同位素均为深源,暗示金的深部来源:矿体石英包裹体中 CO_2的δ~(13)C 为低于-10‰的有机碳,反映了本区年轻的富含有机质的沉积地层参与了金的成矿。此外,本文首次提出了富硫型阔尔真阔腊金矿床成矿流体中有侵入岩浆热液参与,深部有多金属成矿远景;贫硫型石英滩金矿没有侵入岩浆热液的参与,成矿仅与火山古热液活动有关,其成矿较单一。此外,阔尔真阔腊金矿中低温流体活动较强,金矿化也较强:石英滩金矿低温流体活动相对较弱,金矿化也较弱,也体现了该类型金矿床低温流体活动的越强烈,金矿化越强的规律。  相似文献   

浙东火山岩型银矿成矿条件及勘查方法   总被引：1，自引：0，他引：1  

华锡棠  王勤生 《矿产与地质》1991,5(2):96-106

本区火山岩型银矿赋存于上侏罗—下白垩统陆相火山岩中;由于中生代太平洋板块向西俯冲.大陆边缘火山岩浆活动强烈.嵊县—黄岩地区由于断裂为造、火山岩发育而形成南北向的矿化集中区.成矿与火山岩浆活动晚期的潜火山岩、脉岩有关.属于浅成中低温热液矿床.根据矿床围岩蚀变、矿化类型及成晕元素的分带规律,可指导找矿及预测隐伏矿床.并初步建立了勘查模式.总结了成矿预测、综合找矿、详细评价三个层次的勘查方法.  相似文献   

Petrology,geochemistry and U–Pb geochronology of magmatic rocks from the high-sulfidation epithermal Au–Cu Chelopech deposit,Srednogorie zone,Bulgaria     

Isabelle Chambefort  Robert Moritz  Albrecht von Quadt 《Mineralium Deposita》2007,42(7):665-690

The Chelopech deposit is one of the largest European gold deposits and is located 60 km east of Sofia, within the northern part of the Panagyurishte mineral district. It lies within the Banat–Srednegorie metallogenic belt, which extends from Romania through Serbia to Bulgaria. The magmatic rocks define a typical calc-alkaline suite. The magmatic rocks surrounding the Chelopech deposit have been affected by propylitic, quartz–sericite, and advanced argillic alteration, but the igneous textures have been preserved. Alteration processes have resulted in leaching of Na₂O, CaO, P₂O₅, and Sr and enrichment in K₂O and Rb. Trace element variation diagrams are typical of subduction-related volcanism, with negative anomalies in high field strength elements (HFSE) and light element, lithophile elements. HFSE and rare earth elements were relatively immobile during the hydrothermal alteration related to ore formation. Based on immobile element classification diagrams, the magmatic rocks are andesitic to dacitic in compositions. Single zircon grains, from three different magmatic rocks spanning the time of the Chelopech magmatism, were dated by high-precision U–Pb geochronology. Zircons of an altered andesitic body, which has been thrust over the deposit, yield a concordant ²⁰⁶Pb/²³⁸U age of 92.21 ± 0.21 Ma. This age is interpreted as the crystallization age and the maximum age for magmatism at Chelopech. Zircon analyses of a dacitic dome-like body, which crops out to the north of the Chelopech deposit, give a mean ²⁰⁶Pb/²³⁸U age of 91.95 ± 0.28 Ma. Zircons of the andesitic hypabyssal body hosting the high-sulfidation mineralization and overprinted by hydrothermal alteration give a concordant ²⁰⁶Pb/²³⁸U age of 91.45 ± 0.15 Ma. This age is interpreted as the intrusion age of the andesite and as the maximum age of the Chelopech epithermal high-sulfidation deposit. ¹⁷⁶Hf/¹⁷⁷Hf isotope ratios of zircons from the Chelopech magmatic rocks, together with published data on the Chelopech area and the about 92-Ma-old Elatsite porphyry–Cu deposit, suggest two different magma sources in the Chelopech–Elatsite magmatic area. Magmatic rocks associated with the Elatsite porphyry–Cu deposit and the dacitic dome-like body north of Chelopech are characterized by zircons with ɛHf_T90 values of ∼5, which suggest an important input of mantle-derived magma. Some zircons display lower ɛHf_T90 values, as low as −6, and correlate with increasing ²⁰⁶Pb/²³⁸U ages up to about 350 Ma, suggesting assimilation of basement rocks during magmatism. In contrast, zircon grains in andesitic rocks from Chelopech are characterized by homogeneous ¹⁷⁶Hf/¹⁷⁷Hf isotope ratios with ɛHf_T90 values of ∼1 and suggest a homogeneous mixed crust–mantle magma source. We conclude that the Elatsite porphyry–Cu and the Chelopech high-sulfidation epithermal deposits were formed within a very short time span and could be partly contemporaneous. However, they are related to two distinct upper crustal magmatic reservoirs, and they cannot be considered as a genetically paired porphyry–Cu and high-sulfidation epithermal related to a single magmatic–hydrothermal system centered on the same intrusion.  相似文献   

Geophysical Expression of Low Sulphidation Epithermal Au-Ag Deposits and Exploration Implications –Examples from the Hokusatsu Region of SW Kyushu, Japan–     

Craig A. FEEBREY  Hajime HISHIDA  Ken YOSHIOKA  Ken NAKAYAMA 《Resource Geology》1998,48(2):75-86

Abstract: Low sulphidation epithermal Au-Ag deposits constitute a major exploration target for many mining companies worldwide. These deposits are commonly characterized by quartz vein systems which formed at temperatures often in the range 150–250°C giving rise to major alteration halos. Accompanying mineralization and associated alteration is the destruction and redistribution of magnetite in the host rocks and the formation of various K-bearing minerals such as adularia, illite and alunite. These alteration halos can often cover an area of at least several square kilometres and as such have the potential to be detected during reconnaissance geological surveys utilizing high resolution airborne aeromagnetic and radiometric sensors.
Analysis of airborne magnetic and radiometric data recently acquired over the Hokusatsu Region of SW Kyushu indicates that major low sulphidation epithermal Au-Ag deposits are characterized by several distinct geophysical features varying with the degree of post-mineralization cover and level of erosion. Several deposits coincide with extensive magnetic "flat" and high radiometric K–counts. In addition, several workers have shown that a very close association exists between Bouguer gravity highs and epithermal Au mineralization in the Hokusatsu Region. The combined use of areomagnetics, radiometrics and gravity data therefore provides an exceptionally effective approach to exploration for low sulphidation epithermal Au–Ag deposits in the Hokusatsu Region of Japan.  相似文献   

Cenozoic high-K alkaline magmatism and associated Cu–Mo–Au mineralization in the Jinping–Fan Si Pan region,southeastern Ailao Shan–Red River shear zone,southwestern China–northwestern Vietnam     

《Journal of Asian Earth Sciences》2014

The Jinping–Fan Si Pan (JFP) Cenozoic magmatic and Cu–Mo–Au metallogenic belt in the southeastern part of the Ailao Shan shear zone host the Tongchang, Chang′an, Habo, and Chinh Sang Cu–Mo–Au deposits. These deposits form an integrated epithermal-porphyry regional mineralization system associated with 40–32 Ma high-K alkaline magmatism. The magmatic rocks in the belt have relatively low TiO₂ (<0.73 wt%), P₂O₅ (<0.29 wt%), and FeO^* (<4.99 wt%), and high Na₂O (2.86–4.75 wt%) and K₂O (4.01–7.98 wt%). They also have high contents of incompatible trace elements, and are enriched in LILE (Rb, Ba, K, Sr) and LREE. They have marked Nb, Ta, Ti and P depletion in primitive mantle-normalized spidergrams, and plot close to the EMII mantle field in the Sr–Nd isotopic diagram. These characteristics are similar to those of the Eocene high-K alkaline rocks along the northern Ailao Shan belt, eastern Tibet plateau. The sulfur and lead isotope analyses of sulfide minerals from both the ores and related magmatic rocks confirm the involvement of a magmatic ore fluid. The Cenozoic alkaline intrusions and Cu–Mo–Au mineralization in the JFP were formed prior to the initiation of left-lateral shearing along the Ailao Shan shear zone. The magmas appear to have been derived from enriched mantle, possibly with mixing of materials from the buried Tethyan oceanic lithosphere, and/or crust.  相似文献   

Examining potential genetic links between Jurassic porphyry Cu–Au ± Mo and epithermal Au ± Ag mineralization in the Toodoggone district of North-Central British Columbia,Canada     

Paul Duuring  Stephen M. Rowins  Bradley S. M. McKinley  Jenni M. Dickinson  Larry J. Diakow  Young-Seog Kim  Robert A. Creaser 《Mineralium Deposita》2009,44(4):463-496

The Toodoggone district comprises Upper Triassic to Lower Jurassic Hazelton Group Toodoggone Formation volcanic and sedimentary rocks, which unconformably overlie submarine island-arc volcanic and sedimentary rocks of the Lower Permian Asitka Group and Middle Triassic Takla Group, some of which are intruded by Upper Triassic to Lower Jurassic plutons and dikes of the Black Lake suite. Although plutonism occurred episodically from ca. 218 to 191 Ma, the largest porphyry Cu–Au ± Mo systems formed from ca. 202 to 197 Ma, with minor mineralization occurring from ca. 197 to 194 Ma. Porphyry-style mineralization is hosted by small-volume (<1 km³), single-phase, porphyritic igneous stocks or dikes that have high-K calc-alkaline compositions and are comparable with volcanic-arc granites. The Fin porphyry Cu–Au–Mo deposit is anomalous in that it is 16 m.y. older than any other porphyry Cu–Au ± Mo occurrence in the district and has lower REEs. All porphyry systems are spatially restricted to exposed Asitka and Takla Group basement rocks, and rarely, the lowest member of the Hazelton Group (i.e., the ca. 201 Ma Duncan Member). The basement rocks to intrusions are best exposed in the southern half of the district, where high rates of erosion and uplift have resulted in their preferential exposure. In contrast, low- and high-sulfidation epithermal systems are more numerous in the northern half of the district, where the overlying Hazelton Group rocks dominate exposures. Cogenetic porphyry systems might also exist in the northern areas; however, if they are present, they are likely to be buried deeply beneath Hazelton Group rocks. High-sulfidation epithermal systems formed at ca. 201 to 182 Ma, whereas low-sulfidation systems were active at ca. 192 to 162 Ma. Amongst the studied epithermal systems, the Baker low-sulfidation epithermal deposit displays the strongest demonstrable genetic link with magmatic fluids; fluid inclusion studies demonstrate that its ore fluids were hot (>468°C), saline, and deposited metals at deep crustal depths (>2 km). Sulfur, C, O, and Pb isotope data confirm the involvement of a magmatic fluid, but also suggest that the ore fluid interacted with Asitka and Takla Group country rocks prior to metal deposition. In contrast, in the Shasta, Lawyers, and Griz-Sickle low-sulfidation epithermal systems, there is no clear association with magmatic fluids. Instead, their fluid inclusion data indicate the involvement of low-temperature (175 to 335°C), low-salinity (1 to 11 equiv. wt.% NaCl) fluids that deposited metals at shallow depths (<850 m). Their isotope (i.e., O, H, Pb) data suggest interaction between meteoric and/or metamorphic ore fluids with basement country rocks.  相似文献   

The Engineer Mine,British Columbia: An example of epithermal Au-Ag mineralization with mixed alkaline and subalkaline characteristics     

《Ore Geology Reviews》2017

The Engineer Mine epithermal precious metal deposit in British Columbia, Canada, is related to Eocene Sloko-Skukum-Group (SSG) volcanism and, according to previous studies, contains roscoelite in intimate association with electrum. Roscoelite, a vanadian mica, is considered characteristic of low-sulfidation epithermal deposits related to alkaline magmatism. This contradicts the fact that the SSG volcanics are subalkaline. In order to address this ambiguity and to accurately classify the style of epithermal mineralization at the Engineer Mine we conducted detailed petrographic, mineralogical, geochronological, fluid inclusion, and stable isotope studies.The principal ore assemblage of the Engineer Mine epithermal veins precipitated in response to boiling during a hydrothermal event at 49.90 Ma ± 0.25 Ma. During this event electrum, arsenopyrite, pyrite ± chalcopyrite ± sphalerite ± löllingite ± tetrahedrite-group phases ± allargentum ± acanthite ± hessite ± dyscrasite ± stibarsen ± galena and an unidentified Ag-rich phase were deposited in conjunction with amorphous silica, platy and rhombic calcite, K-feldspar, and vanadian illite. Fluid inclusion and stable isotope data suggest that the ore-forming fluid was boiling at ∼220 °C during vein mineralization and had an isotopic composition derived from local meteoric water. Based on these results the Engineer Mine is classified as an epithermal low-sulfidation deposit, which shares similarities with alkaline and subalkaline epithermal low-sulfidation deposits. This is attributed to the fact that the SSG volcanic rocks are borderline subalkaline to alkaline in character and that the sedimentary host rocks are vanadium-bearing. These sedimentary rocks contributed the bulk of the vanadium to the Engineer Mine epithermal system. The presence of roscoelite at the Engineer Mine could not be confirmed during this study. The mica referred to as roscoelite in previous publications instead is vanadian illite. To our knowledge the only alkaline low-sulfidation epithermal precious metal deposit that contains V-mica which exclusively qualifies as true roscoelite is the Porgera deposit, Papua New Guinea.  相似文献