滇东老厂地区地热水成因：来自水化学和碳氢氧硫同位素的约束          下载免费PDF全文

陶兰初  朱星强  马一奇  张七道  庞龙  涂春霖  和成忠 《沉积与特提斯地质》2023,43(2):295-310

滇东弥勒-师宗断裂带地热资源丰富,但是由于研究程度较低,成因机制不明,制约了区内地热资源的可持续开发利用。本文以弥勒-师宗断裂带北段老厂地区天然温泉水和地热钻孔水为研究对象,综合应用野外调查、水文地球化学和环境同位素方法,对区内地热水的地球化学特征和成因机制进行了研究。结果显示,区内地热水pH值介于7.30～8.12之间,TDS在224～382 mg/L之间,属于弱碱性淡水。地热水水化学类型为HCO₃·SO₄^Ca型和HCO₃·SO₄-Ca·Na型,且含有较高含量的Fe、As、Sb等微量组分,不宜饮用。地热水中HCO₃^-的δ¹³C值为-3.31‰～-7.79‰,计算得出参与水岩作用的CO₂的δ¹³C值为-9.50‰～-15.68‰,具有明显的沉积有机质来源特征。离子比值分析及硫同位素特征表明碳酸盐岩矿物和石膏的溶解是区内地热水主要离子来源的控制因素,此外赋存于浅部断裂带内...  相似文献   

“井水不犯河水”水文地质学含义初步探讨   总被引：1，自引：0，他引：1  

刘元章  武强  刘久荣  林沛  邢立亭  刘守强 《地下水》2011,(6):122-127

利用水化学及同位素水文地质学的方法,对密云水库、潮白河及位于潮白河边的2个地下水分层专门监测井进行取样测试,并结合收集相关资料,从水位、水质及氚、氘、氧-18等同位素方面进行分析研究,对中国古语“井水不犯河水”的水文地质学方面的含义进行了一定的微观层次的分析探讨.得出研究点处潮白河水对50 m外的25 m深的浅井井水有...  相似文献   

Geochemistry and pollution of shallow aquifers in the Mafraq area, North Jordan     

Nadir Eraifej  Nizar Abu-Jaber 《Environmental Geology》1999,37(1-2):162-170

 Chemical data are used to clarify the hydrogeological regime in the Mafraq area in northern Jordan, as well as to determine the status of water quality in the area. Groundwater from the shallow aquifer in the Mafraq area can be divided into two major groups according to geographical locations and chemical compositions. Water in the basaltic eastern part of the study area is characterized by the dominance of chloride, sulfate, sodium, and potassium, whereas waters in the limestone aquifers in the west are dominated by the same cations but have higher concentrations of bicarbonate. Stable isotopes show that the shallow aquifers contain a single water type which originated in a distinct climatic regime. This water type deviates from the Global Meteoric Water Line (MWL), as well as from the eastern Mediterranean meteoric water line. The waters are poor in tritium, and thus can be considered generally older than 50 years. Chemical mass balance models suggest that water is moving from the west towards the north of the study area. This suggests that waters from the different basins are separated from each other. Degradation of water quality can be attributed to agricultural fertilizers in most cases, although the waste-water treatment plant at Khirbet es Samra is a contributor to pollution in the southwestern part of the study area. Received: 20 August 1997 · Accepted: 3 February 1998  相似文献   

The Impact of Human Activities on CO2 Intake by Carbonate Weathering: A Case Study of Conglin Karst Ridge-trough at Fuling Town,Chongqing, China     

Chang-li LIU  Chao SONG  Hong-bing HOU  Xiu-yan WANG  Yun ZHANG  Jun-kun WANG  Jian-mei JIANG  Li-xin PEI  Bo SONG 《地下水科学与工程》2014,2(1):29-38

The chemical weathering can consume atmosphere/soil CO2. Human activities such as pollution, fertilization and acid precipitation have exerted a large impact on CO2 intake by carbonate weathering. Thus, based on the analysis on chemical component change of the karst groundwater in the karst ridge watershed of Conglin Village, Fuling District of Chongqing City, the influence of human activities such as fertilization, sewage discharges from mustard tuber processing, breeding industry and acid rain precipitation on carbonate weathering and CO2 intake in 1980, 2003 and 2006 was studied. The results showed that CO2 intake by carbonate rock declined with year. Because H+ derived from acid sewage discharge, fertilization and acid precipitation reacted with carbonate rock when mustard tuber production and swine breeding were developed fleetly after 2000 as well as the burning amount of high-sulfur coal augmented persistently, which led to the increase of (Ca2++Mg2+)/HCO3-. The difference on charge between Ca2++Mg2+ and HCO3- was balanced by NO3-+SO42-. The control on pollution and acid rain, especially the pre-neutralization of acid waste water, would rejuvenate the atmospheric CO2 intake strength of carbonate weathering besides the protection of water and soil environment  相似文献   

Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: The southern Venice Lagoon coastland   总被引：3，自引：0，他引：3  

Julie C. Gattacceca  Christine Vallet-Coulomb  Adriano Mayer  Christelle Claude  Olivier Radakovitch  Enrico Conchetto  Bruno Hamelin   《Journal of Hydrology》2009,378(1-2):46-61

The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ¹⁸O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.  相似文献   

Monitoring of percolation water to discriminate surficial inputs in a karst aquifer     

S. Covelli  F. Cucchi  R. Mosca 《Environmental Geology》1998,36(3-4):296-304

 A long-term study on the chemistry of percolating waters in a very large touristic karst cave (Grotta Gigante, northern Italy) was carried out in order to define recharge zones, flowpaths, and possible anthropogenic contamination from the neighboring area. On the basis of a multivaried analysis of the chemical parameters, a discrimination of the dripping points was attempted. Percolation waters whose recharge zone is in the northernmost sector of the cave appeared permanently affected by the anthropic settlements and agricultural activity on the ground surface. Received: 28 April 1997 · Accepted: 3 February 1998  相似文献   

Hydrogeochemistry and isotope analyses used to determine groundwater recharge and flow in low-gradient catchments of the province of Buenos Aires,Argentina   总被引：7，自引：3，他引：4  

O. M. Quiroz Londoño  D. E. Martínez  C. Dapeña  H. Massone 《Hydrogeology Journal》2008,16(6):1113-1127

The region known as Pampa Plain, in Argentina, is a vast area characterized by slopes of less than 0.05%. The surface sediment is silty sand, mainly Aeolian, referred to as Pampean Loess, which is a phreatic aquifer unit of utmost importance for the water supply of the region. On account of the slight gradient, hydrogeological analyses using only hydraulic measurements are difficult to perform, often leading to confusing results. Thus, the study presented relies on hydrochemical modeling and isotopic determinations as well. The study area comprises three catchments in the inter-mountainous area corresponding to El Moro, Tamangueyú and Seco creeks, and covering 2,570 km² in the province of Buenos Aires. Measurements of piezometric levels and samples of groundwater, surface water and rainwater were carried out between January and March 2005. Major ion results were analyzed by means of hydrochemical graphs and hydrogeochemical modelling using NETPATH. The resulting data show that it is possible to identify local changes in recharge, flow direction and stream/groundwater relationship by using hydrochemical and isotopic information, which may become a useful and more precise tool for the study of particularly flat landscapes.  相似文献   

Hydrogeology and hydrochemistry of a shallow alluvial aquifer,western Saudi Arabia   总被引：2，自引：0，他引：2  

Abdulaziz M. Al-Shaibani 《Hydrogeology Journal》2008,16(1):155-165

A hydrogeological and hydrochemical study was conducted on a shallow alluvial aquifer, Wadi Wajj, in western Saudi Arabia to assess the influence of protection measures on groundwater quality. The hydrochemistry was assessed up-gradient and down-gradient from potential contamination sources in the main city in dry and wet seasons prior to and after the installation of major drainage and wastewater facilities. Wadi Wajj is an unconfined aquifer where water is stored and transmitted through fractured and weathered bedrock and the overlying alluvial sediments. Natural recharge to the aquifer is about 5% of rainfall-runoff. Hydrochemistry of the aquifer shows temporal and seasonal changes as influenced by protection measures and rainfall runoff. Both groundwater and runoff showed similar chemical signature, which is mostly of chloride-sulfate-bicarbonate and sodium-calcium type. Groundwater downstream of the city, though of poorer quality than upstream, showed significant improvement after the installation of a concrete runoff tunnel and a wastewater treatment plant. Concentrations of many of the groundwater quality indicators (e.g., TDS, coliform bacteria, and nitrate) exceed US Environmental Protection Agency drinking-water standards. Heavy metal content is, however, within allowable limits by local and international standards. The chemical analyses also suggest the strong influence of stream runoff and sewage water on the groundwater quality.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Une étude hydrogéologique et géochimique a été menée sur l’aquifère phréatique alluviale Wadi Wajj dans l’Ouest de l’Arabie Saoudite afin d’évaluer l’influence de mesures de protection sur la qualité de l’eau souterraine. L’hydrogéochimie de l’eau a été étudiée en amont et en aval de sources potentielles de contamination dans la ville principale, pendant les saisons sèches et humides, avant et après l’installation de réseaux majeurs de drainage et d’eaux usées. L’aquifère Wadi Wajj est libre, l’eau est stockée et s’écoule dans les sédiments alluviaux et dans le socle fracturé et altéré sous-jacent. La recharge naturelle de l’aquifère représente 5% des eaux de pluie et de ruissellement. L’hydrogéochimie de l’eau de l’aquifère montre que les changements saisonniers et temporaires sont influencés par les mesures de protection et par le ruissellement des eaux pluviales. L’eau souterraine et l’eau de ruissellement ont présenté le même faciès chimique, de type bicarbonatée-sulfatée-chlorée et calco-sodique. En aval de la ville, l’eau souterraine, bien que de moins bonne qualité qu’en amont, a présenté une nette amélioration après l’installation d’un système de récupération et d’une station de traitement des eaux usées. Les concentrations de plusieurs paramètres indicateurs de la qualité de l’eau (tels que la charge totale dissoute, les coliformes, et les nitrates) dépassent les normes de potabilité de l’eau de consommation de l’agence américaine de la protection de l’environnement. Les teneurs en métaux lourds en revanche n’excèdent pas les normes locales et internationales. Les analyses chimiques indiquent aussi l’influence importante de l’écoulement par ruissellement et des eaux usées sur la qualité de l’eau souterraine.

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Resumen Un estudio hidrogeológico e hidroquímico fue hecho en un acuífero somero de Wadi Wajj, en Arabia Saudi oeste para evaluar la influecia de medidas de protección en la calidad del agua subterránea. La hidroquímica fue evaluada gradiente-arriba y gradiente-abajo de las fuentes potenciales de contaminación de la ciudad principal durante las estaciones seca y lluviosa, antes y después de la instalación de sistemas principales de drenaje y aguas servidas. Wadi Wajj es un acuífero no-confinado donde el agua es almacenada y transmitida a través de roca fracturada y meteorizada, y los sedimentos aluviales que le sobreyacen. La recarga natural del acuífero es de cerca del 5% de la precipitación-escorrentía. La hidroquímica del acuífero muestra cambios temporales y estacionales influenciados por las medidas de protección y la escorrentía de precipitación. Ambas, agua subterránea y escorrentía mostraron composición química similar, siendo mayoritariamente de tipos cloruro-sulfato-bicarbonato y sodio-calcio. El agua subterránea aguas arriba de la ciudad, aunque de calidad más pobre que aguas abajo, mostró significante mejoría después de la instalación de un tunel de concreto para escorrentía y una planta de tratamiento de aguas servidas. Las concentraciones de muchos de los indicadores de calidad de agua subterránea (e.g., STD, coliformes, y nitrato) exceden los estándares de la Agencia de Protección Ambiental USA para agua potable. El contenido de metales pesados está, sin embargo, dentro de los límites permisibles de los estándares locales e internacionales. Los análisis químicos también sugieren la fuerte influencia de la escorrentía y aguas residuales en la calidad del agua subterránea.

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Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain   总被引：1，自引：0，他引：1  

Elena Giménez Forcada  Ignacio Morell Evangelista 《Hydrogeology Journal》2008,16(3):547-557

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.  相似文献   

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA     

Mark A. Engle  Fraser Goff  David G. Jewett  Gregory J. Reller  Joel B. Bauman 《Hydrogeology Journal》2008,16(3):559-573

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

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