Lead isotope evolution of the Central European upper mantle:Constraints from the Bohemian Massif     

《地学前缘(英文版)》2020,11(3):925-942

The Pb isotope composition of the upper mantle beneath Central Europe is heterogeneous due to the subduction of regionally contrasting material during the Variscan and Alpine orogenies.Late Variscan to Cenozoic mantlederived melts allow mapping this heterogeneity on a regional scale for the last ca.340 Myr.Late Cretaceous and Cenozoic anorogenic magmatic rocks of the Bohemian Massif(lamprophyres,volcanic rocks of basanite/tephrite and trachyte/phonolite series) concentrate mostly in the Eger Rift.Cretaceous ultramafic lamprophyres yielded the most radiogenic Pb isotope signatures reflecting a maximum contribution from metasomatised lithospheric mantle,whereas Tertiary alkaline lamprophyres originated from mantle with less radiogenic ~(206)Pb/~(204)b ratios suggesting a more substantial modification of lithospheric source by interaction with asthenosphericderived melts.Cenozoic volcanic rocks of the basanite/tephrite and trachyte/phonolite series define a linear mixing trend between these components,indicating dilution of the initial lithospheric mantle signature by upwelling asthenosphere during rifting.The Pb isotope composition of Late Cretaceous and Cenozoic magmatic rocks of the Bohemian Massif follows the same Pb growth curve as Variscan orogenic lamprophyres and lamproites that formed during the collision between Laurussia,Gondwana,and associated terranes.This implies that the crustal Pb signature in the post-Variscan mantle is repeatedly sampled by younger anorogenic melts.Most Cenozoic mantle-derived rocks of Central Europe show similar Pb isotope ranges as the Bohemian Massif.  相似文献   

不同氧化还原条件下铅锌矿尾砂中重金属元素活化迁移规律     

李晓艳  张青伟  洪松涛  袁雨婷  余金燕  潘俐傧  刘莹红 《吉林大学学报(地球科学版)》2022,52(2):434-441

以广西大厂镇鲁塘铅锌矿尾砂为研究对象,通过淋滤实验研究了不同氧化还原条件下尾砂中Cu、Cd、Zn、Pb和As等元素的活化和迁移规律。结果表明：经高浓度氧化、高浓度还原条件处理的尾矿表现为pH<7的酸性环境,经低浓度氧化环境条件处理的尾砂呈现pH>7的弱酸性至弱碱性环境;尾砂中Cu、Cd元素活化迁移受pH值的影响明显,即高浓度还原和高浓度氧化条件可以促进Cu和Cd元素的迁移,酸性条件对Cu和Cd元素的迁移起到促进作用;Zn与Cd元素存在竞争吸附关系,但二者仍有明显差别;Pb和As元素受到还原条件的影响,能有效促进Pb和As元素的释放迁移。在淋滤实验前期,铅锌矿的表面阻力较小,由于环境酸碱性的改变,初始尾砂对重金属元素的吸附位能发生变化,重金属元素初期迁移能力得到加强;淋滤后期,矿物颗粒表面由于发生氧化还原反应,促使颗粒表面的阻力增加,重金属元素的溶出量减少,迁移能力受到抑制。  相似文献   

Rhizofiltration of a Heavy Metal (Lead) Containing Wastewater Using the Wetland Plant Carex pendula     

Brijesh K. Yadav  Maarten A. Siebel  Johan J. A. van Bruggen 《洁净——土壤、空气、水》2011,39(5):467-474

Rhizofiltration is a subset technique of phytoremediation which refers to the approach of using plant biomass for removing contaminants, primarily toxic metals, from polluted water. The effective implementation of this in situ remediation technology requires experimental as well as conceptual insight of plant–water interactions that control the extraction of targeted metal from polluted water resources. Therefore, pot and simulation experiments are used in this study to investigate the rhizofiltration of a lead containing wastewater using plants of Carex pendula, a common wetland plant found in Europe. The metal contaminant extraction along with plant growth and water uptake rates from a wastewater having varying Pb concentration is studied experimentally for 2 wk. The temporal distribution of the metal concentration in the wastewater and the accumulated metal in different compartments of C. pendula at the end are analyzed using atomic absorption spectrometry. Parameters of the metal uptake kinetics are deduced experimentally for predicting the metal removal by root biomass. Further, mass balance equations coupled with the characterized metal uptake kinetics are used for simulating the metal partitioning from the wastewater to its accumulation in the plant biomass. The simulated metal content in wastewater and plant biomass is compared with the observed data showing a good agreement with the later. Results show that C. pendula accumulates considerable amounts of lead, particularly in root biomass, and can be considered for the cleanup of lead contaminated wastewaters in combination with proper biomass disposal alternatives. Also, the findings can be used for performing further non‐hydroponics experiment to mimic the real wetland conditions more closely.  相似文献   

广东龙门上仓铅锌矿成矿特征及成矿规律研究          下载免费PDF全文

古志宏 《江苏地质》2011,35(2):130-133

龙门上仓铅锌矿是广东省上仓式沉积改造型铅锌矿的典型矿床。通过对龙门上仓铅锌矿的矿床特征进行研究,综合前人的研究成果,归纳总结出该矿床的成矿要素,并且对矿床的成矿模式进行了初步探讨。研究表明,由大赛坝组构成槽部的开阔向斜以及南西翼帽子峰组层间破碎带构成的控矿构造是该矿的必要成矿要素。矿床成因属于岩浆热液—沉积改造型。  相似文献   

新疆尼勒克县喀英迪地区铅锌矿地质特征及成因     

姚德刚  赵环金  贺业峰 《山东国土资源》2011,27(9)

喀英迪铅锌矿主要产于早石炭世阿克沙克组及其与晚奥陶世呼独克达坂组的接触带上。通过普查工作共圈定15个铅锌矿体。其中主要矿体4个,Ⅰ-4矿体处于晚奥陶世呼独克达坂组灰岩与早石炭世阿克沙克组的不整合接触面上及其两侧,工程控制总长度为523m,最大斜深100m。倾向70°～100°,倾角一般20°～50°,连续性较好。该矿体铅单工程厚0.86～5.64m,平均2.86m,厚度变化系数为70.57%;锌单工程厚0.80～5.64m,平均1.81m,厚度变化系数为93.97%,属于变化较稳定型矿体。铅单工程品位0.62%～16.47%,平均4.53%,品位变化系数114.34%;锌单工程品位0.53%～12.37%,平均3.78%,品位变化系数57.47%。属于有用组分分布较均匀型矿体。通过对矿床地质特征的研究,认为该矿床属沉积岩容矿的、层控的、构造控制非岩浆型低温热液矿床。  相似文献   

Stable isotopes and metal contamination in caged marine mussel Mytilus galloprovincialis   总被引：1，自引：0，他引：1  

S. Deudero  A. Box  J. Tintoré 《Marine pollution bulletin》2009,58(7):1025-1031

Metal concentrations and isotopic composition were measured in different tissues of the mussel Mytilus galloprovincialis in waters of the Balearic Islands (Western Mediterranean) in order to assess pollution levels. The isotopic composition was correlated with lead, cadmium, selenium and nickel obtained from the digestive gland and foot of the mussels. Significant negative correlations were found between cadmium, selenium and zinc and the mussel foot, mainly for ¹³C. Significant correlations were also found between lead and cadmium and the digestive gland. Pearson correlations indicated that the ¹³C isotopic signal in foot is a good proxy for the concentration of metals such as lead, cadmium, selenium and zinc. Similarly, ¹⁵N isotopic signatures in the digestive gland reflected the lead and cadmium concentration.  相似文献   

Effect of Natural Zeolite Application on Nitrite Concentrations in Rape (Brassica campestris L.) in Pb‐Contaminated Soils in Peri‐Urban Areas          下载免费PDF全文

Wei‐yu Shi  Hua Li  Sheng Du  Yiping Chen  Kaibo Wang 《洁净——土壤、空气、水》2015,43(3):408-413

  相似文献   

Investigation on piezoelectric lead zirconate titanate detector bombarded obliquely with hypervelocity iron particles     

S. Takechi  T. Onishi  T. Miyachi  N. Hasebe  K. Nogami  S. Sasaki  T. Iwai  R. Srama 《Planetary and Space Science》2008,56(9):1309-1313

A cosmic dust detector for use onboard a satellite is currently being constructed from piezoelectric lead zirconate titanate (PZT). The characteristics of the PZT detector were studied by bombarding it with hypervelocity iron particles, which were supplied by a Van de Graaff accelerator. There was a linear relationship between the rise time of the signal observed from the detector and the particle's velocity, which was above 10 km/s on impact. It was also found that the rise time was almost independent of the collisional angle between the particles and the PZT surface within the limits of the particle's parameters used in this experiment.  相似文献   

The distribution of dissolved lead in the coastal waters of the East China Sea     

Yan Li  Rujun Yang  Aibin Zhang  Shirong Wang 《Marine pollution bulletin》2014

The distribution of dissolved lead in the coastal waters of the East China Sea was investigated seasonally. The average concentrations in surface waters during the spring and autumn were 0.52 nM and 0.27 nM, respectively. In the spring, the concentration of dissolved Pb in the surface waters and bottom waters ranged from 0.13 to 1.86 nM and from 0.15 to 0.94 nM, respectively. For both the surface water and the bottom water, the highest values were observed at the Yangtze River Estuary. Seasonal variability of D-Pb between spring and autumn in the ECS was observed. These results suggested that riverine inputs and atmospheric inputs may be the main sources of lead in this area, while adsorption and co-precipitation on suspended particles at the river estuary and biological process may be the major sinks.  相似文献   

Anthropogenic lead concentrations and sources in Baltic Sea sediments based on lead isotopic composition     

Agata Zaborska 《Marine pollution bulletin》2014

The Gulf of Gdańsk is influenced by heavy metals of anthropogenic origin. In this study, temporal concentration changes of Pb, Zn, Cd, and Cu were studied in six, 50 cm long sediment cores. The main aim of the study was to concentrate on the history of Pb fluxes and Pb isotopic composition (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) to trace Pb sources. The lowest Pb concentrations (19 μg g⁻¹) were measured in sediments deposited circa 1860, while the highest Pb concentrations (63–147 μg g⁻¹) were measured in sediments deposited between 1960s and 70s. Pre-industrial Pb fluxes were 7 Pb m² year⁻¹, while after WWII they reached 199 Pb m² year⁻¹. Highest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.22) were measured in the oldest sediment layers, and the lowest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.165) were measured in the sediments deposited in 1970s–90s. During the period of highest Pb contamination, the anthropogenic Pb fraction reached up to 93%. A general discussion of the Pb sources, emissions, and loads for Poland is included.  相似文献