Application of Lithium Isotope Geochemistry to the Study of the Continental Geothermal System     

Xiaocan Yu  Chenglin Liu  Chunlian Wang 《地球科学进展》2020,35(3):246-258

The lithium-rich brine in salt lakes is the main raw material of the world’s lithium products, while the continental geothermal fluids with a high salinity often contain a high concentration of lithium. Continental geothermal system is the focus in the study of geothermal formation mechanism. However, less attention is paid to the system due to the complexity of lithology, and the application of lithium isotopes in this field has not been systematically recognized. The newest application and progress of lithium isotope geochemistry in continental geothermal research in recent years were discussed, the problems in this field were put forward, and future research methods and directions were expected. The study of continental geothermal fluids should attach great importance to the application of Li-B-Sr-U multi-isotopic method, and should also be combined with water-rock reaction experiments under different temperature conditions. Moreover, in the future, the research on continental geothermal system should pay more attention to the various sediment/rock lithium isotopic compositions and their spatio-temporal distribution characteristics in the regional or geothermal field’s scales, mineralogy of reservoir rock, and behaviors of lithium isotopes related to the formation of secondary minerals in the process of water-rock interaction, in order to reveal the complex process of fluid evolution in the geothermal system and provide scientific reference for the exploration, exploitation and utilization of lithium resources in the system.  相似文献   

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

MC-ICP-MS锂同位素溶液分析技术与应用     

田世洪  路娜  侯增谦  苏本勋  肖燕  杨丹 《地质论评》2021,67(3):67040029-67040029

Li同位素是一种新兴的非传统稳定同位素示踪工具,在地质学、地球化学研究中具有广阔的应用前景。目前,Li同位素溶液分析技术主要采用热电离质谱仪（TIMS）和多接收电感耦合等离子质谱仪（MC-ICP-MS）,与TIMS相比,MC-ICP-MS具有分析精度高、样品量少、测试速度快等诸多优点。本研究团队近年来建立了MC-ICP-MS高精度Li同位素分析方法,在天然样品、标准物质以及石英包裹体的Li同位素测定中都取得了良好结果。以此为依托,研究团队建立了适用于西藏本地岩石成因研究的Li同位素地质端元,并将Li同位素应用于青藏高原岩石圈结构及其隆升历史、川西碳酸岩型稀土矿床富集机制、四川呷村VMS型矿床成矿流体来源和四川甲基卡硬岩型Li矿床富集机理等方面。本文比较详细地综述了这些研究进展,旨在加深对Li同位素溶液分析技术的理解,展示其在地球化学研究中的良好应用前景。  相似文献   

可见光下Li+/CNTS-TiO2光催化剂降解海洋柴油污染的研究          下载免费PDF全文

于晓彩  王力萍  刘京华  郭美岑  朱婉婷  廖佳琪  吴云英 《海洋学研究》2019,37(1):52-58

通过溶胶-凝胶法,以CNTS-TiO₂为前驱物制备了Li⁺掺杂CNTS-TiO₂的纳米复合光催化剂(以下均称为Li⁺/CNTS-TiO₂),采用X射线衍射(XRD)、扫描电镜(SEM)等测试手段对光催化剂进行表征,结果表明制得的催化剂为纳米材料且在TiO₂的基础上增大了比表面积。利用掺杂量为3%的Li⁺掺杂CNTS-TiO₂复合光催化剂(以下均称为3%Li⁺/CNTS-TiO₂)光催化降解海洋柴油污染,在可见光条件下考察了Li⁺掺杂量、煅烧温度、光催化剂投加量、柴油初始质量浓度、光催化反应时间、H₂O₂质量浓度等条件对光催化实验的影响。进行正交实验,确定最优化工艺条件为:Li⁺掺杂量为3%,光催化剂的煅烧温度为600 ℃,3%Li⁺/CNTS-TiO₂的投加量为0.1 g/L,降解柴油初始质量浓度为0.4 g/L,光催化反应时间为3 h,H₂O₂质量浓度为0.6 g/L,降解率可以达到95%以上。同时对此光催化剂进行应用试验,试验结果表明光催化剂去除效果优异,去除率可达91.87%。  相似文献   

利用近震高频接收函数研究四川理县西山村滑坡体结构   总被引：2，自引：1，他引：1       下载免费PDF全文

危自根  储日升  李志伟  盛敏汉  张海江  王宝善 《地球物理学报》2017,60(10):3793-3803

远震接收函数已广泛用于反演台站下方的结构,然而由于地球的非弹性衰减作用,远震数据较难获得高频接收函数,对浅地表结构约束不足.为了克服这一问题,我们使用近震数据的高频接收函数来研究浅表速度结构,并应用于四川理县西山村滑坡体上3个宽频带地震仪记录到的近震事件.本文发展了接收函数V_P-k(V_P/V_S)叠加方法,结合接收函数H-k叠加和波形反演方法获得了台站下方滑坡体的厚度、S波速度和平均V_P/V_S比,并与钻孔得到的滑坡体厚度进行对比.结果表明,滑坡体具有小尺度的横向不均匀性,台站下方滑坡体的平均V_P/V_S比在2.4~3.1之间变化并且在底层存在78~143m·s~(-1)左右的S波低速层.本文观测到的高V_P/V_S比和底层低的S波速度结构,与电磁法获得的滑坡体底层低的电阻率和底部富水特征一致,表明滑坡体h1底界面的抗剪强度相对较弱,是潜在的滑坡危险区域.本文研究结果表明,利用近震接收函数能有效约束浅表的速度结构,进而能为滑坡灾害治理提供一定的地震学参考.  相似文献   

论唐大历才子李端的诗歌体式及其美学风格     

彭洁莹 《广东海洋大学学报》2013,(5):44-49

唐大历才子李端的诗歌各体兼备各具特色：七律明净清丽、浏亮工整;五律锻琢工稳、奇逸清华;五七言绝句体情细腻、含蓄隽永。李端的古风歌行高于大历诸才子,其七言歌行韵调流畅、气势飞动,五言歌行清音古致、婉转惆怅,最得乐府神理。其歌行的韵调气势,情致遣词,在中唐诗坛中占有一定地位和影响。  相似文献   

赣西北狮子岭花岗岩型锂矿床成因：来自岩石地球化学和锆石U-Pb年代学的约束     

刘金宇  王成辉  刘善宝  秦锦华  陈振宇  刘泽  赵晨辉 《矿床地质》2024,43(1):195-214

赣西北矿集区是中国重要的花岗岩型锂矿资源基地,以发育多期次多阶段岩浆作用和大规模锂等稀有金属矿床著称。区内花岗质岩浆与稀有金属成矿关系密切,为进一步研究该地区花岗质岩浆演化特征及其与稀有金属成矿的联系,确定相关花岗岩成岩时代及成因类型,查明稀有金属成矿机制,笔者选择九岭地区狮子岭花岗岩作为研究对象,对其开展了岩相学、锆石U-Pb年代学及岩石地球化学分析。结果显示,狮子岭花岗岩属高钾钙碱性系列,具有高Si,富P,贫Ca、Mg、Fe,富集U、Hf等高场强元素,亏损Ba、Sr等大离子亲石元素,稀土元素总量较低（ΣREE=2.12×10^-6~146.24×10^-6）,轻稀土元素相对富集（LREE/HREE=3.5~16.53）,弱Eu负异常（δEu=0.23~0.59）的特征。整体上具有S型花岗岩的地球化学特征。锆石U-Pb定年显示,黑云母二长花岗岩成岩年龄为（141.02±0.59）Ma,锂（白）云母碱长花岗岩成岩年龄为（113.96±0.72）Ma。锂（白）云母碱长花岗岩成岩过程中形成磷锂铝石及锂云母等含锂矿物,其成岩年龄可视为锂等稀有金属成矿年龄。该区稀有金属矿化受燕山晚期岩浆结晶分异作用及后期热液交代作用共同影响,岩浆结晶分异作用是Li、Nb、Ta成矿的决定性因素,后期热液交代作用为Li等成矿元素的二次富集提供条件。  相似文献   

Lithium Abundances in the Atmospheres of SLR C-Giants WZ Cas and WX Cyg from Resonance and Subordinate Li I Lines     

Larisa A. Yakovina  Yakiv V. Pavlenko  Carlos Abia 《Astrophysics and Space Science》2003,288(3):279-286

Lithium abundances in the atmospheres of the super Li-rich C-giants WZ Cas and WX Cyg are derived by the spectral synthesis technique using the Li I resonance line at λ670.8 nm and three subordinate lines at λλ 812.6, 610.4 and 497.2 nm. The differences between the Li abundances derived from the λ670.8 nm line and the λλ 497.2, 812.6 nm lines do not exceed ±0.5 dex. The lithium line at λ610.4 nm provides typically lower abundances than the resonance line (by ≈ 1 dex). The mean LTE and NLTE Li abundances from three Li I lines (excluding λ610.4 nm) are 4.7, 4.9 for WZ Cas, and 4.6, 4.8 for WX Cyg, respectively. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

提高Li/MnO2扣式电池质量的研究   总被引：4，自引：0，他引：4       下载免费PDF全文

余世英  房艳 《盐湖研究》1999,7(4):68-72

探索了提高ＭｎＯ２ 电化学活性的方法,正极材料和电解液的配比和用量,以及工艺过程中应注意的问题。  相似文献   

区域气候模式侧边界的处理对东亚夏季风降水模拟的影响   总被引：27，自引：3，他引：24  

魏和林  符淙斌  王维强 《大气科学》1998,22(5):779-790

在区域气候模式模拟中,侧边界的作用是引入大尺度强迫场。如何处理好侧边界,即大尺度强迫场和区域气候模式本身之间的关系问题,对于区域气候模式模拟和预报东亚夏季风降水具有重要意义。本文利用美国纽约州立大学Albany分校的区域气候模式（SUNYA-ReCM）,设计了两种不同的侧边界处理方法,来探讨侧边界对东亚夏季风降水模拟的影响。驱动区域模式的大尺度强迫场来自欧洲中期天气预报中心（ECMWF）及热带海洋大气研究计划（TOGA）的分析资料场。试验结果表明:（1）当模式的区域较大时,采用较小的侧边界缓冲区会在缓冲区与模式内部的交界处产生不连续;扩大缓冲区并且考虑不同尺度强迫在垂直方向上的不同作用,可以避免这一缺陷。（2）更重要的是采用后一种方案,即减少了区域气候模式在模拟大尺度环流场方面所起的作用,使得模式更多地依赖侧边界来得到更真实的、对东亚夏季风降水起重大影响的一些气流,如副高、西南季风和南海季风,对东亚夏季风降水无论是在大小上还是在雨带位置的演变上都能进行更好的模拟。  相似文献