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近年来全岩电感耦合等离子体质谱（ICP-MS）和原位激光剥蚀电感耦合等离子体质谱（LA-ICP-MS）微量元素地球化学测试在地球科学领域的应用越来越广泛。霓长岩化是碳酸岩型稀土矿常见的蚀变类型，但其中的蚀变矿物微量元素特征与稀土矿化关系并不清楚。本文对川西牦牛坪矿床两期霓长岩化脉（无矿脉和含矿脉）中的霓辉石、钠铁闪石同时开展ICP-MS和LA-ICP-MS微量元素测试。结果表明：同期次的霓长岩化脉中，霓辉石、钠铁闪石全岩ΣREE含量远高于单矿物原位ΣREE含量，背散射图像显示霓辉石、钠铁闪石矿物中叠加了一些氟碳铈矿、重晶石微矿物。不同期次霓长岩化脉中霓辉石原位微量对比，含矿脉中的霓辉石具有更高的La/Nd值（0.19~0.23）、LREE/HREE值（6.58~7.79）、Ce/Nd值（0.95~1.11）、LaN/YbN值（2.07~2.33）。对比全岩微量组成，含矿脉中高含量的La、Ce、LREE、ΣREE，强烈的轻重稀土分异，可能代表了高稀土通量的霓长岩化流体。霓长岩化脉的出现以及脉体中霓辉石、钠铁闪石这些全岩微量、原位微量地球化学指标，可为碳酸岩型稀土矿床找矿勘查提供参考。 相似文献
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Michael A.W. Marks Roberta L. Rudnick Thomas Ludwig Horst Marschall Thomas Zack Ralf Halama William F. McDonough Detlef Rost Thomas Wenzel Edward P. Vicenzi Ivan P. Savov Rainer Altherr Gregor Markl 《Geostandards and Geoanalytical Research》2008,32(3):295-310
Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ7Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ7Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request. 相似文献
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在新疆哈尔里克山石城子地区新发现了一套侵位于晚古生代后碰撞二长花岗岩中的钠铁闪石花岗斑岩岩墙群。该类岩墙具斑状,斑晶以条纹长石和反条纹长石为主,基质矿物组成为正长石、钠长石、石英、钠铁闪石和霓石,为钠铁闪石花岗斑岩。主量元素特征显示为高硅、高碱,低铝、低镁和低钙;稀土元素总量较高,轻重稀土分馏明显,显著富集轻稀土元素;稀土元素配分模式曲线呈明显右倾的"V"型,Eu亏损强烈;微量元素特征显示为高10~4 Ga/Al、Zr和Zr+Nb+Ce+Y,强烈亏损Ba、Sr、P、Ti,富集Th、U、Zr和Hf;岩石学、地球化学特征显示其为碱性A型花岗岩。正ε_(Nd)(t)(4.13~4.75)和年轻的Nd模式年龄(t_(DM2)),指示其源区为亏损地幔来源的新生陆壳物质。LA-ICP-MS锆石U-Pb年龄结果显示岩墙的结晶年龄为晚二叠世(259.7±4.5Ma),围岩中捕获的老锆石年龄集中在2168~2635Ma和1677~1973Ma两个峰期,说明哈尔里克山地区可能存在前寒武纪古老基底,但已被新生陆壳物质改造。结合区域地质背景认为,哈尔里克山地区晚石炭世-早二叠世,为后碰撞伸展阶段;晚二叠世,进入陆内伸展阶段。 相似文献
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白云鄂博REE-Nb-Fe矿床的富钠岩石类型析及成因分 总被引：4，自引：1，他引：4
白云鄂博稀土-铌-铁矿是世界最大的稀土多金属矿床之一,主要产于中元古界富钠岩石、白云岩和富钾板岩中。富钠岩石与含矿碳酸岩、富钾板岩一起在白云鄂博广泛分布,特别是在主矿和东矿南侧分布广泛,也产在含矿围岩和底盘围岩中。富钠岩石包括富钠长石岩、含钠闪石钠长岩脉、钠闪石岩脉及钠闪石碳酸岩脉和钠闪石化蚀变白云岩。富钠岩石在一个地质单元内出现,但成分略有不同,其岩石化学分析表现出富钠特征,大部分样品的w(Na2O)在6%以上,w(Na2O+K2O)>8%,w(Na2O)>w(K2O)。富钠长石岩的里特曼指数δ为2.96~8.56,n(A l)/n(K+Na)>1,n(A l)/n(K+Na+Ca)<1,表明为弱碱性偏铝质岩石。富钠岩石以富集地壳不相容元素、亏损地幔元素为特征,其稀土总量低于矿化白云岩,但轻稀土元素高度富集,具弱负铕异常,与含矿白云质火山岩一致。根据岩石产状、组构及化学成分分析,富钠长石岩属于富钠火山岩,而其他含钠闪石岩脉则属于岩浆分异侵入的岩脉与岩浆热液充填岩脉。钠化交代以霓石化、钠铁闪石化和钠长石化出现为特征。另外,富钠流体与白云岩反应形成了钠铁闪石化白云岩,强烈的钠化蚀变作用主要出现在稀土强烈富集的主矿和东矿。比较蚀变与未蚀变岩石的化学成分,表明蚀变作用引起稀土的重新分配和弱负铕异常。钠铁闪石化白云岩的w(S iO2)、w(TiO2)、w(K2O)和w(Na2O)升高,w(P2O5)降低。钠化蚀变前的碳酸岩中稀土元素已经富集,热液蚀变引起稀土元素的活化和重新分配,但是没有提供新的稀土来源。 相似文献
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火山口附近是多种岩性、岩相叠合的地区,堆积厚度大、储层孔隙度大、储层物性好,是天然气勘探开发的有利目标区.火山口位置的确定对天然气的勘探开发部署具有特殊意义.利用岩石薄片X衍射技术,在松辽盆地深层富碱酸性火山岩中识别出特征的碱性暗色矿物--钠铁闪石,从而确定其为碱流岩.碱流岩是富碱岩浆演化晚期的产物,岩浆喷发到地表时粘度大,流动性差,往往堆积在火山口附近.碱流岩可以作为确定火山口存在的重要标志之一,它的确定对提高深层火山岩天然气勘探开发的效率具有重要的指示意义. 相似文献
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