地质聚合物技术的发展近况     

KoIKEDA DangFENG AkiraMIKUNI 《地学前缘》2005,12(1):206-213

概要介绍了一种无机聚合物———地质聚合物。首先对地质聚合物材料的制备过程作了介绍。根据原料的不同,地质聚合物材料的制备可以有两种途径:一种是以偏高岭石为基础原料,一种是以粉煤灰为主要原料。通常以硅酸钠水溶液作为单体硅源,氢氧化钠溶液作为碱激发剂以提高原料的溶出性。对某些在常温和低于100 ℃下制备的独石材料作了介绍。对煅烧高岭石,叶蜡石,粉煤灰和钢渣的溶出特性作了阐述。应用SEM EDX,对以粉煤灰为原料的地质聚合物材料的化学组成作了分析。最后对地质聚合物材料的经济性以及在环境保护等领域的应用前景,特别是在减少二氧化碳排放与废弃物处理方面的意义作了介绍。  相似文献   

Stabilisation/solidification and bioaugmentation treatment of petroleum drill cuttings     

《Applied Geochemistry》2016

Petroleum drill cuttings are usually treated by techniques suitable for particular contaminant groups. The significance of this study consists in the development of a treatment technology that can simultaneously handle the hydrocarbon and metal constituents of drill cuttings. Bioaugmentation is combined with stabilisation/solidification (S/S), within S/S monoliths and in granulated S/S monoliths. Portland cement was used for S/S treatment at 30% binder dosage. Bioaugmentation treatment involved two bacterial densities of a mixed culture bio-preparation. The effects of inclusion of compost, fertiliser and activated carbon were also evaluated. After 28 days, the combined S/S and bioaugmentation treatments recorded up to 15% higher total petroleum hydrocarbon (TPH) loss than control S/S treatment without bioaugmentation. Embedding fertiliser, activated carbon and higher bacterial density within S/S monoliths resulted in the highest (99%) TPH reduction but higher concentrations of metals. The addition of compost and lower bacterial density to granulated S/S monoliths led to similar (98%) TPH degradation and lower amounts of metals. The results suggest that with better mixture optimisation, combining S/S and bioaugmentation could engender more sustainable treatment of drill cuttings.  相似文献   

Micro-spectroscopic investigations of highly heterogeneous waste repository materials   总被引：1，自引：0，他引：1  

A.M. Scheidegger  D. Grolimund  C.R. Cheeseman  R.D. Rogers 《Journal of Geochemical Exploration》2006,88(1-3):59

Assuring safe disposal and long-term storage of radioactive and toxic wastes corresponds to a primary environmental task of present societies. To improve any technical limitation, a mechanistic understanding of the processes governing the binding of heavy metals and radionuclides is required. In this study, the significance of synchrotron-based X-ray microprobes for elucidating the spatial distribution and the speciation of radionuclides in highly heterogeneous waste repository materials will be outlined. A case study on the uptake process of Co in cementitious engineered barrier materials exposed to microbial degradation will be presented.  相似文献   

生物炭对磷石膏中磷的固化作用     

敖翔  徐冠立  李珎  柏涵 《岩石矿物学杂志》2024,43(1):100-108

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。  相似文献   

膨胀土干缩变形特性试验研究     

王东伟  唐朝生  李胜杰  曾浩  施斌  张必勇 《高校地质学报》2019,25(5):756

膨胀土是一种典型的问题性土,对气候变化非常敏感,在干旱气候条件下,极易发生体积收缩变形,引发各种工 程地质问题。为了研究膨胀土的干缩变形特性,开展了一系列室内干燥试验,测定了膨胀土的收缩特征曲线,重点分析 了初始含水率和干密度对干缩变形过程的影响,并进一步探讨了水泥固化抑制膨胀土干缩变形的效果和机理。结果表 明：（1） 膨胀土的干缩变形过程存在三个典型阶段：正常收缩、残余收缩和零收缩;（2） 初始含水率越高,试样蒸发速 率越快,且干缩变形完全后试样孔隙比越小而最终收缩应变越大,干缩变形越明显;（3） 初始干密度越大,试样蒸发速 率和最终体积收缩应变越小,提高初始干密度对试样干缩变形具有一定的抑制作用;（4） 在膨胀土中掺入适量的水泥能 显著降低试样的体积收缩应变,对干缩变形具有良好的抑制效果;（5） 膨胀土的干缩变形具有明显的各向异性特征,并 且与初始状态有关。  相似文献   

MTA固井技术在煤层气井中应用的实验研究     

张文平  王青贵  张素  何吉标  顾军 《中国煤炭地质》2013,(10)

MTA固井技术在油气田中的运用已经取得了显著效果,能够提高二界面的抗剪切强度以及抵抗地层水对二界面的冲蚀。通过室内实验,对MTA固井技术在煤层气井中的运用进行探索。实验结果表明,MTA技术在煤层气井的固井模拟实验中,也能够有效的提高二界面的抗剪切强度,实现二界面的整体固化胶结,抵抗地层水对煤层气二界面的冲蚀,这些特点对于提高煤层气井的产能具有重要意义。作为一种施工简捷、效果显著的固井技术,MTA固井方法在煤层气井中的应用前景是极为广阔的。  相似文献   

Enhancing the mechanical properties of marine clay using cement solidification     

Bhim Kumar Dahal  Rong-Jun Zhang  Ding-Bao Song 《Marine Georesources & Geotechnology》2013,31(6):755-764

Abstract

The use of soft clay and dredged marine clays as the construction material is challenging. This is because the high water content, high compressibility and low permeability of the clay causing the instability of ground and structure. This detrimental effect of soft clay can be improved by the cement solidification process, which is relatively cheap and efficient. This paper mainly focuses on the study of improvement on the mechanical behavior of cement mixed marine clay. The soil is reconstituted by using ordinary Portland cement of 5%, 10%, 15% and 20% by its mass. The study reveals that cementation of clay significantly improves the peak and residual strength of soil. Similarly, the primary yield stress of the soil is also improved from 16 to 275?kPa as cement content increases from 5% to 20%, respectively. By using statistical tools, the relationships between various parameters are established, which are very important to define the mechanical behavior of the clay. This study reveals that the yield surface of the solidified marine clay is not a smooth elliptical surface. Rather it is composed of two linear surfaces followed by a log-linear surface which can be modeled by using simple parameters obtained from triaxial tests.  相似文献   

水泥固化锌污染土电阻率与强度特性研究     

张少华  李熠  寇晓辉  董晓强 《岩土力学》2015,36(10):2899-2906

以标准砂及普通硅酸盐水泥为试验材料,制作水泥固化锌污染土样,进行了一系列电阻率和无侧限抗压强度试验。研究了交流电频率对水泥固化锌污染土电阻率的影响、不同含量锌离子对水泥缓凝作用的影响、锌离子含量和龄期分别对水泥土电阻率和强度的影响、电阻率与无侧限抗压强度的关系。结果表明：电阻率随电流频率的增加而明显降低,尤其当频率低于50 kHz时为甚;不同含量的锌离子对水泥土的缓凝作用影响明显,随着锌离子含量的增大,水泥土强度的充分发挥所需时间逐渐增长,但在锌离子含量为500 mg/kg时,缓凝作用表现异常;电阻率和强度均随龄期的增加而增长,随锌离子的含量的增加上下波动,电阻率在锌离子含量为50 mg/kg和500 mg/kg时出现极值,强度在锌离子含量为100 mg/kg和500 mg/kg时出现极值;在各个龄期下,电阻率与强度均呈现出很好的线性关系。  相似文献   

固化铅污染土的干湿循环耐久性试验研究   总被引：2，自引：0，他引：2  

曹智国  章定文  刘松玉 《岩土力学》2013,34(12):3485-3490

在商用高岭土、膨润土与商业黄砂混合物中加入硝酸铅溶液,添加水泥和石灰两种固化剂,采用室内压实制样方法获得固化的铅污染土试样。进行干、湿循环试验,测试固化体的质量损失和无侧限抗压强度等参数随干、湿循环次数的变化规律,评价固化铅污染土的干、湿耐久性。测试结果表明,本试验8种配比的试样都满足干、湿循环的要求;黏土矿物为膨润土的试样干、湿循环耐久性比黏土矿物为高岭土的试样要差;水泥固化土的干、湿循环耐久性要略优于石灰固化土;加入 8 000 mg/kg的铅可略增大土体的抗干、湿循环耐久性。水泥和石灰固化/稳定化重金属污染土时,土体中含水率是保证加固效果的关键参数之一。土体中含水率应能满足固化剂充分水化、水解、火山灰和碳酸化反应之需要。  相似文献   

固化淤泥三轴试验研究     

张春雷  朱伟  黄英豪  刘青松  大木宜章 《岩土力学》2006,27(Z2):591-594

对不同水泥掺加量固化淤泥进行了固结不排水(CU)三轴剪切试验,对固化淤泥的破坏模式和抗剪强度参数进行了分析。试验结果表明：应力-应变曲线随着水泥量增加由理想弹塑性向应变软化型转变;当水泥量为50 kg/m3时,随固结压力的增加应力-应变曲线有理想弹塑性、应变软化和应变硬化三种类型;当水泥量高于100 kg/m3时,试样都呈脆性破坏模式。淤泥经水泥改良后成为一种结构性土,固结压力在小于试样结构屈服应力时对抗压强度影响不大。有效粘聚力随水泥量的增加呈较大的增长趋势,而有效内摩擦角分布在32o~42o,表明水泥固化淤泥的作用主要是提高土颗粒间的胶结,而填充孔隙的作用较弱。  相似文献