长江经济带城市土地利用效率的影响因素及其空间溢出效应研究     

周晓艳  章芳  张苗苗 《测绘与空间地理信息》2020,(4):1-6

在人多地少的基本国情下,提高城市土地利用效率是促进区域可持续发展和建设生态文明的内在要求。本文在对2009-2016年长江经济带108个地级及以上城市土地利用效率的研究基础上,采用空间相关性研究方法分析了时空分布格局,通过构建空间杜宾模型(SDM)对其空间溢出效应进行分析。研究结果表明:1)2009-2016年长江经济带城市土地利用效率整体呈现稳定上升趋势;基本呈现以上海、南京、武汉等不同城市群中心城市向外逐步降低的“中心-外围”的分布格局。2)通过构建空间杜宾模型分析发现,经济发展水平、产业结构有显著为正的直接效应和溢出效应;土地市场化水平有显著为正的溢出效应;城市固定资产投资对城市土地利用效率具有正的直接效应和负的溢出效应;政府财政支出水平则对城市土地利用效率的直接效应和溢出效应均不明显。3)不同影响因素对经济带上中下游城市土地利用效率的空间效应存在一定差异性。  相似文献   

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

秦岭山地气候变化的地形效应     

孟清  白红英  赵婷  郭少壮  齐贵增 《山地学报》2020,38(2)

研究不同地形下的山地气候变化对于植被生长、不同动物种群的生存习性及对气候的应激性有重要意义。本文基于陕西秦岭地区1959—2016年32个国家站的日气温和降水资料,采用Anusplin插值法、标准化降水蒸散指数(SPEI)、稳健回归和Theil-sen回归法等方法分析了山区地形对气候变化的影响。结论如下:(1)58年来秦岭四个坡向上年均温度随着海拔的升高呈现显著下降趋势,年降水随着海拔的升高呈现不同程度的上升趋势。温度随坡度的增加表现出下降趋势;除秦岭南坡西段外,降水随着坡度的增加呈现出上升趋势,但均不显著。(2)年尺度上,秦岭山地南坡和南坡东段的气温呈显著增温趋势,南坡西段和北坡呈不显著增温趋势;四个方向上的降水均呈显著下降趋势。秦岭山地四个方向上的干湿等级为正常,北坡和南坡西段的干湿状况一致,58年年均SPEI均为0.07,南坡东段较暖湿(0.08),南坡较暖干(0.05)。(3)季节尺度上,秦岭山地四个方向上除了夏季外,其他季节的气温均表现出不同程度的升温趋势,降水均呈下降趋势。秦岭四个方向上四季干湿变化属于正常等级。秦岭北坡出现春季干暖化趋势;南坡秋季较暖湿;南坡东段和西段的冬季呈暖湿化特征;南坡西段夏季呈现暖干化特征。  相似文献   

土地利用景观格局空间尺度效应研究——以武汉市为例     

王璐  袁艳斌  董恒  黄解军  黄鹏  张城芳 《世界地理研究》2020,29(1)

城市土地利用景观格局研究对城市规划设计和土地资源管理具有重要的理论价值和现实意义,而研究尺度的选择是其必不可少的部分。本文基于景观生态学方法,以武汉市为研究区域,选取聚集分散指数、斑块类型指数、形状指数三种类型指数对土地利用景观格局进行分析,同时引入层次分析法,研究武汉市土地利用景观格局的空间尺度效应及其响应特征,结果表明武汉市土地利用景观格局具有明显的空间尺度效应,随着空间尺度的增大,景观破碎程度增大,景观分布越来越分散,景观异质性减小,斑块之间连接度越来越弱。在此基础上,建立最佳尺度选择模型,并基于分型理论对最佳尺度的合理性进行验证,最终得出武汉市土地利用景观格局研究的最佳空间尺度为60 m。  相似文献   

黑河中游夏季昼夜水汽同位素特征及水汽来源分析          下载免费PDF全文

孟鸿飞  张明军  王圣杰  邱雪  杜铭霞  张亚宁  余秀秀  周苏娥 《干旱区地理》2020,43(2):360-370

基于2012年6~8月的实测水汽同位素数据及相关气象数据，对黑河中游夏季昼夜的同位素基本特征、水汽来源方向及潜在蒸发源地进行了研究。结果表明：空气水汽线斜率白天大于夜晚和水汽过量氘值白天大于夜晚，综合说明白天局地蒸发较夜晚强烈；夏季受西风水汽影响显著。其中，6月主要受西风水汽和北冰洋水汽影响，7、8月主要受西风水汽和东南方向水汽影响，且8月受东南方向水汽影响最为明显；水汽运移路径上下垫面地形和气压带移动会影响水汽后向轨迹高度，西北方向上水汽输送通道较顺畅，风速较大，有利于水汽的输送；水汽蒸发源地主要集中在研究区周围及以东、以北部，其次是西北部。绿洲是主要的水汽蒸发源地，其次是城市和河流，白天较夜晚局地蒸发强烈且面积大。  相似文献   

Ab　Initio　Prediction　of　^29Si-NMR　Chemical　Shifts     

CHUShidong LIYingxia SONGNi GUANHuashi 《青岛海洋大学学报(英文版)》2002,1(1):63-65

The ability of several ab initio models to predict experimental 29Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allyltrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6-31G^*, B3LYP/6-31G^* , HF/6-311 G^**, B3LYP/6-311 G^** and MPWlPW91/6-311 G^** models respectively. The 29Si chemical shifts calculated by GIAO method using HF/6-311 G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.  相似文献   

CO2—H2O平衡法分析常量水中氧同位素的一些计算问题          下载免费PDF全文

刘士琳  严正 《地震地质》1996,18(2):104-108

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晶质铀矿自发裂变产生钌,银,碲的同位素探索     

李岩  王驹 《国外铀金地质》1995,12(1):7-12

为了阐明对铀的自发裂变现象，采用热电离质谱测定法对几种类型晶质铀矿样品的Ｒｕ，ｔＥ和Ａｇ的同位素组成作了测定，由于自发裂变碎片有可能加入天然同位素中，在几个样品中的Ｒｕ，Ｔｅ清楚地显示出了＾９９Ｒｕ，＾１０１Ｒｕ，＾１０２Ｒｕ，＾１０４Ｒｕ，＾１２８Ｔｅ，＾１３０Ｔｅ同位素测量中得到裂变成因的Ａｇ，从Ｍｏｒｏｇｏｒｏ（坦桑尼亚）某晶质铀矿得到的Ｒｕ裂变模式表明，这种晶质铀矿可能已经处于中子诱发＾２  相似文献