The cumulative characteristics of PAEs in PM2.5 in Changji,Northwest China     

Yuyan Liu  Caiye Ji  Bo Fu  Yongxin Yu  Haofeng Liu  Yaxing Shen 《自然地理学》2020,41(4):332-342

ABSTRACT

This paper discusses characteristics of the seasonal variation in phthalate acid esters (PAEs) in the PM_2.5 in the city of Changji, which is located an arid area of Xinjiang Province, northwest China. Samples were collected using a Laoying 2030 median discharge intelligent total suspended particulate (TSP) sampler and analyzed by a Shimadzu GC-2010 gas chromatograph. The results showed that PAEs in PM_2.5 were mainly composed of phthalic acid dibutyl phthalate (DBP) and phthalic acid (2-)ethyl hexyl ester (DEHP). DBP and DEHP are the most commonly used plasticizers, accounting for the majority of plasticizers used, and have large environmental emissions. Compared with the proportions of TSPs, proportions of DBP and DEHP in the PM_2.5 were lower, while the proportions of DMP and DEP were higher. A correlation exists between the distribution of PAEs and the particle size and concentration of atmospheric particulates. Seasonal variations in DBP and DEHP were the same, with lowest concentrations in the summer. Although seasonal variation in DMP was not the same as those of DBP and DEHP, the general trend was similar. Seasonal variation in DEP was different from those of other PAEs. This pattern is related to PAE characteristics and seasonal variations in their sources.  相似文献   

长江三角洲晚第四纪地层沉积特征与生物气成藏条件分析     

林春明  张霞  徐振宇  邓程文  殷勇  承秋泉 《地球科学进展》2015,30(5):589-601

对长江三角洲晚第四纪地层沉积特征进行了精细研究,探讨了研究区层序地层格架,在此基础上分析了浅层生物气成藏条件、特征和分布规律。研究表明,长江三角洲晚第四纪发育3期下切河谷,形成了3套沉积层序;因后期河流的强烈下切破坏,早期沉积层序往往被剥蚀殆尽,仅残留下部的河床相粗粒沉积,造成不同期河床相的叠置;相对而言,末次冰期以来形成的下切河谷沉积层序以相对完整的沉积相组合被保存下来。长江三角洲浅层天然气是未经运移的原生生物气,其主要富集于末次冰期以来的沉积层序内,气藏为自生自储同生型的岩性圈闭。河口湾—河漫滩和浅海相泥质沉积物既是气源岩,又是盖层,后者可作为良好的区域盖层;河口湾—河漫滩和河床相砂质沉积物为主要储集层。因此,研究区晚第四纪多期下切河谷沉积层序有利于浅层生物气藏的形成,特别是晚期下切河谷内河口湾—河漫滩相砂质透镜体以及河床相砂体可作为优先勘探目标。  相似文献   

莺歌海盆地乐东地区石英裂隙内流体包裹体特征及其对天然气成藏制约     

税蕾蕾  梁茹  孟祥豪  郭来源  许克伟 《沉积与特提斯地质》2020,40(1):45-52

莺歌海盆地乐东地区是我国典型高温超压天然气勘探领域,其关键储层黄流组砂岩以天然气富含CO_2为特征,对其中石英颗粒内裂隙包裹体的研究能为CO_2来源和天然气成藏信息提供重要线索。本文通过对黄流组砂岩石英颗粒内包裹体进行岩相学、显微测温与激光拉曼分析,结果表明黄流组砂岩石英颗粒内正常捕获流体包裹体均一温度主要分布在155～165℃与170～180℃两个温度区间,流体包裹体成分为CO_2(气)和H_2O(液)两种或CO_2(气)和CO_2(液)、H_2O(液)三种。这些特征表明乐东地区黄流组至少经历两期富含CO_2的热液活动,记录了埋藏晚期无机CO_2在火山活动或深大断裂发育期充注成藏的信息。  相似文献   

Seasonal DOC accumulation in the Black Sea: a regional explanation for a general mechanism   总被引：2，自引：0，他引：2  

Gustave Cauwet  Gaëlle Dliat  Anton Krastev  Galina Shtereva  Sylvie Becquevort  Christiane Lancelot  Andr Momzikoff  Alain Saliot  Adriana Cociasu  Lucia Popa 《Marine Chemistry》2002,79(3-4)

During three cruises in the Black Sea, organised in July 1995 and April–May 1997, biological and chemical parameters that can influence the carbon budget were measured in the water column on the NW shelf, particularly in the mixing zone with Danube River waters. We observed in early spring (end of April–May) conditions an important input of freshwater organisms that enhanced the microbial activity in the low salinity range. High bacterial activity regenerates nitrogen in the form of nitrates, but is also responsible for an important consumption of ammonium and phosphate, leading to a high N/P ratio and a strong deficit in phosphorus. The consequence is a limitation of phytoplankton development but also a production of carbohydrates that accumulate all along the salinity gradient. These mechanisms are responsible for a seasonal accumulation of dissolved organic carbon (DOC) that increases from 210 μM in winter to about 280 μM in summer. All this excess DOC disappears during winter, probably degraded by bacterial activity. The degradation of carbon-rich organic matter increases the phosphorus demand by bacteria bringing limitation to phytoplankton primary production.  相似文献   

上海潮滩沉积物重金属的动力学累积特征   总被引：65，自引：3，他引：65  

许世远  陶静  陈振楼  陈中原  吕全荣 《海洋与湖沼》1997,28(5):509-515

１９９３年７－８月，在上海长江口南岸和杭州湾北岸淤泥质潮滩不同地貌部位，采集表层沉积物和柱状沉积物样品，采用筛析法，离心法、火焰原子吸收法，＾２１０Ｐｂ法等分别对沉积物粒度、重金属总量，不同粒级重金属含量以及沉积速率等进行了和测定。结果表明，潮滩沉积物重金属的空间分布格局并不受沿岸排污的直接影响，而与沉积动力作用密切相关。在水动力条件较弱的淤涨岸段和高潮滩部位，伴随着细颗粒起泥沙的大量堆积，Ｃｕ，  相似文献   

麻痹性贝毒PSP在紫贻贝体内的累积、转化与排出   总被引：13，自引：2，他引：13  

颜天  傅萌  李钧  于仁诚  周名江 《海洋与湖沼》2001,32(4):420-427

于1998年9月在青岛鲁迅公园附近礁石区采集紫贻贝（Mytilus edulis)，采用实验室培养的方法，初步研究了塔玛亚历山大藻（Alexandrium tamarense,ATHK)产生的麻痹性贝毒（Paralytic Shellfish Poison,PSP)在其体内累积、转化与排出的规律。结果表明，在累积实验阶段，紫贻贝内脏的和肌肉中的PSP毒素含量均随实验时间的延长而逐渐增加，累积实验结束时，平均每只贝体内的PSP毒素含量为13.40nmol，毒性水平为12.24ugSTXEq/100g，紫贻贝内脏中的毒素含量远远高于肌肉，内脏中PSP毒素占贝体内PSP毒素总量的97.5%。在8天的排出实验阶段，贝体内的PSP毒素总量呈下降趋势，实验结束时，PSP毒素共排除了约50%，每天排除率约为9%。  相似文献   

南海北部神狐区域 SH2 站位甲烷水合物成藏动力学模拟研究     

关进安  梁德青  万丽华  谷任国 《工程地质学报》2014,22(5):997-1002

南海北部神狐区域海底的高丰度水合物储层与生物成因为主的甲烷气源表明该区域很可能是一种特殊的复合型海洋水合物系统,其成藏动力学机制有待进一步的研究和澄清。建立了一个耦合沉积层地质属性-流体流动过程-水合物反应动力学的传输-反应模型,区别了两种不同类型的水合物形成(分解)动力学过程:(1)在通常情况下溶解甲烷和游离气共同形成水合物,(2)特殊情况下游离气直接生成水合物,结果表明在神狐海域热力学环境下游离气形成水合物速度比溶解甲烷快约4倍,气体含量和动力学常数比值越大生成水合物越快,而对比水合物分布的模拟结果与实测数据表明该区域水合物储层聚集和产状很可能受到了其他地质活动的影响。  相似文献   

河北大庙Fe-Ti-P矿床中铁钛磷灰岩的成因: 来自磷灰石的证据   总被引：4，自引：3，他引：1  

陈伟  赵太平  魏庆国  徐勇航 《岩石学报》2008,24(10):2301-2312

铁钛磷灰岩仅由磷灰石和铁钛氧化物组成,常赋存于岩体型斜长岩中,成因上有不混溶和分异堆晶两种不同的认识。本文从磷灰石角度讨论河北大庙铁钛磷灰岩的形成机制。大庙铁钛磷灰岩常产出于浸染状Fe—P矿体内部,有时与块状铁矿石交互出现形成韵律条带状矿石,为岩浆结晶分异的产物。铁钛磷灰岩中磷灰石呈浑圆状,含量变化于15％-34％。铁钛磷灰岩的全岩和磷灰石微量元素分析显示,磷灰石比全岩相对富集稀土元素达2．96—6．93倍,但两者的配分型式基本平行。质量平衡计算（Rocl／F）的结果表明,铁钛磷灰岩中几乎100％的稀土元素赋存于磷灰石中。综合上述特征,反映磷灰石为结晶分离的堆晶矿物,铁钛磷灰岩应为堆晶成因。因为如果磷灰石结晶于铁钛磷灰岩不混溶熔体,它的稀土元素分配系数也不会变化达2．3倍（变化于2．96—6．93）。计算出该磷灰石的母岩浆稀土元素组成,与浸染状Fe．P矿石最为相似,结合它与铁钛磷灰岩之间紧密共生的野外特征以及相似的全岩及磷灰石稀土元素配分型式,认为磷灰石最可能是在浸染状Fe．P矿浆中,经结晶分离作用形成铁钛磷灰岩。  相似文献   

塔里木盆地轮西地区奥陶系潜山油藏:一个海西期充注并降解的稠油油藏成藏实例分析          下载免费PDF全文

潘文庆  赵孟军  张宝民  韩剑发  柳少波  秦胜飞 《地质科学》2008,43(2):321-332

塔北隆起的轮西地区具有以裂缝、溶蚀裂缝和溶洞为主的下奥陶统潜山储集体,且继承型古隆起一直成为油气运移和聚集的指向区,因此具有较为优选的成藏地质条件。海西晚期是轮西地区稠油藏的主要成藏期,海西末期石炭-二叠系地层遭受强烈剥蚀使海西晚期聚集的奥陶系潜山原油降解,成为重质稠油油藏,并不受印支晚期至喜马拉雅期运动的影响。印支晚期之后Ⅰ级断裂活动停滞,使轮西地区奥陶系潜山以稠油为主的油藏基本上未受晚期油气充注的影响。对轮西奥陶系潜山油藏研究得到的重要启示是:应加强塔里木盆地克拉通地区早期成藏勘探潜力的认识。  相似文献   

Accumulation by securitization: Commercial poaching,neoliberal conservation,and the creation of new wildlife frontiers     

《Geoforum》2016

Part of a broader interest in the escalating securitization of conservation practice, scholars are beginning to take note of an emerging relationship between conservation–securitization, capital accumulation, and dispossession. We develop the concept of accumulation by securitization to better grasp this trend, positioning it in the critical literatures on neoliberal conservation, green grabbing, and conservation-security. The concept captures the ways in which capital accumulation, often tied to land and resource enclosure, is enabled by practices and logics of security. Security logics, moreover, increasingly provoke the dispossession of vulnerable communities, thereby enabling accumulation. We ground the concept by turning to the Greater Lebombo Conservancy (GLC) in the Mozambican borderlands. This is a new privately-held conservancy built as a securitized buffer zone to obstruct the movement of commercial rhino poachers into South Africa’s adjacent Kruger National Park. We show how wildlife tourism-related accumulation here is enabled by, and in some ways contingent upon, the GLC’s success in curbing poaching incursions, and, relatedly, how security concerns become the grounds upon which resident communities are displaced. In terms of the latter, we suggest security provides a troubling, depoliticized alibi for dispossession. Like broader neoliberal conservation and green grabbing, we illustrate how accumulation by securitization plays out within complex new networks of state and private actors. Yet these significantly expand to include including security actors and others motivated by security concerns.  相似文献