| A simulating experiment on the geochemical variation trend at the initial period of meteoric waters converting to underground waters and ore fluids |
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| 作者姓名： | ZHU Xiaoqing |
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| 作者单位： | [1]Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China [2]Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
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| 基金项目： | Chinese Academy of Sciences，中国科学院资助项目 |
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| 摘 要： | Experimental studies were undertaken on leaching of sedimentary rocks （ dolomite and sandstone） and Hg, Sb ores by distilled water under the condition of a completely open system （room temperature and room pressure）. The aim is to find whether the halogen elements or metal elements first enter the solution at the early stage of meteoric waters converting to groundwaters and ore fluids, and, at the same time, to understand how and when they enter distilled water solutions from the rocks. The experimental resuhs have shown that F and Cl began to enter the fluids in the initial period of thirty days. With increasing leaching duration, the amounts of the elements that entered the fluids increased steadily. During the period from 120 days to 150 days the amounts increased more drastically, followed a slow increase. It is found that the capability of Cl entering the solutions is much greater than that of F. Hg and Sb were found not to have entered the solutions till 120 days later. During this period of time the pH value of the solutions began to drop. As for Hg and Sb ores, Hg and Sb began to enter the solutions on the 60th or 90th day, greatly ahead of schedule, but the two metallic elements in the rock samples began to enter the solutions 150 days later. Relatively speaking, Hg is more easily leached out than Sb from the rocks. In some rock samples, Sb could be detected in the solutions at the end of the experiment. However, Cu, Pb and Zn had not been detected in the leaching solutions from the beginning to the end of the experiment. In the whole leaching process the pH value of the solutions tend to decrease slowly from 7.1 at the beginning to 6.5 at the end. That is to say, in the interaction between pure water and rock the halogen elements in the rocks were preferentially leached out and then entered the fluids. With increasing water/rock reaction duration and amount of halogen-group elements in the solution and with decreasing pH value of the solution, some active metallic elements began to release in small amounts. This experimental result can explain the source and mechanism of volatile components and trace metals in underground waters. Meanwhile, as for those ore deposits produced by ore fluids derived from meteoric waters, the experimental result is also helpful to the understanding of the geochemical variation trend at the initial stage of conversion of meteoric waters to ore fluids.
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| 关 键 词： | 地下水 矿石 流动性 地球化学 蒸馏水 |
A simulating experiment on the geochemical variation trend at the initial period of meteoric waters converting to underground waters and ore fluids |
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| Xiaoqing Zhu,Yan Huang,Qian Zhang,Yuliang He,Chaohui Zhu.A simulating experiment on the geochemical variation trend at the initial period of meteoric waters converting to underground waters and ore fluids[J].Chinese Journal of Geochemistry,2005,24(4):306-315. |
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| Authors: | Xiaoqing Zhu Yan Huang Qian Zhang Yuliang He Chaohui Zhu |
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| Institution: | (1) Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, 550002 Guiyang, China;(2) Graduate School of the Chinese Academy of Sciences, 100039 Beijing, China |
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| Abstract: | Experimental studies were undertaken on leaching of sedimentary rocks (dolomite and sandstone) and Hg, Sb ores by distilled water under the condition of a completely open system (room temperature and room pressure). The aim is to find whether the halogen elements or metal elements first enter the solution at the early stage of meteoric waters converting to groundwaters and ore fluids, and, at the same time, to understand how and when they enter distilled water solutions from the rocks. The experimental results have shown that F and Cl began to enter the fluids in the initial period of thirty days. With increasing leaching duration, the amounts of the elements that entered the fluids increased steadily. During the period from 120 days to 150 days the amounts increased more drastically, followed a slow increase. It is found that the capability of Cl entering the solutions is much greater than that of F. Hg and Sb were found not to have entered the solutions till 120 days later. During this period of time the pH value of the solutions began to drop. As for Hg and Sb ores, Hg and Sb began to enter the solutions on the 60th or 90th day, greatly ahead of schedule, but the two metallic elements in the rock samples began to enter the solutions 150 days later. Relatively speaking, Hg is more easily leached out than Sb from the rocks. In some rock samples, Sb could be detected in the solutions at the end of the experiment. However, Cu, Pb and Zn had not been detected in the leaching solutions from the beginning to the end of the experiment. In the whole leaching process the pH value of the solutions tend to decrease slowly from 7.1 at the beginning to 6.5 at the end. That is to say, in the interaction between pure water and rock the halogen elements in the rocks were preferentially leached out and then entered the fluids. With increasing water/rock reaction duration and amount of halogen-group elements in the solution and with decreasing pH value of the solution, some active metallic elements began to release in small amounts. This experimental result can explain the source and mechanism of volatile components and trace metals in underground waters. Meanwhile, as for those ore deposits produced by ore fluids derived from meteoric waters, the experimental result is also helpful to the understanding of the geochemical variation trend at the initial stage of conversion of meteoric waters to ore fluids. |
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| Keywords: | distilled water leaching reaction element meteoric water underground water ore fluid |
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