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Matrix bound phosphine in sediments of the Changjiang Estuary and its adjacent shelf areas
Authors:Jian-Bing Li  Gui-Ling Zhang  Jing Zhang  Zhuo-Yi Zhu  Jing-Ling Ren  Su-Mei Liu
Institution:1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education of the People’s Republic of China, Department of Marine Chemistry, College of Chemistry and Chemical Engineering, Ocean University of China, 238 Songling Road, Qingdao 266100, China;2. Qingdao Supervision and Testing Center of Product Quality, 173 Shenzhen Road, Laoshan District, Qingdao 266061, China;3. State Key Laboratory of Estuarine and Coastal Research, East China Normal University, 3663 Zhongshan Road North, Shanghai 200062, China
Abstract:Matrix bound phosphine (MBP) is commonly considered an important phosphorus form in the natural environment. This paper presents an investigation of the spatial distribution of MBP and its relationship with the environmental factors in the Changjiang Estuary and its adjacent shelf areas (29.5–32°N, 122–124°E). A total of 32 surface sediment samples were collected from April 24 to 30, 2008. MBP was detected in all samples from the Changjiang Estuary and its adjacent shelf surface sediments (0.1–29.7 ng kg−1). The concentration of MBP decreased from the Changjiang Estuary to the East China Sea shelf. Environmental factors such as organic matter, type of sediments, and redox conditions were found to affect the concentration and distribution of MBP in the marine sediments. Although the MBP levels were low in the marine sediments, the marine biogeochemical cycles of MBP in sediments were established and the information presented here will contribute to the understanding of the biogeochemical cycle of phosphorus.
Keywords:phosphorus  matrix bound phosphine (MBP)  sediments  Changjiang estuary  East China sea
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