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湖南沃溪金-锑-钨矿床成因的稀土元素地球化学证据
引用本文:顾雪祥,刘建明,Oskar Schulz,Franz Vavtar,付绍洪.湖南沃溪金-锑-钨矿床成因的稀土元素地球化学证据[J].地球化学,2005,34(5):428-442.
作者姓名:顾雪祥  刘建明  Oskar Schulz  Franz Vavtar  付绍洪
作者单位:1. 中国地质大学,地球科学与资源学院,北京,100083;中国科学院,地球化学研究所,贵州,贵阳,550002
2. 中国科学院,地质与地球物理研究所,北京,100029
3. 茵斯布鲁克大学,矿物与岩石研究所,A-6020 茵斯布鲁克,奥地利
4. 中国科学院,地球化学研究所,贵州,贵阳,550002
基金项目:国家自然科学基金,奥地利国家自然科学基金,中国科学院"百人计划",科技部专项基金
摘    要:沃溪金-锑-钨矿床的稀土元素地球化学组成良好地反映了成矿作用的条件和过程,并为示踪矿床成因提供了有用的信息.以流体包裹体为代表的成矿溶液,以较高的稀土总量、显著的轻稀土富集和缺乏明显的铕异常为特征,代表了一种通过在碎屑沉积物柱中循环而萃取矿质的演化的海水热液.矿石相对于成矿流体(母液)富集重稀土而轻微亏损铕,反映了矿石沉淀过程中来自于海水的稀土元素掺合.同一矿层内由下往上,重稀土相对富集的程度逐渐增大而稀土总量则逐渐降低,表明随着热液化学沉淀作用的进行,海水掺合的影响逐渐增强.矿石的稀土元素组成,无论在分布模式还是在轻重稀土之间的分馏程度上,均与其他许多 Sedex型多金属矿床十分相似,暗示了这些矿床具有相似的成因机制.稀土元素地球化学特征支持矿床同生沉积成因的观点.

关 键 词:稀土元素  地球化学  矿床成因论  金-锑-钨矿床  沃溪  湖南省
文章编号:0379-1726(2005)05-0428-15
收稿时间:2005-02-02
修稿时间:2005年2月2日

REE geochemical evidence for the genesis of the Woxi Au-Sb-W deposit, Hunan Province
GU Xue-xiang,LIU Jian-ming,Oskar Schulz,Franz Vavtar,FU Shao-hong.REE geochemical evidence for the genesis of the Woxi Au-Sb-W deposit, Hunan Province[J].Geochimica,2005,34(5):428-442.
Authors:GU Xue-xiang  LIU Jian-ming  Oskar Schulz  Franz Vavtar  FU Shao-hong
Abstract:The REE geochemical compositions of the Woxi Au-Sb-W deposit well reflect the conditions and processes of the hydrothermal mineralization and provide some useful information for tracing the genesis of the deposit. The ore-forming hydrothermal fluids, as demonstrated by fluid inclusions, are characterized by relatively high total REE contents, marked LREE enrichment and no significant Eu-anomalies. They were mostprobably derived from evolved seawater that acquired ore-forming materials by circulating in the clastic sediment pile. The bulk ores are enriched in HREE and slightly depleted in Eu relative to their parent fluids, indicating the influence of seawater. Within a single ore layer, the degree of HREE enrichment tends to increase upward, while the total REE contents decrease, reflecting greater influence and dilution of seawater with time. There is a broad similarity in chondrite-normalized REE patterns and the amount of REE fractionation of the ores in this study and exhalites from many other Sedex-type polymetallic ore deposits, suggesting a similar genesis for these deposits. The REE geochemistry supports a syngenetic model for the Woxi deposit.
Keywords:geochemistry  ore genesis  Au-Sb-W deposit  Woxi  Hunan Province
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