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1.
在Clark-Lubs缓冲溶液(pH9.8)中,锰(Ⅱ)能催化过氧化氢氧化酸性铬蓝K的反应。据此,建立了测定痕量锰的分光光度新方法。方法灵敏度为1.49×10~(-6)μg/m~2。测定范围0～50ng/25ml。据Arrhenius方程式测得催化反应表观活化能为86.41KJ/mol。方法已用于硅酸盐单矿物中锰的测定,变异系数5.90％。 相似文献
2.
研究了在3.2mol/L HCl介质中乙醇或乳化剂OP存在下,DBCCPA与Th(Ⅳ)的显色反应。有色络合物最大吸收峰为644nm,组成比为Th(Ⅳ):DBCCPA=1:2。乙醇存在时ε_(644)=1.13×10~5L·mol~(-1)·cm~(-1),0-13μgTh/25ml范围符合比尔定律;OP存在时,ε_(644)=1.17×10~5L·mol~(-1)·cm~(-1)n,0—12μgTh/25ml范围符合比尔定律。拟定了独居石中Th的测定方法,样品测定结果令人满意。 相似文献
3.
《矿物岩石地球化学通报》2016,(2)
为探究盐类矿床中Br和I元素的影响因素及其对钾盐矿床成因的指示意义,采集思茅盆地勐野井的石盐、钾盐样品,采用X射线衍射方法分析了其盐类矿物组成,用ICP-OES和离子色谱仪测试了阳离子(K~+、Ca~(2+)、Na~+、Mg~(2+))和阴离子(Cl~-、Br~-、I~-、SO_4~(2-))组成。结果显示,样品的Br含量为89.08×10~(-6)~555.45×10~(-6),高于海水含量,Br×10~3/Cl的质量比值为0.13~0.86,Br的主要影响因素是溶液的主要成分(SO_4~(2-),K~+,Ca~(2+)和Mg~(2+))和蒸发作用;I含量为0.07×10~(-6)~0.27×10~(-6),I×10~6/Cl的摩尔比值为0.03~0.11,略高于海水值,I含量随I×10~6/Cl摩尔比值的增加呈上升趋势,说明蒸发作用是影响卤水I含量的因素之一。但Br和I呈负相关,表明有机质的含量是I含量的主要影响因素,蒸发作用可能是次要影响因素,I和I×10~6/Cl摩尔比值可能是判断海陆相的潜在指标之一。 相似文献
4.
巯基棉富集—化学发光法测定钨 总被引：3，自引：0，他引：3
本文研究了H_2O_2-KI-W(Ⅵ)-鲁米诺体系化学发光测定W的条件。所拟定的方法测定W的浓度范围为1×10~(-10)—1×10~(-6)g/ml,检测限为3×10~(-11)g/ml W。通过巯基棉吸附W,使与干扰离子分离并对痕量W富集。应用于天然水及岩矿样品中W的测定,获得满意结果。 相似文献
5.
离子色谱法同时测定地质样品中氟氯磷硫 总被引：5，自引：0，他引：5
本文研究了离子色谱同时测定地质样品中F~-、Cl~-、PO_4~(3-)、SO_4~(2-)的前处理过程,选择了色谱测定最佳条件。在Na_2CO_3全熔的样品溶液中,加入(NH_4)_2CO_3使Si、Al随大多数金属离子同时沉淀;再用预处理柱除去熔剂引入的大量Na~+及CO_3~(2-)消除其干扰;并在流出液中补加相应试剂与淋洗液相匹配,实现了多种地质样品中F~-、Cl~-、PO_4~(3-)和SO_4~(2-)的测定。方法检出限(3s,μg/ml)分别为F~-0.05、Cl~-0.1、PO_4~(3-)0.3、SO_4~(2-)0.5。测定范围为F~-0.05—3μg/ml,Cl~-0.1—6μg/ml,PO_4~(3-)0.3 —30μg/ml,SO_4~(2-)0.5—30μg/ml。 相似文献
6.
新疆西准噶尔巴尔努克早石炭世富Nb岛弧玄武岩的发现及其地质意义 总被引：9，自引：6，他引：3
黑山头组玄武岩-玄武安山岩组合是西准噶尔早石炭世海相火山-沉积建造的重要组成部分,其与高Mg安山岩及O型adakite共生。此次分析的所有样品均为玄武质岩石,Si O2含量为49.62%~55.68%,平均为52.70%;明显高Ti O2(1.16%~1.99%),平均为1.56%;显著富Na2O而贫K2O,Na2O为3.17%~6.35%,平均为4.90%,Na2O/K2O为1.19~26.08,绝大多数样品该比值4(平均8.93)。样品明显富集Nb、Sr、Zr等,Nb含量均7×10-6(7.29×10-6~12.32×10-6,平均为9.48×10-6);全部样品Sr均400×10-6(618×10-6~1107×10-6,平均为825×10-6);Zr158×10-6(159×10-6~217×10-6,平均为182.6×10-6);Zr/Y比值4(6.63~11.09,平均为8.62)。显著高于一般岛弧玄武质岩类。轻稀土明显富集而重稀土亏损显著,且有基本一致的弱正Eu异常。(La/Nb)PM比值0.7(1.23~2.26,平均1.94),(87Sr/86Sr)i=0.7035~0.7039;143Nd/144Nd=0.5128~0.5129;εNd(t)=5.49~7.13。这些地球化学特征与Sajona et al.(1993,1994,1996)确立的富Nb岛弧玄武岩基本一致,而与一般岛弧玄武岩有显著区别。这一发现,为确认西准噶尔早石炭世存在富Nb岛弧玄武岩提供了地球化学佐证,丰富了新疆乃至我国富Nb岛弧玄武岩的产地与层位,也为确认本区早石炭世岛弧构造环境提供了重要依据。 相似文献
7.
Lu-Hf年代学研究——以大别榴辉岩为例 总被引：3，自引：2，他引：3
本文利用多接收电感耦合等离子体质谱仪(MC-ICP-MS)进行了同位素稀释法Lu-Hf年代学研究,建立了全岩Lu、Hf的分离条件。分离后Lu溶液中~(176)Lu/~(176)Yb大于30,分离后Hf溶液中Lu和Yb对Hf的干扰(~(176)Lu/~(176)Hf和~(176)Yb/~(176)Hf分别小于2×10~(-6)和2×10~(-4))采用指数法则进行校正。建立了MC-ICP-MS进行Lu、Hf同位素高精度准确测试的校正方法。天然样品中Hf同住素~(176)Hf/~(177)Hf的内部测试精度优于0.0015%,外部精密度优于0.0010%。应用本文建立的方法获得大别双河榴辉岩石榴子石-全岩Lu-Hf等时线年龄为254±16Ma(2σ)。年龄误差稍大与该样品石榴子石中较低的Lu含量(1.1μg/g)和石榴子石-全岩的未充分分开的~(176)Lu/~(177)Hf比值(分别为0.05和0.01)有关。 相似文献
8.
催化光度法测定矿石中痕量金 总被引：1，自引：0，他引：1
本法研究了金(Ⅲ)在1.2mol·L~(-1)硫酸中对铈(Ⅳ)-汞(Ⅰ)体系的催化作用。选择和确定了试剂最佳浓度、催化时间、加热温度,观察了共存离子等的影响。检出限为2.0gAu。金浓度在2.5—250ng/10ml范围内呈线性关系,适用于测定矿石中小于0.2g/t的金。 相似文献
9.
提出了用meso-四(4-三甲铵苯基)卟啉荧光熄灭法测定痕量Au,对反应机理进行了初步探讨。该体系稳定,25ml体积中Au量0～0.1μg时与△F值呈良好的线性关系,检出限为0.1ng/ml。对于0.08μgAu测定12次,其RSD为2.3％。方法已应用于金矿中痕量Au的测定。 相似文献
10.
流动注射-光度法测定地质样品中痕量碘 总被引：2，自引：2，他引：2
利用I~-对4,4′-四甲基二氨基二苯甲烷(4,4′-TMB-DPM)与氯胺T反应的催化作用,建立了流动注射-分光光度测定地质样品中痕量碘的方法。采用不等流速合并带法,分析速度快、节省试剂、灵敏度高。与高温水解法释放I~-相结合,使样品处理简单、干扰离子少。对于含I~-10μg/L的水样,其RSD(n=19)为1.1％,检出限为0.3ng/ml。用于水系沉积物、土壤分析时,含碘1.6×10~(-6)的样品RSD(n=10)为6.1％,检出限为0.08×10~(-6)。测量速度50N/h。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
12.
Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
13.
The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
14.
15.
Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozac&#x;h Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
16.
正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.) 相似文献
17.
正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology, 相似文献
18.
正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.) 相似文献
19.
正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se- 相似文献
20.
正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with 相似文献