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1.
为加强连云港市海域的海洋倾废管理和海洋生态环境保护,文章在该海域主要疏浚工程区的49个站位开展采样调查,并采用潜在生态风险指数法,评价表层疏浚物的重金属污染程度及其潜在生态风险。研究结果表明:连云港市海域疏浚物质量总体较好,重金属含量的变化范围和分布的区域差异较小,其中含量最高的为锌、最低的为汞;污染程度最大的重金属为镉,较小的重金属为铬;潜在生态风险指数由大到小的重金属依次为镉、汞、砷、铜、铅、铬和锌,除镉和汞(连云港港区)外,其余潜在生态风险等级为低;潜在生态风险指数由大到小的区域依次为连云港港区、徐圩航道、外航道内段、田湾核电站取水口和外航道外段,除连云港港区外,其余区域的潜在生态风险等级为低;应高度关注镉和汞等重金属的污染状况以及近岸区域的潜在生态风险。  相似文献   

2.
中国陆架沉积环境地球化学研究表明,我国近海和远海海域的海洋沉积物质量保持良好,部分近海海域沉积物质量较差。探讨了我国陆架海域沉积物的有机物、重金属元素和生源要素等环境地球化学。  相似文献   

3.
The Kimmeridge Clay is considered a major oil source rock for the North Sea hydrocarbon province. The formation is also developed onshore in an organic-rich mudstone facies. This paper examines the possibility of onshore oil generation from the Kimmeridge Clay. Geochemically, onshore basin margin sediments contain rich, potential source horizons with mainly Type l/Type ll oil-prone kerogen, but are immature. Some deeper Cleveland Basin sediments have reached marginal maturity. Burial history reconstruction suggests significant formation palaeoburial depths in central areas of the Cleveland and Wessex Basins. Computed vitrinite isoreflectance contours show the Wealden and Isle of Wight Kimmeridge Clay to be thermally mature. Basin modelling suggests an early Palaeogene onset of oil generation in parts of the Cleveland Basin, while maximum oil generation could have been reached by the formation base in the Isle of Wight area during the late Cretaceous. Although basin subsidence ceased in the Neogene, in the Weald and Isle of Wight, where the formation is still deeply buried, oil generation probably continued for some time during uplift. Thus significant quantities of oil could have been generated. Whether or not this oil is present today however, would depend on the correct timing of suitable migration and trap structures.  相似文献   

4.
As with many countries, the Korea government has made a variety of efforts to meet the precautionary principle under the London Convention and Protocol acceded in 1994 and 2009. However, new strategies for the suitable marine dumping of waste materials have since been developed. In this study, the distribution and contamination of heavy metals including Al, Fe, Mn, Li, Co, Cr, Ni, Cu, Zn, As, Cd, Pb and Hg in bottom sediments were analyzed and compared to various criteria in order to evaluate the effectiveness of the management of the East Sea-Jung (ES-Jung) dumping site by the Korea government. The results indicate that the average metal concentrations were significantly lower than Effects Range Low (ERL) values, and generally similar to or lower than the Threshold Effect Levels (TEL) from the Sediment Quality Guidelinces (SQGs). According to analyses of various metal contamination indexes (Enrichment Factor: EF, Pollution Load Index: PLI and the Index of Geoaccumulation: Igeo), most areas were found to be uncontaminated by heavy metals with the exception of several moderately contaminated stations (ESJ 33, 54, 64 and ESJR 20). Heavy metal concentrations in areas grouped as G1, G2, DMDA, N-Ref and S-Ref which showed similar characteristics between 2007-2013 and 2014, were compared. Unexpectedly, most concentrations in the northern reference area (N-Ref) were much higher than those in the actual dumping areas (G1 and G2), may be due to the influences from nearby cities to the west of the ES-Jung site, rather than from the dumping site itself. Additionally, heavy metal concentrations in the dredged material dumping area (DMDA) were found to be low although they have slightly increased over time and those in the southern reference area (S-Ref) were found to have gradually decreased with year. The concentrations of most metals in the East Sea-Jung dumping site were similar to or less than those in the Earth’s crust and approximately the same as those in continental sediments. As a result, this site can be considered as uncontaminated or slightly contaminated. This implies that the efforts made by the Korea government to manage and govern the dumping site through various policies, including ‘the focal point system’, ‘the responsibility zones system’ and ‘the principle of pollution causing party liability’, have been successful.  相似文献   

5.
本文综合运用单因子污染指数法、Hakanson潜在生态风险指数法和沉积物质量基准法3种方法,研究和评价了2012年和2013年山东近岸海域表层沉积物重金属的污染特征和潜在生态风险。结果表明:山东近岸海域94%以上站位的表层沉积物重金属含量符合第一类海洋沉积物质量标准,沉积物质量良好;山东近岸海域重金属综合潜在生态风险低,各重金属潜在生态风险由高到低为HgAsCdPbCuCrZn(2012年)和HgCdAsPbCuCrZn(2013年),Hg在个别站位达中潜在生态风险程度,为主要污染因子;50%以上站位As含量介于美国佛罗里达州和加拿大沉积物质量基准的TEL—PEL之间,表明负面生物效应偶尔发生。应加强对山东近岸海域表层沉积物中重金属Hg和As的监测,重点关注二者相对高值区的潜在生态风险和负面生物效应。  相似文献   

6.
7.
Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.  相似文献   

8.
为了解黄河尾闾及近岸沉积物中重金属的污染特征,采用电感耦合等离子体质谱仪(ICP-MS)测定了黄河河道和河口48个样品中Cr、Cu、Zn、Cd、Pb和As等6种重金属的含量,并对其分布和生态风险进行了评价。结果表明,黄河尾闾及近岸重金属的总含量沿河道至河口方向呈现先增加后降低再增加的趋势,至近岸B断面,As、Pb、Cd和Zn含量呈明显增加趋势,Cu和Cr含量增加幅度较小;黄河河口沉积物中重金属浓度明显高于河道沉积物中重金属的浓度。与我国其他流域相比,研究区域重金属含量处于较低水平。潜在生态风险评价结果表明,黄河尾闾及近岸沉积物6种重金属潜在生态风险系数从高到低依次为:CdAsPbZnCuCr,黄河尾闾及近岸沉积物的潜在生态风险主要由Cd和As引起,两者的贡献率分别为55.90%和29.54%,研究区域生态风险低,污染轻。研究结果将为黄河尾闾及近岸生态保护、环境管理和污染治理提供一定基础数据。  相似文献   

9.
深圳近海海域沉积物重金属污染状况评价   总被引:3,自引:0,他引:3       下载免费PDF全文
根据2000—2007年深圳近海海域表层沉积物的基础监测资料, 采用地累积指数和潜在生态危害指数两种评价方法, 对该区域沉积物中重金属的污染状况进行了分析和研究。结果表明, 深圳近海海域沉积环境在一定程度上已受到了重金属的污染, 除固戍近海外, 大部分海域基本上为II类沉积物, 其污染程度大小顺序为: 固戍近海>深圳湾中>深圳湾口>沙头角湾口。其中沉积物中Cu和Zn超标严重, 固戍近海沉积物中Cu和Zn平均含量分别为128.96mg.kg-1和199.40mg.kg-1, 为III类沉积物。研究还表明, 深圳近海海域基本上不存在重金属潜在的生态危害, 7种重金属潜在的生态危害大小顺序为: Hg>Cd>Cu>As>Pb>Cr>Zn。  相似文献   

10.
Total magnetic intensity and bathymetric surveys were carried out in the offshore area of Ratnagiri on the western continental shelf of India and an isomagnetic anomalies map at a contour interval of 50 nT was prepared which reveals N-S trends of magnetic anomalies. Two-dimensional model and spectral studies of these anomalies were carried out, and subsurface models of the geology in the area have been derived from anomalies at a number of places. The results suggest that the anomalies occur over a magnetic crystalline basement at a depth of 1–1.2 km which is similar (in magnetization) to onshore basalts of northwest India. These anomalies are believed to be an expression of a considerable thickness (around 1.7 km) of basalt, underlain by sediments. Identification of these basalts in offshore areas along the northwestern continental shelf of India would support (1) the idea that the onshore Deccan basalts of western India and the rhyolitic tuffs at the Laccadive ridge system (DSDP Site 210) are related to the same volcanic events, and (2) subsequent downfaulting of onshore Deccan basalts into the Arabian Sea and submergence below the Tertiary sediments.  相似文献   

11.
重矿物组合、含量变化和特征矿物的分布及变化规律是沿海泥沙来源和运移趋势判断的重要手段之一。通过对廉州湾南部海域海底表层沉积物的重矿物分析 ,发现该区重矿物分布以北海地角为界 ,其百分含量和特征矿物南北有别 ,可能分别代表不同的物质来源区。其中廉州湾北部南流江流域来沙是该区主要物源 ,运移趋势为自 NE向 SW;地角西南岸段、岭南侧海岸侵蚀及银滩来沙也为该区提供了部分物源 ,运移趋势为绕过冠头岭沿海岸向 N方向运移。由于缺乏北海陆域陆相地层重矿物含量等相关资料 ,暂未做物质来源区的具体判断  相似文献   

12.
The present paper deals with the distribution patterns of heavy metals and the associated influencing factors in the Yalu River Estuary and its adjacent coastal waters.Based upon the analysis of the surficial and core sediments measurements,the pollution of heavy metal and potential ecological risk were evaluated.The burial flux and contents of heavy metals(except for copper) have been continuously increasing since the 1920s.Therefore,the gross potential ecological risk for the sedi-ments was high or very high,and the study area was endangered by heavy metals contamination.Heavy metals originated mainly from upstream pollutant input,correlation analysis showed that chromium,nickel,zinc,cadmium,lead,arsenic,and mercury in the sediments of the middle and west channels as well as the sea area of the western Yalu River Estuary concentrations were most probably derived from similar sources.In contrast,the metal of copper most probably originated from sources different from the other metals.Preliminary studies indicate that copper contamination was most likely the result of emission from mining activities situated at the upstream of the river.The contents of heavy metals in the sediments of estuarine turbidity maximum zone of Yalu River were larger than those of any other areas in the middle channel.With large portion of fine sediments,weaker hydrodynamics,and richer sources of heavy metals,the sediments of the west channel,were even more enriched with heavy metals than those of the middle channel.  相似文献   

13.
Sedimentary material from coastal and nearshore areas in the Mississippi Delta region are comprised of different organic carbon sources with diverse ages that require isotopic and elemental records for resolving the various sources of plant residues. Carbon isotopic ((13)C, (14)C) values were used to differentiate contributions from plants using the C3, C4, and/or CAM (crassulacean acid metabolism) carbon fixation pathways., and iodine concentrations indicated that wetland plant residues are a significant source of organic carbon in a sediment core from the Mississippi River delta region collected at a 60 m water depth. This sediment core had been extensively described in Oktay et al. [Oktay, S.D., Santschi, P.H., Moran, J.E., Sharma, P., 2000. The (129)Iodine Bomb Pulse Recorded in Mississippi River delta Sediments: Results from Isotopes of I, Pu, Cs, Pb, and C. Geochim. Cosmochim. Acta 64 (6), 989-996.] and significantly, includes unique features that had not previously been seen in the marine environment. These special features include a plutonium isotopic close-in fallout record that indicates a purely terrestrial source for these sediment particles and the elements associated with it, and a distinct iodine isotopic peak (as well as peaks for plutonium and cesium isotopes) that indicate little bioturbation in this core. Our carbon isotopic and iodine data can thus be compared to published records of changes in drainage basin land use, river hydrology, and hydrodynamic sorting of suspended particles to elucidate if these changes are reflected in nearshore sediments. This comparison suggests a significant contribution for organic carbon (OC) from C4 plants to these sediments during the 1950's to early 1960's. Relative older carbon isotopes, and episodically high iodine concentrations (up to 34 ppm) were observed during this time period that (1) indicate sediment deposition that is coincident with the times of major hydrological changes induced from dam and levee building in both the upper and lower reaches of the Mississippi River drainage basin, and (2) suggest episodic organic carbon deposition from wetland plant residues.  相似文献   

14.
报道了厦门西海域拟疏浚沉积物中的重金属含量水平及分布,并对其污染状况进行了潜在生态危害评价,为进一步开展疏浚物去污染技术研究提供了科学依据.研究结果表明:与其他海域的相比,马銮湾及其湾口外、筼筜湖的Cd、Hg、Cr、Zn含量较高.综合来看,厦门西海域拟疏浚沉积物重金属含量不很高(RI<150),属于轻微生态危害.但东渡码头外的X4站、马銮湾M2站沉积物中的Cd,及马銮湾M2站和筼筜湖Y2站沉积物中的Hg含量(40≤Er <80)都达到中等生态危害程度.  相似文献   

15.
Benthic invertebrates have many characteristics which make them prime candidates for burial studies in dredged material. A major concern in dredging and disposal projects is the effect of burial on the survival of benthic invertebrates. The purpose of the research reported in this paper was to determine the ability of estuarine benthos—in particular three species of molluscs (Mercenaria mercenaria, Nucula proxima and Ilyanassa obsoleta)—to migrate vertically in natural and exotic sediments and to determine the survival of benthos when exposed to particular amounts of simulated dredged material.Mortalities generally increased with increased sediment depth, with increased burial time and with overlying sediments whose particle size distribution differed from that of the species native sediment. Temperature affected mortalities and vertical migration. It was concluded that vertical migration is a viable process which can significantly affect rehabilitation of a dredged disposal area. Under certain conditions, vertical migration should be considered, together with larval settling and immigration from outside impacted areas, as a mechanism of recruiting a dredgedump site.  相似文献   

16.
渤海、黄海、东海沉积物中矿物组合的研究   总被引:12,自引:2,他引:12  
本文对黄海、渤海、东海以及长江、黄河、辽河表层沉积物中的轻、重矿物进行了研究。分析资料表明,调查区内共有三种类型的矿物:陆源矿物、自生矿物和海底火山喷发形成的火山型矿物。根据轻、重矿物组合的差异,可把调查区分成8个矿物区。其物质来源主要为黄河与长江。黄河物质主要沉积在黄海、渤海;长江物质沉积在东海陆架区,而冲绳海槽则发现有海底火山喷发物质与浊流沉积。  相似文献   

17.
以盐城海岸带为研究对象,分析了Cr,Cu,Fe,Mn,Ni,V,Zn,Co,Cd 9种重金属元素在二维空间分布的异质性,以及沿着经纬度方向的梯度变化,并通过主成分分析和元素区域背景值的分析,探讨重金属元素的可能来源.结果表明:自陆向海存在着逐渐减少的格局梯度,而在区域的北部分布着重金属元素的峰值;二维分析的结果表明,重...  相似文献   

18.
A heavy mineral (HM) study and light and heavy rare earth elements (LREE and HREE) analysis were performed in coastal and inland dune sands, El Vizcaino Desert, Central Baja California Peninsula, Mexico. Our study shows high abundances of hornblende and apatite in the El Vizcaino dune sands, suggesting a dominance of granodiorites/intermediate plutonic rocks and marine authigenic phosphorite in the dune sands. There is a relationship between unstable heavy minerals like hornblende, pyroxenes, and sphene, and heavy rare earth elements (HREE) that suggests that unstable heavy minerals are potential carriers of HREE in the dune fields. However, there is a slight depletion of HREE in relation to LREE, especially in one locality of the inland dunes probably associated with the wind regime and weathering of unstable heavy minerals in the sands. Inland, transitional, and coastal dune fields can be observed as different dune provinces by means of grouping HM and REE data in two separate dendograms. It seems that HREE are correlated with fine-grained sand sizes and correlated with high CIA values linked to slightly weathered sands.  相似文献   

19.
为加强闽江流域的环境治理以及支撑闽江口重金属污染的管控工作,文章基于闽江口14个采样站位的实测数据,综合运用相关性分析、主成分分析和潜在生态风险指数等方法,系统评价闽江口表层沉积物重金属分布及其潜在生态风险。研究结果表明:闽江口表层沉积物重金属含量差异显著,除个别站位的锌和汞外,其他重金属含量均符合第一类海洋沉积物质量标准;影响铅分布的主要因素是工业排污,影响其他重金属元素分布的主要因素是有机质和沉积环境;闽江口表层沉积物重金属潜在生态风险的低风险程度和中风险程度占比分别为71.43%和28.57%,其中琅岐岛的东部和南部为中风险区,琅岐岛的北部和东北部以及川石水道外侧为低风险区;镉和汞为主要潜在生态风险重金属元素,达到较高风险程度,须加强风险监控。  相似文献   

20.
海洋疏浚工程的环境影响及对策措施   总被引:1,自引:0,他引:1  
以黄骅港航道扩建项目为例,利用二维数值模型模拟分析了航道疏浚产生悬沙对水质的影响,并计算了项目产生悬沙对海洋生态环境的影响。经分析,黄骅港航道扩建项目使约376.1km2的海域水质环境受到悬沙的影响,造成约180t底栖生物、231t浮游动物、1 503t鱼卵和3 757t仔鱼损失。提出了“实现疏浚土的综合利用”、“提高施工效率,缩短施工期限”、“合理安排施工时间”、“对受损的海洋生物进行增殖放流”等措施,以降低航道疏浚工程施工期间对海洋环境的影响。  相似文献   

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