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1.
The Urach volcanic field is unique within the Tertiary–Quaternary European volcanic province (EVP) due to more than 350 tuffaceous
diatremes and only sixteen localities with extremely undersaturated olivine melilitite. We report representative Pb-Sr-Nd
isotopic compositions and incompatible trace element data for twenty-two pristine augite, Cr-diopside, hornblende, and phlogopite
megacryst samples from the diatremes, and seven melilitite whole rocks. The Pb isotopic compositions for melilitites and comagmatic
megacrysts have very radiogenic 206Pb/204Pb ratios of 19.4 to 19.9 and plot on the northern hemisphere mantle reference line (NHRL). The data indicate absence of an
old crustal component as reflected in the high 207Pb/204Pb ratios of many basalts from the EVP. This inference is supported by 206Pb/204Pb ratios of ∼17.6 to 18.3 and ɛNd of ∼−7.8 to +1.6 for five phlogopite xenocryst samples reflecting a distinct and variably rejuvenated lower Hercynian basement.
The 87Sr/86Sr ratios of 0.7033 to 0.7035 in the comagmatic megacrysts are low relative to their moderately radiogenic Nd isotopic compositions
(ɛNd +2.2 to +5.1) and consistent with a long-term source evolution with a low Rb/Sr ratio and depletion in light rare-earth elements
(LREE). The melilitite whole-rock data show a similar range in Nd isotopic ratios as determined for the megacrysts but their
Sr isotopic compositions are often much more radiogenic due to surface alteration. The REE patterns and incompatible trace
element ratios of the melilitites (e.g. Nb/Th, Nb/U, Sr/Nd, P/Nd, Ba/Th, Zr/Hf) are similar to those in ocean island basalts
(OIB); negative anomalies for normalized K and Rb concentrations support a concept of melt evolution in the lithospheric mantle.
Highly variable Ce/Pb ratios of 29 to 66 are positively correlated with La/Lu, La/K2O, and Ba/Nd and interpreted to reflect melting in the presence of residual amphibole and phlogopite. The data suggest an
origin of the melilitites from a chemical boundary layer very recently enriched by melts from old OIB sources. We suggest
that the OIB-like mantle domains represent low-temperature melting heterogeneities in an upwelling asthenosphere under western
Europe.
Received: 9 March 1995/Accepted: 24 July 1995 相似文献
2.
Petrology and geochemistry of potassic and ultrapotassic volcanism in central Italy: petrogenesis and inferences on the evolution of the mantle sources 总被引：15，自引：0，他引：15
Major, trace element, Sr isotopic and mineral chemical data are reported for mafic volcanic rocks (Mg-value 65) from the northern-central sector of the potassic volcanic belt of Central Italy. The rocks investigated range from potassic series (KS) and high-K series (HKS) to lamproitic (LMP) and kamafugitic (KAM) through a transitional series (TRANS), thus covering the entire compositional spectrum of potassic and ultrapotassic magmas. KAM rocks are strongly silica undersaturated and, compared with the other rock series, have low SiO2, Al2O3, Na2O, Sc and V and high CaO, K/Na, (Na + K)/Al. KS and HKS have high Al2O3, CaO and variable enrichment in K2O and incompatible elements. LMP rocks are saturated in silica and have high SiO2, K2O, K2O/Na2, MgO, Ni and Cr and low Al2O3, CaO, Na2O, Sc and V. TRANS rocks display intermediate compositional characteristics between LMP and KS.
All the rocks under study have fractionated hygromagmaphile element patterns with high LIL/HFS element values and negative anomalies of Ti, Ta, Nb and Ba. Negative Sr anomalies are observed in the LMP and TRANS rocks. LIL elements show overall positive correlations with K2O, whereas different trends of Sr and HFSE vs. K2O are defined by LMP-TRANS and KS-HKS-KAM. 87Sr/86Sr range from about 0.710 to 0.716. KS, HKS and KAM rocks have similar 87Sr/86Sr values clustering around 0.710. LMP and TRANS rocks have the highest 87Sr/86Sr values.
Geochemical and isotopic data reported for the most primitive Italian potassic and ultrapotassic rocks support the hypothesis that the interaction between crustal and mantle reservoirs was a main process in the genesis of Italian potassic magmatism. Simple mass balance calculations exclude, however, an important role of crustal assimilation during ascent of subcrustal magmas to the surface and indicate that the sources of Central Italy volcanics underwent contamination with fluids and/or melts released by upper crustal material previously brought into the mantle by subduction processes.
Different trends of incompatible elements vs. K2O observed in the studied rocks suggest distinct metasomatic processes for the sources of the investigated magmas. Liquids derived by bulk melting of pelitic sediments are believed to be the most likely contaminants of the source of LMP rocks. Fluids or melts rich in Ca, Sr and with high LILE/HFSE value and Sr isotopic composition around 0.710 are the most likely contaminant of the source region of KS, HKS and KAM volcanics. Variations in CaO, Na2O and ferromagnesian element abundances and ratios suggest that, in some zones, the mantle source of potassic magmas experienced partial melting with extraction of basaltic liquids prior to metasomatism. 相似文献
3.
Major, trace element and radiogenic isotope results are presented for a suite of hypabyssal kimberlites from a single pipe, at the Finsch Mine, South Africa. These are Group 2 kimberlites characterised by abundant phlogopite ± serpentine ± diopside; they are ultrabasic (SiO2 < 42 wt.%%) and ultrapotassic (K2O/Na2O > 6.9) igneous rocks, they exhibit a wide range in major element chemistry with SiO2 = 27.6−41.9 wt. % and MgO = 10.4−33.4 wt. %. (87Sr/86Sr)i=0.7089 to 0.7106, εNd is −6.2 to −9.7 and they have unradiogenic (207Pb/204Pb)i contents which ensure that they plot below the Pb-ore growth curve. They have high incompatible and compatible element contents, a striking positive array between Y and Nb which indicates that garnet was not involved in the within suite differentiation processes, and a negative trend between K/Nb and Nb contents which suggests that phlogopite was involved. In addition, some elements exhibit an unexpected order of relative incompatibility for different trace elements which suggests that the intra-kimberlite variations are not primarily due to variations in the degree of partial melting. The effects of fractional crystallization are difficult to establish because for the most part they have been masked by the entrainment of 50–60% mantle peridotite. Thus, the Finsch kimberlites are interpreted as mixtures of a melt component and entrained garnet peridotite, with no evidence for significant contamination with crustal material. The melt component was characterised by high incompatible element contents, which require both very small degrees of partial melting, and source regions with higher incompatible element contents than depleted or primitive mantle. Since the melt component was the principal source of incompatible elements in the kimberlite magma, the enriched Nd, Sr and Pb isotope ratios of the kimberlite are characteristic of the melt source region. The melt fractions were therefore derived from ancient, trace elements enriched portions of the upper mantle, most probably situated within the sub-continental mantle lithosphere, and different from the low 87Sr/86Sr garnet peridotite xenoliths found at Finsch. Within the sub-continental mantle lithosphere old, incompatible element enriched source regions for the kimberlite melt fraction are inferred to have been overlain by depleted mantle material which became entrained in the kimberlite magma. 相似文献
4.
Isotopic characteristics of potassic rocks: evidence for the involvement of subducted sediments in magma genesis 总被引：23，自引：0，他引：23
David R. Nelson 《Lithos》1992,28(3-6):403-420
The potassic igneous rock suite (with molar K2O/Na2O > 1) can be divided into an “orogenic” subgroup that occur in subduction-related tectonic settings and an “anorogenic” sub-group that are confined to stable continental settings. Representatives of both sub-groups possess trace element and isotopic features consistent with the contamination of their magma sources by incompatible element rich and isotopically evolved “metasomatic” components. It is argued here that these metasomatic components are principally derived from subducted lithosphere, including subducted sediments. Most examples of orogenic potassic magmatism (e.g. Italian potassic rocks, Spanish lamproites, Sunda arc leucitites) have trace-element and Sr, Nd and Pb isotopic characteristics consistent with the contamination of their mantle sources by a component derived from marine sediments. Anorogenic sub-group potassic magmas have generally similar incompatible trace element and Sr and Nd isotopic characteristics to those of orogenic potassic magmas, but many examples have unusual Pb isotopic compositions with unradiogenic 206Pb/204Pb. Modern marine sediments characteristically have low U/Pb ratios and the unradiogenic 206Pb/204Pb of anorogenic potassic magmas may have evolved during long-term storage of subducted sediments (or components derived from them) within the subcontinental lithosphere. These unusual Pb isotopic compositions require substantial time periods (> 1 Ga) to have elapsed between the fractionation events lowering the U/Pb ratio (i.e. erosion and sedimentation at the Earth's surface) and subsequent potassic magmatism and it is therefore not surprising that most examples of anorogenic potassic magmatism are not associated with recent subduction processes. Although the eruption of potassic magmas is commonly related to rifting or hotspot activity, these processes do not necessarily play an important role in the genesis of the unusual sources from which potassic magmas are derived. 相似文献
5.
The overwhelming part of the continental crust in the high-grade part of the Damara orogen of Namibia consists of S-type granites, metasedimentary rocks and migmatites. At Oetmoed (central Damara orogen) two different S-type granites occur. Their negative εNd values (− 3.3 to − 5.9), moderately high initial 87Sr/86Sr ratios (0.714–0.731), moderately high 206Pb/204Pb (18.21–18.70) and 208Pb/204Pb (37.74–37.89) isotope ratios suggest that they originated by melting of mainly mid-Proterozoic metasedimentary material. Metasedimentary country rocks have initial εNd of − 4.2 to − 5.6, initial 87Sr/86Sr of 0.718–0.725, 206Pb/204Pb ratios of 18.32–18.69 and 208Pb/204Pb ratios of 37.91–38.45 compatible with their variation in Rb/Sr, U/Pb and Th/Pb ratios. Some migmatites and residual metasedimentary xenoliths tend to have more variable εNd values (initial εNd: − 4.2 to − 7.1), initial Sr isotope ratios (87Sr/86Sr: 0.708–0.735) and less radiogenic 206Pb/204Pb (18.22–18.53) and 208Pb/204Pb (37.78–38.10) isotope compositions than the metasedimentary rocks. On a Rb–Sr isochron plot the metasedimentary rocks and various migmatites plot on a straight line that corresponds to an age of c. 550 Ma which is interpreted to indicate major fractionation of the Rb–Sr system at that time. However, initial 87Sr/86Sr ratios of the melanosomes of the stromatic migmatites (calculated for their U–Pb monazite and Sm–Nd garnet ages of c. 510 Ma) are more radiogenic (87Sr/86Sr: 0.725) than those obtained on their corresponding leucosomes (87Sr/86Sr: 0.718) implying disequilibrium conditions during migmatization that have not lead to complete homogenization of the Rb–Sr system. However, the leucosomes have similar Nd isotope characteristics than the inferred residues (melanosomes) indicating the robustness of the Sm–Nd isotope system during high-grade metamorphism and melting. On a Rb–Sr isochron plot residual metasedimentary xenoliths show residual slopes of c. 66 Ma (calculated for an U–Pb monazite age of 470 Ma) again indicating major fractionation of Rb/Sr at c. 540 Ma. However, at 540 Ma, these xenoliths have unradiogenic Sr isotope compositions of c. 0.7052, indicating depleted metasedimentary sources at depth. Based on the distinct Pb isotope composition of the metasedimentary rocks and S-type granites, metasedimentary rocks similar to the country rocks are unlikely sources for the S-type granites. Moreover, a combination of Sr, Nd, Pb and O isotopes favours a three-component mixing model (metasedimentary rocks, altered volcanogenic material, meta-igneous crust) that may explain the isotopic variabilty of the granites. The mid-crustal origin of the different types of granite emphasises the importance of recycling and reprocessing of pre-existing differentiated material and precludes a direct mantle contribution during the petrogenesis of the orogenic granites in the central Damara orogen of Namibia. 相似文献
6.
The paper describes olivine melilitites at Oldoinyo Lengai, Tanzania, and from tuff cones from the Tanzanian rift valley in the vicinity of Oldoinyo Lengai. Oldoinyo Lengai is the only active carbonatite volcano and is distinguished by its alkali-rich natrocarbonatites. Lengai is also unique for its extreme peralkaline silicate lavas related directly to the natrocarbonatites. Primitive olivine melilitites are, according to their Mg# and Ni, Cr contents, the only candidates in the Lengai area for primary melt compositions. Incompatible trace elements, including REE, constrain the melting process in their sub-lithospheric sources to very low degrees of partial melting in the garnet stability field. The strong peralkaline trend at Oldoinyo Lengai is already recognisable in these primary or near-primary melts. More evolved olivine melilitites, with Mg# < 60 allow the fractionation line in its major and trace element expressions to be followed. Nevertheless, a large compositional gap separates the olivine melilitites and olivine-poorer melilitites from the phonolites and nephelinites that form the bulk of the Lengai cone. These silicate lavas show a high degree of peralkalinity and are highly evolved with very low Mg, Ni and Cr. Prominent examples of the recent evolution are the combeite–wollastonite nephelinites that are unique for Lengai. In their Sr, Nd, and Pb isotope relationships the olivine melilitites define a distinct group with the most depleted Sr and Nd ratios and the most radiogenic Pb isotopes. They are closest to a supposed HIMU end member of the Lengai evolution, which is characterised by an extreme spread in isotopic ratios, explained as a mixing line between HIMU and EM1-like mantle components. 相似文献
7.
Geochemical constraints on the origin of Mesozoic alkaline intrusive complexes from the North China Craton and tectonic implications 总被引：28，自引：0，他引：28
Mesozoic alkaline intrusive complexes are widespread in the southern portion of the North China Craton and can provide some important constraints on the evolution of the Mesozoic lithosphere beneath the region. Three selected intrusive complexes (Tongshi, Hongshan, and Longbaoshan) are generally high in alkalis (K2O+Na2O=913 wt.%) and Al2O3 (1421.6 wt.%) and low in CaO and TiO2 (<0.6 wt.%), with high and variable SiO2 contents. Rocks from these complexes are all enriched in LREE and LILE (Cs, Rb, Ba, U, Th), depleted in Nb and Ti, have a highly positive Pb anomaly, and are characterized by lack of a clear Eu anomaly despite trace element abundances and isotopic ratios that vary greatly between complexes. The Tongshi complex has high Cs (2.68.5 ppm) and REE abundances (∑REE=112.6297 ppm, (La/Yb)N=13.130.9) and MORB-like Sr–Nd–Pb isotopic ratios ((87Sr/86Sr)i<0.704; εNd>0; (206Pb/204Pb)i>18). The Hongshan complex has low REE concentrations (∑REE=28.2118.7 ppm, (La/Yb)N=4.614.7) and is moderately enriched as demonstrated by their Sr–Nd isotopic ratios ((87Sr/86Sr)i>0.706; εNd<−7). The Longbaoshan complex is extremely REE enriched (∑REE=211.3392.6 ppm, (La/Yb)N=32.460.9) and has an EM2-like Sr–Nd isotopic character ((87Sr/86Sr)i>0.7078; εNd<−11). We suggest that the Tongshi complex originated from the asthenosphere and the Hongshan complex and the Longbaoshan complex were derived from the partial melting of previously subduction-modified lithospheric mantle, in response to post-collisional lithospheric extension and asthenospheric upwelling. The occurrence of these alkaline intrusive complexes demonstrates that the lithosphere beneath the region must have been considerably thinned at the time of intrusion of these complexes. This study also shed light on the temporal evolution of the Mesozoic lithosphere and the timing of the lithospheric thinning. 相似文献
8.
甘肃西秦岭地区存在钾霞橄黄长岩和钾质粗面玄武岩(钾玄岩)两类钾质火山岩,出露在甘肃西秦岭礼县、宕昌县等,地理坐标大致相当于104°20′～104°50′E,33°30′～34°10′N。钾霞橄黄长岩是一种不含斜长石,但普遍含有高钛金云母、黄长石、白榴石、霞石的岩石,全岩化学成分具低SiO2和Al2O3,富TiO2、CaO、MgO和高K/Na、高Mg#值的特征;钾质粗面玄武岩(钾玄岩)含有大量斜长石但是缺乏高钛金云母、黄长石、白榴石和霞石,全岩化学中SiO2、Al2O3明显高于前者,而TiO2、CaO、MgO、K/Na和Mg#值要比钾霞橄黄长岩低。钾霞橄黄长岩的全岩K/Ar和金云母单矿物的39Ar/40Ar同位素定年落在7.1～23Ma,而钾玄岩的全岩39Ar/40Ar同位素定年落在9Ma左右,因此它们同为中新世产物。两类钾质火山岩具有相似的富集不相容元素和轻稀土的特征。两类钾质火山岩的初始87Sr/86Sr分别在0.70403～0.70749和0.70412～0.70522;143Nd/144Nd分别在0.51274～0.51294和0.51265～0.51276;εNd分别在1.12～5.95和0.3～2.3。206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别落到18.3746～18.9986、15.529～15.6693和38.4971～39.4144。在火山岩源区示踪的143Nd/144Nd-87Sr/86Sr,207Pb/204Pb-206Pb/204Pb,208Pb/204Pb-206Pb/204Pb,143Nd/144Nd-206Pb/204Pb,87Sr/86Sr-206Pb/204Pb和Ba/Nb-La/Nb图解中,一致显示两类钾质火山岩具有与OIB相似的地球化学特征,源区可能与地幔柱有关,并具有EM1、DMM和HIMU端员混合特征。结合前人对该区深部地球物理和断裂构造的研究,论证了火山岩的起源与成因,指出作为对印度—欧亚大陆强烈碰撞的吸收与调节,高原下软流圈地幔流沿400km界面向北东方向的侧向流动以及西秦岭周边克拉通块体的阻挡,是形成西秦岭断裂系左行走滑特征和巨大拉分盆地的主要原因,也是导致西秦岭新生代两类钾质火山岩和碳酸岩起源与成因的动力学机制,较好地解释了西秦岭新生代岩浆作用起源深度大,具有地幔柱源的地球化学特征,岩石组合与地球化学有别于高原内部及其周边地区新生代钾质火山岩的原因。 相似文献
9.
M. Tichomirowa G. Grosche J. Gtze B.V. Belyatsky E.V. Savva J. Keller W. Todt 《Lithos》2006,91(1-4):229-249
We investigated the isotope composition (O, C, Sr, Nd, Pb) in mineral separates of the two Precambrian carbonatite complexes Tiksheozero (1.98 Ga) and Siilinjärvi (2.61 Ga) from the Karelian–Kola region in order to obtain information on Precambrian mantle heterogeneity. All isotope systems yield a large range of variations. The combination of cathodoluminescence imaging with stable and radiogenic isotopes on the same samples and mineral separates indicates various processes that caused shifts in isotope systems. Primary isotope signatures are preserved in most calcites (O, C, Sr, Pb), apatites (O, Sr, Nd), amphiboles (O), magnetites (O), and whole rocks (Sr, Nd).
The primary igneous C and O isotope composition is different for both complexes (Tiksheozero: δ13C = − 5.0‰, δ18O = 6.9‰; Siilinjärvi: δ13C = − 3.7‰, δ18O = 7.4‰) but very uniform and requires homogenization of both carbon and oxygen in the carbonatite melt. The lowest Sr isotope ratios of our carbonates and apatites from the Archaean Siilinjärvi (0.70137) and the Palaeoproterozoic Tiksheozero (0.70228) complexes are in the range of bulk silicate earth (BSE). Positive εNd values of the two carbonatites point to very early Archaean enrichment of Sm/Nd in the Fennoscandian mantle. No HIMU components could be detected in the two complexes, whereas Tiksheozero carbonatites give the first indication of Palaeoproterozoic U depletion for Fennoscandia.
Sub-solidus exchange processes with water during emplacement and cooling of carbonatites caused an increase in the oxygen isotope composition of some carbonates and probably also an increase of their 87Sr/86Sr ratio. A larger increase of initial Sr isotope ratios was found in carbonatized silicic rocks compared to carbonatite bodies. The Svecofennian metamorphic overprint (1.9–1.7 Ga) caused reset of Rb/Sr (mainly mica) and Pb/Pb (mainly apatite) isochron systems. 相似文献
10.
The Tabar–Lihir–Tanga–Feni (TLTF) volcanic island chain occurs in a zone of lithospheric extension superimposed on a post-collisonal tectonic setting along the Pacific and Indo-Australian plates northeast of Papua New Guinea. We present geochemical and Sr, Nd, and Pb isotope data for volcanic rocks from these islands and three recently discovered seamounts located at Lihir island. Major element data document an alkalic affinity of the sample suite and trachybasalts as the predominant rock type. Negative Nb-anomalies in extended trace element patterns, enrichment of the light rare earth elements, and Ce/Pb ratios of about 4 are typical of the values in calc alkaline island arc volcanics and support an origin from subduction-modified mantle. 87Sr/86Sr ratios of 0.7037 to 0.7044 and Nd values of +5.6 to +6.8 indicate that the upper mantle evolved with a time-integrated depletion in LREE, however, not as severe as that recorded in basalts from the East Pacific Rise. Variable 87Sr/86Sr ratios at less variable 143Nd/144Nd ratios suggest that 87Sr/86Sr ratios of the melts were modified by secondary processes, such as assimilation of seawater Sr from crustal rocks. The Pb isotope ratios are uniform, moderately radiogenic (206Pb/204Pb ca. 18.7 to 18.8), and similar to those reported for the active Mariana arc. Elevated 207Pb/204Pb ratios relative to Pacific MORB suggest melting of small amounts of subducted sediments (ca. 1–2 wt.%). An important control of subducted sediment on the chemistry of the melts can also be inferred from the ratios of highly incompatible trace elements (e.g., Th, U, Pb, La, and Nb). Additional mantle enrichment by subduction derived fluids is reflected in high values of highly incompatible trace element ratios between fluid mobile (e.g., Ba) and fluid immobile elements (e.g., Th, Nb). The results of this study document that the chemical composition of igneous rocks from post-collisional tectonic settings are strongly influenced by previous plate tectonics. This conclusion implies that the information conveyed by tectonic discrimination diagrams for these rocks must be interpreted with care. 相似文献
11.
亏损上地幔中的富钾熔体和碳酸盐交代作用:来自CCSD预先导孔橄榄岩的地球化学证据 总被引：1，自引：0，他引：1
中国大陆科学钻探工程预先导孔(CCSD-PP1) 打在苏鲁超高压变质带芝麻坊超镁铁岩体上,钻孔穿透超镁铁岩体115m.超镁铁岩体由二辉橄榄岩、方辉橄榄岩和少量单辉橄榄岩和纯橄岩组成,与上下围岩接触的橄榄岩被强烈蛇纹石化.多数橄榄岩含有石榴石或其假象,普遍含有金云母和菱镁矿,少量样品中有钛斜硅镁石.在化学成分上,橄榄岩的Mg#指数变化于90.392.6之间,MgO含量(36.61%49.15%,平均45.17%) 与Na2O (0.01%0.25%)、Al2O3 (0.07%3.71%,多数 < 2.0%,平均1.46%)和CaO (0.12%2.53%,一个高达3.30%,平均1.00%) 呈负相关关系.与主量易熔元素相对亏损的特点相反,橄榄岩中显示了稀土元素富集、分馏和配分曲线显示近于平行和相似的特点,(La/Lu) N比值为3.1833.05;此外,多数样品具有高Ba (最高比原始地幔高100多倍) 含量,在蛛网图上显示Rb、Nb、Ta、Zr、Hf和Sr的负异常,Ti/Eu比值均低于1300.岩相学特征和难熔主量元素与不相容元素之间的无相关性表明橄榄岩至少受到了形成金云母和菱镁矿的2次交代作用.富含金云母的橄榄岩(例如C25-143-61,C32-149-71) 具有富钾趋势,并且显示K2O与Rb、Ba和Th等大离子亲石元素的正相关关系,未见K2O和稀土元素、Sr和Ca之间的相关关系.这些特征表明橄榄岩被含水、硅铝质碱性熔体交代,之后又被高Ba低Rb和高场强元素的镁质(菱镁矿) 碳酸岩熔体交代,并且强烈地改变了Ba的丰度和显示了特定地幔碳酸盐的稀土元素配分型式.全岩具有不均一的高放射性Sr (87Sr/86Sr=0.70840.7201)和低放射性Nd (εNd (t) =-1.14-8.55) 组成,结合已有的氧同位素研究资料,表明预先导孔PP1中的橄榄岩所代表的地幔可能在早期就遭受了来自深部的介质的交代作用. 相似文献
12.
The Erlangmiao granite intrusion is located in the eastern part of the East Qinling Orogen.The granite contains almost 99 vol.％ felsic minerals with accessory garnet,muscovite,biotite,zircon,and Fe-Ti ... 相似文献
13.
In the Kakkaponnu area within the Achankovil Shear Zone (ACSZ), southern India, an undeformed ultramafic body occurs within intensely deformed granulite facies metamorphic rocks of Pan-African age. The Kakkaponnu ultramafic body is composed of spinel-dunite, phlogopite-dunite, glimmerite, graphite-spinel-glimmerite, and phlogopite-graphite-spinellite. The spinel-dunite is a fine- to medium-grained rock composed mainly of olivine and aluminous spinel and is characterized by relatively high MgO (50.39–50.90 wt.%), (Mg/ (Mg+Fe) = 0.95), Al2O3 (7.8–8.98 wt.%), and low Ni (10–14 ppm). The phlogopite-dunite comprises serpentinized olivine, phlogopite and subordinate amounts of dolomite and is high in MgO (36.5 wt.%), Mg# [(Mg/(Mg+Fe) = 0.97], and K2O (%%5.5 wt.%). Olivine in the spinel-dunite is marked by unusually high MgO (Mg# = 0.96) and extremely low NiO (<0.14 wt.%). Spinels in all rock variants are highly aluminous with low Cr# [Cr/(Al+Cr)] ratio (<0.01). Magnesian ilmenite [Mg# = 59], rutile, zirconolite and baddeleyite are main accessory phases. No significant compositional variation is noted between large grains and small inclusions for all minerals. Abundant graphite, magnesite, melt and ubiquitous CO2 fluid inclusions are identified in the olivine and spinel grains. The data imply that the Kakkaponnu ultramafic body was formed by progressive crystallization of highly potassic CO2-rich melts injected into lower crustal levels. K-Ar ages of 470.5±9.3 and 464.5±9.2 Ma are obtained for phlogopite separates from glimmerite and phlogopite-dunite respectively. These ages are comparable to the phlogopite K-Ar ages reported from lithospheric shear zones in southern Madagascar, which was once conjugated to the Southern Peninsular India prior to the Gondwana breakup. This implies widespread highly potassic CO2-rich fluid/melt influx along shear zones in this part of East Gondwana continent. 相似文献
14.
Takeshi Hanyu Laure Dosso Osamu Ishizuka Kenichiro Tani Barry B. Hanan Claudia Adam Shun’ichi Nakai Ryoko Senda Qing Chang Yoshiyuki Tatsumi 《Contributions to Mineralogy and Petrology》2013,166(5):1285-1304
We present the first report of geochemical data for submarine basalts collected by a manned submersible from Rurutu, Tubuai, and Raivavae in the Austral Islands in the South Pacific, where subaerial basalts exhibit HIMU isotopic signatures with highly radiogenic Pb isotopic compositions. With the exception of one sample from Tubuai, the 40Ar/39Ar ages of the submarine basalts show no significant age gaps between the submarine and subaerial basalts, and the major element compositions are indistinguishable at each island. However, the variations in Pb, Sr, Nd, and Hf isotopic compositions in the submarine basalts are much larger than those previously reported in subaerial basalts. The submarine basalts with less-radiogenic Pb and radiogenic Nd and Hf isotopic compositions show systematically lower concentrations in highly incompatible elements than the typical HIMU basalts. These geochemical variations are best explained by a two-component mixing process in which the depleted asthenospheric mantle was entrained by the mantle plume from the HIMU reservoir during its upwelling, and the melts from the HIMU reservoir and depleted asthenospheric mantle were then mixed in various proportions. The present and compiled data demonstrate that the HIMU reservoir has a uniquely low 176Hf/177Hf decoupled from 143Nd/144Nd, suggesting that it was derived from an ancient subducted slab. Moreover, the Nd/Hf ratios of the HIMU basalts and curvilinear Nd–Hf isotopic mixing trend require higher Nd/Hf ratios for the melt from the HIMU reservoir than that from the depleted mantle component. Such elevated Nd/Hf ratios could reflect source enrichment by a subducted slab during reservoir formation. 相似文献
15.
碳酸岩Sr、Nd、Pb 同位素地球化学研究评述 总被引：3，自引：0，他引：3
碳酸岩是出露相对较少的幔源岩石，其中Sr与Nd是研究地幔物质组成的主要对象之一。本文统计了世界上主要碳酸岩的锶、钕、铅同位素组成特征；研究显示，碳酸岩源区主要是洋岛玄武岩高U／Pb的HIMU端员和富集端员(EM1或EM2)的混合作用；此外大部分碳酸岩的锶、钕同位素落在大洋玄武岩范围内；这些均表明其成因与地慢柱有密切联系。碳酸岩及与之共生的硅酸岩的同源或独立源区模式部很难充分解释两者同位素组成特征，逭反映碳酸岩的演化模式涉及更复杂的过程。可能是俯冲作用使碳酸岩源区经历不同时间和程度的富集、亏损过程导致地幔源区成分不均一。 相似文献
16.
Chantal Alibert Annie Michard Francis Albarde 《Geochimica et cosmochimica acta》1986,50(12):2735-2750
Basalts from the San Francisco Peaks and North Rim of Grand Canyon, nephelinites from the Hopi Buttes and Navajo minettes (Colorado Plateau) have been analyzed for trace element contents and Sr, Nd, Pb isotope compositions. The ages increase eastward from the Quaternary (basalt) to 5 Ma (nephelinite) and 30 Ma (minette) as does the depth of melt generation inferred from xenolith mineralogy and major element geochemistry.
The three rock types present an enrichment of incompatible elements (although minettes present negative concentration spikes for Nb, Zr, Ti, Ba, Sr) relative to other magma types. The chondrite-normalized Ce/Yb ratio changes from 8–22 (basalt) to 25–30 (nephelinite) and 33–60 (minette) and reflects small degrees of partial melting of a mantle source with a garnet/clinopyroxene ratio increasing with depth. The negative Eu anomaly present in minette, the low Sr/Nd and high Pb/Ce suggest the presence of a recycled continental crust component in their mantle source.
The 87Sr/86Sr ratio varies from 0.7032-0.7045 (basalt and nephelinite) to 0.7052-0.7071 (minette), while εNd is remarkably more constant at +0.8 to +3.7 (nephelinite) and −2.6 to +2.2 (basalt and minette). Good linear correlations are observed in both 207Pb/204Pb and 208Pb/204Pb vs. 206Pb/204Pb diagrams with basalt being the least and nephelinite the most radiogenic and indicate a 2.3 ±0.1 Ga age and a Th/U of 3.4.
Three lithospheric source components are indicated: a) an OIB-type depleted mantle source, b) an end-member with unradiogenic Sr, Nd and Pb for basalt and nephelinite and c) a recycled crustal component for minette. 相似文献
17.
M. Schilling R.V. Conceio G. Mallmann E. Koester K. Kawashita F. Herv D. Morata A. Motoki 《Lithos》2005,82(3-4):485-502
Cerro Redondo is an ancient cinder cone now almost completely eroded, sited over a sill that corresponds to a sub-volcanic magma chamber, in Santa Cruz province, Patagonia, Argentina. It is composed of Pliocene-Pleistocene alkaline basalt containing spinel-facies lherzolite and harzburgite mantle xenoliths. Core compositions of pyroxenes indicate temperatures of 823 °C to 1043 °C and pressures of 12.4 kb to 21.4 kb. Based on P–T estimates, petrographic, geochemical, and isotopic characteristics, we propose that Cerro Redondo xenoliths come from a thick homogeneous mantle column (36 km to 63 km depth), and present different degrees of basalt infiltration. A simple mixing model based on Sr isotopes was used to quantify the host basalt infiltration, and contamination values of 0.0%, 0.2%, 3%, and 12% were obtained for samples X-F, X-D, X-C, and X-B, respectively. For unknown reasons, samples X-G and X-E suffered selective isotopic and trace element modification, respectively, associated with 1% of basalt infiltration. Sample X-F best represents the sub-continental lithospheric mantle column, conserving primary equilibrium textures with sharp grain boundaries, and having TiO2, CaO, Na2O, K2O, and P2O5 contents lower than average spinel lherzolite, flat chondrite-normalized REE pattern, and 87Sr/86Sr and 143Nd/144Nd ratios of 0.70519 and 0.51297, respectively. This sample records a decoupling of the Sr–Nd system where Sr ratios increase at constant Nd ratios, possibly caused by chromatographic processes. Its 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios are 17.987, 15.556, and 37.959, respectively. As the interaction with the host basalt increases, xenoliths show a gradual increase of disequilibrium textures such as reaction rims and exsolution lamellae in orthopyroxene and clinopyroxene, and increase of TiO2, CaO, Al2O3, Na2O, K2O, P2O5, LREE, and incompatible element concentrations. The Sr–Nd system shows an unusual positive trend from the unmodified sample X-F toward the host basalt isotope composition with 87Sr/86Sr and 143Nd/144Nd ratios of 0.70447 and 0.51279, respectively, while 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios tend to increase toward those of the host basalt (18.424, 15.648, and 38.728, respectively) as the xenolith–basalt interaction increases. The basalt–xenolith reaction probably started during the transport of the xenoliths to the surface, and continued during the residence of xenoliths in the sub-volcanic magma chamber of Cerro Redondo. 相似文献
18.
冈底斯成矿带内的岩浆岩是印度板块与欧亚板块碰撞造山的产物,更是研究碰撞造山与成矿作用的理想对象。多仁则—桑阿卡地区位于冈底斯火山-岩浆弧中段中南部,区内含矿岩体为灰白色中细粒黑云母花岗闪长岩。LA-ICP-MS锆石U-Pb测年、岩石地球化学和Sr-Nd同位素研究表明：岩体就位年龄为（49.0±0.7）Ma,其形成时代为始新世;岩石具有高硅（w（SiO2）为67.13%）、高钾（w（K2O）为3.72%）、富碱（w（K2O+Na2O）为7.48%）、贫MgO（w（MgO）为1.34%,小于3%）的特征,为高钾钙碱性系列的高分异I型花岗岩;Eu负异常（δEu为0.70）和Sr的亏损暗示岩浆发生斜长石的分离结晶作用;岩石的微量元素表现出Th、U、K、Nd、Zr、Hf富集和Nb、Ta、Sr、Ti、P亏损的特征;全岩Sr-Nd同位素（（87Sr/86Sr）i为0.705 280~0.705 530、εNd（t）为-2.2~-1.6）、微量元素及元素比值揭示岩浆源区是壳幔混源,是在印度板块与欧亚板块俯冲-碰撞后板片断离构造背景下,热的软流圈地幔物质通过板片断离窗上涌,并诱发下地壳部分熔融,形成该地区壳幔混源岩浆-热液成矿作用。综合研究认为,多仁则—桑阿卡地区斑岩型-热液型铜多金属成矿作用是早始新世岩浆活动大爆发滞后的成矿响应,是与冈底斯成矿带内的壳幔花岗岩有关的Cu-Au-Mo-Fe-Pb-Zn成矿系统（52~47 Ma）的重要组成部分。 相似文献
19.
The nature of the sub-continental mantle: constraints from the major-element composition of continental flood basalts 总被引：1，自引：0，他引：1
Many continental flood basalts (CFB) have isotope and trace-element signatures that differ from those of oceanic basalts and much interest concerns the extent to which these reflect differences in their upper mantle source regions. A review of selected data sets from the Mesozoic and Tertiary CFB confirms significant differences in their major- and trace-element compositions compared with those of basalts erupted through oceanic lithosphere. In general, those CFB suites characterised by low Nb/La, high (87Sr/86Sr)i and low εNdi tend to exhibit relatively low TiO2, CaO/Al2O3, Na2O and/or Fe2O3, and relatively high SiO2. In contrast, those which have high Nb/La, low (87Sr/86Sr)i and high εNdi ratios, like the upper units in the Deccan Traps, have major- and trace-element compositions similar to oceanic basalts. It would appear that those CFB that have distinctive isotope and trace-element ratios also exhibit distinctive major-element contents, suggesting that major and trace elements have not been decoupled significantly during magma generation and differentiation.
When compared (at 8% MgO) with oceanic basalt trends, the displacement of many CFB to lower Na2O, Fe2O3*, TiO2 and CaO/Al2O3, but higher SiO2, at similar Mg#, is not readily explicable by crustal contamination. Rather, it reflects source composition and/or the effects of the melting processes. The model compositions of melts produced by decompression of mantle plumes beneath continental lithosphere have relatively low SiO2 and high Fe2O3*. In contrast, the available experimental data indicate that partial melts of peridotite have low TiO2, Na2O and Fe2O3*CaO/Al2O3, if the peridotite has been previously depleted by melt extraction. Moreover, melting of hydrated, depleted peridotite yields SiO2-rich, Fe2O3- and CaO-poor melts. Since anhydrous, depleted peridotite has a high-temperature solidus, it is argued that the source of these CFB was variably melt depleted and hydrated mantle, inferred to be within the lithosphere. Isotope data suggest these source regions were often old and relatively enriched in incompatible trace elements, and it is envisaged that H2O±CO2 were added at the same time as the incompatible elements. An implication is that a significant proportion of the new continental crust generated since the Permian reflected multistage processes involving mobilization of continental mantle lithosphere that was enriched in minor and trace elements during the Proterozoic. 相似文献
20.
Origin of lamprophyres by the mixing of basic and alkaline melts in magma chamber in Beiya area, western Yunnan, China 总被引：6，自引：0，他引：6
Lamprophyres consisting mainly of diopside, phlogopite and K-feldspar formed in the early Tertiary around 60 Ma in the Beiya area and are characterized by low SiO2 ± 46–50 wt.%), Rb (31–45 ppm) and Sr (225–262 ppm), high Al2O3, (11.2–13.1 wt.%), CaO (8.0–8.7 wt.%), MgO (11.5–12.1 wt.%), K2O(4.9–5.5 wt.%), TiO2 (2.9–3.3 wt.%) and REE (174–177 ppm), and compatible elements (e.g. Sc, Cr and Ni) and HSF elements (e.g. Th, U, Zr, Nb, Ta, Ti and Y), and low 143Nd/144Nd 0.512372–0.512536, middle 87Sr/86Sr 0.707322–0.707395, middle 206Pb/204Pb 18.50–18.59, 207Pb/204Pb 15.60–15.65 and 208Pb/204Pb 38.75–38.8. These rocks developed peculiar quartz megacrysts with poly-layer reaction zones, melt inclusions, and partial melted K-feldspar and plagioclase inclusions, and plastic shapes. Important features of these rocks include: (1) hybrid composition of elements, (2) abrupt increase of SiO2 content of the melt, recorded by zoned diopside, (3) development of sanidine and aegirine-augite reaction zones, (4) alkaline melt and partial melted K-feldspar and plagioclase inclusions, (5) deformed quartz inclusions associated with quartz megacrysts, (6) the presence of quartz megacrysts in plastic shape with their parent melts, (7) the occurrence of olivine, high-MgO ilmenite and spinel inclusions within earlier formed diopside, phlogopite and magnetite. Median 87Sr/86Sr values between Tertiary alkaline porphyries in the Beiya area and the western Yunnan and Tertiary basalt in the western Yunnan indicate that the Beiya lamprophyre melts were derivative and resulted from the mixing between basic melts that were related to the partial melting of phenocrysts of spinel iherzolite from a mantle source. The alkaline melts originated from partial melting along the Jinshajiang subduction ductile shear zone at the contact between the buried Palaeo-Tethyan oceanic lithosphere and the upper mantle lithosphere. The alkaline melts are composed of 65% sanidine (Or70Ab28An2) and 35% SiO2. The melt mixing occurred in magma chambers in the middle-shallow crust at 8–10 km before the derivative lamprophyre melts intruded into the shallow cover in Beiya area. This mixing of basic and alkaline melts might represent a general process for the formation of lamprophyre in the western Yunnan. 相似文献