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1.
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2.
Trace elements in the Geological Survey of Japan carbonate reference materials Coral JCp-1 and Giant Clam JCt-1 were determined by inductively coupled plasma-mass spectrometry after digestion with 2% v/v HNO3. A standard addition method was adopted in this determination in order to neutralise the Ca matrix effect. In addition, Sc, Y, In and Bi were used as internal standards to control the matrix effect and correct instrumental drift. Of the eighteen elements measured in JCp-1, precisions for fourteen elements, including Cu, Cd and Ba, were better than 10% RSD and concentrations ranged from 0.002 μg g-1 (Cs) to 8.02 μg g-1 (Ba). The concentrations of measured trace elements in JCt-1, except for Cu, were lower than those in JCp-1. Precisions for all elements with concentrations higher than 0.04 μg g-1 in JCt-1 were also better than 10% RSD and concentrations were found to be between 0.001 μg g-1 (Cs) and 4.84 μg g-1 (Ba). The concentrations of more than fifteen trace elements in the aragonite reference materials are reported here for the first time. Both reference materials are suitable for use in geochemical studies of environmental reconstruction based upon biogenic carbonate materials.  相似文献   

3.
Two new geochemical reference materials, copper ore JCu-1 and zinc ore JZn-1 have been prepared by the Geological Survey of Japan (GSJ) for the determination of major and minor elements and isotopic compositions. JCu-1 is a sample of Cu-bearing sulfide ore typical of the Kamaishi mine in Iwate Prefecture, Japan, and is composed mainly of hedenbergite, chalcopyrite, quartz and calcite. Pyrrhotite, magnetite and actinolitic amphibole were also commonly found. The Zn-rich ore, JZn-1 is a crude ore from the Kamioka Pb-Zn mine in Gifu Prefecture, Japan. The sample consists of hedenbergite, quartz, calcite, sphalerite and epidote as main crystalline phase. Homogeneity test results showed that all studied constituents including ore elements such as Cu, Pb and Zn can be considered to be homogeneously distributed. Provisional collaborative analyses were carried out in ten laboratories, and the data were evaluated using a robust statistical method using z-scores. Recommended values for a number of major elements including TiO2, Al2O3, MnO, MgO, CaO, Na2O, K2O, Fe (total), Zn, Cu and Pb were established. In addition, information values for eighteen major, minor and trace elements are presented to support future collaborative analyses.  相似文献   

4.
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5.
Three Cobalt-Rich Seamount Crust Reference Materials: GSMC-1 to 3   总被引：1，自引：0，他引：1  
A research project involving the preparation of three Co-rich crust reference materials (GSMC-1 to 3) has been preliminarily completed. The samples were collected from the eastern and central Pacific seamount zones and their main chemical composition is MnO2. After the raw materials were dried in ambient air and at low temperature (60-100 C), they were ground in a ball mill to form a well-mixed powder. The proportion of particle size fractions of < 74 μm and < 3 μm was over 98% and 50% respectively. The homogeneity of the materials was tested using wavelength dispersive X-ray fluorescence spectrometry (WD-XRF). The relative standard deviation (% RSD) of the measurements for all the selected elements in forty sub-samples randomly taken from the bottles was less than 0.4%. Sixteen laboratories from Germany, Russia, France, Australia and China participated in the collaborative analysis programme. Fifty seven elements or constituents were analysed, and among those, forty six elements were certified in each sample. The sum of contents of the major and minor elements or components was 99.5% for GSMC-1, 99.6% for GSMC-2 and 99.2% for GSMC-3.  相似文献   

6.
Archean komatiites of Goiás, central Brazil, have experienced deformation and low-grade metamorphism, but several outcrops preserve primary volcanic features. Samples from less deformed komatiites of four out of five greenstone belts (Crixás, Guarinos, Pilar de Goiás, and Santa Rita) have been investigated for their geochemical properties. Komatiites from the Crixás greenstone belt have very low Al2O3/TiO2, high CaO/Al2O3, and a hump-shaped rare earth element (REE) pattern. Those from the Guarinos and Pilar de Goiás belts have similar REE patterns, characterized by a slight enrichment in LREE coupled with almost flat HREE, but differ in their inter-incompatible element ratios. Compared with those from Pilar de Goiás and Guarinos, samples from the Santa Rita belt have fractionated REE patterns with LREE enrichment, as well as high Al2O3 contents, corresponding to Al-undepleted komatiites. Komatiites from Crixás have the lowest (La/Sm)N, (La/Yb)N, and Zr/Zr* ratios compared with their equivalents from the other belts, which suggests their source was relatively depleted in LREE and high field strength elements (HFSE), probably due to the retention of garnet in the residue. Komatiites from the Guarinos, Pilar de Goiás, and Santa Rita greenstone belts are enriched in incompatible elements, which can be attributed to either low-degree partial melting at high pressures or a source previously enriched in incompatible elements. Some of the studied komatiites belong to Al- and HREE-depleted and others to the Al- and HREE-undepleted types. The depleted komatiites probably derived by melting at depths greater than 200 km, the undepleted at less than 200 km. Therefore, the komatiites of the four belts may have been derived from either one single mantle plume with different melting depths or sources from distinct plumes.  相似文献   

7.
Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g−1). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g−1 level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g−1 levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.  相似文献   

8.
Chandrayaan-1: Science goals   总被引：1，自引：0，他引：1  
The primary objectives of the Chandrayaan-1 mission are simultaneous chemical, mineralogical and topographic mapping of the lunar surface at high spatial resolution. These data should enable us to understand compositional variation of major elements, which in turn, should lead to a better understanding of the stratigraphic relationships between various litho units occurring on the lunar surface. The major element distribution will be determined using an X-ray fluorescence spectrometer (LEX), sensitive in the energy range of 1–10 keV where Mg, Al, Si, Ca and Fe give their Kα lines. A solar X-ray monitor (SXM) to measure the energy spectrum of solar X-rays, which are responsible for the fluorescent X-rays, is included. Radioactive elements like Th will be measured by its 238.6 keV line using a low energy gamma-ray spectrometer (HEX) operating in the 20–250 keV region. The mineral composition will be determined by a hyper-spectral imaging spectrometer (HySI) sensitive in the 400–920 nm range. The wavelength range is further extended to 2600 nm where some spectral features of the abundant lunar minerals and water occur, by using a near-infrared spectrometer (SIR-2), similar to that used on the Smart-1 mission, in collaboration with ESA. A terrain mapping camera (TMC) in the panchromatic band will provide a three-dimensional map of the lunar surface with a spatial resolution of about 5 m. Aided by a laser altimeter (LLRI) to determine the altitude of the lunar craft, to correct for spatial coverage by various instruments, TMC should enable us to prepare an elevation map with an accuracy of about 10 m. Four additional instruments under international collaboration are being considered. These are: a Miniature Imaging Radar Instrument (mini-SAR), Sub Atomic Reflecting Analyser (SARA), the Moon Mineral Mapper (M3) and a Radiation Monitor (RADOM). Apart from these scientific payloads, certain technology experiments have been proposed, which may include an impactor which will be released to land on the Moon during the mission. Salient features of the mission are described here. The ensemble of instruments onboard Chandrayaan-1 should enable us to accomplish the science goals defined for this mission.  相似文献   

9.
A new geochemical reference material, coral Porites sp. JCp-1 has been prepared by the Geological Survey of Japan (GSJ). Provisional values for twenty one major, minor and trace elements are presented. The homogeneity tests showed that all elements studied are considered to be homogeneously distributed.  相似文献   

10.
This paper describes the creation of two new reference samples of black shale, SCHS-1 and SLg-1, collected in the Bodaibo Region of Irkutsk District (Siberia, Russia). These samples have been developed as State Standard Samples to meet the requirements of Russia's Normative Documents, so that they can be recognised by the Russian State Certification Agency and included on the State Register of certified reference materials. SCHS-1 was produced from shale of the Khomolkho suite; SLg-1 represents the average composition of the Sukhoy Log gold deposit (within Au mineralisation). The homogeneity was assessed by applying the concept of potential inhomogeneity, and the inhomogeneity uncertainties (σinhom) for the indicator elements that were estimated experimentally by silicate XRF analysis. It was found that a majority of the indicator elements was characterised by σinhom/Δp < 1/8 (Δp is the permissible certification uncertainty), and so σinhom was neglected for the indicator elements and all other elements that were included in their respective group. The value of σinhom calculated for Fe (σinhom,Fe/Δp > 1 /8) was taken into consideration for the noble metals and their associated elements (e.g., Ag, As, Au, etc.). More than fifty laboratories (thirty-seven from Russia) were involved in the interlaboratory experiment (ILE) to analyse these reference samples. The data obtained from the ILE allowed SCHS-1 and SLg-1 to be certified for, fifty-one and forty-three elements, respectively, as State Standard Samples.  相似文献   

11.
本文结合岩石薄片、古生物孢粉、同位素、铂族元素、野外露头剖面等资料,对塔里木盆地麦盖提斜坡皮山北新1井钻遇的一套白云质角砾岩地层时代进行了厘定。结果认为：6 884~7 068 m段归属古近系吐依洛克组,化石含量较少;7 068~7 150 m段归属白垩系依格孜牙组,孢粉化石丰富。该井古近纪与白垩纪地层界线深度7 068 m,该位置碳同位素的突变指示海洋环境的剧烈变化,这可以与全球K/E界线处对比。同时,铂族元素在该深度见到明显的异常,其含量明显增大,尤其以Rh、Ru、Ir、Os等最为明显。通过此次厘定,丰富了对麦盖提斜坡晚白垩世—古近纪早期沉积格局的认识。  相似文献   

12.
Rare earth element analyses are widely used in geology, environmental science and archaeology. Over the past decade inductively coupled plasma-mass spectrometry has become an important source of rare earth data on geological material. However, ICP-MS analysis of rock samples without pre-concentration can be problematic because of complex sample matrices that can generate significant molecular isobaric interferences on rare earth peaks and which need to be corrected. Such problems are exacerbated for ultramafic rocks because the low levels of rare earth elements demand more concentrated solutions in order to maintain signals above background levels. These high solid loads result in intra-run changes in instrument sensitivity which need to be monitored. Pre-concentration chemistries have been developed in order to avoid high solid loads but these are time-consuming and must offer quantitative recoveries or use a yield tracer. Here, we describe an alternative method for rare earth element analysis by ICP-MS, which involves no pre-concentration and is, therefore, able to deliver data rapidly. Our approach is to apply an external correction procedure, based on the analysis of a reference material closely matched in composition to the unknown samples, which allows correction for both interferences and variations in instrument sensitivity. Testing this method, we obtained accurate rare earth element results for basaltic rocks with a precision of about 2% (1s). We demonstrate that the method is also applicable to ultramafic rocks with abundances at ultra-trace (ng g−1) level and present data for twelve separate dissolutions of the peridotite USGS PCC-1 and four separate dissolutions of the dunite DTS-1 reference materials. The repeatability of the data is between 3% and 9% (1s).  相似文献   

13.
孙焕振 《物探与化探》1988,12(3):161-168
本文对1:5万地球化学普查样品中分析元素的选择问题提出了一些应考虑的原则和依据,并例举了我国在化探找矿实践中曾采用且已取得效果的指示元素选用的实例,以供读者在工作中参考。作者根据地矿部各野外队实验室的经验提出了1:5万样品分析的质量监控方法、几项质量参数及这些质量参数的计算式和统计方法。为了客观地评价1:5万化探样品分析的质量等级,文章提出了“优秀”、“良好”、“及格”和“不及格”四个质量等级和它们相应的质量参数。  相似文献   

14.
Three new rock reference samples, Rhyolite JR-3, Gabbro JGb-2 and Hornblendite JH-1 have been prepared by the Geological Survey of Japan for collaborative studies on their chemical composition. Twenty-eight major, minor and trace elements were determined and presented. The results of homogeneity tests showed that all elements are considered to be distributed homogeneously in each reference sample. Geological and mineralogical characteristics are also described.  相似文献   

15.
Platinum-Group Element Geochemical Certified Reference Materials (GPt1-7)   总被引：2，自引：0，他引：2  
Unlike the situation for other elements, few reference materials certified for the platinum-group elements are currently available. Therefore, the GPt1-7 series of PGE geochemical CRMs, prepared by the IGGE, represent an important addition and comprise a range of matrix types, including a soil, stream sediment, Mg-rich ultramafic rock, Fe-rich ultramafic rock, platinoid ore depleted in Cu, Ni and Fe, and a chromitite. The concentration of PGE in these samples ranges over 4-5 orders of magnitude and the samples were shown to have good homogeneity as assessed by a variance test. Analytical methods based on different principles were used in sample certification, including several fire assay and wet chemical procedures used for decomposition and preconcentration. Certified values for the elements Pt, Pd, Os, Ru, Ir, Rh and Au were determined by AAS, catalytic colourimetry (COL), catalytic polarography (POL), atomic emission spectrometry (AES), ICP-MS and NAA. Recently, the GPt1-7 samples were approved as national primary CRMs by the State Bureau of Technical Supervision of China.  相似文献   

16.
西沙群岛西科1井致密白云岩具有低孔低渗特征,前人证实其是由填隙物与围岩2个相互独立的岩石矿物学端元组成,同时西沙群岛远离陆架,其内碳酸盐岩中的地球化学指标尤其稀土元素可以很好地指示古海洋和沉积环境。作者以致密白云岩围岩为研究对象,通过显微观察、SEM-EDS(场发射扫描电子显微镜-X射线能谱仪)、激光原位剥蚀技术分析其矿物及稀土元素特征。结果表明围岩中白云石以细晶白云石为主,包括自形、半自形及他形,孔隙细小,发育典型雾心亮边构造。稀土配分表现为LREE亏损、La正异常、Ce负异常、高Y/Ho值等典型海相碳酸盐岩稀土元素特征。此外Eu具有正异常,认为与来自海底的热液活动有关。  相似文献   

17.
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18.
1:100万中华人民共和国数字地质图空间数据库   总被引：3，自引：3，他引：0       下载免费PDF全文
中华人民共和国1∶100万数字地质图数据库是根据统一标准和要求编制的专题数字地质图,以中华人民共和国1∶50万数字地质图数据库为数据源,在综合研究的基础上,充分吸收近年来地质调查1∶25万、1∶20万、1∶5万等区调工作新成果、新资料,应用地质编图新技术、新理论和新方法编制而成。以年代地层单位为主、辅以岩石地层的表示方法,侵入岩按“岩性加年代”表示方法,进一步提高了基础地质的研究程度。地质图数据库内容丰富,信息量大,数据量约为1.2 GB,标示了岩石地层单位5347个图例,侵入体“岩性加时代”单位1780个图例,跨省区重要断裂93条,各省（市、自治区）内重要断层558条,同位素年龄数据1545个（组）,有代表性的钻孔382个。所有地质体的面元及线元、同位素年龄和钻孔都建立了相应的属性,相邻图幅之间进行了接图处理,编写了编图说明书和元数据。数据库采用统一的线型库、符号库、色标库等,成图过程全部采用MapGIS6.5平台计算机辅助成图,成图精度高,质量好,符合设计要求,全国64幅图采用分4个片区的工作方法,最后统一编制而成。该数字地质图是目前中国资料最全、内容最新的1∶100万地质图,是中国第一份应用GIS技术的1∶100万数字地质图的最新成果,充分反映了中国地质构造特点和当前地质研究的新水平。  相似文献   

19.
Additional data for gabbro, GOG-1, were determined by instrumental-neutron-activation analysis, atomic-absorption spectrometry, and semi-quantitative spectrographic analysis. F ratios calculated in the analysis of variance for 26 sets of data for elements determined by the three methods were not significant, and hence the elements are distributed homogeneously among the bottles. The agreement between our data and the averages previously published ranges from very good to poor. More analytical data are necessary to establish reliable estimates of the concentrations of elements in GOG-1 and in two other gabbros so that three gabbros may be available to geochemists for use as standards.  相似文献   

20.
西沙石岛西科1井生物礁碳酸盐岩地球化学特征   总被引：2，自引：0，他引：2       下载免费PDF全文
对西科1井生物礁碳酸盐岩样品进行了地球化学(常量组分、微量及稀土元素含量等)分析, 旨在探讨生物礁的形成演化以及所记录的环境变化信息.结果表明: 西科1井岩心在井深36 m附近存在地球化学参数的显著变化, 暗示该深度是一处重要的地层界面或环境突变界面.岩心中的常量组分可以分为3类组合: 以CaO为主, 辅以K2O的原生碳酸岩组分, 该组分对应的主要造岩矿物是方解石, 代表了未经白云岩化的生物礁原生碳酸盐沉积; 以MgO为主, 辅以Na2O和P2O5, 代表了白云岩化作用中的富集组分, 反映了相对封闭的泻湖环境; 以SiO2为主, 加以Al2O3、TiO2、Fe2O3和MnO, 代表造礁生物对这些组分的富集作用, 但不能排除火山组分少量混入的可能性.相对于全球第四纪碳酸盐岩、上陆壳及页岩的平均值, 岩心碳酸盐岩中大部分微量元素和稀土元素含量都较低.岩心中氧化还原敏感性微量元素(RSE)含量较低, 指示岛礁发育过程中大部分时期处于氧化环境条件下, 而RSE含量在岩心中的大幅波动体现出氧化/还原环境的交替变化.微量元素含量、ΣREE、ΣLREE、ΣHREE、LREE/HREE、δCe、δEu等地球化学指标在岩心中的分布与岩心样品的矿物组成无明显的相关性, 说明成岩作用和白云岩化作用并没有造成微量和稀土元素含量及特征指标的明显变化.   相似文献   

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