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1.
仁里矿田位于扬子陆块与华夏陆块交汇的江南隆起造山带中段、幕阜山岩体西南缘的舌状体区域。稀有金属伟晶岩矿化类型在空间上具分带性,矿田北东部为白云母伟晶岩,西南部为锂辉石白云母伟晶岩。本文对矿田内3条代表性的锂辉石白云母伟晶岩开展了地质和地球化学特征研究。测试结果为:SiO2含量为62.0%~78.0%(平均71.8%);Al2O3为14.8%~18.0%(平均16.1%),Al2O3/(K2O+Na2O+CaO)摩尔比(A/CNK=1.52~13.0)大于1.1,分异指数(DI)89.7~97.5,∑REE=2.07~14.8μg/g,LREE/HREE=6.90~15.9。研究表明:①仁里矿田伟晶岩为过铝质岩浆系统下高分异、富碱、富稀有金属、富铪锆型花岗质伟晶岩,锂铌钽等稀有金属矿化与磷灰石化关系密切。②锂辉石白云母伟晶岩具有良好的分带性,其结晶分异时间晚于白云母伟晶岩,我们推测伟晶岩岩浆的结晶、分异时间越长越有利于Li元素的富集;矿田稀有金属矿化组合呈现Be+Nb+Ta→Be+Nb+Ta+Li→Be+Li的演化规律。③仁里矿田锂矿资源丰富,主要集中在矿田西南部,有望在进一步增加矿田钽铌资源量的基础上,提交一处高品位的大型锂矿床;在锂矿找矿工作中,尤其注意伟晶岩中的贫Nb、Ta锂辉石白云母伟晶岩地段。 相似文献
2.
湖南仁里稀有金属矿田是中国近年来新发现的一处重要的花岗伟晶岩型铌、钽、锂等稀有金属矿产地,文章针对矿田含锂伟晶岩地球化学特征、成矿时代及其与花岗岩的关系,选取传梓源锂铌钽矿床内规模最大的206号锂辉石伟晶岩脉开展地球化学和白云母Ar-Ar定年工作,并与区内其他伟晶岩、花岗岩的地球化学特征、成岩时代对比分析.传梓源206号锂辉石伟晶岩属高分异稀有金属伟晶岩,形成时代为(135.4±1.4)Ma,岩石地球化学表现为高硅、高铝、低钙、相对富碱、钙碱性及过铝质特征;稀土元素总量很低,以轻稀土元素为主;微量元素富集Cs、Rb、U、Ta、Nb、Zr、Hf,相对亏损Ba、Ti,Zr/Hf、Nb/Ta比值低且集中.幕阜山地区稀有金属成矿可分为2期:第1期稀有金属成矿时代约145 Ma,与燕山早期岩浆活动有关;第2期稀有金属成矿时代135～125 Ma,为主成矿期,该期稀有金属伟晶岩与燕山晚期的二云母二长花岗岩存在成因联系,两者为同源岩浆连续结晶分异过程中不同阶段的产物.稀有金属富集成矿经历了岩浆-热液两阶段作用,Be、Nb、Ta、Li、Rb、Cs等稀有元素的富集多发生于岩浆结晶分异晚期,热液作用使Ta、Li、Rb、Cs再次富集. 相似文献
3.
《International Geology Review》2012,54(10):1133-1137
We studied distribution of vein formations (from quartz veins and pegmatites of different types to migmatites) in three regions with well-developed metamorphic zonation, with a similar temperature range of metamorphism but a variable total pressure. We considered the tectonic position of the metamorphic belts, the geochemical features of the progressive stage of metamorphism, granitization, and the formation of the pegmatite veins. After analyzing the geological and geochemical data, and physicochemical parameters (T, Ptotal, Pstress, and Pfl), we conclude that change in pressure and the composition of the volatile components plays the principal role in the degree of development of particular types of pegmatites in the various facies series of metamorphism, and that the distribution of pegmatites of different types is determined by the relationships between the temperature of crystallization of the melts and that of the surrounding rocks. —Authors. 相似文献
4.
L.G. Kuznetsova 《Russian Geology and Geophysics》2018,59(12):1660-1678
We present new data on the age, composition, and environments of formation of granites of the Kystarys complex and the associated Li-rich rare-element pegmatites of the South Sangilen pegmatite belt including the large Tastyg lithium deposit. It has been established that they formed during the Early Paleozoic collisional orogeny in the Tuva-Mongolian massif at the Cambrian-Ordovician boundary. The granites of the Kystarys complex are moderately alkaline high-K rocks and are enriched in Zr, Nb, Y, and REE; therefore, they are classified as postcollisional, transitional to within-plate (A-type). The spodumene pegmatites of the South Sangilen pegmatite belt are similar to the above granites in age and isotopic and geochemical parameters, which suggests a paragenetic relationship between these rocks. Pegmatites form several pegmatite fields within the belt, which differ in trace-element signatures. In addition to predominant Li, Cs, and Ta, specific to all spodumene pegmatites (LCT family), pegmatites of two fields have high contents of Nb, Y, REE, and Zr, which are indicator elements of NYF family pegmatites. It has been established that the formation of spodumene pegmatites with combined LCT-NYF geochemical signatures was preceded by the intrusion of dikes of monzogabbro with the geochemical characteristics of OIB and of alkali aegirine granites and by the formation of associated metasomatites enriched in Zr, Nb, Y, and REE. Based on the geological, mineralogical, and geochemical data, we substantiate the hypothesis of the formation of Li-bearing granite-pegmatite melts from a mixed source resulted from the influence of fluids of an alkaline igneous complex of mantle genesis on the crustal protolith. 相似文献
5.
Gehad M. Saleh Mohamed M. ElGaly Mohamed A. Obeid 《中国地球化学学报》2008,27(1):9-20
Rare metal mineralization of Sn, Nb-Ta and W is encountered in the Gebel Dihmit area （GDA）, southeastern Aswan, Egypt. The mineralization is related to muscovite granites and their pegmatite derivatives. The pegmatites are divided into three types according to their main mineral assemblages： K-feldspar-muscovite-tourmaline, K-feldspar-albite-muscovite and albite-K-feldspar-lepidolite veins. Petrogenetic studies indicate that Sn and Nb-Ta mineralization extends from the late-magmatic stage to the pegmatite and hydrothermal stages of the （GDA） suite. The albite-K-feldspar-lepidolite granite is composed dominantly of albite, lepidolote, and quartz, with topaz, K-feldspar and amblygonite. The accessory minerals are zircon, monazite, pollucite, columbite-tantalite, microlite and Ta-rich cassiterite. Phenocrysts of quartz, topaz and K-feldspar contain abundant inclusions of albite laths and occasional lepidolite crystals along growth zones （snowball texture）, indicating simultaneous crystallization from a subsolvus, residual magma. The origin of the pegmatites is attributed to extreme differentiation by fractional crystallization of a granitic magma. The economic potential for rare metals was evaluated in the geochemical discrimination diagrams. Accordingly, some of the pegmatites are not only highly differentiated in terms of alkalis, but also the promising targets for small-scale Ta and, to a less extent, Sn. The pegmatites also provide the first example of Fe-Mn and Nb-Ta fractionation in successive generations of granites to cassiterite-bearing pegmatites, which perfectly ex- hibit similar fractionation trends established for primary columbite-tantalite in the corresponding categories of pegmatites. Uranium and Th of magmatic origin are indicated by the presence of thorite and allanite, whereas evidence of hydrothermal mineralization is the alteration of rock- foring minerals such as feldspar and the formation of secondary minerals such as uranophane.. 相似文献
6.
《Geochimica et cosmochimica acta》1987,51(4):1011-1018
The extent of fractionation of Rb and Sr is routinely used in petrogenetic modelling of igneous processes, including internal fractionation of individual pegmatites as well as large-scale evolution of pegmatite groups and fields. However, highly evolved granitic pegmatites may contain as much as 14000 ppm Rb and less than 150 ppm Sr. The total Sr in K-feldspar and micas from geologically old and Rb-rich pegmatites may consist predominantly of radiogenic 87Sr, which obscures the original relationship of Rb to common Sr at the time of crystallization. A subtraction of radiogenic 87Sr calculated from the Rb content and age of emplacement is possible, but it commonly results in negative concentrations of Sr. The relative immobility of Rb, analytically determined isotopic composition of Sr, apparent ages of the Rb, Sr-bearing minerals, high concentration of 87Sr in coexisting Rb-poor phases, and experimental evidence indicate that post-crystallization migration of radiogenic 87Sr is significant. Where isotopic data are not available, RbSr trends in geologically old and highly fractionated pegmatites are misleading and cannot be used for geochemical interpretation of pegmatite derivation or evolution. 相似文献
7.
An initial phase of an extensive geochemical study of pegmatites from the Black Hills, South Dakota, indicates potassium feldspar composition is useful in interpreting petrogenetic relationships among pegmatites and among pegmatite zones within a single pegmatite. The and ratios and Li and Cs contents of the feldspars within each zoned pegmatite, to a first approximation, are consistent with the simple fractional crystallization of the potassium feldspar from a silicate melt from the wall zone to the core of the pegmatites. Some trace element characteristics (i.e. Cs) have been modified by subsolidus reequilibration of the feldspars with late-stage residual fluid. ratios of the potassium feldspar appear to be diagnostic of the pegmatite mineral assemblage. The relationship between and mineralogy is as follows: Harney Peak Granite (barren pegmatites) > 180; Li-Fe-Mn phosphate-bearing pegmatites = 90?50; spodumene-bearing pegmatites = 60?40; pollucitebearing pegmatites < 30. Although the ratios suggest that the pegmatites studied are genetically related by fractional crystallization to each other and the Harney Peak Granite, overlapping ratios and the general increase in Sr and Ba with decreasing indicate the genetic relationship is much more complex and may also be dependent upon slight variations in source (chemistry and mineralogy) material composition and degrees of partial melting. 相似文献
8.
新疆阿尔泰造山带是我国重要的稀有金属矿床矿产资源基地,尤以富Li和富Be伟晶岩型矿床广泛发育为特色。本研究选择阿尔泰造山带卡鲁安-阿祖拜矿田富Li和富Be伟晶岩型矿床开展典型解剖,以贯穿岩浆阶段-伟晶岩阶段的白云母矿物为研究主线,探讨不同矿化类型伟晶岩中云母的成分演化规律、花岗岩与伟晶岩的成因联系。矿物学特征显示富Be伟晶岩中发育大量磷酸盐矿物,而富Li伟晶岩含较多橙色锰铝榴石、锂云母而缺乏典型的Fe-Mn磷酸盐。白云母成分分析显示,从白云母花岗岩→富Be伟晶岩→富Li伟晶岩,白云母总体呈Nb含量和Nb/Ta值降低,指示白云母花岗岩、富Be伟晶岩经历了不同程度的分离结晶作用,也代表了富Li伟晶岩的岩浆分异演化程度更高。尽管利用云母成分变化(尤其是K、Rb、Cs等大离子亲石元素)模拟岩浆结晶演化过程,显示可由初始花岗质岩浆经瑞利分离结晶作用依次形成白云母花岗岩→富Be伟晶岩→富Li伟晶岩的假设。但研究区年代学、矿物学、同位素证据指示富Li伟晶岩和富Be伟晶岩具有不同的熔体性质和形成时代。因此,应用云母成分探讨伟晶岩的成因联系应当建立在花岗岩-伟晶岩系统具有合理的时空分布和其它支持源自同一... 相似文献
9.
铜绿山Fe-Cu(Au)矿床是长江中下游铁铜成矿带最重要的矽卡岩型矿床之一,矿床的形成与铜绿山石英闪长岩岩株有关.矿区东南部发育有花岗伟晶岩,其形成时间介于石英闪长岩和矽卡岩之间.花岗伟晶岩主要由钾长石、斜长石和石英组成;由石英和钾长石组成的文象结构非常发育.激光阶段加热40Ar/39Ar定年表明,花岗伟晶岩的侵位时间为136.5±0.7 Ma(2σ),与石英闪长岩的侵位时代和铜绿山矿床的成矿时代完全一致. 铜绿山石英闪长岩与花岗伟晶岩的钾长石具有非常相似的主量元素,平均组成分别为Or81Ab18和Or78Ab21.根据岩相学观察和地球化学分析认为,花岗伟晶岩中的文象结构是在快速冷却体系条件下、钾长石晶体生长边界层的SiO2和Al2O3浓度因生长不平衡发生周期性变化而导致石英和钾长石交替生长形成的.铜绿山石英闪长岩和花岗伟晶岩中钾长石的大离子亲石元素(LILE)含量均较高,但与前者相比,花岗伟晶岩中钾长石的Rb、Pb含量明显增加,Ba、Sr含量显著降低,Li、Cs含量略微降低.大离子亲石元素图解(Rb-Ba、La-Ba、K/Ba-Ba、Rb/Sr-Ba)指示花岗伟晶岩是铜绿山石英闪长岩岩浆晚期高度结晶分异演化的结果.但花岗伟晶岩钾长石中Pb、Li、Ga等元素的变化却与岩浆结晶分异演化趋势相悖,表明流体作用在花岗伟晶岩的形成过程中扮演了重要角色.花岗伟晶岩中的石英发育大量熔融包裹体和高盐度流体包裹体,后者的均一温度为260~435 ℃,进一步证实花岗伟晶岩是从流体-熔体共存体系中结晶的. 相似文献
10.
Yueqing Yang Yunxiang Ni Yongquan Guo Nianming Qiu Chenghu Chen Chaofa Cai Yaping Zhang Jiabin Liu Yuexian Chen Yaping Zhang 《中国地球化学学报》1988,7(2):120-135
The Xikeng pegmatite field lies on the eastern margin of the south China fold system in Fujian Province, and it is located
at the junction of three major tectonic units.
The distribution of pegmatites is obviously controlled by the fold system. There exists apparent injection relationship between
the pegmatites and the surrounding Sinian schist and granulitite. The granitoids extensively distributed in the field belong
either to the Variscan or to the Yenshanian cycle, and it is evident that the pegmatites are genetically related to Variscan
migmatitic granites.
The pegmatites can be grouped into four types: muscovite-orthoclase-albite pegmatite (I), muscovite albite-orthoclase pegmatite
(II), muscovite-orthoclase-albite pegmatite (III), and muscovite-albite-spodumene pegmatite (IV). Owing to strong metasomatism
and multi-stage emplacement of pegmatitic meltsolution, the sequence of interior assemblage zones in the pegmatites does not
always represent the sequence of original crystallization.
The mineral composition of the pegmatites is extremely complicated. 81 kinds of minerals have so far been found. From type
I to type IV, the mineral assemblage tend to get increasingly complex, together with the synchronous intensification of rare-metal
and Sn mineralizations. Most of the type-IV pegmatites are of economic value.
The features of fluid inclusions in the minerals are significantly different not only in different types of pegmatite, but
also in different parts of a single pegmatite vein. Theδ
18O values of migmatitic granite and pegmatites are comparatively low (9.3–10.4‰), and those of rock-forming fluids are higher
than 9.5‰.
Isotopic ages of the pegmatites range from 235 to 328 Ma with initial87Sr/86Sr ratios being 0.715–0.746.
According to the temporal and spatial relationships between the pegmatites and the migmatitic granite, combined with the features
of the pegmatites themselves, it can be concluded that the Xikeng pegmatites are the product of differentiation closely related
to the migmatitic granite. 相似文献
11.
纳米比亚湖山铀矿位于达马拉造山带的中央南部地区,工业铀矿物为晶质铀矿,属于伟晶岩型铀矿床。关于不同矿石中铀元素的富集与沉淀机制还存在一定争议。为了揭示伟晶质岩浆演化与铀矿化作用的关系,本文对矿区内不同矿物组成的伟晶岩型矿石开展了岩石和矿物地球化学研究。野外及镜下鉴定结果显示,矿化伟晶岩可以分为“简单类型”矿体和“复杂类型”矿体。前者具有正常的花岗伟晶结构,晶质铀矿均匀分布于造岩矿物之间,矿化程度低到中等;后者表现出非均匀的结构特征,且矿化程度极高,晶质铀矿在成因上与大量黑云母团块有明显的空间联系。地球化学研究表明:在“简单类型”伟晶岩中,铀元素主要通过伟晶质岩浆的分离结晶作用富集;“复杂类型”伟晶质岩浆的演化则明显受控于同化混染作用,其铀矿化为岩浆同化混染与分离结晶(assimilation-fractional crystallization,AFC)作用产物。具体而言,外来基性组分(FeO,MgO,TiO2,MnO)的混入导致“复杂类型”熔体中矿物的结晶顺序发生改变,长石类矿物的“延后”结晶为黑云母提供了更加有利的结晶空间和条件,促使黑云母以团块状聚集的形式产出。黑云母的大量析出会引发残余岩浆中UFm4-m络合物的水解,导致晶质铀矿在团块黑云母内部或周围沉淀。因此,本文有关“简单类型”和“复杂类型”产铀伟晶岩的研究,有效地揭示了岩浆演化过程与铀矿化机制,丰富了伟晶岩型铀矿床理论,为后期勘查开发提供了科学依据。 相似文献
12.
Tantalum, an important metal for high-technology applications, is recovered from oxide minerals that are present as minor constituents in rare-metal granites and granitic rare-element pegmatites. Columbite-group minerals (CGM) account for the majority of the current tantalum production; other Ta–Nb oxides (TNO) such as tapiolite, wodginite, ixiolite, rutile and pyrochlore-supergroup minerals may also be used.In this paper mineralogical and geochemical data with a focus on opaque minerals as well as age determinations on CGM using the U–Pb method are presented for 13 rare-element granite and pegmatite districts in Africa, covering Archean, Paleoproterozoic, Neoproterozoic, Paleozoic and Mesozoic provinces. Geological, economic and geochronological data are reviewed.Each period of Ta-ore formation is characterised by peculiar mineralogical and geochemical features that assist in discriminating these provinces. Compositions of CGM are extremely variable: Fe-rich types predominate in the Man Shield (Sierra Leone), the Congo Craton (Democratic Republic of the Congo), the Kamativi Belt (Zimbabwe) and the Jos Plateau (Nigeria). Mn-rich columbite–tantalite is typical of the Alto Ligonha Province (Mozambique), the Arabian–Nubian Shield and the Tantalite Valley pegmatites (southern Namibia). Large compositional variations through Fe–Mn fractionation, followed by Nb–Ta fractionation are typical for pegmatites of the Kibara Belt of Central Africa, pegmatites associated with the Older Granites of Nigeria and some pegmatites in the Damara Belt of Namibia. CGM, tapiolite, wodginite and ixiolite accommodate minor and trace elements at the sub-ppm to weight-percent level. Trace elements are incorporated in TNO in a systematic fashion, e.g. wodginite and ixiolite carry higher Ti, Zr, Hf, Sn and Li concentrations than CGM and tapiolite. Compared to tapiolite, CGM have higher concentrations of all trace elements except Hf and occasionally Zr, Ti, Sn and Mg. The composition of TNO related to rare-element pegmatites is rather different from rare-metal granites: the latter have high REE and Th concentrations, and low Li and Mg. Pegmatite-hosted TNO are highly variable in composition, with types poor in REE, typical of LCT-family pegmatites, and types rich in REE — showing affinity for NYF-family or mixed LCT–NYF pegmatites. Major and trace elements show regional characteristics that are conspicuous in normalised trace element and REE diagrams. In general, CGM from Ta-ore provinces are characterised by the predominance of one type of REE distribution pattern characterised by ratios between individual groups of REE (light, middle, heavy REE) and the presence and intensity of anomalies (e.g. Eu/Eu*).Despite textural complexities such as complex zoning patterns and multiple mineralisation stages, the chemical compositions of CGM, tapiolite and wodginite–ixiolite from rare-metal granite and rare-element pegmatite provinces indicate that they are cogenetic and reflect specific source characteristics that may be used to discriminate among rocks of different origin.Geochronological data produced for CGM from ore districts are discussed together with the respective ore mineralogy and minor and trace element geochemistry of TNO to reconsider the geodynamics of pegmatite formation. In Africa, formation of rare element-bearing pegmatites and granites is related to syn- to late-orogenic (e.g., West African Craton, Zimbabwe Craton), post-orogenic (Kibara Belt, Damara Belt, Older Granites of Nigeria, Adola Belt of Ethiopia) and anorogenic (Younger Granites of Nigeria) tectonic and magmatic episodes. The late-orogenic TNO mineralisation associated with A-type granites in the Eastern Desert of Egypt shares geochemical features with the anorogenic Younger Granites of Nigeria. 相似文献
13.
Randall L. Gresens 《Contributions to Mineralogy and Petrology》1967,16(1):1-28
The Kiawa pegmatites, New Mexico, are thought to have formed by the process outlined in part I of this paper, i.e., by the reaction, Quartz + Muscovite + (Na+, K+) Perthite + H+.The pegmatites and country rocks were mapped and sampled in detail and geochemical data were obtained by spectrochemical analysis of separated minerals for 17 major and trace elements.Structural compatibility with the model is demonstrated by the occurrence of the pegmatites in structurally low pressure zones. Geochemical evidence indicates that quartz and muscovite, the raw materials for the reaction, were available before formation of the pegmatites. The distribution of major and trace elements in the minerals of the pegmatites and country rocks supports the model. Elements that were released by major reactions are found in secondary minerals in the country rocks and/or in pegmatite minerals. The distribution of barium in the minerals is that which would be predicted from its known geochemical behavior. Geologic evidence suggests that the pegmatites formed synkinematically during regional metamorphism.Other features of the Kiawa pegmatites, such as albitization, structural control of element distributions, and possibly an older generation of pegmatites, are shown to be in accord with the proposed model. Certain features of the pegmatites are not amenable to a magmatic explanation. 相似文献
14.
Granitic pegmatites: an assessment of current concepts and directions for the future 总被引：9，自引：0，他引：9
Although many explanations have been proposed for the internal zonation of granitic pegmatites, the most widely accepted model is attributed to R.H. Jahns. Jahns and Burnham [Jahns, R.H., Burnham, C.W., 1969. Experimental studies of pegmatite genesis: I. A model for the derivation and crystallization of granitic pegmatites. Econ. Geol. 64, 843–864] said that pegmatites owe their distinctive textural and zonal characteristics to the buoyant separation of aqueous vapor from silicate melt, giving rise to K-rich pegmatitic upper portions and Na-rich aplitic lower zones of individual pegmatites. Jahns and Tuttle [Janhs, R.H., Tuttle, O.F., 1963. Layered pegmatite–aplite intrusives. Spec. Pap.-Miner. Soc. Am. 1, 78–92] cited experiments as confirmation of this effect, but several experimental studies contradict the partitioning behavior that was the premise of Jahns' model. More recent work indicates that pegmatite-forming melts should cool quickly, or in any case, more quickly than crystallization can keep pace with. The distinctive textural and zonal features of pegmatites have been replicated in experiments that employ constitutional zone refining of melts that are substantially undercooled before crystallization commences. Melt boundary layers formed by this process would represent the last silicate liquids to crystallize in pegmatites, which explains the tendency in pegmatites for abrupt transitions from simple to evolved mineral and rock compositions. The sources of pegmatite-forming melts and of the causes of regional zonation within pegmatite groups represent important directions for future research. 相似文献
15.
Columbite-group minerals (CGM) account for the majority of the production of tantalum, an important metal for high-technology applications. Along with other Ta–Nb oxides such as tapiolite, wodginite, ixiolite and pyrochlore supergroup minerals, CGM are recovered from rare-metal granites and granitic rare-element pegmatites. In this paper mineralogical and geochemical data with a focus on CGM, tapiolite, wodginite and ixiolite are presented for rare-element granites and pegmatites from worldwide occurrences except Africa that has been covered in a previous contribution (Melcher et al., 2015). Major and trace element data of the Ta–Nb oxides are presented and compared for a total of 25 granite/pegmatite provinces, and one carbonatite for comparison. Based on CGM compositions, the data allow to distinguish between various subgroups of Li–Cs–Ta (LCT)-family pegmatites, Nb–Y–F (NYF)-family pegmatites, mixed LCT–NYF pegmatites, and rare-element granites.Each period of Ta-ore formation in Earth history is characterised by peculiar mineralogical and geochemical features. Some of the largest and economically most important rare-element pegmatite bodies are located within Archean terrains and intruded ultramafic and mafic host rocks (e.g., Tanco/Canada, Wodgina and Greenbushes/Western Australia, Kolmozero/Kola). They are highly fractionated, of LCT affinity throughout and yield complex mineralogical compositions. The variety of minor and trace elements incorporated attests to a rather insignificant role of the immediate host rocks to their geochemical signature and rather points to the significance of the composition of the underlying crustal protoliths, internal fractionation and the processes of melt generation. Many of the Archean pegmatites carry significant Li mineralization as spodumene, petalite, and amblygonite, and all of them are also characterised by elevated Li in CGM. In addition, Sb and Bi are important trace elements, also reflected by the occasional presence of stibiotantalite and bismutotantalite. REEN patterns of CGM are dominated by the MREE or HREE, and range from very low to high total REE concentrations. Negative Eu anomalies are omnipresent. Scandium contents are also highly variable, from very high (Tanco) to very low concentrations (Wodgina, Kolmozero).A second period of worldwide pegmatite formation was in the Paleoproterozoic. All CGM analysed derive from LCT-family pegmatites except samples from the Amazonas region where Ta is mined from rare-metal granites at Pitinga. Pegmatites intruded highly variable lithologies including metasediments, metabasites, gneiss, granite and quartzite within a variety of structural and paleogeographic settings; however, most of them are syn- to post-orogenic with respect to major Paleoproterozoic orogenic events. Minor and trace element signatures are similar to CGM from Archean pegmatites. Some are characterised by considerable REE enrichment (São João del Rei/Brazil; Amapá/Brazil; Finnish Lapland/Finland), whereas others have normal to low total REE concentrations (Black Hills/USA, Bastar/India). Examples with high REE commonly are enriched in Sc and Y as well, and are often transitional to NYF-family pegmatites.The Mesoproterozoic period is comparatively poor in rare-element pegmatites and rare-metal granites. Mineralogical and chemical attributes of ixiolite–wodginite, tapiolite, CGM and rutile from placer material in Colombia point to an unusual pegmatite source of NYF affinity, yielding high total REE, Sc and Th at low Li and Bi. REE patterns have typical negative Eu and Y anomalies.A third major period of pegmatite formation was the Early Neoproterozoic at around 1 Ga, documented in the Grenvillian (North America), the Sveconorwegian (northern Europe) and the Kibaran in central Africa. CGM are present in numerous, mostly small pegmatites, although larger examples also occur (e.g., Manono in the D.R. Congo; Melcher et al., 2015). Pegmatite fields often display a zonal arrangement of mineralised pegmatites with respect to assumed “fertile” parent granites. They intrude metasediments, metabasites, gneiss and granite of middle to upper crustal levels and display a variety of mineralogical and chemical characteristics. Pegmatites of the Sveconorwegian and Grenville domains are usually of the NYF type and CGM are characterised by elevated Y, REE, Th and Sc. In contrast, the pegmatites of central (Kibara Belt) and southwestern Africa (Orange River Belt) are commonly of LCT affinity carrying spodumene, beryl and cassiterite (Melcher et al., 2015). These CGM have elevated conce ntrations of Li, Mg, Sn and Hf. Total REE concentrations are low except for the Sveconorwegian, and exhibit a variety of shapes in normalised diagrams.The fourth major pegmatite-forming event coincides with amalgamation of Gondwana at the Neoproterozoic/Paleozoic boundary around 550 Ma ago. This event is omnipresent in Africa (“Panafrican”) and South America (“Brasiliano event” documented in the Eastern Brazilian pegmatite and Borborema provinces). Pegmatites often intruded high-grade metamorphic terrains composed of metasediments including schist, marble, quartzite, as well as gneiss, amphibolite, ultramafic rocks, and granite. Within the Neoproterozoic, rare-metal granites of NYF affinity are locally abundant. Pegmatites show both LCT and NYF affinities, and mixed types occur in Mozambique. The Alto Ligonha and Madagascar provinces are characterised by abundant REE and Sc both within Ta–Nb-oxides and as separate mineral phases. Notably, some pegmatite provinces are almost devoid of cassiterite, whereas others carry cassiterite in economic amounts.In the Phanerozoic (younger than 542 Ma), pegmatites formed at all times in response to orogenetic processes involving various continents and terranes during the long-time amalgamation of Pangea and the Alpine orogenies. Whereas some activity is related to the Pampean, Acadian and Caledonian orogenies, the Variscan/Hercynian and Alleghanian orogenies are of utmost importance as manifested in pegmatite formation associated with Sn–W mineralised granites in central and western Europe as well as in the Appalachians. Most of the Variscan and Alleghanian pegmatites are of LCT affinity, although NYF and some mixed types have been described as well. Variscan pegmatite formation culminated at ca. 330 to 300 Ma, whereas Alleghanian pegmatites range in age from about 390 Ma to about 240 Ma. Most are syn- to post-orogenic and were emplaced at different crustal levels and into a variety of host rocks. Degree of fractionation as well as minor and trace element geochemistry of Ta–Nb oxides are rather variable and cover the complete field of CGM compositions. REE patterns are characterised by prominent negative Eu anomalies.Some Mesozoic and Cenozoic pegmatites and rare-metal granites from Southeast Asia and the Russian Far East are included in the compilation. Rare-metal granites of the Jos Plateau (Nigeria) were previously investigated (Melcher et al., 2015). The proportion of NYF pegmatites and rare-metal granites in the Mesozoic is striking, i.e. illustrated by Jos, Orlovka, Ulug Tanzek as well as the southeast Asian deposits related to tin granites. CGM from these areas are invariably rich in REE, Sc, Y and Th. In all rare-metal granites, Ta–Nb oxides are characterised by high total REE concentrations and both, negative Eu and Y anomalies in chondrite-normalised REE diagrams.Although constituting a vastly different magmatic system compared to rare metal pegmatites and granites, we included the Upper Fir carbonatite from the Canadian Cordillera, for comparison, because it is characterised by unusal high Ta contents. As expected, the CGM differ from the pegmatitic CGM by having high Mg and Th, and low U concentrations in columbite-(Fe) and lack an Eu anomaly. However, they also show similarities to primitive CGM from rare metal pegmatites of the NYF family in terms of the REE pattern and the increase in #Ta and #Mn towards the margins of the CGM. Our findings support recent results presented in Chudy (2014) indicating that the Ta enrichment in some carbonatites might be attributed to magmatic processes and conditions that are similar to the pegmatitic systems. 相似文献
16.
陕西陈家庄铀矿床是我国北秦岭商州—丹凤伟晶岩型铀矿集区中一个重要的矿床,铀矿体均产于加里东期花岗岩体周边花岗伟晶岩脉与围岩(秦岭群变质杂岩)的接触部位。本文对矿区花岗岩体、花岗伟晶岩脉开展了详细的岩石学、岩石地球化学、锆石U-Pb年代学研究,进而对其成因、成岩构造环境和铀矿化机理进行了探讨。LA-ICP-MS锆石U-Pb年代学研究表明,黄龙庙黑云母花岗岩体,陈家庄二长花岗岩体和非矿、贫矿、富矿花岗伟晶岩脉的成岩年龄分别为(446±3) Ma、(419±2) Ma、(417±3) Ma、(414±4) Ma和(416±3) Ma。地球化学分析显示：黄龙庙黑云母花岗岩体具有Ⅰ型花岗岩、埃达克质岩特征,源自加厚下地壳的部分熔融,形成于块体碰撞构造环境;陈家庄二长花岗岩体也具有I型花岗岩特征,但源区深度略浅,形成于碰撞后的减压环境。花岗伟晶岩脉与陈家庄二长花岗岩体近于同时形成,且具有亲缘性。铀矿物及富铀黑云母均产于花岗伟晶岩脉中。对比研究揭示,非矿、贫矿、富矿花岗伟晶岩脉地球化学特征和铀赋存状况的差异由同化混染作用程度高低所致。在花岗伟晶岩脉与秦岭群变质杂岩的接触部位,同化混染作用较弱的部位形成的二云母花岗伟晶岩脉仅具有弱的铀富集,同化混染作用较强的部位所形成的富石英、黑云母花岗伟晶岩脉则高度富集铀且构成铀矿体。综合研究表明,花岗伟晶岩脉成岩期后的同化混染作用是铀富集成矿的主导因素。 相似文献
17.
Hartmut Beurlen Marcelo R. R. Da Silva Rainer Thomas Dwight R. Soares Patrick Olivier 《Mineralium Deposita》2008,43(2):207-228
The Borborema Pegmatitic Province (BPP), northeastern Brazil, is historically important for tantalum mining and also famous
for top-quality specimens of exotic Nb–Ta oxides and, more recently, for the production of gem quality, turquoise blue, ‘Paraíba
Elbaite.’ With more than 750 registered mineralized rare-element granitic pegmatites, the BPP extends over an area of about
75 by 150 km in the eastern part of the Neoproterozoic Seridó Belt. The Late Cambrian pegmatites are mostly hosted by a sequence
of Neoproterozoic cordierite–sillimanite biotite schists of the Seridó Formation and quartzites and metaconglomerates of the
Equador Formation. The trace-element ratios in feldspar and micas allow to classify most pegmatites as belonging to the beryl–columbite
phosphate subtype. Electron microprobe analyses (EMPA) of columbite, tapiolite, niobian–tantalian rutile, ixiolite and wodginite
group minerals from 28 pegmatites in the BPP are used to evaluate the effectiveness of Nb–Ta oxide chemistry as a possible
exploration tool, to trace the degree of pegmatite fractionation and to classify the pegmatites. The columbite group mineral
composition allows to establish a compositional trend from manganoan ferrocolumbite to manganocolumbite and on to manganotantalite.
This trend is typical of complex spodumene- and/or lepidolite-subtype pegmatites. It clearly contrasts with another trend,
from ferrocolumbite through ferrotantalite to ferrowodginite and ferrotapiolite compositions, typical of pegmatites of the
beryl–columbite phosphate subtype. Large scatter and anomalous trends in zoned crystals partially overlap and conceal the
two main evolution patterns. This indicates that a large representative data set of heavy mineral concentrate samples, collected
systematically along cross-sections, would be necessary to predict the metallogenetic potential of individual pegmatites.
Other mineral species, e.g. garnets and/or tourmaline, with a more regular distribution than Nb–Ta oxides, would be more appropriate
and less expensive for routine exploration purposes. The currently available Nb–Ta oxide chemistry data suggest the potential
for highly fractionated Ta–Li–Cs pegmatites in the BPP, so far undiscovered, and encourages further, more detailed research. 相似文献
18.
东秦岭伟晶岩区是秦岭造山带规模最大、稀有金属矿化最丰富的伟晶岩区.该区稀有金属矿化种类齐全,产出贫矿、铀矿化、铍矿化、锂矿化和复杂稀有金属矿化伟晶岩,以锂矿化和铀矿化伟晶岩为主.稀有金属伟晶岩类型丰富,包括绿柱石-铌铁矿亚型、锂辉石亚型、锂云母亚型和钠长石-锂辉石型.伟晶岩内部结构分带型式多样,包括对称分带、分层和均一结构.铀矿化伟晶岩分带简单,铍矿化和复杂稀有金属矿化伟晶岩以对称分带结构为主,锂矿化伟晶岩具有多种内部结构分带型式.伟晶岩分异演化程度跨度大.结晶分异影响着复杂稀有金属矿化伟晶岩的成矿过程.该区主要产出古生代伟晶岩,形成于晚志留世—中泥盆世,集中于两期,处于晚造山-造山后阶段.伟晶岩形成时代与伟晶岩空间分布、岩浆岩分异演化程度、稀有金属矿化类型等关联不大.东秦岭地区中大面积不同时代花岗岩体的侵位、变质沉积岩地层的发育以及长期复杂的造山演化历史,包括地壳加厚和抬升,是形成高度分异演化的伟晶岩岩浆的有利地质条件.该区具有寻找铍矿和复杂稀有金属矿的潜力,且需要关注长石、石英和云母等矿物的综合利用.稀有金属伟晶岩的岩浆成因是未来研究的重要方向. 相似文献
19.
20.
N. Varlamoff 《Mineralium Deposita》1972,7(2):202-216
The author summarises the results of his studies of Central and West African rare-metal pegmatites and supplements them by the newest datas obtained by H. Adam in Ivory Coast. He compares then the classification of African rare-metal pegmatites with the classifications obtained in U.S.S.R., in U.S.A. and in Canada for the same kind of pegmatites. The author's conclusions may be summarised as follows: (a) The rare-metal pegmatite types succeed each other in a more or less defined order which is independent from the ages of the orogenies as well as from the nature and from the degree of metamorphism of enclosing rocks. (b) The spatial distribution of the rare-metal pegmatite types in or around the granitic intrusions depends from the depth at which the parent granites are crystallizing. — When the granites are crystallizing at relatively shallow depths, the rare-metal pegmatites and partially the quartz veins and the associated mineralizations are located in the granitic bodies them selves. When the granites are crystallizing at more and more greather depths, the rare-metal pegmatites, the quartz veins and the associated mineralizations as well as the secondary phenomena such as albitization and greisenization are no more restricted to the granitic intrusions, but with the increasing depth of their crystallization are more and more penetrating in the roofs of the granitic cupolas. In addition it must be underlined that in granites crystallizing at shallow depths, the dimensions of the individual pegmatites are small and have no economic value; the rare-metal pegmatites associated with granitic intrusions cyrstallizing at greather depths may reach gigantic dimensions and certain types may be mined for tin, niobium, tantalum, beryl and lithium minerals; (c) In the same metallogenic province may co-exist granitic intrusions having crystallized at diffrent depths or at diffrent geological ages. To each depth of crystallization of the granitic intrusions corresponds a specific spatial distribution pattern of rare-metal pegmatites characterized by the distance of different pegmatite types to the granitic contacts as well as by the dimensions of the pegmatite types and by the size of their minerals. This may outline a special zonation within a metallogenic province. — At the end of the paper, the author gives a comparison of Central and West African rare-metal pegmatite type classification with similar classifications obtained in U.S.S.R., in U.S.A. and in Canada. From this comparison it results that the evolution of the pegmatitic process remains the same throughout geological epochs and is independent of the nature of the enclosing rocks. The magnitude and the fullness of this process are depending from the depth of crystallization of the granitic intrusions.
Résumé L'auteur résume ses observations sur les pegmatites à métaux rares du centre et de l'ouest africain, il les complète par des nouvelles données et notamment par celles de H. Adam, relatives à la Côte d'Ivoire et les compare aux données obtenues sur d'autres continents et notamment en URSS, au Canada et aux Etats Unis. — Les conclusions relatives aux pegmatites à métaux rares du centre et de l'ouest africain sont résumées ci-dessous: (a) les types de pegmatites à métaux rares se succèdent dans un ordre déterminé indépendant de l'âge, de la nature et du degré de métamorphisme des roches dans lesquelles elles cristallisent; (b) la répartition spatiale ou la zonéographie des types de pegmatites à métaux rares dépend de la profondeur de la mise en place des intrusions granitiques auxquelles les pegmatites sont associées. Lorsque les intrusions granitiques cristallisent à faible profondeur, les pegmatites et partiellement les filons de quartz avec leurs minéralisations sont contenus dans les granites. Lorsque les granites cristallisent à des profondeurs de plus en plus grandes, les pegmatites à métaux rares, les filons de quartz et les minéralisations de columbo-tantalite, de béryl, de minerais lithiques, de cassitérite et de wolfram, quittent les granites et, à mesure que la profondeur de mise en place augmente, se localisent de plus en plus loin des contacts dans les roches encaissantes; de plus, dans les granites de faible profondeur, les dimensions des pegmatites à métaux rares sont très faibles; les pegmatites associées avec des intrusions plus profondes peuvent atteindre des dimensions géantes de même leurs minéraux. Seules ces dernières offrent un intérêt économique; (c) dans une même province métallogénique, on peut rencontrer des intrusions granitiques mises en place à des profondeurs différentes et, parfois, à des époques différentes. A chaque profondeur de mise en place correspond une distribution spatiale particulière des types de pegmatites à métaux rares, caractérisés par leurs dimensions et par la grandeur des minéraux individuels. — Ces distributions spatiales différentes des types de pegmatites, jointes aux différences des dimensions des pegmatites et de leurs minéraux peuvent, à leur tour, dessiner une zonation à l'intérieur d'une province métallogénique. — A la fin de la note, l'auteur fait une comparaison rapide de la classification des types de pegmatites à métaux rares du centre et de l'ouest africain avec les classifications de la même catégorie des pegmatites de l'URSS, du Canada et des Etats Unis. De cette comparaison il en résulte que le processus pegmatitique évolue de manière très semblable à travers les époques géologiques indépendamment de la nature des roches encaissantes; mais l'ampleur du processus dépend de la profondeur de la mise en place des intrusions granitiques auxquelles les pegmatites sont associées.相似文献