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1.
Campaigns were conducted to measure Organic Carbon (OC) and Elemental Carbon (EC) in PM2.5 during winter and summer 2003 in Beijing. Modest differences of PM2.5 and PM10 mean concentrations were observed between the winter and summer campaigns. The mean PM2.5/PM10 ratio in both seasons was around 60%, indicating PM2.5 contributed significantly to PM10. The mean concentrations of OC and EC in PM2.5 were 11.2±7.5 and 6.0±5.0μg m-3 for the winter campaign, and 9.4±2.1 and 4.3±3.0 μg m-3 for the summer campaign, respectively. Diurnal concentrations of OC and EC in PM2.5 were found high at night and low during the daytime in winter, and characterized by an obvious minimum in the summer afternoon. The mean OC/EC ratio was 1.87±0.09 for winter and Z39±0.49 for summer. The higher OC/EC ratio in summer indicates some formation of Secondary Organic Carbon (SOC). The estimated SOC was 2.8 μg m-3 for winter and 4.2μg m-3 for summer.  相似文献   

2.
春季中国东部气溶胶化学组成及其分布的模拟研究   总被引：2，自引：0，他引：2  
本文利用区域空气质量模式RAQMS（Regional Air Quality Model System）,对2009年春季中国东部气溶胶主要化学成分及其分布进行了模拟研究。与泰山站观测资料的对比结果显示,模式能比较合理地反映气溶胶浓度的逐日变化特征。整体上,模式对无机盐气溶胶的模拟好,分别高估和低估黑碳和有机碳气溶胶浓度,其原因与排放源、二次有机气溶胶化学机制和模式分辨率的不确定性有关。模拟结果显示,春季气溶胶浓度高值主要集中于华北、四川东部、长江中下游等地区。受东南亚生物质燃烧和大气输送的影响,中国的云南和广西等地区有机碳浓度高于中国其他地区。中国西北部沙尘浓度较高,而且向东输送并影响到中国东部和南方部分地区。中国东部的华北、四川东部、长江中下游等地PM2.5（空气动力学直径在2.5微米以下的颗粒物）污染严重,4月平均PM2.5浓度超过了我国日平均PM2.5浓度限值。中国东部泰山站的观测和模拟结果都显示近地面硝酸盐浓度超过硫酸盐,中国北部对流层中硝酸盐的柱含量也大于硫酸盐,而在中国南部则相反,这一方面与春季中国云量 南多北少的分布特征以及云内液相化学反应有关,另一方面也与南北温差对气溶胶形成的影响有关。就整个中国东部而言,虽然硫酸盐的柱含量（46 Gg）仍大于硝酸盐（42 Gg）,但比较接近,反映出我国氮氧化物排放迅速增加的趋势。春季中国地区对流层中PM10（空气动力学直径在10微米以下的颗粒物）及其化学成分柱含量分别为:990.8 Gg（PM10）,52.6 Gg（硫酸盐）,48.2 Gg（硝酸盐）,32.1 Gg（铵盐）,22.9 Gg（黑碳）和74.1 Gg（有机碳）,有机碳（OC）中一次有机碳（POC）和二次有机碳（SOC）分别占60%和40%,中国东部PM10中人为气溶胶和沙尘分别占30%和70%,反映了春季沙尘对我国大气气溶胶的重要贡献。  相似文献   

3.
Measurements were performed in spring 2001 and 2002 to determine the characteristics of soil dust in the Chinese desert region of Dunhuang, one of the ground sites of the Asia-Pacific Regional Aerosol Characterization Experiment (ACE-Asia). The mean mass concentrations of total suspended particle matter during the spring of 2001 and 2002 were 317 μg m?3 and 307 μg m?3, respectively. Eleven dust storm events were observed with a mean aerosol concentration of 1095 μg m?3, while the non-dusty days with calm or weak wind speed had a background aerosol loading of 196 μgm?3 on average in the springtime. The main minerals detected in the aerosol samples by X-ray diffraction were illite, kaolinite, chlorite, quartz, feldspar, calcite and dolomite. Gypsum, halite and amphibole were also detected in a few samples. The mineralogical data also show that Asian dust is characterized by a kaolinite to chlorite (K/C) ratio lower than 1 whereas Saharan dust exhibits a K/C ratio larger than 2. Air mass back-trajectory analysis show that three families of pathways are associated with the aerosol particle transport to Dunhuang, but these have similar K/C ratios, which further demonstrates that the mineralogical characteristics of Asian dust are different from African dust.  相似文献   

4.
The concentrations of PM10, PM2.5 and their water-soluble ionic species were determined for the samples collected during January to December, 2007 at New Delhi (28.63° N, 77.18° E), India. The annual mean PM10 and PM2.5 concentrations (± standard deviation) were about 219 (± 84) and 97 (±56) μgm−3 respectively, about twice the prescribed Indian National Ambient Air Quality Standards values. The monthly average ratio of PM2.5/PM10 varied between 0.18 (June) and 0.86 (February) with an annual mean of ∼0.48 (±0.2), suggesting the dominance of coarser in summer and fine size particles in winter. The difference between the concentrations of PM10 and PM2.5, is deemed as the contribution of the coarse fraction (PM10−2.5). The analyzed coarse fractions mainly composed of secondary inorganic aerosols species (16.0 μgm−3, 13.07%), mineral matter (12.32 μgm−3, 10.06%) and salt particles (4.92 μgm−3, 4.02%). PM2.5 are mainly made up of undetermined fractions (39.46 μgm−3, 40.9%), secondary inorganic aerosols (26.15 μgm−3, 27.1%), salt aerosols (22.48 μgm−3, 23.3%) and mineral matter (8.41 μgm−3, 8.7%). The black carbon aerosols concentrations measured at a nearby (∼300 m) location to aerosol sampling site, registered an annual mean of ∼14 (±12) μgm−3, which is significantly large compared to those observed at other locations in India. The source identifications are made for the ionic species in PM10 and PM2.5. The results are discussed by way of correlations and factor analyses. The significant correlations of Cl−, SO42−, K+, Na+, Ca2+, NO3− and Mg2+ with PM2.5 on one hand and Mg2+ with PM10 on the other suggest the dominance of anthropogenic and soil origin aerosols in Delhi.  相似文献   

5.
A coupled regional climate and aerosol-chemistry model, RIEMS 2.0 (Regional Integrated Environmental Model System for Asia), in which anthropogenic sulfate, black carbon, and organic carbon were assumed to be externally mixed (EM), internally mixed (IM) or partially internally mixed (IEM), was used to simulate the impacts of these anthropogenic aerosols on East Asian climate for the entire year of 2006. The distributions of aerosol mass concentration, radiative forcing and hence the surface air temperature and precipitation variations under three mixing assumptions of aerosols were analyzed. The results indicated that the mass concentration of sulfate was sensitive to mixing assumptions, but carbonaceous aerosols were much less sensitive to the mixing types. Modeled results were compared with observations in a variety of sites in East Asia. It was found that the simulated concentrations of sulfate and carbonaceous aerosols were in accord with the observations in terms of magnitude. The simulated aerosol concentrations in IM case were closest to observation results. The regional average column burdens of sulfate, black carbon, and organic carbon, if internally mixed, were 11.49, 0.47, and 2.17 mg m−2, respectively. The radiative forcing of anthropogenic aerosols at the top of the atmosphere increased from −1.27 (EM) to −1.97 W m−2 (IM) while the normalized radiative forcing (NRF) decreased from −0.145 (EM) to −0.139 W mg−1 (IM). The radiative forcing and NRF were −1.82 W m−2 and −0.141 W mg−1 for IEM, respectively. The surface air temperature changes over the domain due to the anthropogenic sulfate and carbonaceous aerosols were −0.067, −0.078, and −0.072 K, with maxima of −0.47, −0.50, and −0.49 K, for EM, IM, and IEM, respectively. Meanwhile, the annual precipitation variations were −8.0 (EM), −20.6 (IM), and −21.9 mm (IEM), with maxima of 148, 122, and 102 mm, respectively, indicating that the climate effects were stronger if the sulfate and carbonaceous aerosols were internally mixed.  相似文献   

6.
黄土高原半干旱区典型日吸收性气溶胶综合观测分析   总被引：2，自引：0，他引：2  
利用兰州大学半干旱气候与环境观测站的太阳光度计、激光雷达、微波辐射计综合观测资料,结合辐射传输模式分析了该地区秋季典型日2012年9月3~4日、21日和28日气溶胶物理特性、垂直分布特征,及其与气象条件的关系。研究时期的气溶胶主要为局地沙尘与人为污染混合气溶胶,吸收性明显,尺度较小。其中,4日西北风增强,远距离传输沙尘气溶胶,气溶胶光学厚度最大,粒子尺度明显增大。尝试利用灰色关联度法确定参考高度,分别为7.41 km、8.47 km、7.13 km和7.66 km,反演气溶胶消光系数,由此积分得到的光学厚度与太阳光度计观测值相关性可达0.975,反演效果较好。研究时期气溶胶的抬升主要受白天热力湍流作用,边界层发展,气溶胶向上传输,每日12时（当地时间,下同）至14时传输至最大高度,气溶胶抬升的高度对应大气加热率的高值区,低层加热率可达1 K d-1。气溶胶在大气层顶和地面造成负辐射强迫,分别为-12.707 W m-2、-25.398 W m-2,大气中表现为正辐射强迫,为12.692 W m-2,大气层顶的辐射强迫对气溶胶的物理特性最为敏感,当气溶胶吸收性明显时,大气层顶的瞬时辐射强迫会出现正值。  相似文献   

7.
Continuous observations of mass concentration and elemental composition of aerosol particles （PM2.5） were conducted at Tongyu, a semi-arid site in Northeast China in the spring of 2006. The average mass concentration of PM2.5 at Tongyu station was 260.9±274.4 μg m^-3 during the observation period. Nine dust events were monitored with a mean concentration of 528.0±302.7 μgm^-3. The PM2.5 level during non- dust storm （NDS） period was 111.65±63.37 μg m^-3. High mass concentration shows that fine-size particles pollution was very serious in the semi-arid area in Northeast China. The enrichment factor values for crust elements during the dust storm （DS） period are close to those in the NDS period, while the enrichment factor values for pollution elements during the NDS period are much higher than those in the DS period, showing these elements were from anthropogenic sources. The ratios of dust elements to Fe were relative constant during the DS period. The Ca/Fe ratio in dust aerosols at Tongyu is remarkably different from that observed in other source regions and downwind regions. Meteorological analysis shows that dust events at Tongyu are usually associated with dry, low pressure and high wind speed weather conditions. Air mass back-trajectory analysis identified three kinds of general pathways were associated with the aerosol particle transport to Tongyu, and the northwest direction pathway was the main transport route.  相似文献   

8.
The direct and semi-direct radiative effects of anthropogenic aerosols on the radiative transfer and cloud fields in the Western United States (WUS) according to seasonal aerosol optical depth (AOD) and regional climate are examined using a regional climate model (RCM) in conjunction with the aerosol fields from a GEOS-Chem chemical-transport model (CTM) simulation. The two radiative effects cannot be separated within the experimental design in this study, thus the combined direct- and semi-direct effects are called radiative effects hereafter. The CTM shows that the AOD associated with the anthropogenic aerosols is chiefly due to sulfates with minor contributions from black carbon (BC) and that the AOD of the anthropogenic aerosol varies according to local emissions and the seasonal low-level winds. The RCM-simulated anthropogenic aerosol radiative effects vary according to the characteristics of regional climate, in addition to the AOD. The effects on the top of the atmosphere (TOA) outgoing shortwave radiation (OSRT) range from ?0.2?Wm?2 to ?1?Wm?2. In Northwestern US (NWUS), the maximum and minimum impact of anthropogenic aerosols on OSRT occurs in summer and winter, respectively, following the seasonal AOD. In Arizona-New Mexico (AZNM), the effect of anthropogenic sulfates on OSRT shows a bimodal distribution with winter/summer minima and spring/fall maxima, while the effect of anthropogenic BC shows a single peak in summer. The anthropogenic aerosols affect surface insolation range from ?0.6?Wm?2 to ?2.4?Wm?2, with similar variations found for the effects on OSRT except that the radiative effects of anthropogenic BC over AZNM show a bimodal distribution with spring/fall maxima and summer/winter minima. The radiative effects of anthropogenic sulfates on TOA outgoing longwave radiation (OLR) and the surface downward longwave radiation (DLRS) are notable only in summer and are characterized by strong geographical contrasts; the summer OLR in NWUS (AZNM) is reduced (enhanced) by 0.52?Wm?2 (1.14?Wm?2). The anthropogenic sulfates enhance (reduce) summer DLRS by 0.2?Wm?2 (0.65?Wm?2) in NWUS (AZNM). The anthropogenic BC affect DLRS noticeably only in AZNM during summer. The anthropogenic aerosols affect the cloud water path (CWP) and the radiative transfer noticeably only in summer when convective clouds are dominant. Primarily shortwave-reflecting anthropogenic sulfates decrease and increase CWP in AZNM and NWUS, respectively, however, the shortwave-absorbing anthropogenic BC reduces CWP in both regions. Due to strong feedback via convective clouds, the radiative effects of anthropogenic aerosols on the summer radiation field are more closely correlated with the changes in CWP than the AOD. The radiative effect of the total anthropogenic aerosols is dominated by the anthropogenic sulfates that contribute more than 80% of the total AOD associated with the anthropogenic aerosols.  相似文献   

9.
The chemical composition of regional background aerosols, and the time variability and sources in the Western Mediterranean are interpreted in this study. To this end 2002–2007 PM speciation data from an European Supersite for Atmospheric Aerosol Research (Montseny, MSY, located 40 km NNE of Barcelona in NE Spain) were evaluated, with these data being considered representative of regional background aerosols in the Western Mediterranean Basin. The mean PM10, PM2.5 and PM1 levels at MSY during 2002–2007 were 16, 14 and 11 µg/m3, respectively. After compiling data on regional background PM speciation from Europe to compare our data, it is evidenced that the Western Mediterranean aerosol is characterised by higher concentrations of crustal material but lower levels of OM + EC and ammonium nitrate than at central European sites. Relatively high PM2.5 concentrations due to the transport of anthropogenic aerosols (mostly carbonaceous and sulphate) from populated coastal areas were recorded, especially during winter anticyclonic episodes and summer midday PM highs (the latter associated with the transport of the breeze and the expansion of the mixing layer). Source apportionment analyses indicated that the major contributors to PM2.5 and PM10 were secondary sulphate, secondary nitrate and crustal material, whereas the higher load of the anthropogenic component in PM2.5 reflects the influence of regional (traffic and industrial) emissions. Levels of mineral, sulphate, sea spray and carbonaceous aerosols were higher in summer, whereas nitrate levels and Cl/Na were higher in winter. A considerably high OC/EC ratio (14 in summer, 10 in winter) was detected, which could be due to a combination of high biogenic emissions of secondary organic aerosol, SOA precursors, ozone levels and insolation, and intensive recirculation of aged air masses. Compared with more locally derived crustal geological dusts, African dust intrusions introduce relatively quartz-poor but clay mineral-rich silicate PM, with more kaolinitic clays from central North Africa in summer, and more smectitic clays from NW Africa in spring.  相似文献   

10.
Summary One of the great unknowns in climate research is the contribution of aerosols to climate forcing and climate perturbation. In this study, retrievals from AERONET are used to estimate the direct clear-sky aerosol top-of-atmosphere and surface radiative forcing effects for 12 multi-site observing stations in Europe. The radiative transfer code sdisort in the libRadtran environment is applied to accomplish these estimations. Most of the calculations in this study rely on observations which have been made for the years 1999, 2000, and 2001. Some stations do have observations dating back to the year of 1995. The calculations rely on a pre-compiled aerosol optical properties database for Europe. Aerosol radiative forcing effects are calculated with monthly mean aerosol optical properties retrievals and calculations are presented for three different surface albedo scenarios. Two of the surface albedo scenarios are generic by nature bare soil and green vegetation and the third relies on the ISCCP (International Satellite Cloud Climatology Project) data product. The ISCCP database has also been used to obtain clear-sky weighting fractions over AERONET stations. The AERONET stations cover the area 0° to 30° E and 42° to 52° N. AERONET retrievals are column integrated and this study does not make any seperation between the contribution of natural and anthropogenic components. For the 12 AERONET stations, median clear-sky top-of-atmosphere aerosol radiative forcing effect values for different surface albedo scenarios are calculated to be in the range of −4 to −2 W/m2. High median radiative forcing effect values of about −6 W/m2 were found to occur mainly in the summer months while lower values of about −1 W/m2 occur in the winter months. The aerosol surface forcing also increases in summer months and can reach values of −8 W/m2. Individual stations often have much higher values by a factor of 2. The median top-of-atmosphere aerosol radiative forcing effect efficiency is estimated to be about −25 W/m2 and their respective surface efficiency is around −35 W/m2. The fractional absorption coefficient is estimated to be 1.7, but deviates significantly from station to station. In addition, it is found that the well known peak of the aerosol radiative forcing effect at a solar zenith angle of about 75° is in fact the average of the peaks occurring at shorter and longer wavelengths. According to estimations for Central Europe, based on mean aerosol optical properties retrievals from 12 stations, the critical threshold of the aerosol single scattering albedo, between cooling and heating in the presence of an aerosol layer, is close between 0.6 and 0.76.  相似文献   

11.
Water-soluble dicarboxylic acids (DCAs), ketoacids, and α-dicarbonyls in the marine aerosol samples collected over the Southern Ocean and western Pacific Ocean were determined. Oxalic acid was the most abundant species, followed by malonic acid and then succinic acid. It is suggested that aerosol concentrations of the organics over the Southern Ocean in this work represent their global background levels. Over the Southern Ocean, total concentrations of DCAs ranged from 2.9 to 7.2 ng m−3 (average: 4.5 ng m−3), ketoacids from 0.14 to 0.40 ng m−3 (av.: 0.28 ng m−3), and dicarbonyls from 0.06 to 0.29 ng m−3 (av.: 0.11 ng m−3). Over the western Pacific, total concentrations of DCAs ranged from 1.7 to 170 ng m−3 (av.: 60 ng m−3), ketoacids from 0.08 to 5.3 ng m−3 (av.: 1.8 ng m−3), and dicarbonyls from 0.03 to 4.6 ng m−3 (av.: 0.95 ng m−3). DCAs over the western Pacific have constituted a large fraction of organic aerosols with a mean DCAs-C/TC (total carbon) of 7.0% (range: 0.59–14%). Such a high value was in contrast to the low DCAs-C/TC (av.: 1.8%; range: 0.89–4.0%) for the Southern Ocean aerosols. Based on the relative abundances and latitudinal distributions of these organics, we propose that long-range atmospheric transport is more important over the western Pacific Ocean, in contrast, in situ photochemical production is more significant over the Southern Ocean although absolute concentrations of the organics are much lower.  相似文献   

12.
The total extent of the atmospheric impacts associated to the aerosol black carbon (BC) emissions from South America is not completed described. This work presents results of BC monitored during three scientific expeditions (2002, 2003 and 2004) on board of a Brazilian oceanographic vessel Ary Rongel that covered the South–West Atlantic coast between 22–62°S. This latitudinal band encloses major urban regions of South America and the outflow region of the SACZ (South Atlantic Convergent Zone), which is an important mechanism of advective transport of heat, moisture, minor gases and aerosols from the South America continental land to the Southern Atlantic Ocean. Our results showed that aerosol BC enhanced concentrations from urban/industrial origin can be transported to the South–West Atlantic Ocean due to the migration of sub-polar fronts that frequently reach tropical/subtropical regions. Despite the decrease of aerosol BC concentrations southwards (from ∼1,200 ng m−3 at latitude 22°S to ∼10 ng m−3 at latitude 62°S), several observed peak events were attributed to regional urban activities. Most of such events could be explained by the use of air mass back trajectories analysis. In addition, a global model simulation is presented (Goddard Institute for Space Studies – GISS GCM BC simulation) to explore the origins of aerosol BC in the South–West Atlantic. The model allowed isolating the biomass emissions from South America and Africa and industrial (non-biomass) pollution from other regions of the globe. This model suggests that the apportionment of about half of the aerosol BC at the South–West Atlantic may derive from South American biomass burning.  相似文献   

13.
Climate forcing by carbonaceous and sulfate aerosols   总被引：3，自引：0，他引：3  
 An atmospheric general circulation model is coupled to an atmospheric chemistry model to calculate the radiative forcing by anthropogenic sulfate and carbonaceous aerosols. The latter aerosols result from biomass burning as well as fossil fuel burning. The black carbon associated with carbonaceous aerosols is absorbant and can decrease the amount of reflected radiation at the top-of-the-atmosphere. In contrast, sulfate aerosols are reflectant and the amount of reflected radiation depends nonlinearly on the relative humidity. We examine the importance of treating the range of optical properties associated with sulfate aerosol at high relative humidities and find that the direct forcing by anthropogenic sulfate aerosols can decrease from −0.81 W m-2 to −0.55 Wm-2 if grid box average relative humidity is not allowed to increase above 90%. The climate forcing associated with fossil fuel emissions of carbonaceous aerosols is calculated to range from +0.16 to +0.20 Wm-2, depending on how much organic carbon is associated with the black carbon from fossil fuel burning. The direct forcing of carbonaceous aerosols associated with biomass burning is calculated to range from −0.23 to −0.16 Wm-2. The pattern of forcing by carbonaceous aerosols depends on both the surface albedo and the presence of clouds. Multiple scattering associated with clouds and high surface albedos can change the forcing from negative to positive. Received: 29 September 1997 / Accepted: 10 June 1998  相似文献   

14.
A time series of microwave radiometric profiles over Arctic Canada’s Cape Bathurst (70°N, 124.5°W) flaw lead polynya region from 1 January to 30 June, 2008 was examined to determine the general characteristics of the atmospheric boundary layer in winter and spring. A surface based or elevated inversion was present on 97% of winter (January–March) days, and on 77% of spring (April–June) days. The inversion was the deepest in the first week of March (≈1100 m), and the shallowest in June (≈250 m). The mean temperature and absolute humidity from the surface to the top of the inversion averaged 250.1 K (−23.1°C), and 0.56 × 10−3 kg m−3 in winter, and in spring averaged 267.5 K (−5.6°C), and 2.77 × 10−3 kg m−3. The median winter atmospheric boundary-layer (ABL) potential temperature profile provided evidence of a shallow, weakly stable internal boundary layer (surface to 350 m) topped by an inversion (350–1,000 m). The median spring profile showed a shallow, near-neutral internal boundary layer (surface to 350 m) under an elevated inversion (600–800 m). The median ABL absolute humidity profiles were weakly positive in winter and negative in spring. Estimates of the convergence of sensible heat and water vapour from the surface that could have produced the turbulent internal boundary layers of the median profiles were 0.67 MJ m−2 and 13.1 × 10−3 kg m−2 for the winter season, and 0.66 MJ m−2 and 33.4 × 10−3 kg m−2 for the spring season. With fetches of 10–100 km, these accumulations may have resulted from a surface sensible heat flux of 15–185 W m−2, plus a surface moisture flux of 0.001–0.013 mm h−1 (or a latent heat flux of 0.7–8.8 W m−2) in winter, and 0.003–0.033 mm h−1 (or a latent heat flux of 2–22 W m−2) in spring.  相似文献   

15.
Characteristics of carbonyl compounds in ambient air of Shanghai,China   总被引：3，自引：0，他引：3  
The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m−3 respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.  相似文献   

16.
This paper presents the main experimental results of surface ozone concentrations measured at a rural area in Northern Spain from February 2000 to December 2005. Daily and seasonal variation of ozone has been analysed. The peak concentration levels are obtained in the afternoon, mean value around 88 μg m−3, with extreme average values of 59 μg m−3 in January and 113 μg m−3 in July. Small differences are found in the mean and median of the ozone levels from April to August, when spring and summer maxima are observed. Despite the great inter-annual ozone variability obtained, most air quality indicators showed a positive trend. Further analysis of the monthly mean ozone concentrations of the main percentiles have also been performed using a harmonic model. The upward trend was 6.2 ± 1.7 μg m−3 for the 98th percentile. To interpret the main features of the annual cycle and describe the ozone peaks, the influence of meteorological factors is studied. In summer, ozone production is governed by local processes, air temperature being the major controlling factor. However, the origin of the spring maximum is not so well identified.  相似文献   

17.
 The atmospheric general circulation model ECHAM-4 is coupled to a chemistry model to calculate sulfate mass distribution and the radiative forcing due to sulfate aerosol particles. The model simulates the main components of the hydrological cycle and, hence, it allows an explicit treatment of cloud transformation processes and precipitation scavenging. Two experiments are performed, one with pre-industrial and one with present-day sulfur emissions. In the pre-industrial emission scenario SO2 is oxidized faster to sulfate and the in-cloud oxidation via the reaction with ozone is more important than in the present-day scenario. The atmospheric sulfate mass due to anthropogenic emissions is estimated as 0.38 Tg sulfur. The radiative forcing due to anthropogenic sulfate aerosols is calculated diagnostically. The backscattering of shortwave radiation (direct effect) as well as the impact of sulfate aerosols on the cloud albedo (indirect effect) is estimated. The model predicts a direct forcing of −0.35 W m-2 and an indirect forcing of −0.76 W m-2. Over the continents of the Northern Hemisphere the direct forcing amounts to −0.64 W m-2. The geographical distribution of the direct and indirect effect is very different. Whereas the direct forcing is strongest over highly polluted continental regions, the indirect forcing over sea exceeds that over land. It is shown that forcing estimates based on monthly averages rather than on instantaneous sulfate pattern overestimate the indirect effect but have little effect on the direct forcing. Received: 16 October 1996/Accepted: 24 October 1996  相似文献   

18.
Black carbon concentration and weather data were online monitored continuously from March 2008 to February 2009 at the Akedala regional atmosphere station in the arid region of Central Asia. We present the daily, monthly and seasonal variations of BC concentration in the atmosphere and discuss the possible emission sources. Black carbon concentration in this region varies in the range of 43.7–1,559.2?ng/m3. A remarkable seasonal variation of BC in the aerosol was observed in the order of winter?>?spring?>?autumn?>?summer. The peak value of BC appeared at 10:00–13:00 while the lowest one at 7:00–9:00 each day. Air masses backward trajectories show the potential emission sources in the northwest from spring to autumn. Through back trajectory also revealed that BC in winter might be attributed to the emission from the anthropogenic activities, including domestic heating, cooking, combustion of oil and natural gas, and the medium-range transport from those cities in northern slope of Tianshan Mountains and Siberia. Some BC aerosols from the arid region of Central Asia were transported to the Pacific Ocean by the Westerlies.  相似文献   

19.
A continuous measurement of number size distributions and chemical composition of aerosol particles was conducted in Beijing in a dust storm event during 21-26 March 2001. The number concentration of coarse particles （ 〉2μm） increased more significantly than fine particles （ 〈2μm） during the dust storm due to dust weather, while the anthropogenic aerosols collected during the non-dust-storm period tended to be associated with fine particles. Elemental compositions were analyzed by using proton-induced X-ray emission （PIXE）. The results show that 20 elements in the dust storm were much higher than in the non-dust-storm period. The calculated soil dust concentration during the dust storm was, on average, 251.8μg m^-3, while it was only 52.1μg m^-3 on non-dust-storm days. The enrichment factors for Mg, A1, P, K, Ca, Ti, Mn, Fe, C1, Cu, Pb, and Zn show small variations between the dust storm and the non-dust-storm period, while those for Ca, Ni and Cr in the dust storm were much lower than those in the non-dust-storm period due to significant local emission sources. A high concentration and enrichment factor for S were observed during the dust storm, which implies that the dust particles were contaminated by aerosol particles from anthropogenic emissions during the long-range transport. A statistical analysis shows that the elemental composition of particles collected during the dust storm in Beijing were better correlated with those of desert soil colleted from desert regions in Inner Mongolia. Air mass back-trajectory analysis further confirmed that this dust storm event could be identified as streaks of dust plumes originating from Inner Mongolia.  相似文献   

20.
运用区域气候模式RegCM3耦合入一个化学过程,对东亚地区三类人为排放气溶胶（硫酸盐、黑碳和有机碳）的时空分布特征及其对夏季风环流的影响进行了数值模拟研究。模拟结果显示,气溶胶的引入会引起东亚地区夏季850 hPa风场发生改变,我国江淮以东洋面上空出现了一个气旋式距平环流中心,中心以西的偏北风气流将削弱东亚地区夏季西南季风。通过讨论春季中国地区气溶胶浓度与夏季东亚地区850 hPa经向风的时滞关系,以及夏季中国地区气溶胶浓度与同期东亚地区850 hPa经向风的关系,可以发现,春、夏季中国地区气溶胶浓度均与夏季东亚地区850 hPa经向风有很好的负相关关系,当春季中国北方和夏季中国南方地区气溶胶浓度增加时,中国东部地区夏季偏南季风减弱。这可能与气溶胶改变了大气层顶和地表的辐射强迫,进而引起了海陆气压差异和位势高度场的变化有关。  相似文献   

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