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1.
Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution230Thexcess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (230Th), 0.43–1.40 ppm (232Th), 0.09–0.49 ppb (234U) and 1.66–8.24 ppm (238U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the230Thexcess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant230Thexcess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.  相似文献   

2.
A deep-sea Mn nodule handpicked from top of a 20 cm diameter North Pacific tripod core was directly counted by an α-spectrometer with a silicon surface barrier detector. A distinct 210Po peak was recorded for the nodule upper side in contact with bottom seawater. Based on the spectrum, the 210Po (supported by 210Pb with 22 year half life) is thought to be confined in the top few microns of the nodule. Since the 210Po peak diminishes considerably for the bottom side resting on sediment, nondestructive α-spectrometry is useful for determining the sea floor orientation of nodules. This method was tested for a western North Pacific dredged Mn nodule, and was successful in identifying the orientation (and also surface loss of the nodule by dredging).Radiochemical analysis was also carried out for carefully scraped samples from the top and bottom of the two nodules. The growth rates of the hand-picked nodule based on excess 230Th and 231Pa profiles were 1 to 4 mm/106 y and apparently varied with time. The dredged sample has grown at 2 to 6 mm/ 106 y and the growth has likely been episodic. The radionuclide composition was significantly different between the top and bottom. Evidence was found that the radionuclide fluxes of 230Th and 231Pa into the nodules considerably changed during the growing histories. The 230Th/232Th activity ratios in the nodule tops are comparable with those in bottom seawater suggesting that the top is growing with metals of seawater origin. However it remains unresolved whether the nodule bottoms are growing by utilizing metals in the sediment pore water.  相似文献   

3.
Fifty buried manganese nodules at different depth intervals were recovered in 12 sediment cores from the Central Indian Ocean Basin (CIOB). A maximum of 15 buried nodules were encountered in one sediment core (AAS-22/GC-07) and the deepest nodule was recovered at 5.50 m below seafloor in core AAS-04/GC-5A. Approximately 80% of the buried nodules are small in size (2 cm diameter) in contrast to the Atlantic Ocean and Peru Basin (Pacific Ocean) where the majority of the buried nodules are large, 8 cm and >6 cm, respectively. Buried nodule size decreases with core depth and this distribution appears to be similar to the phenomenon of “Brazil Nut Effect”. Buried nodules exhibit both smooth and rough surface textures and are ellipsoidal, elongated, rounded, sub rounded, irregular and polynucleated. Buried nodules from siliceous ooze are enriched in Mn, Cu, Ni, Zn, Mo, Ga, V and Rb whereas those from red clay are enriched in Fe, Co, Ti, U, Th, Y, Cr, Nb and Rare Earth Elements (REE). Buried nodules from siliceous ooze suggest their formation under hydrogenetic, early digenetic and diagenetic processes whereas those from red clay are of hydrogenetic origin.REE are enriched more than 1.5 times in buried nodules from red clay compared to siliceous ooze. However, the mode of incorporation of REE into buried nodules from both sedimentary environments is by a single authigenic phase consisting of Fe–Ti–P. Shale-normalized REE patterns and Ce anomalies suggest that nodules from siliceous ooze formed under more oxidizing conditions than those from red clay. Nodules buried at depths between 1.5 and 2.5 m are diagenetic (Mn/Fe ratio 10–15), formed in highly oxic environments (large positive Ce anomalies) and record aeolian dust (high Eu anomalies). Chemical composition, surface texture and morphology of buried nodules are similar to those of surface nodules from the same basin. Furthermore, buried nodule compositions do not exhibit any distinct patterns within the core depth, suggesting that buried nodules neither grow nor dissolve after their burial in the sediment column.  相似文献   

4.
锰结核生长与沉积环境的关系   总被引：2，自引：0，他引：2  
罗尚德  王蕾 《沉积学报》1989,7(4):77-84
本文收集了48组世界大洋各种沉积环境锰结核化学组成和生长速率数据并计算了它们的铁锰通量；讨论了不同环境的锰结核的铁锰含量之间的关系，以及锰通量与铁通量、Mn/Fe比的相关性；导出了由锰结核锰铁含量计算生长速率的经验关系；从本质上揭示了锰结核化学组成、生长速率与沉积环境的内在联系，为探讨锰结核形成机理提供了有力的依据。  相似文献   

5.
Iodometric titration of deep sea sediment from cores at MANOP sites M and H indicate a particulate Mn oxidation state between 3.3 and 3.9 in the top 5 cm. Results from site H show a minimum in the Mn oxidation state at 1.5 cm depth indicating Mn reduction is occurring above the zone of pore water Mn oxidation. Using a simple box model, the rate of reduction is calculated to be 19 mg/cm2 kyr ? 77 mg/cm2 kyr, at least 5 times the flux of Mn to nodules in this region. Although no Mn oxidation state minimum is observed in site M sediments, oxic reduction is inferred from a particulate mass balance, indicating that a large fraction of the Mn rain to this site is not preserved in the sediments and must be remobilized. We suggest that the process of reduction in oxic or suboxic environments near the sediment-water interface may be an important mechanism controlling the concentration of Mn in sediments and provides a mechanism for supplying diagenetic Mn to the nodules at site H.  相似文献   

6.
A small (3 75 km2) impoundment. Union Lake, on the Maurice River in southern New Jersey contains fine-grained sediment and organic material being transported through the surface water system Sedimentation is slow and rates calculated from137Cs-dated cores indicate a decrease through time from 2 6 mm/yr to 0 57 mm/yr Sediment from shallow areas (<3 m) consists of winnowed preimpoundment fluvial sand, whereas sediment from deeper areas (>3 m) is dy composed of diatoms, organic matter, and silt- and clay-sized mineral grains Sediment distribution is controlled by water moving from the river entrance southward toward the outlet and by wind-generated water motion from shallow areas fringing the shore toward deeper portions of the impoundment  相似文献   

7.
胶州湾沉积速率:多种分析方法的对比*   总被引：5，自引：0，他引：5  
汪亚平  高抒 《第四纪研究》2007,27(5):787-796
根据胶州湾内外海域采集的柱状岩芯样品的 210 Pb测试,结合物源分析方法,计算了1952年以来胶州湾的沉积物收支状况和胶州湾区域的平均沉积速率。结果表明,胶州湾百年尺度的沉积速率较高,达到了100mm/a量级(7.43mm/a),沉积通量为10-3g/mm2a量级(7.39×10-3g/mm2a),而胶州湾外邻近海区沉积速率略低(4.46mm/a)。这与其他学者获得的海图地形对比法的结果大致相当。与胶州湾内钻孔岩芯的14 C测年对比表明,万年尺度的沉积速率为10-1mm/a量级(0.25~0.92mm/a),比百年尺度的沉积速率约小一个数量级。分析结果表明,沉积体系的演化过程使沉积速率随时空尺度的不同而产生差异,这是导致不同分析方法所获结果之间存在复杂关系的主要因素。  相似文献   

8.
Bulk chemical, mineralogical and selective leach analyses have been made on a suite of abyssal ferromanganese nodules and associated sediments from the S.W. equatorial Pacific Ocean. Compositional relations between nodules, sediment oxyhydroxides and nearby ferromanganese encrustations are drawn assuming that the crusts represent purely hydrogenetic ferromanganese material. Crusts, δMnO2-rich nodules and sediment oxyhydroxides are compositionally similar and distinct from diagenetic todorokitebearing nodules. Compared to Fe-Mn crusts, sediment oxyhydroxides are however slightly enriched, relative to Mn and Ni, in Fe, Cu, Zn, Ti and Al, and depleted in Co and Pb, reflecting processes of non-hydrogenous element supply and diagenesis. δMnO2 nodules exhibit compositions intermediate between Fe-Mn crusts and sediment oxyhydroxides and thus are considered to accrete oxides from both the water column and associated sediments.Deep ocean vertical element fluxes associated with large organic aggregates, biogenic calcite, silica and soft parts have been calculated for the study area. Fluxes associated with organic aggregates are one to three orders of magnitude greater than those associated with the other phases considered, are in good agreement with element accumulation rates in sediments, and are up to four orders of magnitude greater than element accumulation rates in nodules. Metal release from labile biogenic material in surface sediments can qualitatively explain the differences between the composition of Fe-Mn crusts and sediment oxyhydroxides.Todorokite-rich diagenetic nodules are confined to an eastwards widening equatorial wedge. It is proposed that todorokite precipitates directly from interstitial waters. Since the transition metal chemistry of interstitial waters is controlled dominantly by reactions involving the breakdown of organic carbon, the supply and degradation rate of organic material is a critical factor in the formation of diagenetic nodules. The wide range of (trace metal/Mn) ratios observed in marine todorokite reflects a balance between the release of trace metals from labile biogenic phases and the reductive remobilisation of Mn oxide, both of which are related to the breakdown of organic carbon.  相似文献   

9.
Using available information on the accretion rates and the bulk chemical compositions of oceanic ferromanganese nodules, it can be shown that the accumulation rate of manganese is proportional to the square of the accumulation rate of iron. This relationship has been used to derive an equation that predicts nodule growth rates from their chemical compositions. The equation accurately predicts growth rates up to about 50 mm/106 yr, but yields incorrect rates for faster-growing concretions. From this relationship nodules underneath water of high primary productivity grow most rapidly and accumulate transition metals most rapidly; however, nodules from regions of highest primary productivity do not have the highest concentrations of nickel and copper. Reduction of manganese within the sediment column and remobilization of a fraction to the surface sediments adds manganese to nodules without substantially augmenting the supply of other transition elements. The addition of remobilized manganese to the nodule dilutes the concentrations of nickel, copper and iron, even though their rates of accumulation are also high.  相似文献   

10.
Data from 291 small lakes and mires in eastern North America provide information on the natural variability of rates of sediment accumulation in these environments over the last 18,000 yr. Accumulation rates were calculated by linear interpolation between radiocarbon and biostratigraphic dates from sediment cores taken for pollen analysis. Within the data set, the rates were lognormally distributed with a mean accumulation rate of 91 cm/103 yr, and a range from less than 1 to over 3500 cm/103 yr. The accumulation rate data were divided into five subsets that were temporally or spatially distinct and therefore represent different geomorphic and climatic conditions at the time of deposition. Sediments deposited in basins north of 50°N, south of 40°N, and before 10,000 yr B.P. accumulated at much slower rates than sediments accumulating in midlatitude basins (between 40° and 50°N) between 10,000 and 330 yr B.P. Sediment accumulation over the last 330 yr has, on average, been at rates four to five times faster than any time previously. Inorganic sediments that could be radiocarbon-dated have accumulated at significantly lower rates than organic sediments, reflecting differences in depositional processes. For midlatitude basins during the Holocene, the most likely rate of continuous sediment accumulation within our data set is 65 cm/103 yr. Rates below 10 cm/103 yr are likely to be associated with nonconstant processes of sediment accumulation.  相似文献   

11.
Decay-series isotopes were measured on manganese nodules from three sedimentary environments, characterized by substrates of red clay (R), siliceous ooze (S) and hemipelagic clay (H). Growth rates of nodules are shown to be site dependent: 1–2 mm/Myr at site R, 3–8 mm/Myr at sites S, and 20–50 mm/ Myr at site H. Correlation between growth rate and the parameter Mn/Fe2 suggests that regional diagenetic variations control the compositions and growth rates of the nodules. The frequency of nodule turnover and the period of their growth are assessed from the “top” vs. “bottom” distributions of several nuclides. Based on the 230Th, 231Pa and 226Ra data, turnover times of 103 to 105 years are estimated and they vary with relative size and shape of the specimens at a given site. The presence of unsupported 210Pb and 228Th in the top surfaces but not in the bottom surfaces of the surface nodules suggests active growth during the last decades or years, despite their old ages. The data also indicate that turnover rates are not more frequent than once every several years or decades.The 230Th-226Ra, 226Ra-210Pb and 232Th-228Th disequilibrium relationships in the nodules allow the migratory behavior of 226Ra, 222Rn and 228Ra and their fluxes to be deduced: thus radium leaves the top sides but enters the bottom sides of the surface nodules at sites R and S. At site R there is a net loss of radium to the sea; the opposite is true at site S. Surface nodules at site H trap radium from both sides, probably due to more intense diagenetic input of radium from sediment pore water. The effective diffusivities of 226Ra in nodules vary from 3 × 10?12 to 8 × 10?14 cm2/s, dependent on the textural variation of the nodule material, which crudely reflects the growth rate and hence sedimentary environment. 222Rn diffuses out of nodules from all sides, with an effective diffusivity of ca. (2–6) × 10?8 cm2/s. At all sites nodules serve as a more effective source of 222Rn to sea water than their adjacent sediments. The outward flux of 222Rn from nodules relative to that from adjacent sediments tends to be higher in more reduced environments, an effect caused by the fact that Mn-rich nodules from more reduced environment act as a more efficient trap for 226Ra.  相似文献   

12.
We present a quantification of total and partial (divided by time slices) sedimentary volumes in the Neogene basins of the Betic-Rif orogen. These basins include the Alboran Sea, the intramontane basins, the Guadalquivir and Rharb foreland basins and the Atlantic Margin of the Gibraltar Arc. The total volume of Neogene sediments deposited in these basins is ~ 209,000 km3 and is equally distributed between the internal (Alboran Basin and intramontane basins) and the external basins (foreland basins and Atlantic Margin). The largest volumes are recorded by the Alboran Basin (89,600 km3) and the Atlantic Margin (81,600 km3). The Guadalquivir and Rharb basins amount 14,000 km3 and 14,550 km3, respectively whereas the intramontane basins record 9235 km3. Calculated mean sediment accumulation rates for the early-middle Miocene show an outstanding asymmetry between the Alboran basin (0.24 mm/yr) and the foreland basins (0.06-0.07 mm/yr) and the Atlantic Margin (0.03 mm/yr). During the late Miocene, sedimentation rates range between 0.17 and 0.18 mm/yr recorded in the Alboran Basin and 0.04 mm/yr in the intramontane basins. In the Pliocene-Quaternary, the highest sedimentation rates are recorded in the Atlantic Margin reaching 0.22 mm/yr. Sedimentary contribution shows similar values for the inner and outer basins with a generalized increase from late Miocene to present (from 3500 to 6500 km3/My). Interestingly, the Alboran Basin records the maximum sedimentary contribution during the late Miocene (5500 km3/My), whereas the Atlantic Margin does during the Pliocene-Quaternary (6600 km3/My). The spatial and time variability of the sediment supply from the Betic-Rif orogen to basins is closely related to the morphotectonic evolution of the region. The high sedimentation rates obtained in the Alboran Basin during the early-middle Miocene are related to active extensional tectonics, which produced narrow and deep basins in its western domain. The highest sedimentary contribution in this basin, as well as in the foreland and intramontane basins, is recorded during the late Miocene due to the uplift of wide areas of the Betics and Rif chains. The analysis of the sedimentary supply also evidences strong relationships with the post-Tortonian crustal thickening and coeval topographic amplification that occurred in the central Betics and Rif with the concomitant evolution of the drainage network showing the fluvial capture of some internal basins by rivers draining to the Atlantic Ocean (the ancestral Guadalquivir).  相似文献   

13.
Deep-sea nodules from the Northeast Pacific nodule belt and the Southeast Pacific (Sonne Basin), being formed in areas bordering the equatorial zone of high biological productivity, accumulate by two basically different growth processes: (A) early diagenetic growth by supply from pore water and (B) hydrogenetic growth by supply from near-bottom sea-water. These growth processes lead to different genetic types of nodules: early diagenetic type A, hydrogenetic type B, and mixed-type AB; a further type AC, very rich in Mn, is being formed by increasing influence of early diagenesis. These types can clearly be distinguished by their shapes, surface textures, mineral constituents of oxide fraction, internal microstructures, and geochemistry. A genetical classification is being proposed on the basis of statistically computed interelement relationships. Todorokite, very poor in Fe, is the main Mn phase in the early diagenetic substance; -MnO2 intimately intergrown with FeOOH · xH2O is the main phase in the hydrogenetic substance. Consequently an important difference can be pointed out: the metal supply for the growth of the early diagenetic nodules is based on an ionic solution of Me2+ (e. g. Mn2+, Ni2+, Cu2+, Zn2+), whereas the supply for the hydrogenetic nodules is caused by transport of colloidal particles. Mobilization of Mn2+ and fractionation from Fe is controlled by the amount of decomposing organic matter in the "peneliquid" layer of the sediments. The main factor controlling the intensity of early diagenesis is the biological productivity in surface waters. The crucial "point of reversal" at a Mn/Fe ratio of about 5, obtained by hyperbolical regression of the analyses of nodules from the Southeast Pacific, represents best concentrations in Ni and Cu. Mn/Fe quotients greater than 5 cause a decrease of Ni and Cu content. Nodules from the Northeast Pacific nodule belt generally contain higher concentrations in Cu than nodules from the Southeast Pacific. This can be explained by an additional supply of Cu transported below CCD by siliceous plankton.  相似文献   

14.
Cosmogenic nuclide-based denudation rates and published erosion rates from recent river gauging in the Napo River basin (Peruvian Amazonia) are used to decipher erosion and sedimentation processes along a 600 km long transect from the headwaters to the lowlands. The sediment-producing headwaters to the Napo floodplain are the volcanically active Ecuadorian Andes, which discharge sediment at a cosmogenic nuclide-based denudation rate of 0.49 ± 0.12 mm/yr. This denudation rate was calculated from an average 10Be nuclide concentration of 2.2 ± 0.5 × 104 at/g(Qz) that was measured in bedload-derived quartz. Within the Napo lowlands, a significant drop in trunk stream 10Be nuclide concentrations relative to the Andean hinterland is recorded, with an average concentration of 1.2 ± 0.5 × 104 at/g(Qz). This nuclide concentration represents a mixture between the 10Be nuclide concentration of eroded floodplain deposits, and that of sediment eroded from the Andean hinterland that is now carried in the trunk stream. Evidence for addition of sediment from the floodplain to the trunk stream is provided by published decadal-scale sediment flux measurements from gauging stations operated in the Napo basin, from which an increase from 12 × 106 t/yr at the outflow of the Andes to ～47 × 106 t/yr at the confluence with the Solimões (upper Amazon River) is recorded. Therefore, approximately 35 × 106 t of floodplain sediment are added annually to the active Napo trunk stream. Combined with our nuclide concentration measurements, we can estimate that the eroded floodplain deposits yield a nuclide concentration of ～0.9 × 104 at/g(Qz) only. Under steady state surface erosion conditions, this nuclide concentration would translate to a denudation rate of the floodplain of ～0.47 mm/yr. However, we have no geomorphologic explanation for this high denudation rate within the low relief floodplain and thus suggest that this low-nuclide concentrated sediment is Andean-derived and would have been deposited in the floodplain at a time when erosion rates of the Andes were elevated. Therefore, the recently eroded floodplain sediment provides an Andean “paleo denudation rate” of 1.2 mm/yr that was calculated for high Andean production rates. A likely period for elevated erosion rates is the LGM, where climate and vegetation cover of the Andes differed from that of the Holocene. A possible cause for the erosion of the floodplain is the tectonic uplift of the Eastern Andes, which progressively shifts the Napo River northwards. Hence, the river cuts into ancient lowland sediment, which is admixed to the Andean sediment carried in the main Napo River.  相似文献   

15.
Radiocarbon-dated sediment cores from the Champlain Valley (northeastern USA) contain stratigraphic and micropaleontologic evidence for multiple, high-magnitude, freshwater discharges from North American proglacial lakes to the North Atlantic. Of particular interest are two large, closely spaced outflows that entered the North Atlantic Ocean via the St. Lawrence estuary about 13,200–12,900 cal yr BP, near the beginning of the Younger Dryas cold event. We estimate from varve chronology, sedimentation rates and proglacial lake volumes that the duration of the first outflow was less than 1 yr and its discharge was approximately 0.1 Sv (1 Sverdrup = 106 m3 s−1). The second outflow lasted about a century with a sustained discharge sufficient to keep the Champlain Sea relatively fresh for its duration. According to climate models, both outflows may have had sufficient discharge, duration and timing to affect meridional ocean circulation and climate. In this report we compare the proglacial lake discharge record in the Champlain and St. Lawrence valleys to paleoclimate records from Greenland Ice cores and Cariaco Basin and discuss the two-step nature of the inception of the Younger Dryas.  相似文献   

16.
Manganese nodules and manganese carbonate concretions occur in the upper 10–15 cm of the Recent sediments of Loch Fyne, Argyllshire in water depths of 180–200 m. The nodules are spherical, a few mm to 3 cm in diameter, and consist of a black, Mn-rich core and a thin, red, Fe-rich rim. The carbonate occurs as irregular concretions, 0.5–8 cm in size, and as a cement in irregular nodule and shell fragment aggregates. It partially replaces some nodule material and clastic silicate inclusions, but does not affect aragonitic and calcitic shell fragments.The nodules are approximately 75% pure oxides and contain 30% Mn and 4% Fe. In the cores, the principal mineral phase is todorokite, with a Mn/Fe ratio of 17. The rim consists of X-ray amorphous Fe and Mn oxides with a Mn/Fe ratio of 0.66. The cores are enriched, relative to Al, in K, Ba, Co, Mo, Ni and Sr while the rims contain more P, Ti, As, Pb, Y and Zn.The manganese carbonate has the composition (Mn47.7 Ca45.1 Mg7.2) CO3. Apart from Cu, all minor elements are excluded from significant substitution in the carbonate lattice.Manganese nodules and carbonates form diagenetically within the Recent sediments of Loch Fyne. This accounts for the high Mn/Fe ratios in the oxide phases and the abundance of manganese carbonate concretions. Mn concentrations in the interstitial waters of sediment cores are high (ca. 10 ppm) as also, by inference, are the dissolved carbonate concentrations.  相似文献   

17.
Below the zone where manganese is remobilized as Mn2+(aq), reductively cleaned foraminifera in deep sea sediments have much higher MnCa than those in core tops and sediment traps. MnCa ranges from less than 20 × 10?6 in and above the MnO2 maximum to as high as 700 × 10?6 in reducing Panama Basin sediments. The most plausible explanation for this enrichment is that the tests are coated with Mn carbonate overgrowths. These coatings can account for a significant proportion of the Mn in reduced deep-sea sediments. Uptake of manganous ion by carbonate may explain the absence of Mn nodules in areas of high carbonate accumulation. Extreme degrees of overgrowth can alter foram trace element values, but this artifact can be avoided by avoiding foraminifera with high Mn/Ca.  相似文献   

18.
Recent sediment cores of the western Baltic Sea were analyzed for heavy metal and carbon isotope contents. The sedimentation rate was determined from radiocarbon dates to be 1.4 mm/yr. The ‘recent age’ of the sediment was about 850 yr. Within the upper 20 cm of sediment, certain heavy metals became increasingly enriched towards the surface; Cd, Pb, Zn and Cu increased 7-, 4-, 3- and 2-fold, respectively, whereas Fe, Mn, Ni and Co remained unchanged. Simultaneously, the radiocarbon content decreased by about 14 per cent. The enrichment in heavy metals as well as the decrease in the 14C-concentration during the last 130 ± 30yr parallels industrial growth as reflected in European fossil fuel consumption within that same period of time. The near-surface sediments are affected by residues released from fossil fuels at the rate of about 30 g/m2 yr for the past two decades. The residues have a pronounced effect on the heavy metal and carbon isotope composition of the most Recent sediments allowing estimates to be made for sedimentation, erosion and heavy metal pollution.  相似文献   

19.
Results of the study of shallow-water ferromanganese nodules in the Gulf of Finland of the Baltic Sea, which are of practical interest for metallurgical and chemical industries, are discussed. The nodules contain the following elements: Mn, Fe, Si, Al, Na, Mg, Ti, K, V, Cu, Ni, Zn, P, and Ba. Contents of Mn (～30%) and Fe (～10%) are virtually similar to those in deep-sea oceanic nodules. However, concentrations of Ti, Cu, and Ni are notably lower than average values in oceanic nodules. The helium isotopic composition was studied to reveal cosmic dust in the nodule substance. The measured 3He and 4He concentrations are ～10?12 and ～10?5 cm3/g, respectively. The isotope ratio 3He/4He is approximately 10?7. More than 60% 3He is of cosmic (solar) origin, whereas 4He is of terrigenous (radiogenic) origin. Based on the cosmic duct concentration and the space tracer method, the FMN growth rate is estimated at 8–9 mm/ka at the nodule age varying from ～800 to 1500 yr. The growth rate of nodule has negative correlation with its size. Based on literature data, the growth rate of FMN from the western Baltic Sea is twice as high. An independent calculation of the FMN growth rate based on the diffusion-sorption mechanism (DSM) yielded 8.1 mm/ka, which is very close to the result based on the space tracer method. This value is proposed as the average growth rate of the studied nodules. Comparison with our previous measurements of growth rates for oceanic nodules showed that these values differ only slightly and are equal to n mm/ka, where n < 10. It is inferred that the formation mechanism of both marine and oceanic nodules is based on the same principles that control the generation of mobile forms of Mn in the bottom layer of sediments, i.e., principles related to bioproductivity of sea and ocean basins. Fluxes of lithogenic forms of Mn are of minor importance.  相似文献   

20.
The major and minor element composition of ferromanganese nodules from DOMES Site A has been determined by X-ray fluorescence methods. Three phases appear to control the bulk compositions: Mn and Fe oxyhydroxides and aluminosilicates. Relatively wide compositional variations are evident throughout the area. Nodules with high Mn/Fe ratios, high Cu, Mg, Mo, Ni and Zn concentrations and high todorokite/δ-MnO2 ratios have granular surface textures and are confined to an east-west trending depression with thin Quaternary sediment cover. Nodules with low Mn/Fe ratios, high concentrations of As, Ca, Ce, Co, La, P, Sr, Ti, V, Y and Zr and low todorokite/δ-MnO2 ratios have smooth surfaces and are confined to shallower areas with relatively thick Quaternary sediment to the north and south of the depression.All nodules in the area have compositions which are influenced by diagenesis, but those with the most marked diagenetic signature (high Mn/Fe and Cu/Ni ratios, low Ce/La ratios and more todorokite) are found in areas of very slow or non-existent sedimentation; many of these nodules are actually in contact with outcropping Tertiary sediment. This paradox may be resolved by postulating, by analogy with some shallow-water occurrences, that the nodules accrete from bottom waters which have enhanced particulate and dissolved metal contents derived from diagenetic reaction in areas remote from the site of nodule formation. The metals are supplied in a bottom flow (probably Antarctic Bottom Water) which also erodes, or prevents modern sedimentation in, the depression. Nodules on the flanks of the depression are not evidently affected by this flow and derive at least pan of their constituent metals from diagenetic reaction in the underlying Quaternary sediment.Apparently, abyssal diagenetic nodules can have an immediate and a remote diagenetic metal source. Metal fluxes derived from pore water dissolved metal gradients may not be relevant to particular accreting nodules if a significant fraction of their metals is derived from outside the area in which they form.  相似文献   

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