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1.
The gas and particle phase products from the reaction of -pinene with the atmospheric oxidants O3 and OH radicals in the presence of NOx were investigated using both gas chromatography-mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC) for identification and quantification of reaction products. The nighttime oxidation of -pinene in the presence of O3/air and the daytime oxidation of -pinene in the presence of NOx/air and natural sunlight were carried out in the University of North Carolina large outdoor smog chamber (190 m3) located in Chatham County, North Carolina. A Scanning Mobility Particle Sizer system (3936, TSI) and a Condensation Particle Counter (3025A, TSI) were used to study the secondary organic aerosol (SOA) formation, and a filter pack/denuder sampling system was used for simultaneously collecting gas and particle phase products for analysis. A gas chromatograph coupled to a mass spectrometer (GC-EIMS or GC-CIMS) was used for the identification and quantification of gas and aerosol products. A HPLC method was used for the measurement of small carbonyl compounds (aldehydes and ketones) as their 2,4-dinitrophenylhydrazones (DNPH) derivatives. Mass balances for gaseous and aerosol reaction products were reported over the course of the reaction. More than sixteen products were identified and/or quantified in this study. On average, measured gas and particle phase products accounted for 57 to 71% of the reacted -pinene carbon. Measurements showed that a number of reaction products were found in both O3 and NOx systems (pinic acid, pinalic-3-acid, 4-hydroxypinalic-3-acid, 4-oxonopinone, 1-hydroxynopinone, 3-hydroxynopinone, and nopinone). Pinic acid, pinalic-3-acid, and 4-hydroxypinalic-3-acid were observed in the early stage in the aerosol phase and may play an important role in the early formation of secondary aerosols. Detailed reaction schemes are presented to account for most of the observed reaction products. 相似文献
2.
The gas and particle phase reaction products of a mixture of the atmospherically important terpenes -pinene and -pinene with the atmospheric oxidants O3 and OH/NOx were investigated using both gas chromatography-mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC) for identification and quantification of reaction products. The nighttime oxidation of a mixture of -pinene and -pinene in the presence of O3/air, and the daytime oxidation of a mixture of -pinene + -pinene with NOx air in the presence of natural sunlight were carried out in the University of North Carolina's large outdoor smog chamber (190 m3) located in Chatham County, North Carolina. Mass balances for gaseous and aerosol reaction products are reported over the course of the reaction. More than twenty-nine products were identified and/or quantified in this study. On average, measured gas and particle phase products accounted for 74 to 80% of the reacted -pinen/-pinene mixture carbon. Measurements show that a number of reaction products were found in both O3 and NOx system [pinonaldehyde, pinic acid, pinonic acid, pinalic-3-acid, 4-hydroxypinalic-3-acid, 4-oxonopinone, 1-hydroxy-nopinone, 3-hydroxy-nopinone, and nopinone]. Pinonic acid, pinic acid, pinalic-3-acid, 4-hydroxypinalic-3-acid, and 10-hydroxypinonic acid were observed in the early stage in the aerosol phase and may play an important role in the early formation of secondary aerosols. 相似文献
3.
Bused on January 1962-October 1993 mean value series of monthly mean temperature anomalies of 16 Antarctic stations on 10 standard isobanc surfaces from the surface to the 30 hPa,long term trends and periodic features of climate changes from the troposphere to the lower stratosphere over the Antarctic region are investigated by maximum entropy power spectrum analysis,and the relation between climate change of the stratosphere (troposphere) and tolal ozone (southern 500 hPa circulation) is discussed. 相似文献
4.
Summary In the framework of the Swiss National Research Program 31 Climate changes and natural disasters the question was brought up whether a global warming of the atmosphere would have an influence on the frequency and/or intensity of the extratropical storms of the Swiss winter season. In order to investigate a possible trend, time series of days with a minimum wind speed estimate or measurement equivalent to Beaufort 7, 8 and 9 were established. The longest being a record of the mesonet station Zürich from the period 1864 until 1993 (130 years). Slightly shorter time series for three additional stations in Northern Switzerland were compiled to control the behavior of the longest record and to verify the observed temporal trend. From the location of the four investigated wind records the observational domain was restricted to the part of Switzerland north of the Alps whereas for further meteorological considerations the whole North-Atlantic-European area was included.A negative regional trend in the number of storm days has been observed during the last century. In particular, the period before 1940 has to be interpreted as windier than the following decades. The duration of a storm event also decreased on average. In spite of an increase in cyclonic westwind situations since about 1960 over Europe, Switzerland was hit by fewer storms during the same period. One explanation could be that the whole westwind belt has moved slightly further north where a deepening of the cyclones was observed in recent times. Switzerland is usually situated at the southernmost edge of the particular storm fields and is therefore less influenced by strong gales. Rare exceptions are the cases when a secondary depression directly hits Central Europe, e.g. as happened in February 1990 (storm Vivian).With 11 Figures 相似文献
5.
Sayed M. Elshazly 《大气科学进展》1996,13(4):519-532
Data on instantaneous atmospheric Linke turbidity factor TL (m) are reported for clear days at Qena/Egypt in the period from June 1992 to May 1993.TL(m) is determined using the values of irradiance of direct solar radiation (I),which are calculated from global (G) and diffuse (D) - solar radiation measurements.Monthly and seasonally variations of both diurnal and daily average values of TL (m) increases steadily in the direction of sunset in the months from June to December 1992 as well as Summer and Autumn seasons,while it falls generally in this direction for the months from January to March and Winter season.In April and May,TL (m) fluctuates obviously through the day hours,it is also shown that the average values of TL(m) are particularly large during Summer months compared to other months of the year.This behavior of TL(m) is discussed in view of the variations of some weather elements,which affect the content of water vapor and dust particle in the atmosphere of the study region.It seems t be of s 相似文献
6.
Abstract Snow‐plus‐ice thickness and surface‐ice roughness data collected by a helicopter‐towed sensor package was used to identify surface‐ice properties in March 1992 AVHRR and SAR images for the land‐fast and mobile pack ice off the northern coast of Newfoundland. The sensor package consisted of an electromagnetic induction sensor and laser profilometer. Observed snow depths and ice thicknesses verified that snow‐plus‐ice thickness over undeformed ice can be obtained to an accuracy of ±10 cm. Snow‐plus‐ice thickness and surface roughness data for flight sections covering several hundred kilometres indicated the change in pack ice properties seen in images from thin, smooth coastal ice and open water conditions to thick, rough consolidated offshore pack ice. Ice charts covering the same area showed similar variations in ice conditions based on AVHRR and fixed‐wing reconnaissance data. In the ERS‐1 SAR image, low backscattering coefficients were associated with large, smooth coastal floes interspersed with areas of high backscatter indicating the presence of waves in open water areas. Backscattering coefficients were higher in the rubble areas near the inshore edge of the pack ice than in the interior of the pack ice itself. Distinguishing ice types on the basis of tone alone in SAR imagery was found to be problematic; however in combination with other remotely sensed data such as AVHRR data, SAR data will become more useful in distinguishing ice types. 相似文献
7.
The Indian summer monsoon of 1982 and 1997 depicts disparities, however, maximum sea surface temperature anomaly over Niño 3 region is observed in the following winter of both the years. The inter-annual variation of sea surface temperature anomaly shows maximum peak during 1982/83 and 1997/98 El Niño events. The inter-annual variation of multivariate ENSO index also supports the above observation. The analyses of the entire tropical Pacific basin including the equatorial region reveal an anomalous behavior of the mean sea level pressure (MSLP) and the convective activities. The observations further reveal that the negative anomaly in monsoon rainfall over India prevails throughout the monsoon season except for the month of August in 1982, while in the year 1997 the monsoon rainfall anomaly shows random variations. The comparison between the summer monsoon rainfall of 1982 and 1997 depicts that the magnitude of the positive anomaly is same in the month of August. The condition over tropical Pacific during 1982/83 and 1997/98 has been investigated through the variation of outgoing long wave radiation (OLR), MSLP and pressure vertical velocity. The time–longitude plots of OLR and MSLP reveal the changes in pressure distribution and convective pattern over the tropical equatorial Pacific. The zonal and meridional cross section of pressure vertical velocity over the tropical Pacific and tropical Indian Ocean facilitates to understand the strength of the vertical motion during the monsoons of 1982 and 1997. 相似文献
8.
In the present reported study, the vertical distributions of local atmospheric refractivity were retrieved from ground- based GPS observations at low elevation angles. An improved optimization method was implemented at altitudes of 0-10 km to search for a best-fit refractivity profile that resulted in atmospheric delays most similar to the delays calculated from the observations. A ray-tracing model was used to simulate neutral atmospheric delays corresponding to a given refractivity profile. We initially performed a ＂theoretical retrieval＂, in which no observation data were involved, to verify the optimization method. A statistical relative error of this ＂theoretical retrieval＂ （-2% to 2%） indicated that such a retrieval is effective. In a practical retrieval, observations were obtained using a dual-frequency GPS receiver, and its initial value was provided by CIRA86aQ_UoG data. The statistical relative errors of the practical retrieval range from -3% to 5% were compared with co-located radiosonde measurements, Results clearly revealed diurnal variations in local refractivity prc,files, The results also suggest that the general vertical distribution of refractivity can be derived with a high temporal resolution. However, further study is needed to describe the vertical refractivity gradient clearly. 相似文献
9.
This study uses multiple sea surface temperature(SST) datasets to perform a parallel comparison of three super El Ni os and their effects on the stratosphere. The results show that, different from ordinary El Ni os, warm SST anomalies appear earliest in the western tropical Pacific and precede the super El Ni o peak by more than 18 months. In the previous winter,relative to the mature phase of El Ni o, as a precursor, North Pacific Oscillation-like circulation anomalies are observed. A Pacific–North America(PNA) teleconnection appears in the extratropical troposphere during the mature phase, in spite of the subtle differences between the intensities, as well as the zonal position, of the PNA lobes. Related to the negative rainfall response over the tropical Indian Ocean, the PNA teleconnection in the winter of 1997/98 is the strongest among the three super El Ni os. The northern winter stratosphere shows large anomalies in the polar cap temperature and the circumpolar westerly, if the interferences from other factors are linearly filtered from the circulation data. Associated with the positive PNA response in a super El Ni o winter, positive polar cap temperature anomalies and circumpolar easterly anomalies,though different in timing, are also observed in the mature winters of the three super El Ni os. The stratospheric polar vortex in the next winter relative to the 1982/83 and 1997/98 events is also anomalously weaker and warmer, and the stratospheric circulation conditions remain to be seen in the coming winter following the mature phase of the 2015/16 event. 相似文献
10.
In Dynamic Global Vegetation Models （DGVMs）, the establishment of woody vegetation refers to flowering, fertiliza- tion, seed production, germination, and the growth of tree seedlings. It determines not only the population densities but also other important ecosystem structural variables. In current DGVMs, establishments of woody plant functional types （PFTs） are assumed to be either the same in the same grid cell, or largely stochastic. We investigated the uncertainties in the competition of establishment among coexisting woody PFTs from three aspects： the dependence of PFT establishments on vegetation states; background establishment; and relative establishment potentials of different PFTs. Sensitivity experi- ments showed that the dependence of establishment rate on the fractional coverage of a PFT favored the dominant PFT by increasing its share in establishment. While a small background establishment rate had little impact on equilibrium states of the ecosystem, it did change the timescale required for the establishment of alien species in pre-existing forest due to their disadvantage in seed competition during the early stage of invasion. Meanwhile, establishment purely fiom background （the scheme commonly used in current DGVMs） led to inconsistent behavior in response to the change in PFT specification （e.g., number of PFTs and their specification）. Furthermore, the results also indicated that trade-off between irtdividual growth and reproduction/colonization has significant influences on the competition of establishment. Hence, further development of es- tablishment parameterization in DGVMs is essential in reducing the uncertainties in simulations of both ecosystem structures and successions. 相似文献
11.
Reliability Analyses of Anomalies of NCEP/NCAR Reanalyzed Wind Speed and Surface Air Temperature in Climate Change Research in China 总被引：3，自引：0，他引：3 
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下载免费PDF全文 By means of varied statistical methods,such as normalized root mean square error(RMSE),correlation analysis,empirical orthogonal function(EOF)decomposition,etc.,the reliability of the varied seasonal anomalies of NCEP/NCAR reanalyzed wind speed and surface air temperature(SAT)data frequently used in the climate change research in China is studied.Results show that RMSEs of meteorological variables are smaller in eastern China than in western China,i.e.,the reliability of NCEP/NCAR reanalysis in eastern China is better than that in western China.This could be due to effects of the topography in the reanalysis model and the disposition of"dense-in-eastern-and-sparse-in-western"of meteorological stations in China. The RMSE of anomalies of reanalyzed wind speeds decreases with increasing height,further confirming the possible impact of topography on reliability of reanalysis.Results of correlation analysis inversely correspond to those of RMSE analysis,i.e.,if the RMSE is larger,the correlation between reanalyzed and observed data is worse,and vice versa.It is found from comparing the EOF eigenvectors of anomaly of reanalyzed and observed data that if a meteorological variable has smaller RMSE,the spatial patterns of corresponding EOF eigenvectors of anomaly of reanalyzed and observed data are similar and their time coefficients are significantly correlated,and vice versa.Therefore,the similarity of EOF modes and the consistency of their time coefficients can be used to objectively assess the reliability of the reanalysis.On the whole,the reliability of the reanalyzed wind speed is better in spring,summer,and autumn,but worse in winter;and for the reanalyzed SAT,it is the best in winter and the worst in summer. 相似文献
12.
An Application of the RAMS/FLUENT System on the Multi-Scale Numerical Simulation of the Urban Surface Layer A Preliminary Study 总被引：1，自引：0，他引：1
The Regional Atmospheric Modeling System （RAMS） and the computational fluid dynamics （CFD） codes known as FLUENT are combinatorially applied in a multi-scale numerical simulation of the urban surface layer （USL）. RAMS and FLUENT are combined as a multi-scale numerical modeling system, in which the RAMS simulated data are delivered to the computational model for FLUENT simulation in an offline way. Numerical simulations are performed to present and preliminarily validate the capability of the multi-scale modeling system, and the results show that the modeling system can reasonably provide information on the meteorological elements in an urban area from the urban scale to the city-block scale, especially the details of the turbulent flows within the USL. 相似文献
13.
Li Shi Harry H. Hendon Oscar Alves Matthew C. Wheeler David Anderson Guomin Wang 《Climate Dynamics》2011,37(1-2):313-324
The importance of initializing atmospheric intra-seasonal (stochastic) variations for prediction of the onset of the 1997/1998 El Ni?o is examined using the Australian Bureau of Meteorology coupled seasonal forecast model. A suite of 9-month forecasts was initialized on the 1st December 1996. Observed ocean initial conditions were used together with five different atmospheric initial conditions that sample a range of possible initial states of intra-seasonal (stochastic) variability, especially the Madden-Julian Oscillation (MJO), which is considered the primary stochastic variability of relevance to El Ni?o evolution. The atmospheric initial states were generated from a suite of atmosphere-only integrations forced by observed sea surface temperatures (SST). To the extent that low frequency variability of the tropical atmosphere is forced by slow variations in SST, these atmospheric states should all represent realistic low frequency atmospheric variability that was present in December 1996. However, to the extent that intra-seasonal variability is not constrained by SST, they should capture a range of intra-seasonal states, especially variations in the activity, phase and amplitude of the MJO. For each of these five states, a 20-member ensemble of coupled model forecasts was generated by the addition of small random perturbations to the SST field at the initial time. The ensemble mean from all five sets of forecasts resulted in El Ni?o but three of the sets produced substantially greater warming by months 4?C5 in the NINO3.4 region compared to the other two. The warmer group stemmed from stronger intra-seasonal westerly wind anomalies associated with the MJO that propagated eastward into the central Pacific during the first 1?C2?months of the forecast. These were largely absent in the colder group; the weakest of the colder group developed strong easterly wind anomalies, relative to the grand ensemble mean, that propagated into the central Pacific early in the forecast, thereby generating significantly weaker downwelling Kelvin waves in comparison to the warmer group. The strong reduction in downwelling Kelvin waves in the weakest case acted to limit the warming in the eastern Pacific, resulting in a ??Modoki?? type El Ni?o that is more focused in the central Pacific. Our results suggest that the intra-seasonal stochastic component of the atmospheric initial condition has an important and potentially predictable impact on the forecasts of the initial warming and flavour of the 1997/1998 El Ni?o. However, to the extent that atmospheric intra-seasonal variability is not predictable beyond a month or two, these results imply a limit to the accuracy with which the strength and perhaps the spatial distribution of an El Ni?o can ultimately be predicted. These results do not preclude a predictable role of the MJO and other intra-seasonal stochastic variability at longer lead times if some aspects of the stochastic variability are preconditioned by the evolving state of El Ni?o or other low frequency boundary forcing. 相似文献
14.
M. J. Salinger Simon McGree Florent Beucher Scott B. Power François Delage 《Climate Dynamics》2014,43(3-4):881-892
Quality controlled and recently homogenised mean sea level pressure records for the South Pacific are used to specify the location and variability of the South Pacific convergence zone (SPCZ) during the austral warm season (November–April). The SPCZ is the world’s largest rainfall band during the austral summer, when it dominates the climate of the South Pacific. A new index called the South Pacific convergence zone index (SPCZI) is derived, and is shown to be coherent with changes in low level wind convergence associated with the SPCZ. This index replaces the earlier SPCZ position index because it uses higher quality mean sea level pressure data than the superseded index and extends the time series further forward in time. The SPCZI allows interannual to decadal variability in the climate of the South Pacific to be tracked for more than a century from 1910/1911 to 2011/2012. During El Niño episodes the SPCZ is displaced by about 1°–3° east, and La Niña events 1°–3° west of the mean position on average. The index indicates a striking movement eastward for the period 1977/78–1998/99, compared with 1944/45–1976/77 in association with the Interdecadal Pacific oscillation (IPO). The eastward movement of the SPCZ in the late twentieth century is related to significant precipitation trends in the South Pacific region. Since 1998/99 the SPCZ has regressed westward with the negative phase change of the IPO. The long-term trend in the SPCZI is very small relative to the interannual to decadal variability and is not statistically significant, suggesting that there has been little overall change in the mean position of the SPCZ over the past century. 相似文献
15.
《大气科学进展》1992,(4)
Complex empirical orthogonal function (CEOF) and Fourier analyses are applied to 500 hPa geopotential height anomaly for two selected latitude belts in the Northern Hemisphere from Dec 1978 through Feb 1979 based on the ECMWF FGGE Hl-b data. The positive anomalies in the three leading CEOFs for the high-latitude belt mainly show the preferred locations for blocking activity in the North Atlantic, the North Pacific and to the west of the Ural Mountains. The negative anomalies in the three leading CEOFs for the mid-latitude belt mainly show the preferred locations for cyclogenesis in the east coasts of Asia and North America, and the Mediterranean; weak cyclogenesis is also seen in the western United States and off the coasts of Spain and Morocco. The travelling components of the positive anomalies in the high-latitude belt mainly propagate westward, weakening as approaching the east side of some mountain chains while intensifying to the west side. On the contrary, the travelling components of the negativ 相似文献
16.
A central Pacific(CP) El Ni?o event occurred in 2018/19. Previous studies have shown that different mechanisms are responsible for different subtypes of CP El Ni?o events(CP-I El Ni?o and CP-II El Ni?o). By comparing the evolutions of surface winds, ocean temperatures, and heat budgets of the CP-I El Ni?o, CP-II El Ni?o, and 2018/19 El Ni?o, it is illustrated that the subtropical westerly anomalies in the North Pacific, which led to anomalous convergence of Ekman flow and surface warming in the ... 相似文献
17.
It has long been acknowledged that there are two types of El Nio events, i.e., the eastern Pacific El Nio (EE) and the central Pacific El Nio (CE), according to the initial position of the anomalous warm water and its propagation direction. In this paper, the oceanic and atmospheric evolutions and the possible mechanisms of the two types of El Nio events were examined. It is found that all the El Nio events, CE or EE, could be attributed to the joint impacts of the eastward advection of warm water from the western Pacific warm pool (WPWP) and the local warming in the equatorial eastern Pacific. Before the occurrence of CE events, WPWP had long been in a state of being anomalous warm, so the strength of eastward advection of warm water was much stronger than that of EE, which played a major role in the formation of CE. While for the EE events, most contribution came from the local warming of the equatorial eastern Pacific. It is further identified that the immediate cause leading to the difference of the two types of El Nio events was the asynchronous variations of the Southern Oscillation (SO) and the Northern Oscillation (NO) as defined by Chen in 1984. When the transition from the positive phase of the NO (NO+) to NO- was prior to that from SO+ to SO-, there would be eastward propagation of westerly anomalies from the tropical western Pacific induced by NO and hence the growth of warm sea surface temperature anomalies in WPWP and its eastward propagation. This was followed by lagged SO-induced weakening of southeast trade winds and local warming in the equatorial eastern Pacific. These were conducive to the occurrence of the CE. On the contrary, the transition from SO+ to SO- leading the transition of NO would favor the occurrence of EE type events. 相似文献
18.
It has long been acknowledged that there are two types of El Nio events, i.e., the eastern Pacific El Nio (EE) and the central Pacific El Nio (CE), according to the initial position of the anomalous warm water and its propagation direction. In this paper, the oceanic and atmospheric evolutions and the possible mechanisms of the two types of El Nio events were examined. It is found that all the El Nio events, CE or EE, could be attributed to the joint impacts of the eastward advection of warm water from... 相似文献
19.
After the strong 2015/16 El Ni?o event, cold conditions prevailed in the tropical Pacific with the second-year cooling of the 2017/18 La Ni?a event. Many coupled models failed to predict the cold SST anomalies(SSTAs) in 2017. By using the ERA5 and GODAS(Global Ocean Data Assimilation System) products, atmospheric and oceanic factors were examined that could have been responsible for the second-year cooling, including surface wind and the subsurface thermal state. A time sequence is described to demonstrate how the cold SSTAs were produced in the central-eastern equatorial Pacific in late 2017. Since July 2017, easterly anomalies strengthened in the central Pacific; in the meantime, wind stress divergence anomalies emerged in the far eastern region, which strengthened during the following months and propagated westward, contributing to the development of the second-year cooling in 2017. At the subsurface, weak negative temperature anomalies were accompanied by upwelling in the eastern equatorial Pacific, which provided the cold water source for the sea surface. Thereafter, both the cold anomalies and upwelling were enhanced and extended westward in the centraleastern equatorial Pacific. These changes were associated with the seasonally weakened EUC(the Equatorial Undercurrent) and strengthened SEC(the South Equatorial Current), which favored more cold waters being accumulated in the central-equatorial Pacific. Then, the subsurface cold waters stretched upward with the convergence of the horizontal currents and eventually outcropped to the surface. The subsurface-induced SSTAs acted to induce local coupled air–sea interactions, which generated atmospheric–oceanic anomalies developing and evolving into the second-year cooling in the fall of 2017. 相似文献
20.
An Observational Analysis of the Oceanic and Atmospheric Structure of Global-Scale Multi-decadal Variability简 总被引：5，自引：0，他引：5
The aim of the present study was to identify multi-decadal variability （MDV） relative to the current centennial global warming trend in available observation data.The centennial global wanning trend was first identified in the global mean surface temperature （STgm） data.The MDV was identified based on three sets of climate variables,including sea surface temperature （SST）,ocean temperature from the surface to 700 m,and the NCEP and ERA40 reanalysis datasets,respectively.All variables were detrended and low-pass filtered.Through three independent EOF analyses of the filtered variables,all results consistently showed two dominant modes,with their respective temporal variability resembling the Pacific Decadal Oscillation/Inter-decadal Pacific Oscillation （PDO/IPO） and the Atlantic Multi-decadal Oscillation （AMO）.The spatial structure of the PDO-like oscillation is characterized by an ENSO-like structure and hemispheric symmetric features.The structure associated with the AMO-like oscillation exhibits hemispheric asymmetric features with anomalous warm air over Eurasia and warm SST in the Atlantic and Pacific basin north of 10°S,and cold SST over the southern oceans.The Pacific and Atlantic MDV in upper-ocean temperature suggest that they are mutually linked.We also found that the PDO-like and AMO-like oscillations are almost equally important in global-scale MDV by EOF analyses.In the period 1975-2005,the evolution of the two oscillations has given rise to strong temperature trends and has contributed almost half of the STgm warming.Hereon,in the next decade,the two oscillations are expected to slow down the global warming trends. 相似文献