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1.
Young Sound is a deep-sill fjord in NE Greenland (74°N). Sea ice usually begins to form in late September and gains a thickness of 1.5 m topped with 0–40 cm of snow before breaking up in mid-July the following year. Primary production starts in spring when sea ice algae begin to flourish at the ice–water interface. Most biomass accumulation occurs in the lower parts of the sea ice, but sea ice algae are observed throughout the sea ice matrix. However, sea ice algal primary production in the fjord is low and often contributes only a few percent of the annual phytoplankton production. Following the break-up of ice, the immediate increase in light penetration to the water column causes a steep increase in pelagic primary production. Usually, the bloom lasts until August–September when nutrients begin to limit production in surface waters and sea ice starts to form. The grazer community, dominated by copepods, soon takes advantage of the increased phytoplankton production, and on an annual basis their carbon demand (7–11 g C m−2) is similar to phytoplankton production (6–10 g C m−2). Furthermore, the carbon demand of pelagic bacteria amounts to 7–12 g C m−2 yr−1. Thus, the carbon demand of the heterotrophic plankton is approximately twice the estimated pelagic primary production, illustrating the importance of advected carbon from the Greenland Sea and from land in fuelling the ecosystem.In the shallow parts of the fjord (<40 m) benthic primary producers dominate primary production. As a minimum estimate, a total of 41 g C m−2 yr−1 is fixed by primary production, of which phytoplankton contributes 15%, sea ice algae <1%, benthic macrophytes 62% and benthic microphytes 22%. A high and diverse benthic infauna dominated by polychaetes and bivalves exists in these shallow-water sediments (<40 m), which are colonized by benthic primary producers and in direct contact with the pelagic phytoplankton bloom. The annual benthic mineralization is 32 g C m−2 yr−1 of which megafauna accounts for 17%. In deeper waters benthic mineralization is 40% lower than in shallow waters and megafauna, primarily brittle stars, accounts for 27% of the benthic mineralization. The carbon that escapes degradation is permanently accumulated in the sediment, and for the locality investigated a rate of 7 g C m−2 yr−1 was determined.A group of walruses (up to 50 adult males) feed in the area in shallow waters (<40 m) during the short, productive, ice-free period, and they have been shown to be able to consume <3% of the standing stock of bivalves (Hiatella arctica, Mya truncata and Serripes Groenlandicus), or half of the annual bivalve somatic production. Feeding at greater depths is negligible in comparison with their feeding in the bivalve-rich shallow waters.  相似文献   

2.
During the 2006 Italian Antarctic expedition a diel sampling was performed close to Cape Hallett (Ross Sea) during the Austral summer. Under-ice seawater samples (4 m) were collected every 2 h for 28 h in order to estimate prokaryotic processes' variability and community structure dynamics. Prokaryotic and viral abundances, exoenzymatic activities (β-glucosidase, chitinase, lipase, alkaline phosphatase and leucine aminopeptidase), prokaryotic carbon production (3H-leucine incorporation) and community structure (Denaturing Gradient Gel Electrophoresis – DGGE fingerprints) were analysed. Results showed that the diel variability of the prokaryotic activity followed a variation in salinity, probably as a consequence of the periodical thawing of sea ice (driven by solar radiation and air temperature cycles), while negligible variation in viral and prokaryotic abundances occurred. The Bacterial and Archaeal community structures underwent an Operational Taxonomic Units (OTUs) temporal shift from the beginning to the end of the sampling, while Flavobacteria-specific primers highlighted high variations in this group possibly related to sea ice melting and substrate release.  相似文献   

3.
We report measurements of dissolved iron (dFe, <0.4 μm) in seawater collected from the upper 300 m of the water column along the CLIVAR SR3 section south of Tasmania in March 1998 (between 42°S and 54°S) and November–December 2001 (between 47°S and 66°S). Results from both cruises indicate a general north-to-south decrease in mixed-layer dFe concentrations, from values as high as 0.76 nM in the Subtropical Front to uniformly low concentrations (<0.1 nM) between the Polar Front and the Antarctic continental shelf. Samples collected from the seasonal sea-ice zone in November–December 2001 provide no evidence of significant dFe inputs from the melting pack ice, which may explain the absence of pronounced ice-edge algal blooms in this sector of the Southern Ocean, as implied by satellite ocean-color images. Our data also allow us to infer changes in the dFe concentration of surface waters during the growing season. South of the Polar Front, a comparison of near-surface with subsurface (150 m depth) dFe concentrations in November–December 2001 suggests a net seasonal biological uptake of at least 0.14–0.18 nM dFe, of which 0.05–0.12 nM is depleted early in the growing season (before mid December). A comparison of our spring 2001 and fall 1998 data indicates a barely discernible seasonal depletion of dFe (0.03 nM) within the Polar Frontal Zone. Further north, most of our iron profiles do not exhibit near-surface depletions, and mixed-layer dFe concentrations are sometimes higher in samples from fall 1998 compared to spring 2001; here, the near-surface dFe distributions appear to be dominated by time-varying inputs of aerosol iron or advection of iron-rich subtropical waters from the north.  相似文献   

4.
Benthic foraminiferal biomass, density, and species composition were determined at 10 sites in the Gulf of Mexico. During June 2001 and 2002, sediment samples were collected with a GoMex box corer. A 7.5-cm diameter subcore was taken from a box core collected at each site and sliced into 1-cm or 2-cm sections to a depth of 2 or 3 cm; the >63-μm fraction was examined shipboard for benthic foraminifera. Individual foraminifers were extracted for adenosine triphosphate (ATP) using a luciferin–luciferase assay, which indicated the total ATP content per specimen; that data was converted to organic carbon. Foraminiferal biomass and density varied substantially (2–53 mg C m−2; 3600–44,500 individuals m−2, respectively) and inconsistently with water depth: although two 1000-m deep sites were geographically separated by only 75 km, the foraminiferal biomass at one site was relatively low (9 mg C m−2) while the other site had the highest foraminiferal biomass (53 mg C m−2). Although most samples from Sigsbee Plain (>3000 m) had low biomass, one Sigsbee site had >20 mg foraminiferal C m−2. The foraminiferal community from all sites (i.e. bathyal and abyssal locales) was dominated by agglutinated, rather than calcareous or tectinous, species. Foraminiferal density never exceeded that of metazoan meiofauna at any site. Foraminiferal biomass, however, exceeded metazoan meiofaunal biomass at 5 of the 10 sites, indicating that foraminifera constitute a major component of the Gulf's deep-water meiofaunal biomass.  相似文献   

5.
Quasi-synoptic observations of the horizontal and vertical structure of a cold-core cyclonic mesoscale eddy feature (Cyclone Noah) were conducted in the lee of Hawai’i from November 4–22, 2004 as part of the E-Flux interdisciplinary collaborative research program. Cyclone Noah appears to have spun up to the southwest of the ‘Alenuihaha Channel (between Maui and Hawai’i) as a result of strong and persistent northeasterly trade winds through the channel. Shipboard hydrographic surveys 2.5 months later suggest that Noah weakened and was in a hypothesized spin-down phase of its life cycle. Although the initial surface expression of Noah was limited in scale to 40 km in diameter and, as evidenced by surface temperatures, 2–3 °C cooler than the surrounding waters, depth profiles revealed a fully developed semi-elliptical shallow feature (200 m), 144 km long and 90 km wide (based on sigma-t=23 kg m−3) with tangential speeds of 40–80 cm s−1, and substantial isopycnal doming. Potential vorticity distribution of Noah suggests that radial horizontal flow of the core water was inhibited from the surface to depths of 75 m, with high vorticity confined above the sigma-t=23.5 kg m−3 isopycnal surface. Upward displacements of isopycnal surfaces in the eddy's center (50 m) were congruent with enhanced pigment concentrations (0.50 mg m−3). Comparisons of the results obtained for E-Flux I (Noah) and E-Flux III (Opal) suggest that translation characteristics of cyclonic Hawaiian lee eddies may be important in establishing the biogeochemical and biological responses of the oligotrophic ocean to cyclonic eddies.  相似文献   

6.
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7.
The dynamics of dissolved inorganic carbon (DIC) and processes controlling net community production (NCP) were investigated within a mature cyclonic eddy, Cyclone Opal, which formed in the lee of the main Hawaiian Islands in the subtropical North Pacific Gyre. Within the eddy core, physical and biogeochemical properties suggested that nutrient- and DIC-rich deep waters were uplifted by 80 m relative to surrounding waters, enhancing biological production. A salt budget indicates that the eddy core was a mixture of deep water (68%) and surface water (32%). NCP was estimated from mass balances of DIC, nitrate+nitrite, total organic carbon, and dissolved organic nitrogen, making rational inferences about the unobserved initial conditions at the time of eddy formation. Results consistently suggest that NCP in the center of the eddy was substantially enhanced relative to the surrounding waters, ranging from 14.1±10.6 (0–110 m: within the euphotic zone) to 14.2±9.2 (0–50 m: within the mixed layer) to 18.5±10.7 (0–75 m: within the deep chlorophyll-maximum layer) mmol C m−2 d−1 depending on the depth of integration. NCP in the ambient waters outside the eddy averaged about 2.37±4.24 mmol C m−2 d−1 in the mixed layer (0–95 m). Most of the enhanced NCP inside the eddy appears to have accumulated as dissolved organic carbon (DOC) rather than exported as particulate organic carbon (POC) to the mesopelagic. Our results also suggest that the upper euphotic zone (0–75 m) above the deep chlorophyll maximum is characterized by positive NCP, while NCP in the lower layer (>75 m) is close to zero or negative.  相似文献   

8.
A seasonal simulation from a medium-resolution ocean general circulation mode (OGCM) is used to investigate the vertical structure variability of the Southeast Pacific (SEP). The focus is on the extra-tropical Rossby wave (ETRW) variability and associated forcing mechanism. Some aspects of the model mean state are validated from available observations, which justifies a vertical mode decomposition of the model variability. The analysis of the baroclinic mode contributions to sea level indicates that the gravest mode is dominant over most of the domain at all frequencies. Annual variability is on average twice as large as the semi-annual variability which is confined near the coast for all the modes. The first baroclinic mode contribution to the annual cycle exhibits a clear westward propagation north of the critical latitude. The higher-order modes only contribute near the coast where they are associated with vertically propagating energy. The residual variability, which is the energy at all timescales other than annual and semi-annual periods peaks offshore between 20°S and 30°S for all baroclinic modes. The third baroclinic mode also exhibits a relative maximum variability off the coast of Peru south of the critical latitude of the annual cycle (13°S), where the Peru–Chile Undercurrent is the most intense. Sensitivity experiments to the atmospheric and boundary forcing suggest that the residual variability results from the non-linear interaction between annual Rossby waves and the mean flow, while the annual ETRWs in the model result from the summed-contribution from both the local wind stress and remote equatorial forcing. Overall the study extends the classical analysis of sea level variability in the SEP based on linear theory, and suggests that the peculiarities of the baroclinic modes need to be taken into account for interpreting the sea level variability and understanding its connection with the equatorial variability.  相似文献   

9.
With the recently recovered organic-rich sediments of early Tertiary age from the Lomonosov Ridge by the Integrated Ocean Drilling Program (IODP) Expedition 302, the first data collection directly from source rocks of the central basins of the Arctic Ocean is now available. Using the results of seismic interpretations and published sedimentological and organic geochemical data from Expedition 302, the framework for the first quantitative assessment of source-rock quality and distribution of the Palaeogene sediments was modelled in the central Arctic Ocean. The modelling results suggest that an approximately 100-m-thick Early to Middle Eocene sedimentary sequence of good to very good source rocks exists along a 75 km long transect across the Lomonosov Ridge. In-situ generation of hydrocarbons is unlikely because the overburden (200–250 m) and consequently the thermal maturity are too low. Burial history and thermal modelling reveal that an additional overburden of at least 1000 m is necessary to start hydrocarbon generation along the ridge. However, source-rock modelling results show that good source-rock potential may exist in correlative units in the adjacent Amundsen Basin. Simulated organic carbon contents of 1.5–5%, coupled with an overburden of 1000–1200 m, and heat flow anomalies (117 and 100 mW m−2) due to the vicinity to the Gakkel Ridge spreading centre indicate that necessary conditions for hydrocarbon expulsion are already reached, and point to viability of a potential petroleum system. Our results support the hypothesis that deposition of a potentially good hydrocarbon source rock occurred across the entire Arctic Basin and adjacent margins during the early Tertiary.  相似文献   

10.
Lagrangian time series of dimethylsulfide (DMS) concentrations from a cyclonic and an anticyclonic eddy in the Sargasso Sea were used in conjunction with measured DMS loss rates and a model of vertical mixing to estimate gross DMS production in the upper 60 m during summer 2004. Loss terms included biological consumption, photolysis, and ventilation to the atmosphere. The time- and depth (0–60 m)-averaged gross DMS production was estimated to be 0.73±0.09 nM d−1 in the cyclonic eddy and 0.90±0.15 nM d−1 in the anticyclonic eddy, with respective DMS replacement times of 5±1 and 6±1 d. The higher estimated rate of gross production and lower measured loss rate constants in the anticyclonic eddy were equally responsible for this eddy's 50% higher DMS inventory (0–60 m). When normalized to chlorophyll and total dimethylsulfoniopropionate (DMSP), estimated gross production in the anticyclonic eddy was about twice that in the cyclonic eddy, consistent with the greater fraction of phytoplankton that were DMSP producers in the anticyclonic eddy. Higher rates of gross production were estimated below the mixed layer, contributing to the subsurface DMS maximum found in both eddies. In both eddies, gas exchange, microbial consumption, and photolysis were roughly equal DMS loss terms in the surface mixed layer (0.2–0.4 nM d−1). Vertical mixing was a substantial source of DMS to the surface mixed layer in both eddies (0.2–0.3 nM d−1) owing to the relatively high DMS concentrations below the mixed layer. Estimated net biological DMS production rates (gross production minus microbial consumption) in the mixed layer were substantially lower (by almost a factor of 3) than those estimated in a previous study of the Sargasso Sea, which may explain the relatively low mixed-layer DMS concentrations found here during July 2004 (3 nM) compared to previous summers (4–6 nM).  相似文献   

11.
A new deep-sea laser Raman spectrometer (DORISS—Deep Ocean Raman In Situ Spectrometer) is used to observe the preferential dissolution of CO2 into seawater from a 50%–50% CO2–N2 gas mixture in a set of experiments that test a proposed method of CO2 sequestration in the deep ocean. In a first set of experiments performed at 300 m depth, an open-bottomed 1000 cm3 cube was used to contain the gas mixture; and in a second set of experiments a 2.5 cm3 funnel was used to hold a bubble of the gas mixture in front of the sampling optic. By observing the changing ratios of the CO2 and N2 Raman bands we were able to determine the gas flux and the mass transfer coefficient at 300 m depth and compare them to theoretical calculations for air–sea gas exchange. Although each experiment had a different configuration, comparable results were obtained. As expected, the ratio of CO2 to N2 drops off at an exponential rate as CO2 is preferentially dissolved in seawater. In fitting the data with theoretical gas flux calculations, the boundary layer thickness was determined to be  42 μm for the gas cube, and  165 μm for the gas funnel reflecting different boundary layer turbulence. The mass transfer coefficients for CO2 are kL = 2.82 × 10− 5 m/s for the gas cube experiment, and kL = 7.98 × 10− 6 m/s for the gas funnel experiment.  相似文献   

12.
Biogeochemical processes in sediments under the influence of the Rhône River plume were studied using both in situ microelectrodes and ex situ sediment core incubations. Organic carbon (OC) and total nitrogen (TN) content as well as stable carbon isotopic composition of OC (δ13COC) were analysed in 19 surface sediments to determine the distribution and sources of organic matter in the Rhône delta system. Large spatial variations were observed in both the total O2 uptake (5.2 to 29.3 mmol m−2 d−1) and NH4+ release (−0.1 to −3.5 mmol m−2 d−1) rates at the sediment–water interface. The highest fluxes were measured near the Rhône River mouth where sedimentary OC and TN contents reached 1.81% and 0.23% respectively. Values of δ13COC ranged from −26.83‰ to −23.88‰ with a significant seawards enrichment tracing the dispersal of terrestrial organic matter on the continental shelf. The amount of terrestrial-derived OC reaches 85% in sediments close to the Rhône mouth decreasing down to 25% in continental shelf sediments. On the prodelta, high terrestrial OC accumulation rates support high oxygen uptake rates and thus indicating that a significant fraction of terrestrial OC is remineralized. A particulate organic carbon (POC) mass balance indicates that only 3% of the deposited POC is remineralized in prodelta sediments while 96% is recycled on the continental shelf. It was calculated that a large proportion of the Rhône POC input is either buried (52%) or remineralized (8%), mostly on the prodelta area. The remaining fraction (40%) is either mineralized in the water or exported outside the Rhône delta system in dissolved or particulate forms.  相似文献   

13.
Methods are described for the rapid (11 min) automated shipboard analysis of dissolved sulfur hexafluoride (SF6) in small volume (200 cm3) seawater samples. Estimated precision for the SF6 measurements is 2% or 0.02 fmol kg−1 (whichever is greater). The method also allows for the simultaneous measurement of chlorofluorocarbon-11 (CFC11) and chlorofluorocarbon-12 (CFC12) on the same water sample, with significantly improved sensitivity over previous analytical methods.  相似文献   

14.
Biweekly composite averages of the standing stock of sea-surface chlorophyll (SSC) were derived from SeaWiFS satellite ocean-color data at 44 benthic sampling stations occupied along the continental slope and rise by the Deep Gulf of Mexico Benthos (DGoMB) program. At the 22 DGoMB sites north of 26°N and west of 91°W in the NW Gulf of Mexico, annual average SSC was 0.19 mg m−3, ranging at most locations from annual highs of about 0.3 mg m−3 in November–February to lows of about 0.1 mg m−3 in May–August. Comparison of three years of SeaWiFS data (January 1998–December 2000) showed little inter-annual variation at these NW Gulf stations. In contrast, at the 22 NE Gulf sites north of 26°N and east of 91°W, SSC averaged 2.8 times higher than in the NW Gulf, showing also strong inter-annual variation. Maxima in the NE region occurred in November–February and also during summers. The summer maxima were associated with Mississippi River water transported offshore to the east and southward by anticyclonic eddies in the NE Gulf. The apparent increases in SSC in June–August at NE Gulf stations reached average monthly concentrations >50% greater than in November–February. Based on a primary productivity model and a vertical flux model, the calculated export of particulate organic carbon (POC flux reaching the seafloor) was estimated as 18 mg C m−2 day−1 at the 22 NE Gulf stations, and 9 mg C m−2 day−1 at the 22 NW Gulf stations. These estimates are comparable to fluxes measured by benthic lander by others in the DGoMB program, which may drive the differences in west versus east bathymetric zonation and community structure of macrobenthos that were sampled with large box corers by others in the DGoMB program.  相似文献   

15.
Mesoscale eddies and tropical instability waves in the eastern tropical Pacific, first revealed by satellite infrared imagery, play an important role in the dynamics and biology of the region, and in the transfer of mass, energy, heat, and biological constituents from the shelf to the deep ocean and across the equatorial currents.From boreal late autumn to early spring, four to 18 cyclonic or anticyclonic eddies are formed off the coastal region between southern Mexico and Panama. The anticyclonic gyres, which tend to be larger and last longer than the cyclonic ones, are the best studied: they typically are 180–500 km in diameter, depress the pycnocline from 60 to 145 m at the eddy center, have swirl speeds in excess of 1 m s−1, migrate west at velocities ranging from 11 to 19 cm s−1 (with a slight southward component), and maintain a height signature of up to 30 cm. The primary generating agents for these eddies are the strong, intermittent wind jets that blow across the isthmus of Tehuantepec in Mexico, the lake district in Nicaragua and Costa Rica, and the Panama canal. Other proposed eddy-generating mechanisms are the conservation of vorticity as the North Equatorial Counter Current (NECC) turns north on reaching America, and the instability of coastally trapped waves/currents.Tropical Instability Waves (TIWs) are perturbations in the SST fronts on either side of the equatorial cold tongue. They produce SST variations on the order of 1–2 °C, have periods of 20–40 days, wavelengths of 1000–2000 km, phase speeds of around 0.5 m s−1 and propagate westward both north and south of the Equator. The Tropical Instability Vortices (TIVs) are a train of westward-propagating anticyclonic eddies associated with the TIWs. They exhibit eddy currents exceeding 1.3 m s−1, a westward phase propagation speed between 30 and 40 km d−1, a signature above the pycnocline, and eastward energy propagation. Like the TIWs, they result from the latitudinal barotropically unstable shear between the South Equatorial Current (SEC) and the NECC with a potential secondary source of energy from baroclinic instability of the vertical shear with the Equatorial Undercurrent (EUC).This review of mesoscale processes is part of a comprehensive review of the oceanography of the eastern tropical Pacific Ocean.  相似文献   

16.
The study on dissolved organic ligands capable to complex copper ions (LT), surface-active substances (SAS) and dissolved organic carbon (DOC) in the Northern Adriatic Sea station (ST 101) under the influence of Po River was conducted in period from 2006–2008. The acidity of surface-active organic material (Acr) was followed as well. The results are compared to temperature and salinity distributions. On that way, the contribution of the different pools of ligands capable to complex Cu ions could be determined as well as the influence of aging and transformation of the organic matter. The LT values in the investigated period were in the range of 40–300 nmol l−1. The range of DOC values for surface and bottom samples were 0.84–1.87 mg l−1 and 0.80–1.30 mg l−1, respectively. Total SAS concentrations in the bottom layer were 0.045–0.098 mg l−1 in equiv. of Triton-X-100 while those in the surface layer were 0.050–0.143 mg l−1 in equiv. of Triton-X-100. The majority of organic ligands responsible for Cu binding in surface water originate from new phytoplankton production promoted by river borne nutrients. Older, transformed organic matter, possessing higher relative acidity, is the main contributor to the pool of organic ligands that bind copper in the bottom samples. It was estimated that 9% of DOC in surface samples and 12% of DOC in the bottom samples are present as ligands capable to complex copper ions.  相似文献   

17.
The spatial distributions of dissolved manganese and nutrients were examined in the Columbia River plume off Oregon and Washington during the summer of 2004 and 2005 as part of the River Influence on Shelf Ecosystems (RISE) program. Factors influencing the hydrochemical characteristics of the freshly formed and aged Columbia River plume were investigated. Hydrographic data and nutrient concentrations were used to delineate three distinct water sources for the Columbia River Plume: California Current surface water, coastal upwelled water, and Columbia River water. The warm, intermediate salinity, nutrient poor California Current water contains low levels of dissolved manganese (< 5 nM) and silicic acid (< 5 μM), and is depleted in nitrate. The cold, high salinity, nutrient rich, freshly upwelled water is highly variable (2–20 nM) in dissolved manganese and can be as high as  45 μM in silicic acid and  30 μM nitrate. The variable Columbia River has summer temperatures ranging from  13 to 24 °C, high silicic acid concentrations (ranging from  120 to 200 μM), and lower nitrate concentrations (ranging from  2 to 20 μM). During the summer, the concentrations of silicic acid and dissolved manganese can exceed 100 μM and 200 nM, respectively, in near-field Columbia River plumes. These values are markedly greater than those of surface coastal waters (even during upwelling conditions). As the plume advects and mixes, the concentrations of these two constituents remain relatively high within plume waters. The concentrations of dissolved manganese in the near-field plume vary with tidal amplitude, exhibiting much higher concentrations for a given salinity during spring tides than during neap tides. For example, the Columbia River plume at a salinity of 20 has a concentration of dissolved manganese of  240 nM during spring tides, as compared to only  60 nM during low amplitude tides. Silicic acid concentrations in the near-field plume remain relatively constant throughout the tidal month. Calculations indicate there is roughly an equivalent yearly delivery of dissolved manganese and silicic acid to the coastal waters off Oregon and Washington by upwelled waters and by the Columbia River plume.  相似文献   

18.
Delayed coincidence counters (RaDeCC), used for measuring 223Ra and 224Ra preconcentrated from water onto MnO2-impregnated acrylic fiber (“Mn-fiber”), require a standard Mn-fiber column that has a precisely known activity of 224Ra for calibration. This may be done by adding an aged 228Th standard solution to adsorb both 228Th and its daughter 224Ra quantitatively onto a Mn fiber. We used both seawater and deionized water (DIW) for testing the adsorption efficiency of Th and Ra onto Mn fibers. Our experimental results show that more than 50% of thorium (232Th and 228Th) breaks through the Mn-fiber column when DIW is used as a medium. However, near quantitative recoveries are obtained if filtered (0.45 μm) seawater is used to prepare the standard. In the case of pure DIW, the pH (initial pH  5.3) rises to > 10 after passing through the column while seawater (initial pH  7.8) changes to  7.2. Thus, the lack of thorium adsorption in DIW may be attributed to this huge increase of pH and the consequent formation of Th(OH)4 and polyhydroxyl colloids. Based on these observations, we recommend that one should use either artificial seawater or natural seawater (which has negligible 224Ra and 228Th) as a loading solution after 0.45 μm filtration. In addition, the thorium adsorption efficiency should be confirmed either by thorium analysis of the effluent solution or long-term monitoring of the supported 224Ra on the Mn fiber using the RaDeCC. Similar cautions are likely necessary for making 223Ra standards by adsorption of 227Ac onto Mn fibers.  相似文献   

19.
We present the results of six dye tracer experiments that measured the mixing and circulation at the shelfbreak front on the New England Shelf. The last three were conducted during the New England Shelfbreak Productivity Experiment (NESPEX) with concurrent isopycnal float deployments. The results are consistent with the Chapman and Lentz [Chapman, D.C., and Lentz, S.J. (1994). Trapping of a coastal density front by the bottom boundary layer. Journal of Physical Oceanography, 24, 1465–1479.] model prediction of the separation and upwelling along the shelfbreak front of bottom boundary layer (BBL) water forced by an Ekman buoyancy flux, but show considerable variability. Cross-shelf velocities at the detachment point are 2–3 × 10−2 m/s. But seaward, over the slope region, dye tagged water was sheared from the main patch into small filaments that upwelled along the front with cross-shelf speeds up to 0.1 m/s. Cross-shelf diffusion was of order 10 m2/s in the mixed bottom layer and 1 m2/s in the interior along the front. Within the stratified front, the mean vertical diffusivity was Kz  4 × 10−6 m2/s. The dispersion of shelfwater in the slope region is effected by turbulent flow with advective speeds exceeding the small scale diffusive mixing. The mean flux of the detached BBL water is sufficient to account for the net loss of shelf water during its transit from Cape Cod to Cape Hatteras.  相似文献   

20.
Measurements of bromoform (CHBr3), diiodomethane (CH2I2), chloroiodomethane (CH2ICl) and bromoiodomethane (CH2IBr) were made in the water column (5–100 m depth) of the Southern Ocean within 0–40 km of the Antarctic sea ice during the ANTXX1/2 transect of the German R/V Polarstern, at five locations between 70–72°S and 9–11°W in the Antarctic spring/summer of 2003–2004. Some of the profiles exhibited a very pronounced layer of surface sea-ice meltwater, as evidenced by salinity minima and temperature maxima, along with surface maxima in concentrations of CHBr3, CH2I2, CH2ICl and CH2IBr. These results are consistent with in situ surface halocarbon production by ice algae liberated from the sea ice, although production within the sea ice followed by transport cannot be entirely ruled out. Additional sub-surface maxima in halocarbons occurred between 20 and 80 m. At a station further from shore and not affected by surface sea-ice meltwater, surface concentrations of CH2I2 were decreased whereas CH2ICl concentrations were increased compared to the stations influenced by meltwater, consistent with photochemical conversion of CH2I2 to CH2ICl, perhaps during upward mixing from a layer at  70 m enhanced in iodocarbons. Mean surface (5–10 m) water concentrations of halocarbons in these coastal Antarctic waters were 57 pmol l− 1 CHBr3 (range 44–78 pmol l− 1), 4.2 pmol l− 1 CH2I2 (range 1.7–8.2 pmol l− 1), 0.8 pmol l− 1 CH2IBr (range 0.2–1.4 pmol l− 1), and 0.7 pmol l− 1 CH2ICl (range 0.2–2.4 pmol l− 1). Concurrent measurements in air suggested a sea-air flux of bromoform near the Antarctic coast of between 1 and 100 (mean 32.3, median 10.4) nmol m− 2 day− 1 and saturation anomalies of 557–1082% (mean 783%, median 733%), similar in magnitude to global shelf values. In surface samples affected by meltwater, CH2I2 fluxes ranged from 0.02 to 6.1 nmol m− 2 day− 1, with mean and median values of 1.9 and 1.1 nmol m− 2 day− 1, respectively.  相似文献   

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