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1.
We present a 16-month record of ozone (O3), carbon monoxide (CO), total reactive nitrogen (NOy), sulphur dioxide (SO2), methane (CH4), C2 – C8 non-methane hydrocarbons (NMHCs), C1 – C2 halocarbons, and dimethyl sulfide (DMS) measured at a southern China coastal site. The study aimed to establish/update seasonal profiles of chemically active trace gases and pollution tracers in subtropical Asia and to characterize the composition of the `background' atmosphere over the South China Sea (SCS) and of pollution outflow from the industrialized Pearl River Delta (PRD) region and southern China. Most of the measured trace gases of anthropogenic origin exhibited a winter maximum and a summer minimum, while O3 showed a maximum in autumn which is in contrast to the seasonal behavior of O3 in rural eastern China and in many mid-latitude remote locations in the western Pacific. The data were segregated into two groups representing the SCS background air and the outflow of regional continental pollution (PRD plus southern China), based on CO mixing ratios and meteorological conditions. NMHCs and halocarbon data were further analyzed to examine the relationships between their variability and atmospheric lifetime and to elucidate the extent of atmospheric processing in the sampled air parcels. The trace gas variability (S) versus lifetime (τ) relationship, defined by the power law, Slnx = Aτ− b, (where X is the trace gas mixing ratio) gives a fit parameter A of 1.39 and exponent b of 0.42 for SCS air, and A of 2.86 and b of 0.31 for the regional continental air masses. An examination of ln[n-butane]/ln[ethane] versus ln[propane]/ln[ethane] indicates that their relative abundance was dominated by mixing as opposed to photochemistry in both SCS and regional outflow air masses. The very low ratios of ethyne/CO, propane/ethane and toluene/benzene suggest that the SCS air mass has undergone intense atmospheric processing since these gases were released into the atmosphere. Compared to the results from other polluted rural sites and from urban areas, the large values of these species in the outflow of PRD/southern China suggest source(s) emitting higher levels of ethyne, benzene, and toluene, relative to light alkanes. These chemical characteristics could be unique indicators of anthropogenic emissions from southern China.  相似文献   

2.
The explosive spread of the 2019 novel coronavirus (COVID-19) provides a unique chance to rethink the relationship between human activity and air pollution. Though related studies have revealed substantial reductions in primary emissions, obvious differences do exist in the responses of secondary pollutants, like ozone (O3) pollution. However, the regional disparities of O3 responses and their causes have still not been fully investigated. To better elucidate the interrelationship between anthropogenic emissions, chemical production, and meteorological conditions, O3 responses caused by lockdowns over different regions were comprehensively explored at a global scale. Observational signals of air-quality change were derived from multi-year surface measurements and satellite retrievals. With similar substantial drops in nitrogen dioxide (NO2), ozone shows rising signals in most areas of both East Asia and Europe, even up to ∼14 ppb, while a non-negligible declining signal exists in North America, by about 2–4 ppb. Furthermore, the drivers behind the different O3 responses are discussed based on meteorological analysis and O3 sensitivity diagnosis. On the one hand, O3 responses to NO2 declines can be affected by the primary dependence on its precursors. On the other hand, it is also highly dependent on meteorological factors, especially temperature. Our study further highlights the great importance of taking into consideration both the regional disparities and synergistic effects of precursor reductions and meteorological influence for scientific mitigation of O3 pollution.摘要疫情期间全球各地一次排放大幅削减, 而臭氧等二次污染的响应则存在着区域间差异.结合地面和卫星观测发现, 同在氮氧化物大幅下降的情况下,臭氧在东亚和欧洲呈现出可达14ppb的上升信号, 而北美则下降为主 (约2–4ppb) .我们结合气象分析和臭氧敏感性进一步讨论了臭氧响应差异性的原因, 一方面受臭氧与前体物间关系的影响;另一方面来自于气象, 尤其是温度.研究明晰了人为排放,化学和气象三者的内在关联, 强调了在臭氧控制过程中考虑前体物削减和气象条件协同的重要性.  相似文献   

3.
南京地区大气颗粒物影响近地面臭氧的个例研究   总被引：4，自引：0，他引：4  
通过对2008年4月2～7日南京地区地面气象观测数据以及两个站点空气质量(O3、NOx、PM10)监测资料的分析, 发现O3和PM10之间存在一定程度的反相关。利用一个光化学箱模式对该个例中大气颗粒物影响近地面臭氧的过程进行模拟, 结果发现大气颗粒物浓度的升高使得气溶胶光学厚度增加20％～40%, 导致NO2和O3近地面光解率下降20%～30%, OH和HO2自由基浓度分别减少20%～50%, 造成O3净生成率下降30%～40%。研究表明, 颗粒物对光化学过程的抑制造成了大气氧化能力的降低, 是近地面臭氧浓度减少的可能原因。  相似文献   

4.
In this study, we used satellite data (GOME and MOPITT) together with a global chemical-transport-model of atmosphere (MOZART-2) to characterize the chemical/aerosol composition over eastern China. We then estimated the effects of local emissions in China on the chemical budgets in other regions of the world. Likewise, we also investigated the effects of air pollution from other regions on the chemical budget over eastern China. The study shows that the column CO and NO x concentrations are also high in eastern China. The high CO and NO x concentrations produce modest levels of O3 concentrations during summer (about 40 to 50 ppbv) and very low O3 during winter (about 10 to 20 ppbv) in eastern China. The calculated NO2 column is fairly consistent from the GOME measurement. The calculated CO column is underestimated from the MOPITT measurement. One of the reasons of the underestimation of the predicted CO is due to a fact that the CO emissions were taken without considering the rapid increase of emissions from 1990 to 2000. The calculated surface O3 is consistent with the measured values, with strong seasonal variations. However, the measurement is very limited, and more measurements in eastern China will be needed. The column NO2 has a very strong seasonal variation in eastern China, with the highest concentrations during winter and the lowest concentrations during summer. The cause of this seasonal variability is mainly due to the seasonal changes in the chemical loss of NO x , which is very high in summer and very low during winter. The effects of the local emissions in China and long-range transport from other regions on the chemical distributions in eastern China are studied. The results show that NO x concentrations in eastern China are mostly caused by the local emissions in China, especially during the winter. The CO concentration over eastern China is from both the local emissions (30% to 40%) and the transport from other regions. Likewise, the CO emissions in China have an important effect on the other regions of the world, but the effect is limited in the northern hemisphere. The local emissions in China also have an important effect on surface O3 concentrations. During winter, the local emissions reduce the surface O3 concentrations by 30 to 50%. During summer, the local emissions produce about 50 to 70% of the O3 concentration in eastern China.  相似文献   

5.
一次重雾霾天气成因及湿清除特征分析   总被引：1，自引：1，他引：0  
为了深入了解发生在武汉地区一次重雾霾天气过程的气象条件、污染源和污染物的湿清除特征,本文利用空气质量监测资料、地面观测资料和遥感火点监测资料和实测雨滴谱资料,详细分析了这次过程。结果表明:此次持续10 d的重雾霾天气过程发生在高压天气系统和静风条件下,辐射降温形成的稳定逆温边界层结构有利于污染气溶胶的积累和雾霾的形成和发展,尤其是来自南方持续不断的湿平流使雾霾天气得以长时间持续和发展,整个雾霾天气期间能见度均小于2 km,最低能见度不足50 m。2014年11月23~24日降水过程对此类污染物有明显的清除效果,清除率最高的是颗粒物污染,NO_2、SO_2和CO次之,最差的是O_3,通过与Scott(1982)按平均碰并系数E(E=0.65)得到的清除率和雨强的关系比较,武汉地区稳定性降水对气溶胶的平均碰并系数可取0.25~0.35。  相似文献   

6.
近年来武汉市臭氧污染日益严峻,成为影响空气质量达标的瓶颈,弄清臭氧及其前体物非线性关系是臭氧防控的关键和基础.本研究基于武汉中心城区2018年4—9月臭氧及其前体物在线观测数据,分析出武汉市臭氧浓度受前体物和气象条件等因素的共同影响,呈较为明显的季节变化和日变化特征.观测期间武汉市大气挥发性有机物（VOCs）平均体积分数为32.5×10-9,烷烃是武汉市VOCs的主要组分,其次是含氧VOCs （OVOCs）和卤代烃.利用基于观测的模型定量分析臭氧与前体物之间的关系,发现削减VOCs会引起臭氧生成潜势的显著下降,而削减氮氧化物则会使臭氧生成潜势升高,说明武汉市臭氧生成处于VOCs控制区.在人为源VOCs中,间/对二甲苯和邻二甲苯的相对增量反应活性（RIR）最高,是影响臭氧生成的关键组分.  相似文献   

7.
An easily-evaluated expression for the dimensionless concentration profile (z/z 0,/z 0, z 0/L) = = cu */kQ (or z 0cu*/kQ) downwind of a continuous ground-level area (or line) source in the stable surface layer is obtained by integrating the diffusion equation using the Shwetz approximation method (c = concentration, Q = source strength, k = von Kárman's constant). The analytical solution compares closely with concentration profiles obtained using a trajectory-simulation model over a useful range of heights, the important discrepancies occurring at the upper edge of the plume. The analytical solution is used to generate predictions of ground-level concentration for the Project Prairie Grass experiments; good agreement with the observations is obtained at all downwind distances (50 to 800 m).  相似文献   

8.
Continuous measurements of ozone and its precursors including NO, NO2, and CO at an urban site (32°03′N, 118°44′E) in Nanjing, China during the period from January 2000 to February 2003 are presented. The effects of local meteorological conditions and distant transports associated with seasonal changed Asian monsoons on the temporal variations of O3 and its precursors are studied by statistical, backward trajectory, and episode analyses. The diurnal variation in O3 shows high concentrations during daytime and low concentrations during late night and early morning, while the precursors show high concentrations during night and early morning and low concentrations during daytime. The diurnal variations in air pollutants are closely related to those in local meteorological conditions. Both temperature and wind speed have significant positive correlations with O3 and significant negative correlations with the precursors. Relative humidity has a significant negative correlation with O3 and significant positive correlations with the precursors. The seasonal variation in O3 shows low concentrations in late autumn and winter and high concentrations in late spring and early summer, while the precursors show high concentrations in late autumn and winter and low concentrations in summer. Local mobile and stationary sources make a great contribution to the precursors, but distant transports also play a very important role in the seasonal variations of the air pollutants. The distant transport associated with the southeastern maritime monsoon contributes substantially to the O3 because the originally clean maritime air mass is polluted when passing over the highly industrialized and urbanized areas in the Yangtze River Delta. The high frequency of this type of air mass in summer causes the fact that a common seasonal characteristic of surface O3 in East Asia, summer minimum, is not observed at this site. The distant transports associated with the northern continental monsoons that dominate in autumn and winter are related to the high concentrations of the precursors in these two seasons. This study can contribute to a better understanding of the O3 pollution in vast inland of China affected by meteorological conditions and the rapid urbanization and industrialization.  相似文献   

9.
An updated version of the Regional Acid Deposition Model(RADM)driven by meteorologicalfields derived from Chinese Regional Climate Model(CRegCM)is used to simulate seasonal variationof tropospheric ozone over the eastern China.The results show that:(1)Peak O_3 concentration moves from south China to north China responding to the changing ofsolar perpendicular incidence point from south to north.When solar perpendicular incidence pointmoves from north to south,so does the peak O_3 concentration.(2)In the eastern China.the highest O_3 month-average concentration appears in July.thelowest in January and the medium in April and October.The pattern mainly depends on the solarradiation,the concentration of O_3 precursors NO_x and NMHC and the ratio of NMHC/NO_x.(3)Daily variations of O_3 over the eastern China are clear.Namely,O_3 concentrations rise withthe sun rising and the maximums appear at noon.then O_3 concentrations decrease.The highest dailyvariation range of O_3 appears in summer(40×10~(-9) in volume fraction)and the lowest in winter(20×10~(-9) in volume fraction).(4)Daily variations of O_3 over the western China are not clear.The daily variation range of O_3 isless than 10×10~(-9) in volume fraction.  相似文献   

10.
大气污染严重威胁了我国陆地生态系统的固碳能力,但随着减污降碳协同治理的快速推进,减缓大气污染将有利于提升陆地碳汇,并切实推动碳达峰碳中和目标的实现。为了更好地理解大气污染与生态系统固碳的关系,本文以主要空气污染物臭氧（O3）为例,基于田间控制实验的整合分析、剂量响应关系及机理模型三种评估方法综述了近地层O3污染对植被碳固定影响的最新进展。尽管不同作物种类以及品种、不同功能型木本植物对O3的响应有着显著的差异,且各种方法的评估结果也不尽相同,但目前O3浓度造成我国粮食作物减产、森林生产力降低已是不争的事实。持续升高的O3浓度将严重威胁我国陆地生态系统的固碳能力。利用我国作物和树木的O3剂量响应方程进行评估的结果表明,在CO2减排和O3污染协同治理下,预计2060年我国树木生物量和作物产量将比当前显著提高,增加陆地生态系统碳汇,助力碳中和目标。最后,对如何提高O3污染环境下植物固碳能力也进行了展望。  相似文献   

11.
Measurements of surface ozone (O3), nitric oxide (NO), nitrogen dioxide (NO2), oxides of nitrogen (NOx=NO+NO2) and meteorological parameters have been made at Agra (North Central India, 27°10??N, 78°05??E) in post monsoon and winter season. The diurnal variation in O3 concentration shows daytime in situ photochemical production with diurnal maximum in noon hours ranging from 51 to 54 ppb in post monsoon and from 76 to 82 ppb in winter, while minimum (16?C24 ppb) during nighttime and early morning hours. Average 8-h O3 concentration varied from 12.4 to 83.9 ppb. The relationship between meteorological parameters (solar radiation intensity, temperature, relative humidity, wind speed and wind direction) and surface O3 variability was studied using principal component analysis (PCA), multiple linear regression (MLR) and correlation analysis (CA). PCA and MLR of daily mean O3 concentrations on meteorological parameters explain up to 80 % of day to day ozone variability. Correlation with meteorology is strongly emphasized on days having strong solar radiation intensity and longer sunshine time.  相似文献   

12.
北京秋季一次典型大气污染过程多站点分析   总被引：3，自引：1，他引：2  
多站点多种大气污染物的同步在线观测对深入剖析大气污染的成因和演变机制有重要意义。以龙潭湖、北京325 m塔、双清路和阳坊4监测站点实时NOx、SO2、O3、PM2.5和PM10浓度观测数据为基础,介绍了北京地区2010年10月3～11日发生的一次典型污染过程。不同污染物在污染过程中变化特征不一致,表现为NOx、SO2、O3浓度有明显日变化,而PM浓度升高后一直维持在高值,日变化幅度很小。通过分析不同站点、相同污染物之间的相关性和变异系数发现,4站点间一次污染物NO和SO2空间浓度差别大,变异系数分别为77%和70%,相关系数低于0.44;而二次污染物NO2、PM2.5、O3空间浓度差别较小,变异系数分别为34%、36%和29%,相关系数均超过0.54。结合中尺度气象模式研究发现,该污染过程中,850 hPa高空持续的西南暖平流造成华北地区显著平流逆温,与近地层辐射逆温共同作用,使北京地区混合层高度维持在1200 m以下。低混合层高度和低风速限制了大气垂直和水平扩散,造成北京地区近地层污染物累积,形成重度污染。  相似文献   

13.
利用实况24小时降水、形势场资料及T213、T639、Japan模式降水、形势场的预报资料,对2009年汛期(5-9月,下同)中国降水时空分布进行分析,并对T213、T639、Japan三个常用模式对2009年汛期的天气形势、降水及其影响系统的预报做主客观检验,以期得出2009年汛期降水分布特点及三个模式的降水预报效果对比.结果表明:(1) 2009年汛期华南地区降水量为全国之最,长江中下游和西南东部地区其次,东北和华北地区再次.(2)从TS评分看,Japan模式的小雨～大雨量级评分较高,T639模式暴雨～大暴雨量级评分较高；T213模式对华北地区暴雨、大暴雨量级降水预报评分高于Japan和T639模式.(3)从降水预报偏差看,T213模式对华北预报明显偏强,T639模式对华北预报强度较为适中,两模式对其他区域中等以下强度降水预报偏强,对强降水预报偏弱；T639对中等以下强度降水预报偏强程度明显小于T213,而对强降水除华南和东北区域外,预报偏弱程度明显大于T213；Japan模式预报偏差随降水量级增大而减小,对大雨以上各量级预报均明显偏弱,且偏弱程度明显大于T213、 T639.(4)由代表性形势场预报检验结果可知,除T213对500hPa高度场、850hPa温度场预报效果好于其他两模式外,各模式预报效果相差不大.(5)三个模式对500 hPa副高总体预报偏东、偏北、偏强,但Japan预报效果明显好于T213、T639.(6) T639模式对台风和低涡的预报相对较好,T213较差.  相似文献   

14.
穆松宁  周广庆 《大气科学》2015,39(3):611-633
在作者前期研究(穆松宁和周广庆, 2012)的基础之上, 本文主要利用了EOF分析和相关分析, 对欧亚北部冬季新增雪盖面积(Total Fresh Snow Extent, 记为TFSE)与我国夏季气候异常之间"隔季相关"的机理进行了更进一步的探讨, 主要目的在于寻找TFSE气候效应的冬季增雪面积关键区。结果表明, 虽然欧洲中纬冬季增雪面积(文中均以TFSE-1表示)与我国夏季气候异常的关系不很显著, 但其变化维系了上述"隔季相关"的物理途径, 其变化对TFSE的气候效应而言起关键作用, 但是, 亚洲中纬冬季增雪面积(文中均以TFSE-2表示)的贡献尚不清楚;另外, 对TFSE的气候效应而言, 起作用的实际上是欧亚中纬冬季增雪面积(文中均以TFSE-1-2表示), 其不但与我国夏季气候异常具有更显著的"隔季相关", 而且这种"隔季相关"还具有和TFSE非常相似的、但更为清晰的物理途径, 因此, 在气候预测的意义上, TFSE-1-2可替代TFSE。  相似文献   

15.
It is essential to quantify the background reactivity of smog-chambers, since this might be the major limitation of experiments carried out at low pollutant concentrations typical of the polluted atmosphere. Detailed investigation of three chamber experiments at zero-NO x in the European Photoreactor (EUPHORE) were carried out by means of rate-of-production analysis and two uncertainty analysis tools: local uncertainty analysis and Monte Carlo simulations with Latin hypercube sampling. The chemical mechanism employed was that for methane plus the inorganic subset of the Master Chemical Mechanism (MCMv3.1). Newly installed instruments in EUPHORE allowed the measurement of nitrous acid and formaldehyde at sub-ppb concentrations with high sensitivity. The presence of HONO and HCHO during the experiments could be explained only by processes taking place on the FEP Teflon walls. The HONO production rate can be described by the empirical equation W(HONO)EUPHORE dry = a × j NO 2× exp (− T 0/T) in the low relative humidity region (RH < 2%, a = 7.3×1021 cm−3, T 0 = 8945K), and by the equation W(HONO)EUPHORE humid = W(HONO)EUPHORE dry+ j NO 2× b × RH q in the higher relative humidity region (2% < RH < 15%, b = 5.8×108 cm−3 and q = 0.36, and RH is the relative humidity in percentages). For HCHO the expression W(HCHO)EUPHORE = c × j NO 2exp (− T′0/T) is applicable (c = 3.1×1017 cm−3 and T′0 = 5686 K). In the 0–15% relative humidity range OH production from HONO generated at the wall is about a factor of two higher than that from the photolysis of 100 ppb ozone. Effect of added NO2 was found to be consistent with the dark HONO formation rate coefficient of MCMv3.1.  相似文献   

16.
The mixing ratios of surface O3 were measured at St. John's College, Agra, an urban and traffic influenced area for the period of 2000–2002. The monthly averaged O3 mixing ratios ranged between 8 to 40 ppb with an annual average of 21 ppb. Strong diurnal and seasonal variations in O3 mixing ratios were observed throughout the year except for monsoon season. The mixing ratios of O3 follow the surface temperature cycle and solar radiation (r = 0.72 and r = 0.65 with temperature and solar radiation, respectively). Concentrations were higher with winds associated with NE and NW direction indicating the impact of pollution sources on surface O3 concentration. Exceedance of ozone critical level was calculated using the AOT 40 index and found to be 840 ppb.h and 2430 ppb.h for summer and winter seasons, respectively. The present O3 exposures are lower than the critical level of O3 and suggest that the present level of O3 does not have any impact on reduction in crop yields.  相似文献   

17.
过氧乙酰硝酸酯（PAN）是由VOCs和NOx的光化学反应生成的一种典型二次污染物,比O3更适合作为光化学污染的指示剂.2019年6—10月对浙江中部盆地金华市大气中PAN进行了在线监测,并对影响其体积分数变化的因素进行了分析,同时还分析了一次典型的光化学污染过程.结果表明,观测期间PAN的平均体积分数为0.656×10-9,最高体积分数为4.348×10-9,日均体积分数水平在0.130×10-9~2.203×10-9之间.PAN日变化特征显著,9月为明显的双峰变化,其他月份均为单峰.受气象条件的影响,夏季的污染程度显著低于秋季.9月27—30日典型污染时段内,PAN的小时均值是整个观测期均值的2.8倍,污染以本地积累为主.前体物浓度水平差异与去除机制的不同是影响PAN和O3相关性的重要因素,此外NO/NO2的比值是影响PAN生成速率的重要因素,PAN的峰值基本出现在NO/NO2比值较低的时段.在生成PAN的VOCs物种中,丙烷、乙烷和间/对二甲苯所占比例较大.  相似文献   

18.
A high O3 episode was observed during 23–25 May 2004 at two high-mountain sites reflecting the regional pattern of air pollutants over East China. This episode lasted about three days with the maximum hourly O3 mixing ratios reaching 111 and 114 ppbv at Mt. Tai and Huang, respectively. Backward trajectories and meteorological analysis indicated that regional transport, associated with a weak high pressure system over the East China Sea, might play an important role in the formation of this high ozone episode. The nested air quality prediction modeling system (NAQPMS) was applied to investigate the formation and evolution of this high O3 event. The comparison of model results with observations showed that NAQPMS successfully reproduced the main observed patterns of O3 and meteorological parameters during the simulated period. The model results with emission over the Yangtze Delta and the East Central China switched on/off clearly showed that ozone and its precursors transported from the Yangtze Delta and the East Central China enhanced the high ozone episode at two sites, with a contribution of 20%–50% during the episode. In addition, based on process analysis with the model, chemical production and regional transport appeared to be the main causes of high ozone episode involving a large amount of high-ozone air masses and precursors transported from the surrounding areas. The horizontal transport is more active during the period of high ozone episode than that during the non-episode at Mt. Tai as well as Mt. Huang.  相似文献   

19.
传统的空气质量模型多使用简化的光化学反应机制来模拟大气污染物的形成.这些机制主要基于烟雾箱实验拟合的反应速率和产物来模拟二次产物（如臭氧（O3））前体物的氧化反应,具有一定的不确定性,导致模拟结果产生偏差.针对该问题,本研究将详细的大气化学机理（MCMv3.3.1）与美国国家环境保护局研制的第三代空气质量预报和评估系统CMAQ相结合（CMAQ-MCM）,模拟研究长三角地区2015年8月27—9月5日臭氧高发时段的空气质量.CMAQ-MCM模型可以较好地模拟长三角地区6个代表城市O3和其前体物随时间的变化趋势.对模拟的O3日最大8 h平均浓度的统计分析表明,徐州表现最好（标准平均误差=-0.15,标准平均偏差=0.23）.在长三角地区,居民源对挥发性有机物（VOCs）的贡献最大,占39.08%,其次是交通运输（33.25%）和工业（25.56%）.能源对总VOCs的贡献最小,约为2.11%.对活性氧化氮（NOy）的分析表明,其主要组分是NOx（80%）,其次是硝酸（HNO3）（<10%）.O3的空间分布与NOy和NOx非常相似.HCHO等其他氧化产物的分布与NOx相似,这很可能是由于在高NOx条件下VOCs氧化产生的产物.甲基乙烯基酮（MVK）和甲基丙烯醛（MACR）的空间分布与自然源VOCs （BVOCs）非常相似,表明长三角地区MVK和MACR主要由BVOCs氧化生成.长三角地区受到人为源和自然源排放相互作用的影响.  相似文献   

20.
大气质量的周循环特征反映了人类周期性的活动规律对大气环境的影响。基于安徽省16个城市PM_(2.5)、PM_(10)、CO、NO_2、SO_2和O_3这6种污染物的监测结果,对安徽省大气污染的周循环特征进行了评估。首先基于原始逐小时污染物浓度时间序列在日和周窗口时间宽度上的滑动平均序列,定义了周循环距平百分率序列的计算方法,排除了日循环和长期低频变化的影响。以此为基础,基于合成分析以及贝叶斯统计分析,发现这6种大气污染物中,PM_(2.5)、PM_(10)、CO和NO_2有着较为明显的周循环变化特征,其周循环距平百分率有着较大的变幅;而O_3的周循环特征相对不明显。主成分分析获得的周循环,第1模态发现除O_3以外的其他5种污染物的周循环有着同样的演进模式,即从周三开始持续到周五的累积和周六之后的衰减;O_3的周循环峰值与谷值与其他污染物存在着大于12 h的滞后,反映了在周循环尺度上O_3距平变化对其光化学反应前体距平变化的滞后响应特征。  相似文献   

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