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1.
Differential retardation of organic matter maturation by overpressure   总被引：2，自引：1，他引：2  
Thetraditionalhydrocarbongenerationmodeldoesnottakeintoaccounttheeffectofpressure[1].Astotheroleofpressureinorganicmattermaturationandpetroleumgeneration,threeconflictingopinionshaveeverbeenproposed:(1)Increasingpressurehasnodetectableeffectonorganic-mattermaturation[1,2];(2)increasingpressureenhanceshydrocarbon-thermaldestruction[3];(3)increasingpressuresignificantlyretardsorganic-mattermaturationandhydrocarbongeneration[4,5].Therearemorethan180overpressuredbasinsintheworld.Theroleofoverpress…  相似文献   

2.
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3.
Carbon dynamics of grasslands on the Qinghai-Tibetan Plateau may play an important role in regional and global carbon cycles. The CENTURY model (Version 4.5) is used to examine temporal and spatial variations of soil organic carbon (SOC) in grasslands on the Plateau for the period from 1960 to 2002. The model successfully simulates the dynamics of aboveground carbon and soil surface SOC at the soil depth of 0-20 cm and the simulated results agree well to the measurements. Examination of SOC for eight typical grasslands shows different patterns of temporal variation in different ecosystems in 1960-2002. The extent of temporal variation increases with the increase of SOC of ecosystem. SOC increases first and decreases quickly then during the period from 1990 to 2000. Spatially, SOC density obtained for the equilibrium condition declines gradually from the southeast to the northwest on the plateau and showed a high heterogeneity in the eastern plateau. The results suggest that (i) SOC den-sity in the alpine grasslands shows remarkable response to climate change during the 42 years, and (ii) the net carbon exchange rate between the alpine grassland ecosystems and the atmosphere increases from 1990 to 2000 as compared with that before 1990.  相似文献   

4.
The genus Vibrio,belonging to Gammaproteobacteria of the phylum Proteobacteria,is a genetically and ecologically diverse group of heterotrophic bacteria,that are ubiquitous in marine environments,especially in coastal areas.In particular,vibrios dominate,i.e.up to 10%of the readily culturable marine bacteria in these habitats.The distribution of Vibrio spp.is shaped by various environmental parameters,notably temperature,salinity and dissolved organic carbon.Vibriospp.may utilize a wide range of organic carbon compounds,including chitin(this may be metabolized by most Vibrio spp.),alginic acid and agar.Many Vibrio spp.have very short replication times(as short as～10 min),which could facilitate them developing into high biomass content albeit for relatively short durations.Although Vibriospp.usually comprise a minor portion(typically~1%of the total bacterioplankton in coastal waters)of the total microbial population,they have been shown to proliferate explosively in response to various nutrient pulses,e.g.,organic nutrients from algae blooms and iron from Saharan dust.Thus,Vibrio spp.may exert large impacts on marine organic carbon cycling especially in marginal seas.Genomics and related areas of investigation will reveal more about the molecular components and mechanisms involved in Vibrio-mediated biotransformation and remineralization processes.  相似文献   

5.
Plastic litter accounts for 50-80% of waste items stranded on beaches, floating on the ocean surface and lodged in the seabed. Organic pollutants can be absorbed onto plastic particles from sea water, attached to their surfaces or included in the plastic matrix as additives. Such chemicals may be transported to remote regions by buoyant plastics and ocean currents. We have estimated mass fluxes of polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), and perfluorooctanoic acid (PFOA) to the Arctic via the main ocean currents and compared them to those in the dissolved state and in air. Substance fluxes with atmospheric or sea water currents account for several tons per year, whereas those mediated by plastics are four to six orders of magnitude smaller. However, the significance of various pollutant transport routes does not depend only on absolute mass fluxes but also on bioaccumulation in marine food chains.  相似文献   

6.
Using multidiscipline methodologies, the differences in preservation and enrichment mechanisms of organic matter (OM) in muddy sediment and mudstone are investigated. In clay fractions, concentra- tions of TOC and chloroform bitumen “A” are significantly higher than those in coarser fractions. This indicates that clay minerals (CM) play an important role in enriching OM. The content of chloroform bitumen “A” increases obviously in the clay fraction, which reveals that dissolvable OM is the main composition of coalesce with clay minerals. Furthermore, TG and DTA data show that OM enrichment mechanisms and preservation forms have multiplicity. Several exothermic peaks in the DTA curves demonstrate that muddy sediment and mudstone contain a number of bioclasts and amorphous OM besides dissolvable OM. Through analyzing with XRD and DTA after mudstone samples were pretreated, the conclusions can be arrived at. Firstly, CM interlayer space of XRD curves and exothermic peaks of DTA curves both change as temperature increases. Secondly, the changes of CM interlayer space and exothermic peaks are concordant and stable around 350℃. All these are the features that OM enters CM interlayers to form stable organo-clay complexes. Therefore, the combination format of OM with CM is not only surface adsorption, partial OM enters CM interlayers to form stable organo-clay complexes. Finally, through the research on OM preservation forms and enrichment mechanisms in muddy sedi- ment and mudstone, the hydrocarbon-generation processes and the global carbon cycle and budget can be explained.  相似文献   

7.
High-resolution sampling,measurements of organic carbon contents and 14C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau,and application of 14C tracing technology were conducted in an attempt to investigate the turnover times of soil organic car-bon and the soil-CO2 flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×104 kg C hm-2 to 30.75×104 kg C hm-2 in the alpine meadow eco-systems,with an average of 26.86×104 kg C hm-2. Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO2 flux ranges from 103.24 g C m-2 a-1 to 254.93 gC m-2 a-1,with an average of 191.23 g C m-2 a-1. The CO2 efflux produced from microbial decomposition of organic matter varies from 73.3 g C m-2 a-1 to 181 g C m-2 a-1. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%―81.23% of total CO2 emitted from or-ganic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming,the storage,volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed,which needs further research.  相似文献   

8.
The effect of vertical turbulent mixing on the dynamics of persistent organic pollutants has long been overlooked and its role is still hardly understood. Here we present the first comprehensive analysis of the role of turbulent diffusion on the distribution of those contaminants and its interplay with sinking fluxes. To this end, a 1D dynamic coupled hydrodynamic-contaminant model has been developed and applied to a Mediterranean continental shelf environment. The hydrodynamic sub-model is adapted from COHERENS, the contaminant sub-model is an improvement from the BIODEP model and considers the contaminant in 3 phases: dissolved-colloidal-particulate. The simulation highlights the role of turbulence in determining the POP distribution and variability in the water column. In short, turbulent flux of contaminants strengthens the upward diffusion of sediment entrained contaminants and determines the extent to which inputs from the atmosphere mix into the water column. It acts in parallel with degradation and sinking fluxes, the combined effect yielding a surface enriched - depth depleted - benthic layer enriched region distribution, which presents similarities to reported experimental measures.  相似文献   

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10.
In the comparison research of hydrocarbon regeneration, a low maturity carbonate source rock is heated to different temperatures in a gold tube to obtain a series of samples with different maturities. Then, the heated samples, before and after extraction, are subjected to Rock-Eval pyrolysis through a thermal simulation of hydrocarbon regeneration in order to inspect pyrolysis characteristics and probe into the characteristics of the chemical kinetics of each sample. The results indicate that, whether hy- drocarbon regeneration peak is delayed or advanced, the potential of hydrocarbon regeneration is closely related to the expulsion amount and breakdown maturity of primary hydrocarbon generation. After extraction, the average activation energy of artificially maturated samples increases with the in- creasing maturity, but the chemical kinetic properties of un-extracted samples decrease. The calibrated chemical kinetic models that describe extracted and un-extracted samples are applied to the Bohai Bay and the Songliao Basin, and the results indicate that the combination of the two models can explain some contradictory conclusions previously reported. These results also facilitate the quantitative evaluation of the amount of hydrocarbon regeneration by the chemical kinetic method.  相似文献   

11.
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12.
This paper presents an overview of changes in organic pollution of coastal waters of the Gulf of Gdańsk (Baltic Sea). Toxic pollutants including volatile organic compounds (VOC), volatile organohalogen compounds (VOX), chlorophenols, phenoxyacids, polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were determined in seawater from the Gulf of Gdańsk coastal waters in the period 1996-2001. In the case of the Gulf of Gdańsk, non-conservative behaviour of VOC was observed due to random temporal and spatial of inputs along the Vistula estuary and to the dilution of VOC-enriched river water with seawater. The concentrations of VOX in seawater decreased throughout the period and the concentrations of VOX were in the range of few ng dm(-3) up to 250 ng dm(-3), similar to estuaries elsewhere. The average concentrations of chlorophenols and phenoxyacids were between 0.1 and 6.0 and 0.05 and 2.2 microg dm(-3), respectively. However, remarkably high concentrations of 2,4-dichlorophenol (6 microg dm(-3)) were obtained in samples collected from the Vistula River. Generally concentrations of PCBs did not exceed few ng dm(-3) with the exception of 1999, when all samples exhibited elevated concentrations of PCBs. In addition, higher concentrations of PCBs in the open sea compared to river waters suggested localised inputs. Due to the ability of most organic pollutants to bioaccumulate and biomagnify, especially the persistent organic pollutants, continued monitoring is of crucial importance for the health of marine life in the Gulf of Gdańsk.  相似文献   

13.
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14.
Speleothems and other carbonate deposits such as tufa containing high proportions of detrital material can be difficult to chemically date due to detrital thorium levels causing a high level of error in conventional U-Th disequilibrium dating. Here we investigate the use of an alternative technique centring on radiocarbon dating of organic matter preserved within the detrital fraction. Non-acid soluble humic, particulate and detritally absorbed organic matter was recovered from eight samples from a flowstone sinter formed within a roman aqueduct at Trento in Italy with a maximum age of 100 CE (1850 cal yr BP), and two repeat samples from a dripstone formed within the 20th Century on a wire fence at Lilly-Pilly Cave, Buchan Caves Reserve in Victoria, Australia. In the aqueduct samples the median calibrated 14C ages ranged from 2232 to 2889 cal yr BP, with 95.4% probability age range in the youngest and oldest samples of 2153–2337 and 2342–3449 cal yr BP respectively. The median age of the more modern dripstone was 336 cal yr BP, with a 95.4% probability age range of 148–486 cal yr BP. These results provide very approximate ball-park estimates of the age of the sample, but are consistently too old when compared to the known maximum ages of formation. It is hypothesised that this offset is due to a combination of the nature of the organic carbon transported from the source organic matter pools, and reworking of both modern and old organic carbon by in situ microbial communities.  相似文献   

15.
The nature of the interaction between iron oxyhydroxide compounds and natural organic matter (NOM) may take various forms and is still a matter of debate. It is an important field to understand, especially for water treatment applications and for the knowledge of iron transport in the environment. The nature of association reached between iron oligomeric species and NOM is here investigated using M?ssbauer spectroscopy and electron energy-loss spectroscopy (EELS) at the Fe-L3 edge. Raw water NOM taken from Moselle River (France), natural humic substances extracted from the riverine suspended matter, and a synthesized humic-like substance, are coagulated with iron nitrate according to a jar-test procedure. The results from M?ssbauer spectroscopy indicate that Fe is present in an octahedral coordination environment, which is consistent with prior X-ray absorption spectroscopy reported in the literature. The areas beneath the peaks (Fe L3 edge) and the peak shapes of EELS spectra differ according to the origin of the organic matter, suggesting that various types of Fe populations can be distinguished using the EELS technique. Combining the selectivity of both M?ssbauer spectroscopy for identifying trace, poorly crystalline Fe solids, oxidation state and of EELS for being able to characterize the population of Fe based on L-edge spectra, appears promising for characterizing Fe in systems containing NOM.  相似文献   

16.
A dielectric model for thawed and frozen Arctic organic-rich soil (50% organic matter) has been developed. The model is based on soil dielectric measurements that were collected over ranges of gravimetric moisture from 0.03 to 0.55 g/g, dry soil density from 0.72 to 0.87 g/cm3, and temperature from 25 to −30 °C (cooling run) in the frequency range of 0.05–15 GHz. The refractive mixing dielectric model was applied with the Debye multi-relaxation equations to fit the measurements of the soil’s complex dielectric constant as a function of soil moisture and wave frequency. The spectroscopic parameters of the dielectric relaxations for the bound, transient bound, and unbound soil water components were derived and were complimented by the thermodynamic parameters to obtain a complete set of parameters for the proposed temperature-dependent multi-relaxation spectroscopic dielectric model for moist soils. To calculate the complex dielectric constant of the soil, the following input variables must be assigned: (1) density of dry soil, (2) gravimetric moisture, (3) wave frequency, and (4) temperature. The error of the dielectric model was evaluated and yielded RMSEε′ values of 0.348 and 0.188 for the soil dielectric constant and the loss factor, respectively. These values are on the order of the dielectric measurement error itself. The proposed dielectric model can be applied in active and passive microwave remote sensing techniques to develop algorithms for retrieving the soil moisture and the freeze/thaw state of organic-rich topsoil in the Arctic regions.  相似文献   

17.
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18.
The adsorption of organic matter(OM)onto clay minerals has long been considered as a significant way of OM preservation in source rock.Here we analyzed the relationship between OM and the specific surface area(SSA)of <2μm clay size fraction isolated from 13 source rock cores collected from Dongying depression.Rock-Eval pyrolysis and N2 adsorption experiment were employed to probe the characteristics of OM and SSA(denoted SBET)in samples before and after OM extraction using trichloromethane.The results indicate that various kinds of OM occurrence coexist in clay size fraction and their contributions to hydrocarbon are different in each period of OM evolution.The occurrence and amount of OM affect the S BET of clay size fraction,and a nonlinear negative correlation between total organic carbon(TOC)and S BET can be recognized.The soluble OM(chloroform extract "A"),mainly stored in the pore space of clay size fraction,shows a negative correlation in amount with S BET.Our data also indicate that free hydrocarbon(S1)was stored mainly in the pore space and/or the surface of clay size fraction,whereas pyrolysis hydrocarbon(S2)was mingled mainly with clay minerals.Therefore,to understand various OM occurrences and their relationship with SBET in the clay size fraction is significant in the study of generation,accumulation,and migration of hydrocarbon in muddy source rock.  相似文献   

19.
The results of studying the composition of hydrocarbon gases (C1–C5) and organic matter in bottom sediments of the Ivankovo Reservoir in 1995, 2004, and 2005 are given. The methods used in the study include vapor-phase gas chromatography, instrumental pyrolysis gas chromatography, and mass-spectrometry for determining organic carbon δ 13Corg. The gas field of bottom sediments in different regions of the reservoir varies widely in terms of gas saturation and the spectrum of hydrocarbon gases. This suggests the heterogeneous composition of organic matter in the sediments and different conditions of its input and transformation processes. The gases were found to contain saturated hydrocarbons from methane to pentane C1–C5, including isomers i-C4 and i-C5 and unsaturated compounds C2–C4. A correlation was found to exist between methane distribution and the distribution of its more high-molecular homologues, which confirms their genetic relationship in bottom sediments. The obtained results show an increase in the rate of microbiological processes and organic matter transformation for most regions in the Ivankovo Reservoir. The only exceptions are the zones of Moshkovichskii Bay and the sections at Gorodnya and Konakovo, where technogenic organic matter is being accumulated. The high information value of hydrocarbon gases as biogeochemical markers of the sources of organic matter and the rates of its transformation is demonstrated. The isotopic composition of organic-matter carbon in the bottom sediments of the Ivankovo Reservoir δ 13C varies from ?26.21 to ?30.86‰.  相似文献   

20.
The spatial and diurnal tidal variability of dissolved organic carbon (DOC) concentrations and the composition of dissolved organic matter (DOM), as evaluated by high-temperature catalytic oxidation and excitation–emission matrix combined with parallel factor analysis (EEM–PARAFAC), respectively, were determined in Liverpool Bay. EEM–PARAFAC modeling resulted in six fluorescent components characterized as terrestrial humic-like (two), microbial humic-like (two), and protein-like (two). The spatial distributions of DOC and the four humic-like components were negatively correlated with salinity in the high-salinity waters observed in this study (30.41–33.75), suggesting that terrestrial DOM was conservatively distributed. The spatial patterns of protein-like components were largely different from those of DOC, humic-like components, and chlorophyll a, suggesting that these distributions were the combined result of production and degradation in the bay in addition to river inputs. These findings suggest that the DOM dynamics in Liverpool Bay are strongly controlled by river-dominated allochthonous DOM inputs with some less significant contributions of autochthonous DOM within the bay. In addition, the temporal variations of DOM associated with the diurnal tidal cycles were determined at one inshore (31.34–32.24 salinity) and one offshore (33.64–33.75 salinity) station in the bay. Negative linear relationships between salinity and DOM characteristics, i.e., DOC, humic-like, and protein-like components, were observed at the inshore station. In contrast, no relationship was observed at the offshore station, suggesting that the export of DOM through rivers and possibly tidal flats have a noticeable influence on DOM concentration and composition up to a relatively elevated salinity of around 33 in Liverpool Bay.  相似文献   

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