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1.
Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to ∼650 mmol L−1 at ∼150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at ∼60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (δD-CH4 = −170.8‰ (SMOW), δ13C-CH4 = −61.0‰ (V-PDB), δ13C-C2H6 = −44.0‰ (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 × 106 mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.  相似文献   

2.
Nearly 2000 pockmarks with diameters ranging from a few tens of meters up to 700 m are present on the seafloor of the St. Lawrence Estuary in eastern Canada. Coring of some pockmarks resulted in the recovery of various-sized and shaped carbonate concretions in a predominantly silty mud matrix. Petrographic and geochemical data on four authigenic carbonate concretions are reported as well as data from shell material in the unconsolidated sediment. Video observations and echo-sounder images indicate that the sampled pockmarks are actively gas venting. The video images show significant look-alike microbial mats in areas where gas is venting. The carbonate concretions are primarily made up of carbonate cements with varying percentage of shell fragments, micrite particles and fine-grained clastics. Orthorhombic crystal morphology and diagenetic fabrics including isopachous layers and botryoids characterize the aragonite cement. Oxygen isotopes ratios for the cement crusts do not record any thermal anomaly at the site of precipitation with δ18OVPDB ratios (+3‰) in equilibrium with cold (5 °C) deep marine waters, whereas significant negative δ13CVPDB ratios (−9.9 to −33.5‰) for cement and shell material within concretions indicate that the carbonates largely derive from the microbial oxidation of methane. The δ13CVPDB ratios of aragonite shells (−2.7 to −5.6‰) taken from unconsolidated sediments at some distance from the concretions/vents show variable dilution of HCO3− with negative δ13CVPDB ratios derived from microbial oxidation of methane with isotopically normal (0‰) marine bicarbonate. These results are in agreement with other lines of evidence suggesting that pockmarks formed through the recent and still active release of gas from a reservoir within the Paleozoic sedimentary succession.  相似文献   

3.
We simultaneously followed stable carbon (δ13C) and nitrogen (δ15N) isotopes in a two-source food web model to determine trophic levels and the relative importance of open water- and ice-associated food sources (phytoplankton vs. ice algae) in the lower marine food web in the European Arctic during four seasons. The model is based upon extensive seasonal data from 1995 to 2001.Phytoplankton, represented by samples of particulate organic matter from open water (Pelagic-POM) and ice algae, represented by samples from the underside of the ice (Ice-POM), were isotopically different. Ice-POM was generally dominated by the typical ice diatoms Nitzschia frigida and Melosira arctica and was more enriched than Pelagic-POM in 13C (δ13C = −20‰ vs. −24‰), but less enriched in 15N (δ15N = 1.8‰ vs. 4.0‰). However, when dominated by pelagic algae, Ice-POM was enriched in 13C and 15N similarly to Pelagic-POM.The derived trophic enrichment factors for δ15N (ΔN = 3.4‰) and δ13C (ΔC = 0.6‰) were similar in both pelagic and sympagic (ice-associated) systems, although the ΔC for the sympagic system was variable.Trophic level (TL) range for zooplankton (TL = 1.8-3.8) was similar to that of ice fauna (TL = 1.9-3.7), but ice amphipods were generally less enriched in δ15N than zooplankton, reflecting lower δ15N in Ice-POM compared to Pelagic-POM. For bulk zooplankton, TLs and carbon sources changed little seasonally, but the proportion of herbivores was higher during May-September than in October and March. Overall, we found that the primary carbon source for zooplankton was Pelagic-POM (mean 74%), but depending on species, season and TL, substantial carbon (up to 50%) was supplied from the sympagic system. For bulk ice fauna, no major changes were found in TLs or carbon sources from summer to autumn. The primary carbon source for ice fauna was Ice-POM (mean 67%), although ice fauna with TL > 3 (adult Onisimus nanseni and juvenile polar cod) primarily utilized a pelagic food source.  相似文献   

4.
The aim of this study was to distinguish between sources of the complex variety of Marennes-Oléron Bay suspended particulate organic matter (SPOM) contributing to the tropho-dynamics of the Marennes-Oléron oyster farming bay. Basic biomarkers (Chl a, C/N and POC/Chl a ratios), carbon and nitrogen stable isotopes from SPOM were analyzed and the microalgae community was characterized. The sampling strategy was bimonthly from March 2002 to December 2003; samples were taken from an intertidal mudflat. Four main sources contributed to the SPOM pool: terrigenous input from rivers, neritic phytoplankton, resuspended microphytobenthos and periodic inputs from intertidal Zostera noltii meadows. Seasonal fluctuations were observed in both years of the study period: (1) SPOM collected in the spring of 2002 (δ13C = −25‰ to −23‰) was mainly composed of fresh estuarine inputs; (2) SPOM from the summer and fall of 2002 and 2003 was predominantly neritic phytoplankton (δ13C = − 22‰ to −19‰); (3) SPOM from the winter of 2002, spring of 2003 and winter of 2003 (δ13C = −21 to −23‰) was composed of a mixture of decayed terrigenous river inputs and pelagic phytoplankton, which was predominantly resuspended microphytobenthos. In the summer of 2003—the warmest summer on record in southern France and Europe—SPOM was particularly enriched for 13C, with δ13C values ranging from −14‰ to −12‰. Pulses in δ13C values, indicative of 13C-enriched decaying materials, extended into the fall. These were attributed to benthic intertidal inputs, including both resuspended microphytobenthos and Z. noltii detritus. Changes in SPOM sources in Marennes-Oléron Bay may lead to differences in the quality of the trophic environment available for reared oysters.  相似文献   

5.
The worlds >1500 mud volcanoes are normally in a dormant stage due to the short duration of eruptions. Their dormant stage activity is often characterized by vigorous seepage of water, gas, and petroleum. However, the source of the fluids and the fluid–rock interactions within the mud volcano conduit remain poorly understood. In order to investigate this type of activity, we have combined satellite images with fieldwork and extensive sampling of water and gas at seeping gryphons, pools and salsa lakes at the Dashgil mud volcano in Azerbaijan. We find that caldera collapse faults and E–W oriented faults determine the location of the seeps. The seeping gas is dominated by methane (94.9–99.6%), with a δ13C (‰ V-PDB) in the −43.9 to −40.4‰ range, consistent throughout the 12 analysed seeps. Ethane and carbon dioxide occur in minor amounts. Seventeen samples of seeping water show a wide range in solute content and isotopic composition. Pools and salsa lakes have the highest salinities (up to 101,043 ppm Cl) and the lowest δ18O (‰ V-SMOW) values (1–4‰). The mud-rich gryphons have low salinities (<18,000 ppm Cl) and are enriched in 18O (δ18O = 4–6‰).  相似文献   

6.
Gases were analyzed from well cuttings, core, gas hydrate, and formation tests at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well, drilled within the Milne Point Unit, Alaska North Slope. The well penetrated a portion of the Eileen gas hydrate deposit, which overlies the more deeply buried Prudhoe Bay, Milne Point, West Sak, and Kuparuk River oil fields. Gas sources in the upper 200 m are predominantly from microbial sources (C1 isotopic compositions ranging from −86.4 to −80.6‰). The C1 isotopic composition becomes progressively enriched from 200 m to the top of the gas hydrate-bearing sands at 600 m. The tested gas hydrates occur in two primary intervals, units D and C, between 614.0 m and 664.7 m, containing a total of 29.3 m of gas hydrate-bearing sands. The hydrocarbon gases in cuttings and core samples from 604 to 914 m are composed of methane with very little ethane. The isotopic composition of the methane carbon ranges from −50.1 to −43.9‰ with several outliers, generally decreasing with depth. Gas samples collected by the Modular Formation Dynamics Testing (MDT) tool in the hydrate-bearing units were similarly composed mainly of methane, with up to 284 ppm ethane. The methane isotopic composition ranged from −48.2 to −48.0‰ in the C sand and from −48.4 to −46.6‰ in the D sand. Methane hydrogen isotopic composition ranged from −238 to −230‰, with slightly more depleted values in the deeper C sand. These results are consistent with the concept that the Eileen gas hydrates contain a mixture of deep-sourced, microbially biodegraded thermogenic gas, with lesser amounts of thermogenic oil-associated gas, and coal gas. Thermal gases are likely sourced from existing oil and gas accumulations that have migrated up-dip and/or up-fault and formed gas hydrate in response to climate cooling with permafrost formation.  相似文献   

7.
Multidisciplinary study of seep-related structures on Southern Vøring Plateau has been performed during several UNESCO/IOC TTR cruises on R/V Professor Logachev. High-resolution sidescan sonar and subbottom profiler data suggest that most of the studied fluid discharge structures have a positive relief at their central part surrounded by depression. Our data shows that the present day fluid activity is concentrated on the top of these “seep mounds”. Number of high hydrocarbon (HC) gas saturated sediment cores and 5 cores with gas hydrate presence have been recovered from these structures. δ13C of methane (between −68 and −94.6‰ VPDB) and dry composition of the gas points to its biogenic origin. The sulfate depletion generally occurs within the upper 30–200 cm bsf and usually coincides with an increase of methane concentration. Pore water δ18O ranges from 0.29 to 1.14‰ showing an overall gradual increase from bottom water values (δ18O ∼ 0.35‰). Although no obvious evidence of fluid seepage was observed during the TV surveys, coring data revealed a broad distribution of living Pogonophora and bacterial colonies on sea bottom inside seep structures. These evidences point to ongoing fluid activity (continuous seepage of methane) through these structures. From other side, considerable number and variety of chemosynthetic macro fauna with complete absence of living species suggest that present day level of fluid activity is significantly lower than it was in past. Dead and subfossil fauna recovered from various seep sites consist of solemyid (Acharax sp.), thyasirid and vesicomyid (cf. Calyptogena sp.) bivalves belonging to chemosymbiotic families. Significant variations in δ13C (−31.6‰ to −59.2‰) and δ18O (0.42‰ and 6.4‰) of methane-derived carbonates collected from these structures most probably related to changes in gas composition and bottom water temperature between periods of their precipitation. This led us to ideas that: (1) seep activity on the Southern Vøring Plateau was started with large input of the deep thermogenic gas and gradually decries in time with increasing of biogenic constituent; (2) authigenic carbonate precipitation started at the near normal deep sea environments with bottom water temperature around +5 °C and continues with gradual cooling up to negative temperatures recording at present time.  相似文献   

8.
To assess the potential of stable isotope ratios as an indicator of fish migration within estuaries, stable isotope ratios in important zooplankton species were analyzed in relation to estuarine salinity gradients. Gut contents from migratory juveniles of the euryhaline marine fish Lateolabrax japonicus were examined along the Chikugo River estuary of the Ariake Sea, which has the most developed estuarine turbidity maximum (ETM) in Japan. Early juveniles in March and April preyed primarily on two copepod species; Sinocalanus sinensis at lower salinities and Acartia omorii at higher salinities. Late juveniles (standard length > 40 mm) at lower salinities preyed exclusively on the mysid Acanthomysis longirostris until July and complementarily on the decapod Acetes japonicus in August. These prey species were collected along the estuary during the spring–summer seasons of 2003 and 2004, and their carbon and nitrogen stable isotope ratios (δ13C and δ15N) were evaluated. The δ13C values of prey species were distinct from each other and were primarily depleted within and in close proximity to the ETM (salinity < 10); S. sinensis (−26.6‰) < Acanthomysis longirostris (−23.3‰) < Acartia omorii (−21.1‰) < Acetes japonicus (−18.5‰). The overall gradient of δ13C with salinity occurred for all prey species and showed minor temporal fluctuations, while it was not directly influenced by the δ13C values in particulate organic matter along the estuary. In contrast to δ13C, the δ15N values of prey species did not exhibit any clear relationship with salinity. The present study demonstrated that δ13C has the potential for application as a tracer of fish migration into lower salinity areas including the ETM.  相似文献   

9.
To estimate the influence of mercury emitted from submarine fumaroles, the horizontal and vertical distribution of mercury in sediment of Kagoshima Bay was studied. The fumaroles are located in the northern bay head area, and the sediment samples had been taken from 52 points throughout the bay with a gravity core sampler. The core samples obtained were cut at a thickness of 1–2 cm and used for measurements. The total concentration of mercury in surface sediment in the northern and central areas of the bay was 51–679 μg kg− 1 (average 199 μg kg− 1, n = 22) and 23–100 μg kg− 1 (average 55 μg kg− 1, n = 30), respectively. The highest value was obtained in the vicinity of the fumaroles. The mercury concentration in sediment near the fumaroles varied with depth, which may reflect the variation in fumarolic activity. A successive extraction method was applied to the speciation of mercury in the sediment. The results showed that sediment taken in the vicinity of submarine fumaroles contained a higher percentage of mercury bound with organic matter.  相似文献   

10.
Isotopic analyses of nitrate by the denitrifier method, and indeed by many other analytical methods, do not discriminate between nitrate and nitrite. For samples containing both chemical species, accurate isotopic analysis of nitrate requires either removal of nitrite or independent isotopic analysis of nitrite and subtraction of its contribution to the mixed isotopic signal. This study evaluates the application of a variety of available analytical approaches to the isotopic analysis of mixed nitrate and nitrite solutions, with the goal of producing accurate coupled isotopic analyses of both nitrate and nitrite. These methods are tested on mixtures of standard solutions of nitrate and nitrite, and then applied to the coupled δ15N and δ18O analyses of nitrate and nitrite in waters of the Eastern Tropical North Pacific (ETNP). Results from standard mixtures show that even for extreme values of nitrate and nitrite δ15N and δ18O, both nitrite removal by ascorbate and nitrite isotopic analysis and subtraction from the mixed isotopic signal yield nitrate δ15N and δ18O values that are close to the expected values. Application of these analyses to samples from the ETNP yielded δ15NNO3 and δ18ONO3 values as high as 21‰ vs. AIR and 19‰ vs. VSMOW, respectively. Conversely, very low δ15N values were observed in nitrite, with values ranging from − 7.2 to − 18.5‰ vs. AIR. Removal of nitrite from ETNP samples thus revealed differences of up to 5‰ between NO3- and NO2- + NO3- for both δ15N and δ18O. Moreover, the δ15N offset between co-occurring nitrate and nitrite is greater than expected from the action of denitrification alone and may provide a unique constraint on the processes involved in the cycling of nitrite in and around oxygen deficient zones. Finally, subtraction of the nitrite δ15N and δ18O from ETNP samples allows the extension of the Δ(15,18) tracer into suboxic regions containing nitrite. The magnitude and distribution of Δ(15,18) in these samples suggests an important role for nitrite reoxidation in nitrate isotope variations.  相似文献   

11.
Moored sediment traps were deployed from January 2004 through December 2007 at depths of 550 and 800 m in San Pedro Basin (SPB), CA (33°33.0′N, 118°26.5′W). Additionally, floating sediment traps were deployed at 100 and 200 m for periods of 12-24 h during spring 2005, fall 2007, and spring 2008. Average annual fluxes of mass, particulate organic carbon (POC), ??13Corg, particulate organic nitrogen (PON), ??15N-PON, biogenic silica (bSiO2), calcium carbonate (CaCO3), and detrital material (non-biogenic) were coupled with climate records and used to examine sedimentation patterns, vertical flux variability, and organic matter sources to this coastal region. Annual average flux values were determined by binning data by month and averaging the monthly averages. The average annual fluxes to 550 m were 516±42 mg/m2 d for mass (sdom of the monthly averages, n=117), 3.18±0.26 mmol C/m2 d for POC (n=111), 0.70±0.05 mmol/m2 d for CaCO3 (n=110), 1.31±0.21 mmol/m2 d for bSiO2 (n=115), and 0.35±0.03 mmol/m2 d for PON (n=111). Fluxes to 800 and to 550 m were similar, within 10%. Annual average values of ??13Corg at 550 m were −21.8±0.2‰ (n=108), and ??15N averages were 8.9±0.2‰ (n=95). The timing of both high and low flux particle collection was synchronous between the two traps. Given the frequency of trap cup rotation (4-11 days), this argues for particle settling rates ≥83 m/d for both high and low flux periods. The moored traps were deployed over one of the wettest (2004-2005, 74.6 cm rainfall) and driest (2006-2007, 6.6 cm) rain years on record. There was poor correlation (Pearson's correlation coefficient, 95% confidence interval) of detrital mass flux with: Corg/N ratio (r=0.10, p=0.16); ??15N (r=−0.19, p=0.02); and rainfall (r=0.5, p=0.43), suggesting that runoff does not immediately cause increases in particle fluxes 15 km offshore. ??13Corg values suggest that most POC falling to the basin floor is marine derived. Coherence between satellite-derived chlorophyll a records from the trap location (±9 km2 resolution) and SST data indicates that productivity and export occurs within a few days of upwelling and both of these parameters are reasonable predictors of POC export, with a time lag of a few days to 2 weeks (with no time lag—SeaWiFS chlorophyll a and POC flux, r=0.25, p=0.0014; chlorophyll a and bSiO2 flux, r=0.28, p=0.0002).  相似文献   

12.
Based on measurements of the 18O isotope composition of 247 samples collected over a 3-year period we have assessed the oxygen isotope composition of water masses in the North Sea. This is the first δ18O data set that covers the entire North Sea basin. The waters lie on a mixing line: δ18O (‰VSMOW) = −9.300 + 0.274(S) with North Atlantic sub-polar mode water (SPMW) and surface waters, and Baltic Sea water representing the saline and freshwater end members respectively. Patterns exhibited in surface and bottom water δ18O distributions are representative of the general circulation of the North Sea. Oxygen-18 enriched waters from the North Atlantic enter the North Sea between Scotland and Norway and to a lesser extent through the English Channel. In contrast, oxygen-18 depleted waters mainly inflow from the Baltic Sea, the rivers Rhine and Elbe, and to a lesser degree, the Norwegian Fjords and other river sources. Locally the δ18O–salinity relationship will be controlled by the isotopic composition of the freshwater inputs. However, the range of local freshwater compositions around the North Sea basin is too narrow to characterise the relative contributions of individual sources to the overall seawater composition. This dataset provides important information for a number of related disciplines including biogeochemical research and oceanographic studies.  相似文献   

13.
Authigenic carbonates are common at cold seep sites as a result of microbial oxidation of hydrocarbons. Seep carbonate samples were collected from the surface of the Bush Hill (Green Canyon Block 185, Gulf of Mexico), a mound containing gas hydrate. The carbonates consisted of oily, porous limestone slabs and blocks containing bioclasts and matrix. Analysis by X-ray diffraction shows that aragonite is the dominant mineral (89–99 wt% with an average of 94 wt%) in the matrix of seep carbonate. This cement occurs in microcrystalline, microspar, and sparite forms. The moderate 13C depletion of the seep carbonate (the most depleted one has δ13C value of −29.4‰, and 26 of 38 subsamples have δ13C values >−20.0‰) indicates that the non-methane hydrocarbons was incorporated during seep carbonate precipitation. Relative enrichment of 18O may be related to localized destabilization of gas hydrate or derived from 18O-enriched pore water originated from smectite–illite transition in the deep sediments. The total content of rare earth elements (REE) of the 5% HNO3-treated solution of the carbonates is from 0.40 ppm to 30.9 ppm. The shale-normalized REE patterns show varied Ce anomalies from significantly negative, slightly negative, and no to positive Ce anomalies. Variable content of trace elements, total REE, and Ce anomalies in different samples and even in the different carbonate mineral forms (microcrystalline, microspar and sparite) of the same sample suggest that the formation condition of the Bush Hill seep carbonate is variable and complex, which is possibly controlled by the rate of fluid flux.  相似文献   

14.
Fossil methane from the large and dynamic marine gas hydrate reservoir has the potential to influence oceanic and atmospheric carbon pools. However, natural radiocarbon (14C) measurements of gas hydrate methane have been extremely limited, and their use as a source and process indicator has not yet been systematically established. In this study, gas hydrate-bound and dissolved methane recovered from six geologically and geographically distinct high-gas-flux cold seeps was found to be 98 to 100% fossil based on its 14C content. Given this prevalence of fossil methane and the small contribution of gas hydrate (≤ 1%) to the present-day atmospheric methane flux, non-fossil contributions of gas hydrate methane to the atmosphere are not likely to be quantitatively significant. This conclusion is consistent with contemporary atmospheric methane budget calculations.In combination with δ13C- and δD-methane measurements, we also determine the extent to which the low, but detectable, amounts of 14C (~ 1–2% modern carbon, pMC) in methane from two cold seeps might reflect in situ production from near-seafloor sediment organic carbon (SOC). A 14C mass balance approach using fossil methane and 14C-enriched SOC suggests that as much as 8 to 29% of hydrate-associated methane carbon may originate from SOC contained within the upper 6 m of sediment. These findings validate the assumption of a predominantly fossil carbon source for marine gas hydrate, but also indicate that structural gas hydrate from at least certain cold seeps contains a component of methane produced during decomposition of non-fossil organic matter in near-surface sediment.  相似文献   

15.
In-situ measurements of benthic fluxes of oxygen and nutrients were made in the subtidal region of the Mandovi estuary during premonsoon and monsoon seasons to understand the role of sediment–water exchange processes in the estuarine ecosystem. The Mandovi estuary is a shallow, highly dynamic, macrotidal estuary which experiences marine condition in the premonsoon season and nearly fresh water condition in the monsoon season. The benthic flux of nutrients exhibited strong seasonality, being higher in the premonsoon compared to the monsoon season which explains the higher ecosystem productivity in the dry season in spite of negligible riverine nutrient input. NH4+ was the major form of released N comprising 70–100% of DIN flux. The benthic respiration rate varied from −98.91 to −35.13 mmol m−2 d−1, NH4+ flux from 5.15 to 0.836 mmol m−2 d−1, NO3− + NO2− from 0.06 to −1.06 mmol m−2 d−1, DIP from 0.12 to 0.23 mmol m−2 d−1 and SiO44− from 5.78 to 0.41 mmol m−2 d−1 between premonsoon to monsoon period. The estuarine sediment acted as a net source of DIN in the premonsoon season, but changed to a net sink in the monsoon season. Variation in salinity seemed to control NH4+ flux considerably. Macrofaunal activities, especially bioturbation, enhanced the fluxes 2–25 times. The estuarine sediment was observed to be a huge reservoir of NH4+, PO43− and SiO44− and acted as a net sink of combined N because of the high rate of benthic denitrification as it could remove 22% of riverine DIN influx thereby protecting the eco system from eutrophication and consequent degradation. The estuarine sediment was responsible for ∼30–50% of the total community respiration in the estuary. The benthic supply of DIN, PO43− and SiO44− can potentially meet 49%, 25% and 55% of algal N, P and Si demand, respectively, in the estuary. Based on these observations we hypothesize that it is mainly benthic NH4+ efflux that sustains high estuarine productivity in the NO3− depleted dry season.  相似文献   

16.
A cross-system analysis of bulk sediment composition, total organic carbon (TOC), atomic C/N ratio, and carbon isotope composition (δ13C) in 82 surface sediment samples from natural and planted mangrove forests, bank and bottom of tidal creeks, tidal flat, and the subtidal habitat was conducted to examine the roles of mangroves in sedimentation and organic carbon (OC) accumulation processes, and to characterize sources of sedimentary OC of the mangrove ecosystem of Xuan Thuy National Park, Vietnam. Sediment grain sizes varied widely from 5.4 to 170.2 μm (mean 71.5 μm), with the fine sediment grain size fraction (< 63 μm) ranging from 11 to 99.3% (mean 72.5%). Bulk sediment composition suggested that mangroves play an important role in trapping fine sediments from river outflows and tidal water by the mechanisms of tidal current attenuation by vegetation and the ability of fine roots to bind sediments. The TOC content ranged from 0.08 to 2.18% (mean 0.78%), and was higher within mangrove forests compared to those of banks and bottoms of tidal creeks, tidal flat, and subtidal sediments. The sedimentary δ13C ranged from − 27.7 to − 20.4‰ (mean − 24.1‰), and mirrored the trend observed in TOC variation. The TOC and δ13C relationship showed that the factors of microbial remineralization and OC sources controlled the TOC pool of mangrove sediments. The comparison of δ13C and C/N ratio of sedimentary OC with those of mangrove and marine phytoplankton sources indicated that the sedimentary OC within mangrove forests and the subtidal habitat was mainly composed of mangrove and marine phytoplankton sources, respectively. The application of a simple mixing model showed that the mangrove contribution to sedimentary OC decreased as follows: natural mangrove forest > planted mangrove forest > tidal flat > creek bank > creek bottom > subtidal habitat.  相似文献   

17.
About 120 gas seepage vents were documented along the west and southwest coast of the Hainan Island, South China Sea, in water depths usually less than 50 m. The principal seepage areas include the Lingtou Promontory, the Yinggehai Rivulet Mouth, Yazhou Bay, the Nanshan Promontory and the Tianya Promontory. They occur along three major zones, reflecting the control by faults and lateral conduits within the basement. It is estimated that the total gas emission from these seepage vents is 294–956 m3/year. The seepage gases are characterized by a high CH4 content (76%), heavy δ13C1 values (−38 to −33‰) and high C1/C1–5 ratios (0.95–1.0), resembling the thermogenic gases from the diapiric gas fields of the Yinggehai Basin. Hydrocarbon–source correlation shows that the hydrocarbons in the sediments from seepage areas can be correlated with the deeply buried Miocene source rocks and sandstone reservoirs in the central depression. The 2D basin modeling results based on a section from the source rock center to the gas seepage sites indicate that the gas-bearing fluids migrated from the source rocks upward through faults or weak zones encompassed by shale diapirism or in up-dip direction along the sandstone-rich strata of Huangliu Formation to arrive to seabed and form the nearshore gas seepages. It is suggested that the seepage gases are sourced from the Miocene source rocks in the central depression of the Yinggehai Basin. This migration model implies that the eastern slope zone between the gas source area of the central depression and the seepage zone is also favorable place for gas accumulation.  相似文献   

18.
The distribution of diagenetic alterations in Triassic fluvio-deltaic, quartzarenitic to sublitharenitic, lowstand systems tract (LST) sandstones of the Grès á Voltzia Formation, anastomosing fluvial, quartzarenitic transgressive systems tract (TST) sandstones of the Grès á Roseaux Formation, and shallow marine, quartzarenitic to sublitharenitic, TST sandstones of the Grès Coquiller Formation, the Paris Basin (France), can be linked to transgression and regression events, and thus to the sequence stratigraphic context. Near-surface eogenetic alterations, which display a fairly systematic link to the depositional facies and sequence stratigraphic framework, include: (i) cementation by meteoric water calcite (δ18O=−8.9‰ and δ13C=−9.1‰) in the fluvio-deltaic, LST sandstones, (ii) cementation by mixed marine–meteoric calcite (δ18O=−5.3‰ to −2.6‰ and δ13C=−3.9‰ to −1.3‰) and dolomite (δ18O=−4.6‰ to −2.6‰ and δ13C=−2.9‰ to −2.3‰) in the foreshore, TST sandstones and below parasequence boundaries (PB), and transgressive surface (TS), and in the shoreface, TST sandstones below maximum flooding surfaces (MFS), being facilitated by the presence of carbonate bioclasts, (iii) dissolution of detrital silicates and precipitation of K-feldspar overgrowths and kaolinite, particularly in the fluvio-deltaic, LST sandstones owing to effective meteoric water circulation, and (vi) formation of autochthonous glauconite, which is increases in abundance towards the top of the fluvio-deltaic, LST sandstones, and along TS, and in the shoreface, TST sandstones, by alteration of micas owing to the flux of seawaters into the sandstones during transgression, whereas parautochthonous glauconite is restricted to the TS sandstones owing to marine reworking. Mesogenetic alterations, which include cementation by quartz overgrowths and illite, display fairly systematic link to fluvio-deltaic, LST sandstones. This study has revealed that linking of diagenesis to transgression and regression events enables a better understanding of the parameters that control the spatial and temporal distribution of diagenetic alterations in sandstones and of their impact on reservoir quality evolution.  相似文献   

19.
Hydrocarbon gases were determined in sediments from three mud volcanoes in the Sorokin Trough. In comparison to a reference station outside the mud volcano area, the deposits are characterized by an enrichment of high-molecular hydrocarbons (C2–C4), an absence of unsaturated homologues, a predominance of iso-butane in comparison with n-butane, and the presence of gas hydrate. The molecular composition of the hydrocarbon gases suggests their deep sources and thermogenic origin. In the pelagic sediments at the reference station, the methane concentration is relatively low (up to 49 ml/l); maximum concentrations are reached in deposits of the Dvurechenskii mud volcano (up to 400 ml/l). It was the first time that gas hydrate was sampled at the Dvurechenskii mud volcano. The gas extracted by dissociation of hydrate samples was dominated by methane (99.5%) with low amounts of ethane and propane (less than 0.5%). The isotopic composition of the methane varies between –62 and –66 PDB in 13C, and between –185 and –209 SMOW in D, indicating a mainly biogenic origin with an admixture of thermogenic gas.  相似文献   

20.
Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct–Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C1 through C5) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg− 1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH4. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH4 concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.  相似文献   

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