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1.
Pyrite is a sensitive mineral in the geological environment,and its oxidation produces an important geochemical and environmental effect on the control of the redox and pH conditions.Column experiment results were used for modeling the geochemical processes in uranium mill tailings under leac-hing conditions.Oxidation of pyrite dominates the control of the tailings leaching process.The experi-mental and modeling results show that the leachate chemistry changes substantially with the decrease in pyrite consumption.In the initial stage of the leaching experiment,the pyrite is consumed several hun-dred times grater than that in the later stages,for much more oxygen is present in the tailings in the ini-tial stage.As the experiment continues,the tailings is gradually saturated with water and the oxygen concentration greatly decreases and so does pyrite consumption.The experimental and modeling results are useful for the design of mill tailing decommissioning:oxidation process and transport of radioactive nuclides and heavy metals can be constrained by controlling the oxygen concentration of tailings and the infiltration of meteoric water. 相似文献
2.
This paper studies a landfill where there are three faults running through.As serious pollution has occurred to the geological environment,the landfill is to be closed up and renovated.The paper aims to explore the role of fracture structure in leachate pollution at the landfill.The research was carried out in several stages.First,mathematical models of the pre-renovation landfill with three faults running through and the landfill after renovation were established.And then,the boundary conditions and parameters of the two mathematical models were determined.The groundwater level of the landfills was simulated in order to modify the two mathematical models.As a result,a feasible mathematical model was achieved.Based on this model,a comparison was made of the COD concentration variations in the inside leachate and outside leachate between the two landfills. Accordingly,the impacts of the fracture structure on the pollution of leachate at the landfills could be identified.The study results show that while faults contribute to the migration of leachate,they also serve as a confluence of leachate,thus further deteriorating the environment.The COD concentrations of the inside leachate and the outside leacbate of the pre-renovation landfill are respectively 800 mg/L and 220 mg/L higher than those of the post.renovation landfill.Therefore,measures must be taken to handle the leachate seepage in areas where there are faults as well as the neighboring areas so as to get the environmental pollution under control. 相似文献
3.
Barbara L. Sherriff Kristin A. Salzsauler Stephanie Simpson Nikolay V. Sidenko Jamie VanGulck 《中国地球化学学报》2006,25(B08):29-30
Local water contamination by arsenic can be caused by gold mining activities as in Snow Lake, Manitoba. This project was to f＇md the source （s） and pathways of the arsenic contamination and describe arsenic attenuation in ground and surface water. The project was initiated because arsenic concentrations average 16.0 mg/L in one groundwater monitoring well （MW17）. One potential source of arsenic is the 50 year-old Arsenopyrite Residue Stockpile （ARS）, 100 m upgrade of MW17. Between 1948 and 1959, 250000 tons of cyanide treated, arsenopyrite concentrate were stored in a waste rock impoundment, which was left open until 2000 when it was capped with layers of waste rock, clay and silt to minimize water infiltration and the oxidative release of arsenic. 相似文献
4.
This paper studies a landfill where there are three faults running through. As serious pollution has occurred to the geological environment, the landfill is to be closed up and renovated. The paper aims to explore the role of fracture structure in leachate pollution at the landfill. The research was carried out in several stages. First, mathematical models of the pre-renovation landfill with three faults running through and the landfill after renovation were established. And then, the boundary conditions and parameters of the two mathematical models were determined. The groundwater level of the landfills was simulated in order to modify the two mathematical models. As a result, a feasible mathematical model was achieved. Based on this model, a comparison was made of the COD concentration variations in the inside leachate and outside leachate between the two landfills. Accordingly, the impacts of the fracture structure on the pollution of leachate at the landfills could be identified. The study results show that while faults contribute to the migration of ieachate, they also serve as a confluence of leachate, thus further deteriorating the environment. The COD concentrations of the inside leachate and the outside leachate of the pre-renovation landfill are respectively 800 mg/L and 220 mg/L higher than those of the post-renovation landfill. Therefore, measures must be taken to handle the ieachate seepage in areas where there are faults as well as the neighboring areas so as to get the environmental pollution under control. 相似文献
5.
Shenggao CHENG Lei HUANG Ruili SHEN 《中国地球化学学报》2006,25(B08):108-108
Ecotourism environmental impact assessment is a traveling activity relevant influence prediction and appraisal. And the setting-up of the index system is very important to implement the appraisal of environmental impact of ecological travel. According to the index system, natural ecological environment, humane social environment, the environment of tourist resources and the atmosphere of capacity of tourist environment, four major systems form the first index. Each system formed the second index of several key elements. In addition, it is a key step to appraise the sureness of the factor weight, which influences the rationality of the result directly. Daily method of weighting has the Delphi＇s and the AHP. According to ＂Grade form of characteristic value of Standard of rating for quality of tourist attractions＂ which the National Tourism Administration issues, the paper takes the Jingshan mountains ecological tourist zone as an example and adopts AHP to weight the factors mainly, assisted with the Delphi＇s by the help of computer. The Jingshan ecological tourist zone is good. The result of calculation, comprehensive value of 8.35 after establishment, shows that it doesn＇t change dramatically, attributing to the index of natural ecological environment like atmosphere, quality of surface water, acoustics environment and vegetation coverage. Improvement of traffic states and sanitation caused by the project in the region increases the comprehensive value, while the water and soil loss in partial area caused by construction decrease. 相似文献
6.
《探矿工程》2009,(Z1):170-176
The pneumatic down-the-hole(DTH) hammer is one of the efficient equipments used in medium hard to very hard rock drilling frield,and any change in its structure design affects all performance parameters of a pneuamtic DTH hammer directly.Yet,owing to the complexity of the dynamic interaction among the components in DTH hammer systems,until now it has been difficult to obtain reliable estimates of the design parameter affects.Thus providing an design parameter optimization and the layout of dynamics behavior of DTH hammer is of great importance.This paper documents the development and solution of a computational model for the dynamic response of a pneumatic DTH hammer.The model consists of rigid piston dynamics equation and chamber thermodynamics equations.The resulting model represented by a set of coupled nonlinear differential equations were computed in Visual C++ program.The developed solutions are used to perform a parametric study to illustrate the inffluence of the piston mass and supply pressure on the impact performance of DTH hammer system. 相似文献
7.
Holocene environmental change and environmental archaeology are important components of an international project studying the human-earth interaction system.This paper reviews the progress of Holocene environmental change and environmental archaeology research in the Yangtze River Valley over the last three decades,that includes the evolution of large freshwater lakes.Holocene transgression and sea-level changes,Holocene climate change and East Asian monsoon variation,relationship between the rise and fall of primitive civilizations and environmental changes,cultural interruptions and palaeoflood events,as well as relationship between the origin of agriculture and climate change.These research components are underpinned by the dating of lacustrine sediments,stalagmites and peat to establish a chronology of regional environmental and cultural evolution.Interdisciplinary and other environment proxy indicators need to be used in comparative studies of archaeological site formation and natural sedimentary environment in the upper,middle and lower reaches of the Yangtze River Valley.Modern technology such as remote sensing,molecular bioarchaeology,and virtual reality,should be integrated with currently used dating,geochemical,sedimentological.and palaeobotanical methods of analysis in environmental archaeology macro- and micro-studies,so as to provide a greater comprehensive insight into Holocene environmental and cultural interaction and change in the Yangtze River Valley area. 相似文献
8.
Tamara Tersic Mateja Gosar Robert Sajn 《中国地球化学学报》2006,25(B08):36-36
The Podljubelj mercury mine lies in the NW part of Slovenia. The ore is of hydrothermal-vein type. The ore deposit was exploited between the years 1557 and 1902. Total production of the mine was 110000 tons of ore （360 tons of Hg）. A smelter located close to the mine had been in operation since 1855. The waste material from the mine and the smelter was dumped in close vicinity of the mine. Total quantity of the waste has been estimated at 170000 tons. In order to establish environmental impacts, soil and stream sediment samples were investigated. Soil samples were collected at two different depths （horizons A and B） in a 100 m grid within an 88 ha area. In the vast area also 11 samples of stream sediments were considered. Heavy metals were determined by means of cold vapor atomic absorption spectrometry CV-AAS after aqua regia digestion. Based on the chemical analyses of samples, the estimated mercury mean for soils is 3.67 mg/kg （0.35-244 mg/kg） for horizon A and 1.39 mg/kg （0.17-71.7 mg/kg） for horizon B. The estimated mercury mean for stream sediments is 0.64 mg/kg （0.065-1.36 mg/kg）. The concentrations of mercury in soils generally decrease with depth and distance from the mine. The highest content of Hg was determined in a sample taken in the immediate vicinity of the smelter （719 mg/kg）. The results have shown that on the 9 ha of the study area, the contents of Hg in soils exceeded the officially set limit value for soils （10 mg/kg）. High contents of Hg in soil around the abandoned smelter are a consequence of former atmospheric emissions and technological losses. High contents of Hg were also found in the mine and smelter waste dump. At the edges of the study area and in the samples of stream sediments, Hg concentrations are low. 相似文献
9.
Mining activities have left huge uncovered slopes, large areas of gangue ground and extensive railings dams. In this paper, we studied some impacts of mining activities upon environment in Panzhihua region, southwestern China. The environmental impacts include ecological destruction, geological disasters, environmental pollution, land damage, solid waste and occupational health effect in study area. The author suggested that local government should take some measure to reduce environmental impact in Panzhihua City. First, the countermeasure of reducing environmental impact is to set up ecological rehabilitation and environmental management system, which ensure the sustainable development of resources, environment, economy and society in this region. Second, the area needs to be monitored regularly for trace metal and other pollutants to forewarn urban eco-environmental safety. 相似文献
10.
AhmedA.Melegy T.Paces 《中国地球化学学报》2004,23(2):155-162
Heavy metals in different environmental compartments can be hazardous to ecosystems. Budgets of Cd, Pb and Zn in small ecosystems of the Shubra E1-Kheima area in Egypt are presented. The budgets are not in steady state because they change with time. So the concentrations of the metals are a function of time. The critical loads of heavy metals to soils can be calculated from an inventory of inputs and outputs of the trace components in the catchment area.Critical time is an important parameter for critical load evaluation because it can indicate which of the heavy metals may be the most acute threat to the soils. Egyptian soil in the Shubra ElKheima area seems to be in danger of heavy metal pollution by Zn, Cd and Pb. The calculated critical loads and their exceedances are approximate indicators of the hazards in the soil system.The critical time is a warning signal to initiate an environmental evaluation of possible pollution hazards. 相似文献
11.
Janusz Golas Jerzy Gorecki Mariusz Macherzynski Witold Reczynski Agnieszka Iwanicha Michal Sliwa 《中国地球化学学报》2006,25(B08):191-191
Mineral and organic matter either soluble or suspended are transported by the rivers and when deposited in the bed of the river or in the water reservoir, sediments are formed, whose chemical composition may serve as a fingerprint of the history of the ecosystem. The results of the studies of sediments in water systems （river catchments, reservoirs） can be used not only for the evaluation of the current state of the ecosystem but also to prevent any dangerous environmental changes. Bottom sediments can in many ways accumulate both suspended and soluble components. The process is influenced by several factors like pH, red-ox potential, oxygen content, interactions, etc. The complexity of those phenomena causes that in order to study the accumulation processes of compounds in sediments the application of various analytical techniques is required. The authors participate in two big projects on sediment studies. The AquaTerra Project is the EU funded project on understanding river-sediment-soil-groundwater interactions for support of management of river basins and catchment areas. Our group＇s studies are focused on mercury determination and its speciation in sediments and fish from the Ebro River in Spain. The Dobczyce Project is the national project funded by the Ministry of Education and sciences of Poland which is also a EU member country. The latter covers many aspects of accumulation and fate processes of chemical compounds in sediments of the reservoir which supplies 60% of drinking water to about one million population in the city of Krakow in Poland. 相似文献
12.
A symplectite of pyrite and magnetite in the massive sulphide ore of the Mashan mine,Anhui Province,is interpreted to have been formed by their replacing earlier pyrrhotite.The compositions of pyrrhotite,pyrite and magnetite related to this texture are given by electron microprobe analysis.Such a texture is likely to be formed when the ore-forming system reaches the three-phase point of pyrrhotite,pyrite and magnetite from the pyrrhotite stability field.The very small probability for the system to reach this point could be used to account for the rare occurrence of such symplectite in natural ores. 相似文献
13.
The water system in a rural area of Lanmuchang in Southwest Guizhou is facing a risk of thallium (Tl) contamination due to Tl mineralization around the area. The major trace elements and Tl in the water system are studied to understand the hydrogeochemical processes of Tl constrained by Tl mineralization. The results showed that the dispersion pattern of Tl follows a descending order in concentration from mine groundwater (deep groundwater) →stream water→shallow groundwater→background water, reflecting the impact of Tl mineralization on the hydrogeochemical composition. Tl concentrations in stream water in both regimes are remarkably higher (2-30 fold) downstream than up- and mid-streams, probably caused by the unidentified discharge of deep groundwater. Low Tl levels are detected in the current drinking water, however, the highly elevated Tl in stream water and ground water may pose a potential environmental risk through daily washing and agricultural irrigation. This study suggests that human activities, such as agricultural irrigation, could intensify the environmental risk of Tl. 相似文献
14.
Ping LI Xinbin FENG Guangle QIU Minishi Sakamoto Xiaojie LIU 《中国地球化学学报》2006,25(B08):234-234
Small-scale mercury smelting activities with indigenous method are always extensive in the Wuchuan area, northeastern Guizhou Province, China. Because of the simple processes without any environmental protection, a large amount of mercury vapor released to the ambient air during the processing of cinnabar roasting. So the health of the workers may be negatively affected through inhalation of the mercury-polluted air. Mercury, creatinine and β2-MG contents in urine among the workers in the study areas and the residents in the control site （Changshun County） were determined to discuss the health impact of mercury vapor exposure to the workers in the study areas. Health examinations also were carded out to identify clinical symptoms of mercury poisoning for the smelting workers. Results indicated that the geometric mean value of urinary mercury for the smelting workers was g/g Cr μg/g Cr （N=22）, significantly higher than 1.24 μg/g （N=54） for residents in the control site. β2-MG as a renal biomarker can be used to study human nephrotoxicity at an early stage and it is most useful to define effects for assessing re-absorption function to indicate tubular injury. The results showed a serious adverse effect on renal system for the smelting workers due to mercury exposure. Several workers have already manifested some clinical symptoms of lightly chronic mercury poisoning and the symptoms include finger and eyelid lightly tremor, gingivitis and blue mercury line in mouth. The study illuminated that the workers in gaged in indigenous mercury smelting in the Wuchuan area were seriously exposed to mercury vapor, 相似文献
15.
Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer （salt deposit） in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system （salt deposits） was developed by using the Pitzer theory. Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarhan Salt Lake. 相似文献
16.
LI Wenpeng 《《地质学报》英文版》2008,(5)
Firstly,the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory.The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented,which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake.And secondly,with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference,a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile,the model was applied to model potassium/magnesium transport in Qarban Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarban Salt Lake. 相似文献
17.
Selection and Basic Properties of the Buffer Material for High-Level Radioactive Waste Repository in China 总被引：1，自引：0，他引：1
WEN Zhijian 《《地质学报》英文版》2008,82(5):1050-1055
Radioactive wastes arising from a wide range of human activities are in many different physical and chemical forms, contaminated with varying radioactivity. Their common features are the potential hazard associated with their radioactivity and the need to manage them in such a way as to protect the human environment. The geological disposal is regarded as the most reasonable and effective way to safely disposing high-level radioactive wastes in the world. The conceptual model of geological disposal in China is based on a multi-barrier system that combines an isolating geological environment with an engineered barrier system. The buffer is one of the main engineered barriers for HLW repository. It is expected to maintain its low water permeability, self-sealing property, radio nuclides adsorption and retardation properties, thermal conductivity, chemical buffering property, canister supporting property, and stress buffering property over a long period of time. Bentonite is selected as the main content of buffer material that can satisfy the above requirements. The Gaomiaozi deposit is selected as the candidate supplier for China＇s buffer material of high level radioactive waste repository. This paper presents the geological features of the GMZ deposit and basic properties of the GMZ Na-bentonite. It is a super-large deposit with a high content of montmorillonite （about 75 %）, and GMZ-1, which is Na-bentonite produced from GMZ deposit is selected as the reference material for China＇s buffer material study. 相似文献
18.
Yaping WANG Chunxue XU Suming WANG Ziyi AN 《中国地球化学学报》2006,25(B08):15-15
Along with the rapid development of science and technology, natural matter and energy are further exploited and used. The pollution imposed on nature has also sharply increased. Only do we know the pollution history, can we make a correct appraisal of local environment, get the hold of the main cause of environmental pollution, and then take the effective measures to control the environment？ The evolution of heavy metal concentrations with time in the soil environment in the southern suburbs of Beijing were studied by using annual growth rings of trees. The absorption of 12 elements by different tree species in the same soil type was studied according to their absorption coefficients. The study indicated the differences in adsorption of elements by different species of trees. The adsorption coefficients of the elements Zn, Cd and P are higher. The correlations of nine elements （Na, K, Cu, Zn, As, Sr, Cd, Ba and Pb） in growth rings of poplar trees and those in soils near their roots show that the element contents in growth rings have a positive correlation with the contents in soils near the roots. Based on the logarithmic linear correlation model, the evolution of the contents of the elements Cu, Zn, As, Cd, Ba and Pb in soils from 1982 to 2004 was deduced. The trees have the characters of confirming year precisely, long life and widespread distribution. They are the ideal objects of study on environmental pollution changes. At present, research in China in this aspect is less, and the field of research is expected to further expand. This method can be used to provide richer and more scientific information on the history of environmental pollution and changes during modem urbanization in the past few decades and predicting the evolutionary trend of pollution change. 相似文献
19.
Groundwater is of fundamental significance for human society,especially in semi-arid areas in China.However,due to the fast social and economic development,China has been suffering from the shortage of water resource.In this situation,managed aquifer recharge(MAR)was considered to be an effective measure for the sustainable management of groundwater resources.Since 1960 s,China successfully implemented many MAR schemes for different purposes such as restoration of groundwater tables,prevention of seawater intrusion,increasing urban water supplies and controlling land subsidence.From those successful experiences China developed a scientific and applicable system to implement MAR project.However,there were still many challenges in this field,for example,treated waste water had been barely used for recharge.The present review summarized the achievements in MAR applications in China as well as the associated challenges within the past 55 years before the year 2016. 相似文献
20.
This paper describes how to carry out environmental impact assessment in an environmentally sensitive zone.The principles,the train of thought and methods are proposed in this paper,We have made the water environmental impact assessment on the engineering project of technical reforms in Guiyang Battery Mill.The hasis for engineering construction and environmental protection in this mill has been laid dawn. 相似文献