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秦岭风太矿田的层控铅锌矿床,主要产于中泥盆统古道岭组灰岩与上泥盆统星红铺组千枚岩之间的硅质岩中,具有稳定的层位。矿床的成矿物质来源于深部地层的循环热液,成矿方式有同生热液沉积和后生充填交代两种类型,成矿元素具有分带特点,反映出矿床的海底喷流—沉积成因。矿床的形成主要受地层层位(时控)、古构造背景(裂谷盆地与同生断裂)和古沉积环境(台地边缘洼地)的控制。根据矿床地质特征和控矿地质条件确定的矿床勘查标志,对于寻找和预测新的矿床有重要意义。 相似文献
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陕西省陈家坝铜铅锌多金属矿床地质地球化学特征及矿床成因探讨 总被引：1，自引：0，他引：1
陕西省略阳县陈家坝铜铅锌多金属矿床是"勉-略-阳"矿集区具有代表性的铜多金属矿床之一,在该矿区内已经发现了多个矿(化)体,显示出很好的成矿潜力。本文在室内外研究的基础上,详细论述了该矿床的地质和地球化学特征,采用矿床岩石主量元素、黄铁矿单矿物微量元素地球化学分析和硫同位素测试方法,对陈家坝铜铅锌多金属矿床的成矿地质特征、成矿物质来源和成矿机制进行了探讨。硫同位素特征显示,δ~(34)S主要来自海水硫酸盐,认为该矿床成矿物质主要来源于碧口岩群东沟坝组,NWW和NEE向共轭断裂是矿田内重要的控矿构造。通过黄铁矿微量元素分析显示陈家坝矿床成矿温度为中低温,成矿经历了热液作用的改造过程。综合研究认为该矿床属火山沉积-改造型矿床。 相似文献
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湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据 总被引：9，自引：0，他引：9
为了查明湘中盆地中-低温梯（金）矿床的成矿物质来源，文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定，并结合作者以往分析数据和实验地球化学结果，对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明：Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量，在近似成矿条件下的水/岩反应实验中，成矿元素的淋出率达20%～90%，元古界基底碎屑岩中的金（锑、钨）矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床（化）及其蚀变围岩中；湘中锑（金）矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征，以上微量元素地球化学特征充分证明该区锑（金）矿床锑、金等成矿物质主要来源于元古界底碎屑岩。 相似文献
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通过因子分析这种常用的多元统计方法来揭示元素之间、样品之问以及与地质作用之间的相互关系,了解其中蕴藏着丰富的成矿信息,为研究成矿物质来源和矿床成因提供依据.在研究滇东北巧家松梁铅锌矿床地质特征的基础,以其中Ⅰ号矿体的控矿断裂(F5断裂)内的构造岩为R型因子,得到4组元素组合因子并综合成矿地质条件因子进行分析,结果表明:该矿床严格受构造控制,碳酸盐化蚀变和铅、锌矿化发生在不同的成矿阶段;成矿流体并非完全来自地层,主要来源于深源流体;铅锌等成矿物质具有"多源性",部分来自于地层(白云岩),部分来自于与基底岩石有联系的成矿流体.客矿断裂带内的构造岩裂隙发育,铅锌成矿流体有选择性地沿碎基多、破碎强烈的裂隙充填胶结成矿,矿床应该属赋存于碳酸盐岩中的热液型铅锌矿床. 相似文献
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贵州独山锑矿床成矿物质来源研究 总被引：2，自引：0，他引：2
崔银亮 《有色金属矿产与勘查》1995,4(4):193-199
对独山锑矿床的微量元素和稳定同位素以及矿物包裹体的研究表明：含矿层（中下泥盆统）中成矿元素含量很高，构成了重要的矿源层；硫来自含矿层；有机炭在成矿中起了重要作用；成矿流体中的水应主要为大气降水；铅主要来自泥盆系围岩。因此认为，成矿物质应主要来源于地层，矿床的形成是地下水环流热液强改造成矿作用的结果。 相似文献
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成矿物质来源是矿床研究的重要内容。本文通过里伍铜矿含矿岩石中的石英流体包裹体的温度、成分和盐度测试分析,以及矿床地球化学特征研究,结合区域地质演化历史,揭示其成矿物质来源、成矿物质的运移和浓集机制,为解释里伍铜矿的成矿环境和成因提供依据。 相似文献
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陕西马鞍桥金矿床成因探讨 总被引：6，自引：0，他引：6
马鞍桥金矿是南秦岭泥盆系铅锌金（银汞锑）多金属成矿带中具有代表性的大型金矿床。矿床产于上泥盆统桐峪寺组上部浅变质细碎屑岩系,层位稳定。矿床的地质地球化学特征表明,成矿物质主要来自前沿盆纪基底的地层和岩石,成矿溶液主要为盆地同生水与变质水及大气降水的混合流体。成矿经历了同生沉积、韧性剪切变质变形、矿质活化迁移聚集和构造－热液活动叠加富集的多期成矿过程。综合分析确定,该矿床属受韧－脆性剪切带控制、地下 相似文献
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滇东南白牛厂银多金属矿床成矿元素特征 总被引：3，自引：0，他引：3
成矿物质来源是研究矿床成因的关键问题之一,而地质体（地层和岩浆岩）成矿元素的含量高低是探讨成矿物质来源的基础.为了研究白牛厂超大型银多金属矿床主要成矿元素特征,本文系统测定了外围赋矿地层以及矿区花岗岩和花岗斑岩的成矿元素（Ag、Pb、Zn、Sn）含量,结果表明,Pb、Zn主要来源于矿区花岗岩,寒武系及下伏基底地层可能也提供了部分成矿物质,特别是Zn;由于矿区外围赋矿地层的Sn含量远低于Pb、Zn的含量,也远远低于地壳克拉克值,因此推测,Sn主要来源于花岗岩浆;Ag则主要来源于赋矿地层,花岗岩对其进行了后期的改造作用. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献