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1.
胶州湾李村河口沉积物中酸可溶硫化物与活性金属分布特征 总被引：1，自引：0，他引：1
对胶州湾李村河口9个短柱状样沉积物中活性金属、AVS和有机质含量等参数进行了分析.其中AVS含量:198.4～0.4 μmol/g,平均35.8μmol/g.大部分样品活性金属含量具有 Fe > Zn > Cu > Cr >V > Ni > Pb > Co > Cd 的顺序.活性重金属 Zn, Cu, Cr, V, Ni, Pb, Co, Cd 含量之和 ( ΣM ) 为:0.53～17.39 μmol/g.通过对所测数据分析发现,大多数活性金属间具有较好的相关性,反映了它们具有相同的来源或相似的早期成岩地球化学特征.近河口区沉积物的地球化学特征与远河口区差异明显:近河口区底层水为还原环境,AVS 形成的制约因素是活性铁的可获得性,而活性重金属的分布受到AVS的控制并主要以金属硫化物或硫化物吸附态的形式存在,AVS 仍具有较大的吸附重金属的潜力,同时硫化物中重金属再次释放造成二次污染的潜在性也较大;而在离河口稍远的海域,沉积物中 AVS 形成的控制因素是有机质的供给和环境氧化还原状态的变化,活性重金属主要以铁氧化物结合态存在,表层沉积物中重金属的环境敏感性及生物有效性都较高. 相似文献
2.
以富营养化的胶州湾一个柱状沉积物为例,用细化的铁形态分析及量化的铁氧化物还原活性相结合的方法研究了沉积物中铁的成岩作用过程。结果表明,这两种方法相结合的结果能更详细示踪铁的转化并能从多视角提供铁成岩作用的细微差别。这一方法有望应用于其它研究中更好地揭示复杂的铁和硫的生物地球化学循环。铁微生物还原在上部沉积物铁的还原中起重要作用,但12 cm深度以下铁被硫化物的化学还原为主要过程。最具生物活性的无定形铁氧化物是铁微生物还原的主要参与者,然后依次为弱晶态铁氧化物和磁铁矿,晶态铁氧化物几乎不参与铁的成岩循环。沉积物上部铁微生物还原的重要作用主要是活性铁含量高而活性有机质含量低共同作用的结果,且后者也是沉积物中硫酸盐还原速率以及硫化物积累的最终制约因素。对比研究表明,通过还原性溶解动力学方法表征的微生物可还原的铁氧化物主要由无定形和弱晶态铁氧化物组成,其总体活性常数相当于老化的水铁矿,且随深度增加而减低。 相似文献
3.
对珠江口淇澳岛海岸带3个站位(QA-11,QA-9和QA-14)的沉积物中不同形态的还原硫(酸可挥发性硫,黄铁矿和有机硫)、总有机碳(TOC)和孔隙水中SO42-,甲烷浓度进行了测定,并且利用稳态扩散模型计算其中2个站位(QA-9和QA-14)硫酸盐还原通量[1.74和1.14 mmol/(m2.d)]和甲烷厌氧氧化通量[0.34和0.29 mmol/(m2.d)]。研究结果表明由于潮间带沉积物受到SO42-供给的限制,因此位于潮间带的QA-11站位硫酸盐还原带较浅(约16 cm);在潮下带的QA-9和QA-14站位,随离海岸距离和水深的增加,硫酸盐还原通量呈现减小的趋势,并且硫酸还原逐渐受到可利用活性有机质的限制;甲烷厌氧氧化对硫酸盐还原的贡献表现出增加的趋势,由19.2%增加至25.5%。三个站位沉积物中按不同形态还原硫含量由大到小列出,它们是有机硫(OS)、黄铁矿(DS)、酸可挥发性硫(AVS)。沉积物中AVS的空间分布与硫酸盐还原通量有正相关性。QA-11和QA-14站位的黄铁矿与AVS硫的含量比值大于3,分别为7.9和3.6,表明两个站位的黄铁矿形成可能受硫酸盐还原作用的控制;QA-9站位黄铁矿与AVS硫的含量比值为2.2,暗示AVS向黄铁矿转化受到可利用活性铁的限制。 相似文献
4.
东海沉积物中铁(Ⅲ)氧化物还原活性的动力学表征 总被引：3，自引：1，他引：2
运用还原性溶解动力学实验和活性连续体(reactive continuum)模型表征了东海表层和柱状沉积物中铁(Ⅲ)氧化物的还原活性及反应进程中的动力学行为,通过动力学数据拟合得到了活性铁氧化物理论含量m0、表观速率常数k'和活性非均匀度γ。结果表明,表层沉积物中铁氧化物的m0在26.14~60.51 μmol/g之间,变化较小;表征高活性铁氧化物还原动力学行为的标准化初始还原速率(J/m0=k')变化也较小,最大相差仅7.25倍;但不同站位沉积物中铁氧化物活性的非均匀度变化较大,当铁氧化物溶解达到90%时,其速率与初始速率相差2~4个数量级。表层沉积物中铁氧化物的m0,k'和γ 3个动力学参数之间不存在相关性;柱状沉积物中m0,k'和γ 3个动力学参数都随深度的增加呈总体减小的趋势,且三者之间存在良好的线性关系,这是沉积物早期成岩作用中铁成岩循环的结果。与传统的化学提取相比,活性连续体模型得到3个动力学参数(m0,k'和γ)能从多个角度表征铁氧化物还原活性和动力学行为的细微差别。 相似文献
5.
长江河口及邻近海域表层沉积物中铁溶解和磷释放活性的动力学表征 总被引：1，自引：0，他引：1
运用溶解动力学实验及活性连续体模型表征了长江河口至东海邻近海域表层沉积物中铁(Fe)和磷(P)的活性。通过动力学数据拟合得到了活性组分的理论含量m0和表观速率常数k。结果表明，Fe(Ⅱ)普遍存在于表层沉积物中，这应是高活性有机络合态Fe(Ⅲ)絮凝/沉淀到沉积物中后快速还原的结果。沉积物中黏土及总有机碳（TOC）含量对Fe(Ⅱ)的m0及其k值起重要控制作用。从长江河口至邻近海域沉积物中Fe(Ⅱ)均以FeCO3形态为主，FeCO3的溶解及与之相结合磷(主要为交换态P和自生P)的释放导致Fe(Ⅱ)和P具有相似的溶解动力学特征。与吸附于Fe(Ⅱ)矿物相的P相比，与Fe(Ⅱ)矿物相共沉淀的P的m0较高，但k较低。与TOC含量较低的粗粒沉积物中的Fe(Ⅲ)相比，TOC含量较高的细粒沉积物中Fe(Ⅲ)的m0值较小，但k值较大。以上特征是Fe不同的氧化还原过程导致的。Fe(Ⅲ)氧化物的含量(m0)和活性(k)总体上控制着与之相结合P的含量(m0)及溶解活性(k)。虽然传统活性Fe形态分析未能揭示出长江河口沉积物中活性Fe的富集作用，但溶解动力学表征结果表明，Fe的絮凝/沉淀导致河口沉积物中活性Fe的明显富集，且该过程主要发生在盐度明显增加的低盐度河口区。 相似文献
6.
研究了2003年10月采于珠江口5个站位的沉积物剖面酸挥发性硫化物(AVS)和同时提取的重金属(SEM:Pb,Zn,Cu,Cd,Ni)。其中,站位1、2位于中滩,其沉积物的AVS含量变化范围较小,为0.25—4.06μmol.g-1;站位3、4位于西滩,其沉积物的AVS含量变化范围较大,为0—26.09μmol.g-1。中滩和西滩沉积物的AVS含量均随深度增加。西滩表层沉积物的AVS含量接近于零,这可能与该水域较强的底层流和沉积物的再悬浮作用有关。站位5位于珠江口外侧,其表层沉积物的AVS含量相对较高,且垂向变化较小,可能是还原性沉积物间歇性再悬浮后重新沉积的结果。站位1、2和5沉积物中同时提取的重金属含量大体在0.95±0.2μmol.g-1范围内,随深度增加略呈下降趋势;而西滩沉积物重金属含量相对较高,为1.43—2.42μmol.g-1,且在一定深度范围内随深度增加呈明显下降的趋势,表明珠江口西滩沉积物中的重金属污染有加重的趋势。对AVS/SEM摩尔比值和单个金属的毒性效应研究显示,珠江口内尤其是西滩的表层沉积物存在重金属污染,对其中生活的底栖生物具有潜在的毒性效应。 相似文献
7.
黄河口外沉积物氧化还原环境的表征 总被引：1，自引：0，他引：1
为了评价黄河口外石油开发区沉积物的氧化还原特征,本文根据2002年9月航次所取得的黄河口外41个柱状沉积物样品,研究了该区沉积物氧化还原特征参数Fe^3 ,Fe^2 ,Fe^3 ／Fe^2 及Eh,Es和有机碳、氧化还原度(ROD)等的分布特征,以及这些参数之间的相关关系。研究表明,Fe^3 ,Fe^2 ,Fe^3 ／Fe^2 及Eh,Es和有机碳、氧化还原度(ROD)等在表层沉积物中各站之间的差别不大。Fe^3 和Fe^2 在0～40cm深度范围内变化比较复杂。40cm以后变的相对比较稳定。而Eh和Es有随深度减小的趋势,ROD在整个研究区都小于1,有机碳的含量高于整个渤海的平均值。综合所有氧化还原特征参数的特征,可确认该区沉积物的氧化还原环境为还原性,该还原性特征主要是由有机碳控制的,而活性铁的贡献不明显。 相似文献
8.
以渤海(塘沽海域)沉积物为材料,富集异化铁还原混合菌群。采用三层平板方法,从混合菌群中纯化出一株异化铁还原细菌KB52。通过形态观察和16S r RNA基因序列分析,菌株命名为Klebsiella sp.KB52(Gene Bank号KM233642)。在葡萄糖为电子供体,Fe(OH)_3为电子受体条件下厌氧培养菌株KB52,其细胞生长和Fe(Ⅲ)还原具有明显耦合关系。碳源分别设置为葡萄糖、乳酸钠、丙酮酸钠、乙酸钠、甲酸钠和丙酸钠,在海水培养条件下菌株KB52以丙酮酸钠为碳源时,菌株培养液累积Fe(Ⅱ)浓度最高,为4.41 mmol/L±0.59 mmol/L。菌株KB52在设定NaCl浓度范围内,都能够生长并具有铁还原性质,菌株表现出较强的耐盐性。NaCl质量浓度为4 g/L时,菌株KB52还原Fe(Ⅲ)效率最高,Fe(Ⅱ)达到4.95 mmol/L±0.72 mmol/L。铁还原细菌KB52在淡水和海水条件下能够生长并具有铁还原性质,可用于近海沉积物中微生物介导异化Fe(Ⅲ)还原过程,进一步应用于治理海洋环境污染。 相似文献
9.
为了解红树林与光滩磷、铁地球化学行为的差异,借助薄膜扩散梯度技术(ZrO-Chelex DGT),对厦门同安湾红树林及临近光滩孔隙水中溶解活性磷(DRP)、Fe~(2+)浓度进行了原位测量,并采集了相应沉积物柱状样进行测定分析。结果表明:(1)Fe~(2+)与DRP呈现较好的线性正相关,说明磷的吸附/解吸与铁氧化还原循环有关;(2)在不同深度,光滩孔隙水中DRP浓度均高于对应深度红树林。在浅层,由于溪水的补给造成光滩的磷富集;在深层,红树植物根部吸收导致磷浓度下降,光滩有机质含量较多,矿化释放DRP使其浓度较高;(3)孔隙水中的Fe~(2+)浓度分布表明,红树林区域随着深度的增加,逐渐由好氧环境进入厌氧环境;而光滩沉积物氧化还原环境可能受到红树林的影响,孔隙水Fe~(2+)在垂向上波动分布。 相似文献
10.
根据1980年6月、1981年8月和11月的地球化学调查与实验室分析,进行了以下几方面的探讨:(1)上覆水与间隙水中Fe2+浓度的季节和空间变化;(2)沉积物固相中Fe(Ⅲ)、Fe(Ⅱ)和全Mn的剖面;(3)铁、锰扩散通量和沉积通量的估算与比较。Fe2+的季节与空间变化反映了铁的早期成岩与沉积物粒度成分以及介质中pH、Eh和溶解氧等因子之间的复杂关系。通过对Fe、Mn扩散通量与沉积通量的估算和比较,初步评价和描述了本测区铁、锰的地球化学活动性及其在成岩过程中的作用。 相似文献
11.
Individual transferable quota (ITQ) markets are being used successfully to distribute quotas in single region and single species fisheries. In many parts of the world, the development of well crafted markets for multispecies or multiregional fisheries is still evolving. As a result, there exists an opportunity to inform policy by providing research insights into the relative merits of alternative market designs for such fisheries.This study explored the relative merits of a simultaneous ascending auction design and an iterative combinatorial auction design for a hypothetical multiple region quota market. In a simultaneous auction, separate auctions are run in parallel for individual species or regions. During intermediate rounds, fishers can adjust their bids in auction depending on their position in the other auction. In a combinatorial auction, a fisher can purchase a combination of quotas (or a package quota) for different fish species or regions in the same auction. Being able to acquire bundles of species or regions allows fishers to take advantage of complementarities. To date, the potentials of such auctions have not been thoroughly tested in fisheries quota markets. This study found that while a simultaneous auction design was more efficient than combinatorial auction design overall, combinatorial market design took fewer rounds to make final allocations and performed better in high synergy environments. 相似文献
12.
The Upper Cretaceous Bordighera Sandstone of NW Italy is a coarse-grained, sand-rich elongated turbidite system (ca. 15 × 45 km in outcrop) up to 250 m thick, interpreted to have been deposited in a trench setting. The siliciclastic succession interfingers with muddy calcareous turbidites, which become more abundant toward the lateral and distal domains. Bed type associations allow the distinction of a proximal channelized domain which transitions to a more distal lobe domain, characterized by abundant mudclast-rich sandstones and by bipartite and tripartite beds with a mud-rich middle or upper division (hybrid event beds). The transition between the proximal and distal domains occurs over a relatively limited spatial extent (ca. 5 km). The presence of lenticular bed-sets made up of coarse grained and mud-poor sandstones throughout the distal domain suggests that distributary channels were present, indicating sediment bypass further down-dip toward the most distal and not preserved parts of the system. Hybrid event beds - commonly associated with distal and marginal fan environments such as fan fringes - are present throughout the lobe domain and extend for up to ca. 30 km in down-dip distance. They are more abundant in the proximal and axial depositional lobe domain and their appearance occurs within a short basin-ward distance from the inferred channel-lobe transition zone. Flow expansion at the termination of the channelized domain and the enhanced availability of cohesive substrate due to the presence of intra-basinal muddy calcareous beds are interpreted as the key controls on the widespread occurrence of mudclast-rich and argillaceous sandstone beds. The abrupt appearance and the persistent occurrence of such beds across an extensive domain have implications for characterizing bed-scale (sub-seismic) heterogeneity of deep-water clastic hydrocarbon reservoirs. 相似文献
13.
基于AIS的船舶会遇局面紧迫度量化分析 总被引：1，自引：0，他引：1
近年来船舶大型化、高速化的发展以及数量的不断递增,导致船舶碰撞概率大大增加。为更好地保障船舶航行安全,提出船舶会遇局面紧迫度这一概念。该概念表征船舶在当前航行状态下由于一定范围内所有其他船舶的存在而处于的会遇局面的紧迫程度,其旨在帮助船舶驾驶员实时感知并掌握船舶在海上航行时所处会遇局面的状况,从而据此加以判断并及时采取措施规避碰撞风险。建立了船舶会遇局面紧迫度的计算模型,该模型以考虑到本船速度的动态圆形领域为空间约束条件,综合考虑其他船舶相对于本船的方位分布和距离这两个指标的影响,基于信息量量化紧迫度。利用2016年1月1日天津港AIS数据进行紧迫度的计算与分析,计算结果与实际相符,该计算模型能够准确反映船舶在航行过程中所处会遇局面的紧迫程度。利用双线性内插法建立天津港区域紧迫度二维彩色平面分布图,其表达效果优于传统热度图。 相似文献
14.
In this paper, results of comprehensive finite element (FE) analyses carried out on 81 generated models of tubular K-joints are presented. Results of FE models were verified against experimental data and parametric equations. The fatigue life of a tubular joint, which is commonly found in offshore industry, is not only dependent on the value of hot-spot stress (HSS), but is also significantly influenced by the through-the-thickness stress distribution characterized by the degree of bending (DoB). Data extracted from FE analyses was used to study the effects of geometrical parameters on the DoB values in tubular K-joints subjected to two types of out-of-plane bending (OPB) moment loads. The determination of DoB values in a tubular joint is essential for improving the accuracy of fatigue life estimation using the stress-life (S–N) method and particularly for predicting the fatigue crack growth based on the fracture mechanics (FM) approach. Geometrically parametric investigation was followed by a set of nonlinear regression analyses to develop DoB parametric formulas for the fatigue analysis of K-joints under OPB loadings. 相似文献
15.
Oedometric mechanical compaction tests were performed on brine-saturated synthetic samples consisting of silt-clay mixtures to study changes in microfabric and rock properties as a function of effective stress. The silt consisted of crushed quartz (∼100%) with grain size range between 4 and 40 μm, whereas the clay consisted of 81% kaolinite, 14% mica/illite and 5% microcline of grain size between 0.4 and 30 μm. Five sample pairs ranging in composition from pure silt to pure clay were compacted to 5 and 50 MPa effective stress respectively. SEM studies were carried out to investigate microfabric changes in the mechanically compacted silt-clay mixtures. The degree of alignment of the different minerals present (quartz, mica/illite and kaolinite) were computed by using an image analysis software. Experimental compaction have measured the changes in the rock properties such as porosity and velocity as a function of effective stress for different mixtures of clay and silt. Clay-rich samples showed a higher degree of mineral orientation and lower porosity compared to silt-dominated samples as a function of effective stress. Pure clay sample had 11% porosity at 50 MPa effective stress whereas the pure silt sample retained about 29% porosity at the same effective stress. The experiments showed that low porosity down to 11% is possible by mechanical compaction only. A systematic increase in strain was observed in the silt-clay mixtures with increasing clay content but the porosity values found for the 50:50 silt-clay mixture were lower than that of 25:75 silt-clay mixture. No preferential mineral orientation is expected before compaction owing to the high initial porosity suggesting that the final fabric is a direct result of the effective stress. Both P- and S-wave velocities increased in all silt-clay mixtures with increasing effective stress. The maximum P- and S-wave velocities were observed in the 25:75 silt-clay mixture whereas the minimum Vp and Vs were recorded in the pure silt mixture. At 50 MPa effective stress P- wave velocities as high as 3 km/s resulted from experimental mechanical compaction alone. The results show that fine-grained sediment porosity and velocity are dependent on microfabric, which in turn is a function of grain size distribution, particle shape, sediment composition and stress. At 5 MPa effective stress, quartz orientation increased as a function of the amount of clay indicating that clay facilitate rotation of angular quartz grains. Adding clay from 25% to 75% in the silt-clay mixtures at 50 MPa effective stress decreased the quartz alignment. The clay mineral orientation increased by increasing both the amount of clay and the effective stress, the mica/illite fabric alignment being systematically higher than that of kaolinite. Even small amount of silt (25%) added to pure clay reduced the degree of clay alignment significantly. This study demonstrates that experimental compaction of well characterized synthetic mudstones can be a useful tool to understand microfabric and rock properties of shallow natural mudstones where mechanical compaction is the dominant process. 相似文献
16.
The degree of bending (DoB) characterizing the through-the-thickness stress distribution has a profound effect on the fatigue behavior of tubular joints commonly found in steel offshore structures and the determination of DoB values is essential for improving the accuracy of fatigue life estimation. Probability density functions of the involved random variables are necessary for the fatigue reliability analysis of offshore structures. The objective of present research was the derivation of probability density function (PDF) for the DoB in tubular KT-joints commonly found in jacket-type offshore platforms. A total of 162 finite element (FE) analyses were carried out on 81 FE models of KT-joints subjected to two types of axial loading. Generated FE models were validated using experimental data, previous FE results, and available parametric equations. Based on the results of parametric FE study, a sample database was prepared for the DoB values and density histograms were generated for respective samples based on the Freedman-Diaconis rule. Thirteen theoretical PDFs were fitted to the developed histograms and the maximum likelihood (ML) method was applied to evaluate the parameters of fitted PDFs. In each case, the Kolmogorov-Smirnov test was used to evaluate the goodness of fit. Finally, the Generalized Extreme Value model was proposed as the governing probability distribution function for the DoB. After substituting the values of estimated parameters, six fully defined PDFs were presented for the DoB in tubular KT-joints subjected to two types of axial loading. 相似文献
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东海沿岸海水表层温度的变化特征及变化趋势 总被引：15，自引：0，他引：15
根据东海沿岸引水船、嵊山、大陈、南麂、北礵、平潭、厦门和东山8个海洋观测站的40a表层海水温度(SST)资料进行了统计与分析.研究结果表明:东海沿岸SST主要受制于太阳辐射,呈南高北低分布,但也不同程度地受到当地地理环境、气候环境、水文环境的影响;SST的年变化具有显著的年周期和半年周期;东海沿岸SST存在多种显著周期的振荡,且南北测站SST的主导振荡有差异;就近40a的资料而言,东海沿岸的SST总体呈上升趋势,其中冬季上升幅度最大,暖冬是SST总体呈上升趋势的重要因素. 相似文献
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对渤海、黄海海域冬、夏两季表层沉积物取样,通过激光粒度仪得出粒度参数,进而分析讨论冬季强的沿岸流的作用、黄海暖流、夏季冷水团的影响以及地形、海底地貌特征、物源特征等对表层沉积物分布造成的影响。结果表明,冬、夏两季渤黄海表层沉积物粒度特征总体上相差不大,但部分海域如渤海中北部、渤海中南部、北黄海西北部近渤海海峡北部海域、山东半岛东北部海域、南黄海中部沉积物粒度特征存在明显季节性差异。表层沉积物粒度特征季节性差异与地形地貌、沿岸流、黄海暖流、黄海冷水团及物源密切相关。本研究对于探讨渤黄海不同季节表层沉积物沉积特征的影响机制、了解渤黄海区海洋动力过程的季节差异有积极意义。 相似文献