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1.
Olive oil mill wastewater (OMW) is environmentally hazardous not only because it contains high recalcitrant and toxic compounds, but also due to its high organic load and turbidity. In this study, oxidation of OMW by microwave (MW)‐activated persulfate is investigated. Box–Behnken design is applied to investigate the effects of operating conditions on operating cost, organic matter, and color removal. Multi response optimization is performed according to minimum operating cost, maximum organic matter and color removal efficiencies. At optimum conditions (persulfate anion dose of 266 g L?1, oxidation duration of 23.58 min, MW power of 567 W, and initial pH 2), chemical oxygen demand (COD) removal of 63.38%, color removal of 94.85%, and operating cost of 0.0633 Euro/g total organic carbon (TOC) removal are found. The biochemical oxygen demand (BOD5)/COD ratio is increased from 0.144 to 0.285. Results of Pareto analysis show individual effect of MW power is 92.81% for TOC removal, 15.52% for color removal, 68.99% for operating cost, respectively. According to the results, it is not recommended to use this process as an ultimate treatment unit due to the high amount of oxidizing agent consumed. Instead, it is recommended to be used as a pre‐ or post‐treatment step.  相似文献   

2.
The objective of this study was to investigate the effect of salt concentration on performance of a membrane bioreactor (MBR) for treating an olefin plant wastewater. For this purpose, a lab‐scale submerged MBR with a flat‐sheet ultrafiltration membrane was used for treatment of synthetic wastewater according to oxidation and neutralization unit of olefin plant. The synthetic wastewater was adjusted to have 500 mg/L chemical oxygen demand (COD). Trials on different concentrations of sodium sulfate (Na2SO4) (0–20 000 ppm) in the feed were conducted under aerobic conditions in the MBR. The results showed that increasing the salt concentrations causes an increase in the effluent COD, phenol, and oil concentrations. These results are due to reduction of the membrane filtration efficiency and also decline in the microbial activity that it is indicated by decreasing the sOUR in MBR. But in all the trials, the effluent COD and oil concentration was well within the local discharge limit of 100 and 10 mg/L, respectively. These results indicate that the MBR system is highly efficient for treating the olefin plant wastewater, and although high salt concentrations decreased organic contaminant removal rates in the MBR, the effluent still met the discharge limits for treating the olefin plant wastewater.  相似文献   

3.
The ground track of the annular eclipse of 3 October 2005 crossed the Iberian Peninsula. The main objective of this work was to analyze the variability of the solar irradiance and the total ozone column during the course of this event at El Arenosillo (Southwestern Spain). For achieving this goal, two Kipp & Zonen broadband radiometers (one for measuring total solar irradiance and other for measuring ultraviolet erythemal solar irradiance), one NILU-UV multi-band instrument and one Brewer spectroradiometer were used in this work. Total irradiance (310–2800 nm), and ultraviolet erythemal radiation (UVER) were recorded at a high frequency of 5 s, showing a strong reduction (higher than 80%) of the irradiance at the maximum solar obscuration which was of 79.6%. The irradiance decrease during the course of the eclipse was positively correlated with the percentage of eclipse obscuration, showing a very high agreement (R2～0.99). The irradiance recorded at selected wavelengths from the NILU-UV instrument shows a more pronounced decrease in the UV irradiance at the lower wavelengths during the solar eclipse. Finally, the evolution of the total ozone column (TOC) derived from Brewer and NILU instruments during the eclipse presented an opposite behavior: while the Brewer derived TOC values increase about 15 DU, the NILU derived TOC values decrease about 11 DU. This opposite behavior is mainly related to an artifact in the spectral irradiances recorded by the two instruments.  相似文献   

4.
In the present study, the effects of initial COD (chemical oxygen demand), initial pH, Fe2+/H2O2 molar ratio and UV contact time on COD removal from medium density fiberboard (MDF) wastewater using photo‐assisted Fenton oxidation treatment were investigated. In order to optimize the removal efficiency, batch operations were carried out. The influence of the aforementioned parameters on COD removal efficiency was studied using response surface methodology (RSM). The optimal conditions for maximum COD removal efficiency from MDF wastewater under experimental conditions were obtained at initial COD of 4000 mg/L, Fe2+/H2O2 molar ratio of 0.11, initial solution pH of 6.5 and UV contact time of 70 min. The obtained results for maximum COD removal efficiency of 96% revealed that photo‐assisted Fenton oxidation is very effective for treating MDF wastewater.  相似文献   

5.
The presence of trace antibiotics in domestic and industrial effluents poses a risk of toxicity to fauna and flora. The application of floating treatment wetlands (FTWs) is a low-cost and sustainable approach to remediate wastewater. In this study, the performance of different macrophytes vegetated in FTWs for the remediation of ciprofloxacin (CIP)-contaminated water is investigated. Six macrophytes, Brachia mutica, Typha domingensis, Phragmites australis, Canna indica, Cyperus laevigatus, and Leptochloa fusca, are vegetated in FTWs for the removal of CIP (50 mg L−1) from water. The FTWs show the potential to remove 30–43.58 mg L−1 CIP from water in 28 days. They also reduce the chemical oxygen demand (118–138 mg L−1) and biochemical oxygen demand (35–45 mg L−1) of water. Among the macrophytes, C. indica removes maximum (43.58 mg L−1) and T. domingensis minimum (30 mg L−1) CIP. Canna indica and T. domingensis exhibit the maximum and minimum increase (30% and 12% of dry biomass) in growth, respectively. This study reveals that the FTWs vegetated with different plant species exhibit varying performances in removing CIP from water. This investigation is a step forward toward sustainable bioremediation of water contaminated with antibiotics.  相似文献   

6.
Wastewater production in a hospital laundry and the treatment of the most critical wastewater stream, are assessed. Hospital laundry wastewaters are hazardous to the environment due to their high pollutant concentrations and the chemicals added during the clothes washing process. Heterogeneous photocatalysis with UV, O3 and TiO2 and their possible combinations were used for disinfection purposes. A ramp‐type reactor was used for TiO2 (P25 Degussa) fixation and for photochemical diffusion of the ozonized air. After assessing 5‐day biological oxygen demand, chemical oxygen demand, pH, turbidity, and surfactant content, and checking for the presence of thermotolerant coliforms and Escherichia coli, it was concluded that UV/O3/TiO2 was the best process/combination, yielding a 100% disinfection rate and a microbiological inactivation of 0.5070 min–1 for E. coli and of 0.5505 min–1 for thermotolerant coliforms.  相似文献   

7.
A single bioaugmentation reactor and a side-stream gaslift membrane bioreactor combined with bioaugmentation are conducted to treat real wastewater from a centralized piggery slaughterhouse in Vietnam. The bioaugmented reactor is inoculated with heterotrophic microorganisms (Bacillus sp.) isolated from piggery slaughterhouse wastewater. The results of a single bioaugmentation experiment show high removal efficiency of chemical oxygen demand (COD) (84.8%–97.5%) and total nitrogen (TN) (69.9%–87.2%) at loading rates of 1.28–3.89 and 0.14–0.37 kg m−3 d−1, respectively. The combined system demonstrates a significantly higher TN removal efficiency (89.0%–96.1%) (p < 0.001), more stable flux (36.0–38.4 L m−2 h−1), and transmembrane pressure (0.95–1.05 bar), and better capacity of separation of solid–liquid phases compared to the single bioaugmentation. High COD and TN removal efficiency is possibly due to assimilation and simultaneous nitrification and denitrification processes. The results of this study also indicate the feasibility and propitious efficiency of the bioaugmented gaslift membrane bioreactor for piggery slaughterhouse wastewater treatment.  相似文献   

8.
The UV/H2O2 is one of the popular techniques in the advanced oxidation processes (AOPs) and has been applied in the wastewater treatment during recent two decades. UV exposure on the H2O2 generate highly reactive hydroxyl radicals (OH?), which are used to degrade organic contaminants through oxidation processes in wastewater. This present study involves the estimation of hydroxyl radical rate constants of methyldiethanolamine (MDEA) mineralization at different temperatures by using UV/H2O2 in aqueous solution. Laboratory experiments have been conducted and the profile of MDEA mineralization has been established. The hydroxyl radical rate constants and the activation energy of mineralization process have been calculated. The estimated hydroxyl rate constants and the activation energy are in good agreement with those reported in the literature.  相似文献   

9.
In this work, the treatment of actual agro‐industrial wastewaters (IWW) by a UV/H2O2 process has been investigated. The aqueous wastes were received from industrial olive oil mills and then treated by laboratory scale physicochemical methods, i. e., coagulation using ferrous and aluminum sulfate, decantation, filtration and adsorption on activated carbon. These wastes are brown colored effluents and have a residual chemical oxygen demand (COD) in the range of 1800 to 3500 mgO2 L–1, which cannot be further eliminated with physicochemical processes. The UV/H2O2 treatments were carried out under monochromatic irradiation at 254 nm using a thermostated reactor equipped with a mercury vapor lamp located in an axial position. The effects of initial H2O2 concentration, initial COD, pH and temperature have been studied in order to determine the optimum conditions for maximum color and COD removals. The experimental results reveal the suitability of the UV/H2O2 process for both removal of high levels of COD and effectively decolorizing the solution. In particular, 95% of color removal and 90% of COD removal were obtained under conditions of pH = 5 and 32°C using 2.75 g H2O2 g–1 COD L–1 during 6 h of UV‐irradiation. The treatment is unaffected by pH over the range 2 to 9. In addition, the COD removal is improved by increasing the temperature, whereas the color removal has not been affected by this parameter. The results show that the hydroxyl radicals generated from the catalytic decomposition of H2O2 by UV‐irradiation of the solution could be successfully used to mineralize the organics contained in IWW. The mineralization of the organics seems to occur in three main sequential steps: the first is the rapid decomposition of tannins leading to aromatic compounds, which are confirmed by the decolorization of the IWW; the second step corresponds to the oxidation of aromatics leading to aliphatic intermediates, which occurs by the cleavage of an aromatic ring, and is established by the removal of aromatics, and the final step is the slow oxidation of the aliphatic intermediates, which is measured by the COD removal.  相似文献   

10.
In the present research, laundry wastewater treatment is studied using the electrocoagulation/electroflotation process. For the optimization of treatment conditions such as electrode type (Al–Al, Al–Fe, Fe–Fe, and Fe–Al), initial pH (5–9), current (0.54–2.16 A), and application time (15–60 min), response surface methodology is used. Removal efficiencies of chemical oxygen demand (COD), color, anionic surfactant, microplastic, and phosphate are studied. It is determined that the most effective removal is obtained with 2.16 A current, pH 9, and 60 min reaction time using Fe–Al electrode. Here, 91%, 94%, 100%, and 98% removal efficiencies are achieved for COD, surfactant, color, and microplastic, respectively. The operating cost of the combined process is calculated as $1.32 m?3 for the optimum removal parameters. The adsorption kinetics study shows that the removal follows second‐order kinetics. The laboratory‐scale test results indicate that the electrocoagulation/electroflotation process is feasible for the treatment of laundry wastewater.  相似文献   

11.
A comparative study of methane recovery by co-digesting kitchen waste and saline sewage sludge is performed to evaluate its feasibility for waste minimization. The experiment is performed at 37 °C having a mixing speed of 100 rpm and pH of 6.49–7.5 in anaerobic mixed batch reactors. The higher salinity level of the saline sewage sludge reduces the degradation rate of kitchen waste causing an enhancement in soluble chemical oxygen demand by 133% compared with 280% when co-digesting with the non-saline sample. The inhibitory behavior is in line with the low volatile solid elimination efficiency of 31% of saline against 55% of non-saline sludge. The Gompertz modeling, based on the outcomes, fits the cumulative methane generation trends quite well, with a strong correlation coefficient (>0.994). Besides, use of the non-saline sludge results in three times more methane production than the saline sample digestion. Sludge recovery is 0.07 m3 sludge m−3 wastewater, and water recovery is 0.84 m3 m−3 wastewater. The liquid produced from the fermentation of the slurry can be used for irrigation as well as fertilization. Kitchen waste co-digestion with both sludge samples has been proven to be a practical method for exploiting the extra digestion capacity of wastewater treatment plants currently in operation, but it is more practical for non-saline sludge.  相似文献   

12.
One way to reduce water consumption in urban areas is by using alternative sources of supply that can be provided by collecting rainwater and reusing wastewater for less restricted purposes. Thus, this study evaluated the characteristics of effluents produced by the wastewater treatment plant (WWTP) of São Paulo International Airport (SPIA), Brazil, in order to reuse it in non‐potable situations. The results achieved, indicated high efficiency in the biological system utilized by SPIA. The removal rates is equal to or >90% for most of the parameters analyzed, among them, fluoride, salinity, nitrite, nitrate, ammonium nitrogen, total nitrogen, phosphorus, sedimentable solids, turbidity, conductivity, apparent color, chemical oxygen demand, biochemical oxygen demand, total organic carbon, fecal coliforms, and oils and greases. Despite the final effluents were good enough to be launched in the local streams, they shall be submitted to a complementary treatment in order to fit some quality parameters to be reused for specific demands (landscape irrigation, toilet flushing, vehicle washing, fire fighting, and dust control).  相似文献   

13.
Degradation of Nitroaromatic Xenobiotics by Ozonization and Subsequent Biological Treatment Ozonization for 2,4-dinitrotoluene (DNT) and 4-nitroaniline (NA) was conducted in completely mixed reactors by semi-batch tests. At pH 7, both direct and radical reactions contribute to the oxidation of the nitroaromatic compounds. In the dominantly mass transfer-limited reaction, a specific ozone absorption of A* = 3.0…3.5 g g?1 was measured for a ?98% elimination of the target compounds. About 80…90% of the input ozone were absorbed, and 10…20% left the system unreacted. At pH 7, the degree of DOC reduction increased linearly with the specific ozone absorption to final values of 35% (NA) and 44% (DNT), respectively. A subsequent biological treatment of the oxidation products by non-acclimated bacteria increased the degree of mineralization to 75%. Compared to ozonization alone, 35 and 50% of ozone were thus saved by the sequential chemical-biological process. Batch tests with a real wastewater from the alkaline hydrolysis of a mixture of 2,4,6-trinitrotoluene (TNT) and 1,3-dinitrobenzene (DNB) confirmed the approach. No reduction in the required ozone dosage was achieved in a completely mixed continuous system of ozonization followed by biodegradation even when compared to batch ozonization alone. Therefore, the reduction of longitudinal mixing in continuous ozonization systems is regarded to be of fundamental importance.  相似文献   

14.
Solar photocatalytic decolorization and detoxification of batik dye wastewater using titanium dioxide (TiO2) immobilized on poly‐3‐hydroxybutyrate (P(3HB)) film was studied. The effects of initial dye concentration, catalyst concentration, P(3HB) film thickness, and fabrication methods of the nanocomposite films were evaluated against methylene blue, a standard organic dye. It was observed that 0.4 g of P(3HB)‐40 wt% TiO2 removed 96% of the color under solar irradiation. P(3HB) and TiO2, mixed concurrently in chloroform followed by stirring for 24 h showed a more even distribution of the photocatalyst on the polymer surface and yielded almost 100% color removal. The photocatalytic films were able to completely decolorize real industrial batik dye wastewater in 3 h and induced a chemical oxygen demand (COD) reduction of 80%. Reusability of the 0.4 g P(3HB)‐40 wt% TiO2 film in decolorizing the batik dye wastewater was also possible as it gave a high consistent value of decolorization percentage (>80%) even after the sixth repeated usage. Recovery step of the photocatalysts was also not required in this simple treatment system. The decolorized batik dye wastewater had less/no toxic effects on mosquito larvae, Aedes aegypti, and microalgae, Scenedesmus quadricauda indicating simultaneous detoxification process along with the decolorization process.  相似文献   

15.
In this study, untreated and treated wood fly ash (WA) was used as a low‐cost sorbent in batch sorption tests to investigate the removal of organic pollutants from a real wastewater generated by cleaning/washing of machinery in a wood‐laminate floor industry in Sweden. The experiments focused on the effect of the WA dosage and particle size on the removal efficiency for organic compounds. With a WA dosage of 160 g L?1 and a particle size less than 1 mm, the reductions of chemical oxygen demand (COD), biologic oxygen demand, and total organic carbon were 37 ± 0.4, 24 ± 0.4, and 30 ± 0.3%, respectively. Pre‐treatment of WA with hot water improved the COD removal efficiency by absorption from 37 ± 0.4 to 42 ± 1.6% when the same dosage (160 g L?1) was applied. Sorption isotherm and sorption kinetics for COD using untreated WA can be explained by Freundlich isotherm and pseudo‐second‐order kinetic models. Intra‐particle diffusion model indicates that pore diffusion is not the rate‐limiting step for COD removal. Based on the experimental data, WA could be used as an alternative low‐cost sorption media/filter for removal of organic compounds from real industrial wastewater.  相似文献   

16.
A sudden transient increase of the solar ultraviolet (UV) radiation was detected with a ground-based photometer in Madrid (Spain, 41°N, 3°W) on 25 November 1996 (Cordoba et al., 2000. UV-B irradiance at Madrid during 1996, 1997 and 1998. J. Geophys. Res. 105 (D4) (2000) 4903–4906). The data obtained by the TOMS satellite instrument revealed that this event was related to a reduction of the total ozone column values. This low ozone episode has been analysed. The ozone decrease was accompanied by a reduction of air temperature in the lower stratosphere. The anti-correlation between total ozone and air parcel height along the three-dimensional isentropic back-trajectories suggests that the adiabatic uplift of air contributed significantly to both the ozone and the temperature decreases observed. The uplift could be caused by the propagation into the lower stratosphere of the high-pressure cell located over the mid-Atlantic region.  相似文献   

17.
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18.
Moringa oleifera (MO), also known as drumstick tree, has gained worldwide attention among researchers and policy makers, for showing its remarkable potential in environmental management. Recently, MO seed or press cake (a by-product of oil extraction industry) powder has also emerged as an alternative and promising coagulant for environmental remediation. In this view, attempts have been made in this study to evaluate the efficacy of MO seed and press cake powder (MSP & PCP) for the treatment of municipal wastewater. Both MSP and PCP are characterized by using swelling ratio, scanning and transmission electron microscopy analysis. The effect of various operational parameters such as coagulation–flocculation pH (2–10), coagulant dosage (0.1–1 g L−1), and sedimentation time (0–180 min), etc., is investigated to understand the potential of MSP and PCP. At optimized operational conditions, sedimentation kinetics is also performed suggesting that the treatment process is being governed by the second-order kinetic model. The chemical and biological oxygen demand removals at optimized conditions are observed as follows: ≈38 and ≈73% for MSP and ≈47 and ≈85% for PCP. Overall, the results of the present study elucidated that PCP can be employed as a promising alternative of MSP for municipal wastewater with improved treatment efficiencies.  相似文献   

19.
We simulate twenty, perpetual Januaries each under solar minimum and maximum conditions using the Freie Universität Berlin Climate Middle Atmosphere Model with interactive chemistry (FUB CMAM CHEM), including the 27-day solar rotational cycle. Cross-correlation functions (r) of tropical ozone and ultraviolet (UV) suggest peak values of +0.5 to +0.6 (with % changes in ozone of 0.4–0.6%) in the middle atmosphere. Temperature in the middle atmosphere varies with UV by up to 0.5 K, which appears to be mainly dynamical in origin. We calculate a signal associated with the rotational cycle in the troposphere, although this requires further investigations.  相似文献   

20.
氨氮是地表水常见污染物,尤其在农业区域,氮类化肥的不合理施用会导致周边水体氮浓度迅速升高并保持较高水平.然而,当前对高氮水平下沉水植物腐败和附着氮循环微生物的影响尚不清楚.以轮叶黑藻(Hydrilla verticillata)为研究用沉水植物,在实验室内模拟水体内8和16 mg/L氮浓度下轮叶黑藻腐解过程中营养盐释放及残体表面微生物氮循环功能基因丰度的变化.研究发现水体两种氮浓度下轮叶黑藻腐解过程中残体腐解及营养盐释放速率无显著差异;与对照相比,植物腐败初期水体内碳、磷浓度迅速增加,而溶解氧浓度及氧化还原电位迅速降低,随着时间的推移上述水质指标逐步恢复至初期状态(第146天);水体荧光溶解性有机质主要包括紫外类富里酸、可见类富里酸、色氨酸类蛋白质和酪氨酸类蛋白质等类型.在5个氮循环相关基因中,氮负荷增加对轮叶黑藻残体生物膜内amo A、napA和narG的丰度有显著影响.冗余分析表明氮循环基因丰度受水体总氮浓度的影响较小,与植物总有机碳含量和水体化学需氧量及溶解氧浓度存在相关性.研究结果表明虽然当前氮水平对植物腐败过程影响不大、对氮循环基因丰度有一定影响,但是对该水生植被(尤其是植物腐败初期)和农业退水排放的管理仍需加强,以降低其对水体的影响.  相似文献   

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