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高岭石对重金属离子的吸附机理及其溶液的pH条件 总被引：14，自引：0，他引：14
高岭石对Cu^2+,Pb^2+离子的吸附实验及高岭石的溶解实验表明,高岭石对重金属离子的吸附有别于石英单一表面配位模式,离子交换和表面配位模式并存,并随溶液pH由酸性往碱性的变化发生规律性的演替：pH<6.5时主要表现为外圈层配位的离子交换吸附,且在pH<4时由于受到高岭石表层中铝的高溶出及溶液中较高离子强度的影响,高岭石对Cu^2+,Pb^2+离子的吸附率较低,pH为5～6时由于高岭石端面的荷电性为近中性,吸附率则有明显的提升并且表现为一个吸附平台;pH>6.5时离子交换和表面配位均为重要吸附机制,pH再升高时沉淀机制则起着重要作用。研究表明,pH调控高岭石-水界面溶解与质子化-去质子化反应过程,并影响着Cu^2+,Pb^2+离子的吸附行为。最后采用Sverjensky(1993)表面配位的物理模型对吸附结果作了描述。 相似文献
3.
冲江铜矿位于世界三大斑岩成矿域的特提斯-喜马拉雅成矿域,其大地构造位置属冈底斯-念青唐古拉构造带的冈底斯陆缘火山-岩浆弧中部。矿区含矿岩体与非含矿岩体的岩性相同,很难通过肉眼或常规分析方法把它们区分开来。热释光测试结果表明,矿区岩石的热释光曲线有单峰和双峰两种,矿化主要发生在具单峰的似斑状二长花岗岩中。岩石矿化程度越强,热释光总积分强度值越小。另外,高岭土化对岩石天然热释光有叠加作用,具高岭土化的岩石明显具有更高的热释光值,且高岭土化与矿化成负相关。因此,热释光值可作为判断矿化的一个岩石标型。石英粒度统计也表明,含矿岩体的石英粒度曲线呈韵律式变化,而不含矿的岩石粒度曲线呈渐进式变化。故岩石中的石英粒度也可作为矿化的一个矿物标型。 相似文献
4.
湖光岩玛珥湖沉积物硅藻硅同位素环境示踪 总被引：2，自引：0，他引：2
硅是硅藻生长所必需的养分,硅藻在生长过程中从水体吸收主要以硅酸(H_4SiO_4)形式存在的溶解硅.硅藻δ~(30)Si_(distom)可反映硅藻吸收硅酸比例的变化,进一步可以反映湖区气候与环境变化.为探索湖泊沉积物硅藻δ~(30)Si_(distom)在指示湖泊古环境方面的潜力,我们测定了湖光岩玛珥湖沉积物硅藻硅同位素变化.研究结果表明,沉积物δ~(30)Si_(distom)变化与生物硅和有机碳含量变化呈显著相似性,可作为一种有效的古环境代用指标.同时,与已有温度记录的对比分析表明,两者具有很好一致性.较高的如δ~(30)Si_(distom)指示了温度较高的气候条件下硅藻对硅酸的利用率较高;当δ~(30)Si_(distom)较低时,对应着在温度较低的气候条件下硅藻对硅酸的利用率较低.目前,热带陆地区域古气候重建的方法中可用的温度代用指标很少,此项研究证明了δ~(30)Si_(distom)是一种很有潜力的古环境代用指标,有望在低纬度地区古温度重建中发挥重要作用,值得进一步深入研究. 相似文献
5.
Origin of the difference in the distribution behavior of tellurium and selenium in a soil-water system 总被引：4，自引：0，他引：4
Teppei Harada 《Geochimica et cosmochimica acta》2008,72(5):1281-1294
The distribution behavior of tellurium (Te) between soil and water in a synthetic soil-water system was studied coupled with the speciation of Te both in soil and water phases by using X-ray absorption fine structure (XAFS) spectroscopy and a high-performance liquid chromatography connected to an ICP-MS (HPLC-ICP-MS), respectively. The results were compared with a similar data set for Se, which was simultaneously obtained in this study. The oxidation states and host phases of Te and Se in the soil samples were given by XAFS, while the oxidation states in water were given by HPLC-ICP-MS. It was found that both Te and Se in soil are mainly associated with Fe(III) hydroxides under oxic conditions. From the EXAFS analyses, the outer-sphere complex is important for the Se(VI) sorbed on Fe(III) hydroxides in soils, while Se(IV), Te(IV), and Te(VI) form inner-sphere complexes. Under reducing condition, it was found that Te(0) and Se(0) species were formed and that Se was more readily reduced to Se(0) than Te, as is predicted from their Eh-pH diagrams. The reduction process from hexavalent to zerovalent species was different between Se and Te, that is, the direct reduction from Se(VI) to Se(0) was observed for Se, while Te was reduced stepwise from Te(VI) to Te(0) via Te(IV). In terms of the distribution between soil and water, Se distribution to water was much higher than that of Te under wide redox conditions. For Se, selenate is the predominant species in water even under reducing condition due to the much higher solubility of Se(VI) than Se(IV). Furthermore, a much smaller distribution of Te in water was primarily due to the larger affinities of Te(IV) and Te(VI) to Fe(III) hydroxides than Se(VI), which originates from the formation of the inner-sphere complexes of Te(IV) and Te(VI) to Fe(III) hydroxides. 相似文献
6.
河北平原第四系地下水氦同位素特征 总被引：3，自引：0，他引：3
通过对河北平原第四系地下水He同位素进行比较分析,根据过剩He(4Heexc)、3He/4He比值、δ3He值分析认为,河北平原第四系地下水He同位素有5个特征:(1)地下水中过剩He浓度沿着地下水的流向而增高;(2)地下水中的过剩He浓度随着地下水埋深加大而增高;(3)满城—沧州剖面上过剩He浓度大于石家庄—衡水剖面上的过剩He浓度;(4)河北平原第四系地下水主要是由大气降水补给的;(5)衡水热水过剩He浓度很高(>674 83×10-8cm3STPg-1),这表明以放射成因He为主,地幔成因的He极少。另外地下水的3He/4He比值、R/Ra、δ3He值是判断氦源的一个灵敏的指示剂。 相似文献
7.
Zhao Pengda 《中国地质大学学报(英文版)》1995,(1)
Ｇｅｏｌｏｇｉｃａｌ Ａｎｏｍａｌｙ ｏｆ Ｃｈｉｎａ￥ＺｈａｏＰｅｎｇｄａ（ＦａｃｕｌｔｙｏｆＥａｒｔｈＲｅｓｏｕｒｃｅｓ，ＣｈｉｎａＵｎｉｖｅｒｓｉｔｙｏｆＧｅｏｓｃｉｅｎｃｅｓ，Ｗｕｈａｎ４３００７４）ＷａｎｇＪｉｎｇｇｕｉ；ＲａｏＭｉｎｇｈｕ... 相似文献
8.
Review of Microstructural Evidence of Magmatic and Solid-State Flow 总被引：13，自引：0，他引：13
R.H. Vernon 《Visual Geosciences》2000,5(2):1-23
Evidence of magmatic flow includes: (a) parallel to sub-parallel alignment of elongate euhedral crystals (e.g., of feldspar or hornblende) that are not internally deformed, (b) imbrication (‘tiling’) of elongate euhedral crystals that are not internally deformed, (c) insufficient solid-state strain in regions between aligned or imbricated crystals to accommodate phenocryst rotation, (d) elongation of microgranitoid enclaves without plastic deformation of the minerals, (e) magmatic flow foliations and elongate microgranitoid enclaves deflected around xenoliths, and (f) schlieren layering (if due to flow sorting) in the absence of plastic deformation of the minerals involved. These features are consistent with rotation of crystals in a much weaker medium, namely a melt phase, at a stage when the magma has become viscous enough to preserve the alignment.Evidence of solid-state flow includes: (a) internal deformation and recrystallization of grains, (b) recrystallized “tails,” (c) elongation of recrystallized aggregates (e.g. of quartz and mica), (d) grainsize reduction, (e) fine-grained folia anastomosing around less deformed relics, (f) microcline twinning, (g) myrmekite, (h) flame perthite, (i) boudinage of strong minerals, typically with recrystallized aggregates of weaker minerals (e.g. quartz and mica) between the boudins, (j) foliation passing through, rather than around enclaves, and (k) heterogeneous strain with local mylonitic zones.Several criteria suggest “submagmatic flow,” including recrystallized feldspar, inferred transitions from magmatic imbrication to solid-state S/C arrangements, evidence of c-slip in quartz, and especially evidence of migration of residual melt into lower-pressure sites.Recent experimental studies indicate that a change from grain-supported flow to suspension flow typically occurs in deforming magmas at melt contents of between 20% to 40%, and that large amounts of strain may accumulate in magmas without being recorded by the final fabric. At lower melt percentages, perhaps as low as a few percent, depending on the minerals and their shapes, strain may be accommodated by: (a) melt-assisted grain-boundary sliding, (b) contact-melting assisted grain-boundary migration, (c) strain partitioning into melt-rich zones, (d) intracrystalline plastic deformation (c-slip in quartz indicating plastic deformation at temperatures near the granite solidus), and (f) transfer of melt to sites of low mean stress. The only indication of strain in the absence of crystal plasticity may be an alignment of crystals. Moreover, magmatic flow microstructures may be destroyed by fracturing, crystal plasticity and recrystallization before the magma reaches its solidus.Many rocks show evidence of solid-state flow superimposed on magmatic flow. Evidence of magmatic flow is commonly preserved in deformed felsic metamorphic rocks: for example the alignment of rectangular K-feldspar megacrysts and of microgranitoid enclaves. However, absence of alignment does not preclude a magmatic origin for K-feldspar megacrysts in felsic gneisses, as magmatic flow may cease before the magma becomes viscous enough to preserve an alignment. 相似文献
9.
Types and distribution of silver ore deposits in China 总被引：2，自引：0，他引：2
Silver is generally recovered as a by- and co-product along with Au, Pb, Zn, Cu, Sb, Bi, Hg, Sn and W from polymetallic and
gold mines in China. Chinese silver deposits can be classified into five principal types according to host rocks. These types
and their host rocks are: (1) marine volcanic-sedimentary rocks hosting (la) massive sulfide Pb-Zn-(Cu)-Ag ores and (1b) stratiform
Ag-(Au) ores; (2) continental volcanic-sedimentary rocks containing (2a) various polymetallic-silver veins and/or stockworks,
and (2b) Ag-(Au) veins in pyroclastic rocks; (3) rocks affected by metasomatic processes including (3a) complex Sn-polymetallic-Ag
ores, (3b) Pb-Zn-(Cu)-Ag skarns, (3c) associated W-Ag quartz veins and/or skarns, and (3d) Ag-(Au) zones and veins in altered
carbonate rocks; (4) metamorphic-intrusive rocks, principally Ag-(Au) veins in sheared and brecciated metamorphic rocks; and
(5) sedimentary rocks including (5a) stratiform Pb-Zn-Ag ores in carbonate rocks, (5b) Ag-V mantos in black shales, and (5c)
Cu-(Ag) layers in red sandstones. A sixth grouping includes gossans. The tectonic settings, geological features, and temporal
and spatial distribution of these different types of silver occurrences indicate that silver mineralization reflects to a
great extent the evolution of tectonic environments in China throughout geological time. Type 1 is generally developed in
association with several fold belts from the Caledonian to Yanshanian orogens, while types 2, 3 and 4 correlate with rejuvenation
of the eastern China continent during the Mesozoic period. The three subgroups of type 5 are recognized in different stages
and various sedimentry and diagenetic environments during the development of paraplatforms and fold belts. Type 6 results
from recent weathering of existing sulfide ores or protores.
Editorial handling: DR 相似文献
10.
Metamorphism of the Crystalline Basement of Central Chile 总被引：1，自引：2，他引：1
The metamorphic basement of the Cordillera de la Costa, in CentralChile, consists mainly of slate, meta-sandstone, phyllite, andmica schist but contains small quantities of greenschist. Thegreater part of the basement is comprised in the Curepto series,and is characterized by dynamo-metamorphism whose intensityincreases westward. East of this is the smaller Nirivilo series,characterized by contact metamorphism whose intensity increaseseastward toward a granodiorite batholith. At the northern endof the metamorphic belt lies the Pichilemu series, in whichthe metamorphism is dynamo-thermal and increases in intensityto the east. The rocks in the first two areas are divisibleinto zones that trend north-north-east, essentially parallelto the margin of the batholith and to the Pacific coast; butin the Pichilemu area the zoning trends north-west. In the Cureptoseries three zones were distinguished; these are, in order fromeast to west: (1) a muscovite-chlorite(-albite) slate zone,(2) a muscovite-biotite(-albite) phyllite zone, and (3) a muscovite-chlorite-albite(±garnet) schist zone. The rocks in all three zones belongto the greenschist facies; the chlorite in the third zone isbelieved to be a product of H metasomatism. In the much narrowerNirivilo area no zones were mapped, but the following eastwardsuccession of critical assemblages was recognized: (1) muscovite-biotite-chlorite-albite;(2) muscovite-biotite-chlorite-andalusite-albite; (3) biotite-muscovite-andalusite-oligoclase;(4) biotite(± muscovite)-andalusite-sillimanite (or cordierite).The muscovite in the rocks that have undergone highgrade metamorphismis largely of metasomatic origin. Part of the sillimanite hasbeen formed at the expense of biotite and andalusite. In mostof the Nirivilo area the most strongly metamorphosed rocks areof the hornblende-hornfels facies, but small parts of that areamay contain rocks of the pyroxene-hornfels facies. The Pichilemuarea comprises the following zones and subzones: (1) a biotitezone, which includes (a) a muscovite-chlorite-biotite-albitesubzone and (b) a muscovite-biotite-albite subzone; (2) a garnet-oligoclasezone; (3) a staurolite-andalusite zone; (4) a muscovite-sillimanitezone; and (5) a sillimanite-orthoclase zone which includes (a)a sillimanite-orthoclase subzone and (b) a sillimanite-orthoclase-cordierite-almandinesubzone. Some thermal metamorphism is superimposed on the regionalmetamorphism. The facies grade from the greenschist to the granuliteor intermediate between the granulite and the amphibolite facies.The three series represent different pressure conditions: theNirivilo series corresponds to a low-pressure (contact) type,Pichilemu represents a low-pressure intermediate, dynamo-thermaltype, and Curepto is a dynamothermal, high-pressure intermediatetype series. The Curepto area was affected first, the Pichilemuarea next, and the Nirivilo area last. The metamorphism in allthree series is thought to have occurred during a single tectoniccycle within Late Paleozoic time, but it was probably interruptedby periods of erosional unloading. The width of the contactaureole is thought to have been determined by the irregularexpansion of the batholith. The analogy between the metamorphicseries of the Cordillera de la Costa and Miyashiro's circum-Pacificpaired belts is briefly discussed. 相似文献
11.
传统型铂族矿产，系指与镁铁质岩浆成矿作用有关的铂族矿产资源。华力西运动时期，扬子地台西南缘沿超壳深断裂带发生的大陆裂谷作用，为来自上地幔的镁铁质(拉斑玄武岩质)岩浆的上涌和侵位提供了极为有利的前提条件。含铂基性超基性岩的时空分布，受到大陆裂谷作用的主要发生发展时期和裂谷活动带的控制。通过对典型矿床特征及其成矿作用的探讨，论述了扬子地台西南缘主要的铂族矿床类型；并从四维成矿的角度，阐述了对区域成矿规律的一些基本认识。 相似文献
12.
Aaron J. Slowey 《Geochimica et cosmochimica acta》2010,74(16):4693-9187
Mercury is a global contaminant of concern due to its transformation by microorganisms to form methylmercury, a toxic species that accumulates in biological tissues. The effect of dissolved organic matter (DOM) isolated from natural waters on reactions between mercury(II) (Hg) and sulfide (S(-II)) to form HgS(s) nanoparticles across a range of Hg and S(-II) concentrations was investigated. Hg was equilibrated with DOM, after which S(-II) was added. Dissolved Hg (Hgaq) was periodically quantified using ultracentrifugation and chemical analysis following the addition of S(-II). Particle size and identity were determined using dynamic light scattering and X-ray absorption spectroscopy. S(-II) reacts with Hg to form 20 to 200 nm aggregates consisting of 1-2 nm HgS(s) subunits that are more structurally disordered than metacinnabar in the presence of 2 × 10−9 to 8 × 10−6 M Hg and 10 (mg C) L−1 DOM. Some of the HgS(s) nanoparticle aggregates are subsequently dissolved by DOM and (re)precipitated by S(-II) over periods of hours to days. At least three fractions of Hg-DOM species were observed with respect to reactivity toward S(-II): 0.3 μmol reactive Hg per mmol C (60 percent), 0.1 μmol per mmol C (20 percent) that are kinetically hindered, and another 0.1 μmol Hg per mmol C (20 percent) that are inert to reaction with S(-II). Following an initial S(-II)-driven precipitation of HgS(s), HgS(s) was dissolved by DOM or organic sulfur compounds. HgS(s) formation during this second phase was counterintuitively favored by lower S(-II) concentrations, suggesting surface association of DOM moieties that are less capable of dissolving HgS(s). DOM partially inhibits HgS(s) formation and mediates reactions between Hg and S(-II) such that HgS(s) is susceptible to dissolution. These findings indicate that Hg accessibility to microorganisms could be controlled by kinetic (intermediate) species in the presence of S(-II) and DOM, undermining the premise that equilibrium Hg species distributions should correlate to the extent or rate of Hg methylation in soils and sediments. 相似文献
13.
Analytical methods used for determining dissolved Fe(II) often yield inaccurate results in the presence of high Fe(III) concentrations. Accurate analysis of Fe(II) in solution when it is less than 1% of the total dissolved Fe concentration (FeT) is sometimes required in both geochemical and environmental studies. For example, such analysis is imperative for obtaining the ratio Fe(II)/Fe(III) in rocks, soils and sediments, for determining the kinetic constants of Fe(II) oxidation in chemical or biochemical systems operating at low pH, and is also important in environmental engineering projects, e.g. for proper control of the regeneration step (oxidation of Fe(II) into Fe(III)) applied in ferric-based gas desulphurization processes. In this work a method capable of yielding accurate Fe(II) concentrations at Fe(II) to FeT ratios as low as 0.05% is presented. The method is based on a pretreatment procedure designed to separate Fe(II) species from Fe(III) species in solution without changing the original Fe(II) concentration. Once separated, a modified phenanthroline method is used to determine the Fe(II) concentration, in the virtual absence of Fe(III) species. The pretreatment procedure consists of pH elevation to pH 4.2–4.65 using NaHCO3 under N2(g) environment, followed by filtration of the solid ferric oxides formed, and subsequent acidification of the Fe(II)-containing filtrate. Accuracy of Fe(II) analyses obtained for samples (Fe(II)/FeT ratios between 2% and 0.05%) to which the described pretreatment was applied was >95%. Elevating pH to above 4.65 during pretreatment was shown to result in a higher error in Fe(II) determination, likely resulting from adsorption of Fe(II) species and their removal from solution with the ferric oxide precipitate. 相似文献
14.
锌-砷黝铜矿产于内蒙的某一铅锌矽卡岩矿床中,呈它形粒状集合体,粒径0.2-0.5mm,铅灰色,硬度HvHN=339-388kg/mm2。反射色呈灰蓝色微带绿色。均质性。其成分经电子探针分析(平均值)为:S 25.94,As 10.70,Cu 39.67,Zn 7.36,Sb 9.81,Bi 5.81,Ag 0.18,Fe 0.37(%),化学式为:(Cu10.02Age03)10.05(Zn1.81Fe0.11)1.82(As2.29Sb1.29Bi0.45)4.03S18。X射线分析:晶胞参数a=10.322,粉末衍射强线是2.98,1.82,1.56。 相似文献
15.
The absolute stereochemistry of pristane in a sample of contemporary marine Zooplankton, Messel shale (Germany) and Djatibarang (Java) crude has been determined by gas Chromatographic methods. The relative stereochemistry in Irati shale (Brazil), Green River (U.S.) crude, Halibut (Australia) crude has also been determined, and confirmed for a sample of the Green River shale. The stereoisomer distributions indicate a loss of stereospecificity of the phytol-derived 6(R),10(S) pristane with increasing geological maturation. For example, the least mature geological sample, the Eocene Messel shale, contains solely the 6(R),10(S) isomer, whereas a mature sample, Djatibarang crude, contains 50% of the 6(R),10(S) isomer and 25% of each of the 6(R),10(R) and 6(S),10(S) isomers. 相似文献
16.
A case study of long-term field performance of check-dams in mitigation of soil erosion in Jiangjia stream,China 总被引：3，自引：0，他引：3
This paper examines the long-term field performance of the check-dams in mitigation of soil erosion in the Duozhao catchment
of Jiangjia stream, southwest China. Since their construction between 1979 and 1982, the check-dams have been functioning
effectively. The examination is made via comparisons between the environmental conditions of the Duozhao catchment with its
adjacent Menqian catchment in the stream, because no check dams were constructed in the Menqian catchment. The examination
is based on recent field investigations and aerial photograph analyses, and covers four aspects: (a) bed gradients of catchment
channels; (b) stability of bank slopes; (c) rates of land erosion; and (d) vegetations on bank slopes. The field data demonstrate
that the check-dams have had the following good functions for mitigation of soil erosion: (1) restricting the channel depth
and lateral erosions, (2) protecting the channel erosion base, (3) reducing the bed gradients of debris-flow channels, (4)
fixing the channel bed, (5) stabilizing the bank slopes, as well as (6) facilitating the growth of vegetations.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
17.
塔里木盆地轮南低隆起早古生代油气藏形成的期次与时间研究 总被引：24，自引：0，他引：24
塔里木盆地轮南低隆起早古生代地层中发现有大量运移沥青及有机包裹体。本研究应用地质地球化学相结合的方法对该区沥青及有机包体进行了研究,探讨了其与油气运移与聚集的关系。结果表明这些沥青与有机包裹体可大致划分为三期 :这三期沥青反射率分别是 :1.2 0 %~ 1.35 %;0.80 %~ 0.95 %;<0.0 5 %;与之对应的三期有机包裹体特征是 :黄绿色荧光,共生盐水溶液包裹体均一温度为 80~ 90℃;绿色荧光,均一温度 6 0~ 70℃;兰绿色荧光,均一温度 10 5~ 15 0℃。沥青与有机包裹体是油气生成与运移的直接证据。轮南低隆起早古生代地层中这三期沥青与三期有机包裹体的大量发现,说明在该区曾出现过三次较大规模油气生成与运移。结合该区埋藏史,受热史推断出这三期油气运移与聚集发生在晚志留世-早泥盆世,白垩纪-早第三纪及晚第三纪。本研究成果为该区油气藏的成因研究提供了重要依据。 相似文献
18.
大贵州滩二叠系—三叠系界线附近锶同位素组成特征 总被引：1，自引：0，他引：1
位于贵州南部的“大贵州滩”上,二叠系—三叠系界线附近地层为一套连续的发育完整的碳酸盐岩。二叠系顶部主要为厚层生物屑泥粒灰岩,而三叠系底部则主要为钙质微生物骨架灰岩及厚层粒泥灰岩。穿过二叠系—三叠系界线的取样累计厚度81m,二叠系和三叠系大致各占一半的厚度,共取样品91件,n(87Sr)/n(86Sr)值变化在0.707269～0.707409之间,平均为0.707327,低于现代海水的锶同位素比值的平均值（0.7090737）。锶同位素比值变化曲线表明从晚二叠世末期到早三叠世初期,同位素比值虽小幅度的起伏波动频繁,但总体上没有明显变化,三叠系底部的平均值（0.707330）略高于二叠系顶部的平均值（0.707323）。大贵州滩晚二叠世末至早三叠世初锶同位素组成的总体演化趋势与扬子台地及世界其它地方同时期的锶同位素组成的演化趋势（呈急剧的上升）不同,造成这种状况的原因可能是在全球事件控制的大背景下,由于大贵州滩特殊的环境条件,陆源物质对其影响小,导致了壳源锶对锶同位素组成的制约作用减弱,因而锶同位素组成未发生明显变化。 相似文献
19.
PANG Xiongqi ZHOU Xinyuan LIN Changsong HUO Zhipeng LUO Xiaorong PANG Hong 《《地质学报》英文版》2010,84(5):1011-1034
<正>Many of the sedimentary basins in western China were formed through the superposition and compounding of at least two previously developed sedimentary basins and in general they can be termed as complex superimposed basins.The distinct differences between these basins and monotype basins are their discontinuous stratigraphic sedimentation,stratigraphic structure and stratigraphic stress-strain action over geological history.Based on the correlation of chronological age on structural sections,superimposed basins can be divided into five types in this study:(1) continuous sedimentation type superimposed basins,(2) middle and late stratigraphic superimposed basins,(3) early and late stratigraphic superimposed basins,(4) early and middle stratigraphic superimposed basins,and(5) long-term exposed superimposed basins.Multiple source-reservoir-caprock assemblages have developed in such basins.In addition,multi-stage hydrocarbon generation and expulsion,multiple sources,polycyclic hydrocarbon accumulation and multiple-type hydrocarbon reservoirs adjustment,reformation and destruction have occurred in these basins.The complex reservoirs that have been discovered widely in the superimposed basins to date have remarkably different geologic features from primary reservoirs,and the root causes of this are folding,denudation and the fracture effect caused by multiphase tectonic events in the superimposed basins as well as associated seepage,diffusion,spilling,oxidation,degradation and cracking.Based on their genesis characteristics,complex reservoirs are divided into five categories:(1) primary reservoirs,(2) trap adjustment type reservoirs,(3) component variant reservoirs,(4) phase conversion type reservoirs and (5) scale-reformed reservoirs. 相似文献
20.
Tao Wang Xin Jiang Congying Wang Fang Wang Yongrong Bian Guifen Yu 《Environmental Earth Sciences》2014,71(2):773-782
Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils. 相似文献