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Carbonate ooids, notionally incompatible with an euxinic environment, and some curious reticulate tubular structures with fibrous carbonate walls are described from intraclasts occurring in Proterozoic black shales containing the pyrite deposit at Amjhor. While some of the tubes are visibly due to coalescence of ooids, others are interpreted as worm burrows on the basis of their strata-transgressive orientation, branching nature and larger diameter than those of the ooids.All stages of pyritization of ooids and tube-cores, displaying truncation of the growth-fabric of calcite grains by growing pyrite crystals, point to a late- or post-diagenetic age of pyritization. The clasts containing ooids and tubes are believed to have been transported from a shallow-bank and/or a nearshore environment into a lagoonal, euxinic basin. An environmental model, consistent with the observed data, is proposed to account for the ooid—black shale association.  相似文献   

3.
Plant macrofossils from 38 packrat middens spanning the last ~ 33,000 cal yr BP record vegetation between ~ 650 and 900 m elevation along the eastern escarpment of the Sierra San Pedro Mártir, northern Baja California. The middens span most of the Holocene, with a gap between ~ 4600 and 1800 cal yr BP, but coverage in the Pleistocene is uneven with a larger hiatus between 23,100 and 14,400 cal yr BP. The midden flora is relatively stable from the Pleistocene to Holocene. Exceptions include Pinus californiarum, Juniperus californica and other chaparral elements that were most abundant > 23,100 cal yr BP and declined after 14,400 cal yr BP. Despite being near the chaparral/woodland-desertscrub ecotone during glacial times, the midden assemblages reflect none of the climatic reversals evident in the glacial or marine record, and this is corroborated by a nearby semi-continuous pollen stratigraphy from lake sediments. Regular appearance of C4 grasses and summer-flowering annuals since 13,600 cal yr BP indicates occurrence of summer rainfall equivalent to modern (JAS average of ~ 80–90 mm). This casts doubt on the claim, based on temperature proxies from marine sediments in the Guaymas Basin, that monsoonal development in the northern Gulf and Arizona was delayed until after 6200 cal yr BP.  相似文献   

4.
赵曌  张立军 《沉积学报》2017,35(3):480-488
豫西南淅川上泥盆统王冠组地层中发育大量与层面平行且具有蹼纹的U形遗迹化石Rhizocorallium。利用环境扫描电镜对Rhizocorallium进行微观观察,发现在其边缘管和蹼纹内部发育大量不同形态的莓状黄铁矿及莓状铁氧化物(单晶为五角十二面体,八面体,立方体和近球形),与之对应的围岩中仅见少量黄铁矿单晶颗粒。表面具有覆盖膜的莓状黄铁矿大多存在于潜穴内部,其中边缘管中莓状黄铁矿的单晶直径(0.672~1.603 μm,平均直径1.063 μm)较之蹼纹中部的(0.376~0.877 μm,平均直径0.5 μm)的大。上述特征显示出潜穴中莓状黄铁矿的存在可能与硫酸盐类还原菌有关。Rhizocorallium边缘管和蹼纹中高丰度莓状黄铁矿的发现表明:遗迹化石Rhizocorallium可能是造迹者精心构筑的觅食-花园。由于食物供应和氧化还原条件的不同,Rhizocorallium造迹者在其潜穴内部培植不同的微生物,形成一个互利共生的群落。  相似文献   

5.
Pyritization in late Pleistocene sediments of the Black Sea is driven by sulfide formed during anaerobic methane oxidation. A sulfidization front is formed by the opposing gradients of sulfide and dissolved iron. The sulfidization processes are controlled by the diffusion flux of sulfide from above and by the solid reactive iron content. Two processes of diffusion-limited pyrite formation were identified. The first process includes pyrite precipitation with the accumulation of iron sulfide precursors with the average chemical composition of FeSn (n = 1.10-1.29), including greigite. Elemental sulfur and polysulfides, formed from H2S by a reductive dissolution of Fe(III)-containing minerals, serve as intermediates to convert iron sulfides into pyrite. In the second process, a “direct” pyrite precipitation occurs through prolonged exposure of iron-containing minerals to dissolved sulfide. Methane-driven sulfate reduction at depth causes a progressive formation of pyrite with a δ34S of up to +15.0‰. The S-isotopic composition of FeS2 evolves due to contributions of different sulfur pools formed at different times. Steady-state model calculations for the advancement of the sulfidization front showed that the process started at the Pleistocene/Holocene transition between 6360 and 11 600 yr BP. Our study highlights the importance of anaerobic methane oxidation in generating and maintaining S-enriched layers in marine sediments and has paleoenvironmental implications.  相似文献   

6.
In order to understand the response of authigenic pyrite to gas hydrate geo-systems, pyrite tubes or rods at the sulfate–methane transition (SMT) zone of core GC10 from the northern continental slope of the South China Sea (SCS) were investigated. In situ X-ray diffraction (XRD) results show that the pyrite tube consists of pyrite micro-crystals with trace amount of graphite in the inner tube. Scanning electron microscope (SEM) observations of pyrite tubes indicate various aggregations in the form of framboidal, euhedral, and colloidal pyrite microcrystals. Typical framboidal pyrite is considered as packing of octahedral microcrystals. Interestingly, many framboids in the tubes consist of round or irregular microcrystals and have an outer crust that consists of secondary pyrite. The size of the framboids in the inner wall of the tube is larger than that in the middle wall or foraminifer-filled pyrite. High-resolution transmission electron microscopic (HRTEM) images show marcasite lamellae defects in the spherulitic pyrite crystals, which reveal different solution conditions during the pyrite precipitation. Nano-foil-like graphitic carbon was observed to be closely associated with the pyrite spherules. The occurrence of both marcasite layers and nano-foil-like graphitic carbon suggest that the migration of methane from deep sediment. It is suggested that the formation of pyrite serves as a catalyst during the reaction from methane to elemental carbon under the anaerobic oxidation of methane. Meanwhile, this reaction results in local acidification of the solution inside the pyrite tubes, which favors marcasite lamellae growth on the host pyrite substrate.  相似文献   

7.
《Quaternary Research》1987,28(1):144-156
Equus Cave, in Quaternary tufa near Taung in the semiarid woodland of the southern Kalahari, yielded 2.5 m of sediment in which a rich assemblage of bones and coprolites was preserved. The fossils were accumulated mainly by hyenas during the late Pleistocene and Holocene. Pollen from coprolites reflects diet as well as vegetation over relatively large areas visited by hyenas, while pollen from sediments represents more local sources. The pollen sequence derived from coprolites and sediments demonstrates how the vegetation evolved from open grassland with small shrubs and occasional trees during the late Pleistocene, to open savanna with more small shurbs, then, during the last 7500 yr, to modern savanna. Temperatures were not more than 4°C cooler and it was slightly moister than today during the late Pleistocene phase; it became gradually warmer but relatively dry before optimal temperature and moisture conditions developed around 7500 yr B.P. Climatic conditions slightly less favorable for woodland occurred during part of the late Holocene.  相似文献   

8.
《Applied Geochemistry》2003,18(8):1149-1163
A core collected in the Guaymas Basin contained an organic-poor, Mn oxide-rich and (relatively) Fe oxide-rich turbidite layer that affected the distribution of Fe, Mn, C, S and trace metals. Results indicate that sediments not influenced by the turbidite layer achieved a 100% degree of pyritization and, by extension, that pyrite production is Fe-limited in these sediments. In contrast, the mud slide layer apparently supplied enough reactive Fe to transfer essentially 98% of the total S present at the base of the turbidite (17–19 cm) to the pyrite reservoir. C/S ratios showed rapid decreases with depth, from a high of 38 close to the sediment-water interface, to minimum values of 2.8 at the lower limit of the turbidite layer, a ratio equal to the average C/S value of normal marine modern sediments, where concentrations of organic C and pyrite supposedly have attained quasi-steady values. A significant part of the reactive Mn was associated with carbonates (41±12%) and, to a much lower degree, with pyrite (2.7±1.2%). The turbidite layer is currently showing a depletion of Mn relative to the host sediment. It is possible that Mn, a major metal constituent in these sediments, was initially present in high concentrations in the mud slide, but was eventually mobilized and transferred either to the water column or to the sediments immediately below the turbidite layer. Metals associated with this element probably followed the same path, affecting their incorporation into pyrite. The turbidite layer apparently affected the distribution of most of the trace metals associated with pyrite, except maybe Cd, Pb and, to a certain, extent Cr. However, Cu, Cr, Zn, Ni and Co were all found to be highly pyritized (>80%) in the sediments of the Guaymas Basin.  相似文献   

9.
《Applied Geochemistry》2002,17(7):923-933
The accumulation and storage of trace metals in coastal sediments is an environmental concern. It is, therefore, important to understand better how these metals are bound or released under different redox conditions. This study of Fe and trace metal fixation under continuously anoxic conditions in the bottom sediments and the lower water column of the Nordåsvannet fjord in western Norway contributes further to such understanding. It allows investigation of both an end member redox state and one important mechanism of Fe and trace metal accumulation in sediments, the pyritization of Fe and trace metals. Pyrite formation occurs both in the water column and in the sediments of the Nordåsvannet fjord and favours the fixing of Fe and trace metals in the bottom sediments of the fjord. Thus, these sediments act as a continuous sink for Fe and trace metals. The DOP, and the degrees of trace metal pyritization for Mo, Ni and Cr correlate with organic matter content. While it is generally thought that Fe is the factor limiting pyrite formation in anoxic environments, this study found that degrees of pyritization of Fe (DOP) are clearly below 100%, and the availability of metabolizable organic matter is limiting pyrite formation. This is an important finding, because it indicates that increased supply of organic and mineral matter by higher runoff from land would further enhance the fixation of these metals in the fjord sediments, as would higher organic matter availability from increased productivity due to higher nutrient supply. The metals stored in the bottom sediments could be released into the biogeochemical cycle if redox conditions were to change from anoxic to suboxic or oxic. The fjord would then become a source rather than a sink for these metals.  相似文献   

10.
Authigenic pyrite grains from a section of the Lower Toarcian Posidonia Shale were analysed for their trace‐element contents and sulphur‐isotope compositions. The resulting data are used to evaluate the relationship between depositional conditions and pyrite trace‐element composition. By using factor analysis, trace‐elements in pyrite may be assigned to four groups: (i) heavy metals (including Cu, Ni, Co, Pb, Bi and Tl); (ii) oxyanionic elements (As, Mo and Sb); (iii) elements partitioned in sub‐microscopic sphalerite inclusions (Zn and Cd); and (iv) elements related to organic or silicate impurities (Ga and V). Results indicate that trace‐element contents in pyrite depend on the site and mechanism of pyrite formation, with characteristic features being observed for diagenetic and syngenetic pyrites. Diagenetic pyrite formed within anoxic sediments generally has a high heavy metals content, and the degree of pyritization of these elements increases with increasing oxygen deficiency, similar to the degree of pyritization of reactive Fe. The highest gradient in the increase of the degree of trace element pyritization with bottom‐water oxygenation was found for the elements Ni < Cu < Mo = As < Tl. In contrast, syngenetic pyrite formed within a euxinic water column typically is enriched in As, Mo and Sb, but is low in heavy metals, and the geochemical variation reflects changes in sea water composition.  相似文献   

11.
The Late Pleistocene and Holocene loess deposits of the SE Buenos Aires province are composed of four allostratigraphic units that represent four episodes of loess deposition. The first and the second episodes occurred in Late Pleistocene times. The second episode was followed by a soil forming interval (Early Holocene to Mid-Holocene times). The third episode took place at about 5000 yr BP, after the Holocene sea-level maximum when marine regression began. The fourth episode constitutes a historical event of only local significance.Loess shows a fairly constant granulometric and mineralogical composition. The modal fraction consists of very fine sand and coarse silt (3 to 5 phi). They are classified as sandy silts or silty sands. Three grain-size subpopulations are differentiated: coarse, medium and fine. The medium-size subpopulation, which is the most important, consists of most of the very fine sand and coarse silt. It is thought to be transported by modified saltation and short-term suspension during local dust-storms.The mineralogical composition of loess consists of a volcaniclastic assemblage derived mainly from reworked pyroclastic deposits, primary tephras and volcaniclastic sediments. The source area of these materials was located in the lower Colorado river valley about 400 km SW of the studied area. There was also a direct supply by volcanic ash falls.  相似文献   

12.
Small mammal communities in western North America experienced declines in taxonomic richness across the late Pleistocene to Holocene transition (PHT), a recent natural global warming event. One community also experienced a decline in evenness and others replaced one species with a congener. Variability in response of small mammal communities to PHT warming is apparent. At the presently arid and xeric Marmes site in the Columbia Basin of southeastern Washington State, megafauna were absent by about 13,000 cal yr BP, evenness of small mammals declined about 11,700 cal yr BP and again about 11,400 cal yr BP whereas richness declined about 11,400 cal BP. Regional faunal turnover was, however, minimal among small-bodied taxa. Local mammal communities are depauperate as a result of megafaunal extinctions and subsequent decreases in small-mammal richness and evenness. The latter chronologically corresponds with a decrease in primary productivity driven by increasing warmth and aridity. More faunas must be studied in order to fully document the range of variability in the responses of mammalian communities to PHT warming. Documentation of patterns in those responses will facilitate understanding and enhance predictive accuracy with respect to responses of mammalian communities to modern global warming.  相似文献   

13.
Research was undertaken to establish the present coastal dynamics of the area south of Espinho, Portugal, with special emphasis on the migration inland of beaches and the retreat of cliffs during at least the last century.
Besides the Holocene units (the Silvalde-Paramos tijuca Formation, 2310 ± 80 yr BP to 500 ± 80 yr BP, and the Cortegaca Beach Formation, 6850 ± 60 yr BP to 950 ± 80 yr BP), a Pleistocene unit (the Maceda Beach Formation, 29, 600 ± 690 yr BP to 14300 ± 160 yr BP) with trunks of Pinus sylvestris was recognized. The Cortegaca Beach Formation comprises a truncated podzol profile, the Al horizon dating from 3490 ± 60 yr BP to 950 ± 80 yr BP. The study and the dating of the Pleistocene and the Holocene formations suggest a model of evolution related to sea-level fluctuations and neotectonics, during the interval between 29,000 ± 690 yr BP and the post-XVth century (Little Ice Age).
The final purpose of the research is to apply the results to the prediction of the coastal zone evolution, and particularly to influence policy with respect to coastal zone management. This policy must take into account the inland migration of the beaches and the cliff retreat as a consequence of the natural dynamics of the earth that cannot be arrested or controlled by man.  相似文献   

14.
The late Quaternary history of the middle Caquetá River area in Colombia, northwestern Amazonia is described, based on observations of river bank sections, radiocarbon dates and palynological analyses of organic layers in floodplain and low terrace sediments of the Caquetá River. It is shown that the Late Pleistocene and Holocene climatic changes that took place in the Andean Cordilleras, were related to the depositional and erosional history of the Caquetá River in the Colombian Amazonian lowlands. The low terrace sediments consist of sandy and gravelly deposits covered by clays that sometimes contain lenses of peaty material. From these organic low terrace sediments, seven finite radiocarbon dates were obtained of Middle Pleniglacial age, between 56 000 and 30 000 yr BP. The coarse textured basal deposits of the low terrace apparently stem from the early part of the Middle Pleniglaciai period, during which the effective rainfall in the Andes was relatively high and the Andean glaciers had a considerable extension. Palynological data from silty sediments with organic remains at one site, show an interval when drier and more open types of vegetation on poor soils must have covered a larger area than today, but Amazonian forest was still the dominating type of vegetation. This interval might correspond to one of the Middle Pleniglacial savanna intervals from eastern Amazonia (Carajas). No organic sediments from the Upper Pleniglacial period were found and hence radiocarbon dates were not obtained. In the Andes this period had a very cold climate with low effective rainfall and in the east Amazonian Carajas area it is characterised by the relative extension of open savanna vegetation. The river run-off and sediment transport must have been much lower than in the Middle Pleniglacial and the Caquetá River cut itself down in its own sediments. Two Late-glacial radiocarbon datings obtained at one site (ca. 12 500 yr BP) indicate the existence of a Late-glacial sedimentation phase, separated from the Holocene sequence by a minor erosional phase. Organic layers in the Holocene floodplain sediments yielded 28 radiocarbon dates between 10 000 and 355 yr BP. Holocene sedimentation started with the rapid deposition of (sandy) clay possibly in a partly permanently inundated Caquetá valley. During the major part of the Holocene (silty) clays were deposited, with a dominant seasonal inundation cycle.  相似文献   

15.
In the Central Andes of Argentina, evidences of early human occupations come from the Precordillera, a low mountain system which was under periglacial conditions prior to 14,000 14C yr BP, when the Cordillera Principal and Cordillera Frontal were glaciated. The corridors for human migration across the Andes may have opened before 13,000 14C yr BP. The Pleistocene/Holocene transition gave rise to a substantial variability of environments and consequently of natural resources for early people, who found in the Precordillera new ecosystems with suitable conditions for living. The first human groups arrived ca. 11,000 14C yr BP at Agua de la Cueva rockshelter, located at 2900 m above sea level in the western flank of the Precordillera. The occurrence of raw material outcrops close to the site and the archaeofaunistic record indicate a local and likely seasonal exploitation of mountain resources. These early people lived in a shrub steppe environment under cooler and probably wetter conditions in which camelids were the most important food resource. Since 9000 14C yr BP, warmer and drier conditions were dominant. Except for a lower intensity of human occupations, the site function of Agua de la Cueva seems to have remained the same.  相似文献   

16.
《Geochimica et cosmochimica acta》1999,63(19-20):3373-3378
Interactions of trace metals with sulfide in anoxic environments are important in determining their chemical form and potential toxicity to organisms. In recent years, a considerable body of observational data has accumulated that indicates very different behavior for various trace metals in sulfidic sediments. These differences in behavior cannot be entirely attributed to thermodynamic relationships, but also reflect differences in ligand exchange reaction kinetics, and redox reaction pathways.Pb, Zn, and Cd, which are generally pyritized to only a few percent of the “reactive” fraction, have faster water exchange reaction kinetics than Fe2+, resulting in MeS phases precipitating prior to FeS formation and subsequent pyrite formation, whereas, Co and Ni, which have slower H2O exchange kinetics than Fe2+, are incorporated into pyrite. Although Hg and Cu have faster reaction kinetics than Fe2+, both are incorporated into pyrite or leached from the pyrite fraction with nitric acid. Hg undergoes significant chloride complexation, which can retard reaction with sulfide, but can also replace Fe in FeS to form HgS, which can only be dissolved in the pyrite fraction. Cu2+ is reduced by sulfide and forms a variety of sulfides with and without Fe that can only be dissolved with nitric acid. Mn2+ does not form a MnS phase easily and is incorporated into pyrite at high iron degrees of pyritization (DOP).Oxyanions of Mo and As are first reduced by sulfide. These reduced forms may then react with sulfides resulting in incorporation into pyrite. However, the oxyanion of Cr is reduced to Cr3+, which is kinetically inert to reaction with sulfide and, therefore, not incorporated into pyrite.  相似文献   

17.
Previous radiocarbon ages of detrital moss fragments in basal organic sediments of Lake Emma indicated that extensive deglaciation of the San Juan Mountains occurred prior to 14,900 yr B.P. (Carrara et al., 1984). Paleoecological analyses of insect and plant macrofossils from these basal sediments cast doubt on the reliability of the radiocarbon ages. Subsequent accelerator radiocarbon dates of insect fossils and wood fragments indicate an early Holocene age, rather than a late Pleistocene age, for the basal sediments of Lake Emma. These new radiocarbon ages suggest that by at least 10,000 yr B.P. deglaciation of the San Juan Mountains was complete. The insect and plant macrofossils from the basal organic sediments indicate a higher-than-present treeline during the early Holocene. The insect assemblages consisted of about 30% bark beetles, which contrasts markedly with the composition of insects from modern lake sediments and modern specimens collected in the Lake Emma cirque, in which bark beetles comprise only about 3% of the assemblages. In addition, in the fossil assemblages there were a number of flightless insect species (not subject to upslope transport by wind) indicative of coniferous forest environments. These insects were likewise absent in the modern assemblage.  相似文献   

18.
青岛胶州湾沉积物痕量元素黄铁矿化程度及其剖面类型   总被引:4,自引:0,他引:4  
为了探索青岛近海不同沉积环境下不同痕量元素的黄铁矿化规律, 2003年5月潜水员潜入海底采集了4个不同沉积环境的未扰动柱样, 并利用Huerta-Diaz and Morse (1990)连续提取技术测试分析了沉积物痕量金属的不同存在形式(活性态和黄铁矿结合态) 在垂直剖面上的分布规律.结果表明: 除了在涨潮三角洲上部沉积和潮下带沉积物柱子的Cd和Cr外, 痕量元素的黄铁矿化度的增高取决于其相应剖面上的DOP的增高; 并且不同痕量元素向黄铁矿中转移的规模存在着较大的差别, 即元素As、Hg和Mo转移的规模最大, Cu、Zn、Cd、Cr、Co和Ni中等, Pb和Mn最小; 此外, 还进一步揭示了河流三角洲沉积物的下部各元素的黄铁矿化程度高, 而潮下带沉积物以及涨潮三角洲沉积物低.最后指出在河口水下三角洲进行的清淤工作应注意黄铁矿结合态痕量元素的活化而产生生物有效的毒性元素.   相似文献   

19.
Studies of Late Quaternary sediments in south and central Sweden have yielded a detailed tephrochronology for the Last Glacial–Interglacial transition (LGIT; ca. 15,000–10,000 cal. yr BP) and the Holocene. More than ten tephra layers have been detected and geochemically characterised. The most widespread tephra from the LGIT is the rhyolitic phase of the Vedde Ash (ca. 12,000 cal. yr BP) which has been found in lacustrine sediments and marine clays south of the Younger Dryas moraines in south Sweden. Other horizons from the LGIT identified to date include the Borrobol tephra (ca. 14,400 cal. yr BP), the Hässeldalen tephra (ca. 11,500 cal. yr BP), the 10-ka Askja tephra (ca. 11,300 cal. yr BP) and the Högstorpsmossen tephra (ca. 10,200 cal. yr BP). The most significant Holocene isochrones are Hekla-4 (ca. 4260 cal. yr BP), Hekla-Selsund/Kebister (ca. 3750 cal. yr BP), Hekla-3 (ca. 3000 cal. yr BP) and Askja-1875. Two new Late Holocene tephra horizons (the Stömyren tephra, ca. 2100 cal. yr BP and the Gullbergby tephra; ca. 2700 cal. yr BP) were identified in single sites and are so far less valuable as marker horizons, but are potentially important for the future.  相似文献   

20.
Playas are small, circular basins forming a ubiquitous component of the southern High Plains landscape. They are filled with carbonaceous mud deposited since the terminal Pleistocene. The stratigraphy and geochronology of 30 playas was investigated to better understand the paleoenvironmental record of basin filling. At the base of the fill in some playas is a well sorted eolian sand dated between ~ 13,000 and ~ 11,000 14C yr BP. The beginning of mud deposition, representing aggradation of eolian dust on a moist, vegetated playa floor was largely between ~ 12,000 and ~ 10,500 14C yr BP. Playa filling slowed ~ 9000 to ~ 4000 14C yr BP, probably due to dry conditions, increased ~ 4000 to ~ 2000 14C yr BP, then slowed again. Eolian sand and loam, likely representing regional aridity, accumulated in some basins episodically just prior to ~ 10,700 14C yr BP, between ~ 8600 and ~ 4700 14C yr BP, and at ~ 1300 14C yr BP. Stable C isotopes from one basin indicate that the playa was inundated only seasonally throughout the record beginning ~ 11,500 14C yr BP. The phytolith record in that basin indicates an abrupt shift toward cooling ~ 11,400 to ~ 11,200 14C yr BP and then increasing importance of xeric-adapted C4 grasses through the Holocene.  相似文献   

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