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1.

The Barry Granodiorite is a weakly deformed I‐type, and the Sunset Hills Granite is a moderately deformed S‐type, granite. Both granites were passively intruded into an already foliated greywacke and volcanic sequence. Emplacement may have been facilitated by faults related to the oblique opening of the late Early Silurian Hill End Trough. The granites display a dominant foliation which formed during the late Middle Devonian and subsequently was reoriented during the Early Carboniferous. The Barry Granodiorite and Sunset Hills Granite are on the margin of north‐south ductile shear zones related to the Wyangala Batholith. These granites and the adjacent Carcoar Granodiorite have undergone reorientation during movement on ductile shear zones either due to megakinking during late‐stage north‐south shortening, or southeastward movement of the southern margin of the west‐northwest‐trending Lachlan Transverse Zone.  相似文献   

2.
Most rhyolite eruption episodes of Tarawera volcano have emitted several physiochemically distinct magma batches (∼1–10 km3). These episodes were separated on a millennial timescale. The magma batches were relatively homogeneous in temperature and composition at pumice scale (>4 cm), but experienced isolated crystallisation histories. At the sub-cm scale, matrix glasses have trace element compositions (Sr, Ba, Rb) that vary by factors up to 2.5, indicating incomplete mixing of separate melts. Some quartz-hosted melt inclusions are depleted in compatible trace elements (Sr, Ti, Ba) compared to enclosing matrix glasses. This could reflect re-melting of felsic crystals deeper in the crystal pile. Individual quartz crystals display a variety of cathodoluminescence brightness and Ti zoning patterns including rapid changes in melt chemistry and/or temperature (∼50–100°C), and point to multi-cycle crystallisation histories. The Tarawera magma system consisted of a crystal-rich mass containing waxing and waning melt pockets that were periodically recharged by silicic melts driven by basaltic intrusion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

3.
川西甲基卡二云母花岗岩和伟晶岩内发育大量原生熔体包裹体和富晶体流体包裹体。为了查明甲基卡成矿熔体、流体性质与演化特征,运用激光拉曼光谱和扫描电镜鉴定了甲基卡花岗伟晶岩型锂矿床中二云母花岗岩及伟晶岩脉不同结构带内的原生熔体、流体包裹体的固相物质。分析结果表明,甲基卡二云母花岗岩石英内熔体包裹体的矿物组合为磷灰石+白云母、白云母+钠长石、白云母+石墨;伟晶岩绿柱石内富晶体流体包裹体的矿物组合主要为刚玉、富铝铁硅酸盐+刚玉+锂辉石、锂辉石+石英+锂绿泥石;伟晶岩锂辉石内富晶体流体包裹体的矿物组合主要为磷灰石、锡石、磁铁矿、石英+钠长石+锂绿泥石、萤石、富钙镁硅酸盐+富铁铝硅酸盐+富铁硅酸盐+石英;花岗岩浆熔体与伟晶岩浆熔体(流体)具有一定的差异,成矿熔体、流体成分总体呈现出碱质元素(Na、Si、Al)、挥发分(F、P、CO_2)含量增高及基性元素(Fe、Mg、Ca)降低的特征;包裹体中子矿物与主矿物的化学成分具有一定的差别,揭示出伟晶岩熔体(流体)存在局部岩浆分异作用,具不混溶性及非均匀性。因此认为,伟晶岩熔浆(流体)为岩浆分异与岩浆不混溶共同作用的产物,挥发分含量的增高(F、P、CO_2)使伟晶岩能够与稀有金属组成各类络合物或化合物,这对于稀有金属成矿起到了至关重要的作用。  相似文献   

4.
石英阴极发光在火成岩研究中的应用   总被引：4，自引：0，他引：4  
阴极发光是一种研究火成岩石英显微生长结构的有效技术方法。文章以甲玛斑岩铜矿床中岩体样品分析为例,简要介绍了光学显微镜阴极发光(OM-CL)和扫描电镜阴极发光(SEM-CL)两种图片的特点,并综述了石英阴极发光在火成岩研究中的应用。阴极发光所显示出的火成岩石英中的生长形式和蚀变结构反映了岩浆的结晶历史。相对稳定的以蓝色阴极发光为主的斑晶区域主要与石英中Ti含量的变化有关,它反映了结晶作用的温度。由于在岩浆演化过程中,与铝、锂、钾、锗、硼、铁、磷相比,钛更加相容,因此随着岩浆分异程度的加深,火成岩中铝/钛逐渐升高。石英阴极发光不仅能显示岩浆早期及岩浆晚期的各种结构,如生长环带、重熔表面、溶蚀湾等,还反映了许多次生结构,如显微裂隙等。这些现象在光学显微镜下难以观察区分。晶体的显微结构提供了熔体来源和演化的重要信息。将石英结构和熔融包裹体与微量元素研究相结合反映了岩浆演化详细的PTt轨迹,它是富硅酸盐岩浆演化过程中物理-化学条件改变的敏感指示剂。  相似文献   

5.
石英是一种在地壳上大量分布,有着广泛工业用途和广阔应用前景的矿物。当石英晶体形成演化时,受结晶时环境条件、流体性质、结晶后遭受改造(如变质作用、构造变形和热扰动等)等影响,杂质元素如P、Ti、Ge、Al、B、Be、Ca、Na、K、H、Li等会或多或少存在于石英晶体中,因此在自然界不存在纯SiO2组分的石英。同时,基于石英的微量元素组成,可以反演石英源区和形成演化过程,并用于研究岩石及矿床成因等科学问题。石英晶体内部杂质元素以类质同象替代、气液包裹体、矿物包裹体(不能按尺度分,应该按照状态划分存在形式)3种形式存在。石英中杂质元素的种类、含量、赋存形式,特别是包裹体特征将直接影响石英资源的品质和工业用途。本文还系统地阐述了石英的发光特性、工艺性能以及高纯石英的质量分类与标准和高纯石英原料来源等方面的内容。在本研究中,通过光学显微镜和激光拉曼测试,初步地查明了苏北张锦庄石英砂和广西姑婆山花岗岩石英中流体包裹体的分布和矿物包裹体的种类,这是开展后续研究的基础。高纯石英是优质石英资源经纯化加工得到的高品质石英原材料,可用于石英玻璃、石英坩埚、半导体、高温灯管、光纤、精密光学、微电子和太阳能等高新技术产业中。研究高纯石英原料的评价体系、理想源岩和形成机制有益于持续性地供给高纯石英原料, 极大地提高了石英原料的工业附加值。  相似文献   

6.
The Neoproterozoic pluton of Gabal Gharib granite Eastern Desert of Egypt is intruded in subduction-related calc-alkaline granitic rocks of granodiorite to adamellite composition. A zone of metasomatized granite was developed along the contacts at the expense of the calc-alkaline granite. The granite of Gabal Gharib is hypersolvus, composed mainly of orthoclase-microperthite, quartz, and interstitial arfvedsonite. Fluorite, zircon, ilmenite, allanite, and astrophyllite are the main accessories. Pegmatite pods as well as miarolitic cavities (mineral-lined cavities) are common and ranging in size from a few millimeters to 50?cm. Rare-metal minerals such as columbite, cassiterite, and fluorite have been identified from the miarolitic cavities. Geochemical studies revealed that Gabal Gharib granite is a highly fractionated granite, homogeneous in composition, with high contents of SiO2, and alkalis, high Ga/Al, and Fe/Mg ratios, and low concentrations of Al, Mg, and CaO relative to granodiorite?Cadamellite country rocks. Gabal Gharib granite is metaluminous to peralkaline with ASI (0.94?C1.07). Trace element characteristics of Gabal Gharib granite include abundances of Rb, Nb, Ta, Sn, Th, U, Y, Ga, Zn, rare earth elements (REEs, except Eu), and F, and depletion in Sr, and Ba relative to granodiorite?Cadamellite country rocks. It has the geochemical characteristic of anorogenic A-type granite. The uniform trends of differentiation, normal REE distribution patterns, and low calculated tetrad effects of REE (<0.2) indicate that the effect of post-magmatic subsolidus processes were minimal in the studied granite. Fluid inclusions were studied in quartz crystals from Gabal Gharib granite, quartz pods, and metasomatized granite. The study revealed the presence of high-temperature (480?C550°C), high-salinity (19.45?C39.13?wt.% NaCl eq.) primary inclusions in both metasomatized and rare-metal granites coexisting with melt inclusions and medium-temperature (350?C450°C), medium-salinity (10?C16?wt.% NaCl esq.) aqueous inclusions coexisting hydrocarbon-bearing inclusions. Hydrocarbon is represented by magmatic CH4 in Gabal Gharib granite, while heavier aliphatic compounds may be present in quartz pods. Melt inclusions with temperatures of homogenization >600°C were also reported. Petrographic, geochemical, and fluid inclusion studies constrain that the peralkaline anorogenic granite of Gabal Gharib was derived from highly evolved magma probably originated by fractional crystallization of mantle source.  相似文献   

7.
Summary The northwest-striking Pfahl zone, Bavarian Forest, is a mylonitic shear zone that is associated with brittle-ductile deformation fabrics and a conspicuous hydrothermal quartz mineralization. Two granites from this shear zone yield U–Pb and Pb–Pb evaporation ages between 321–329 Ma and two granodiorites give concordant 238U–206Pb and 235U–207Pb ages of 325±3 Ma and 326±3 Ma, respectively. Zircon populations of the granitoids show sub-types clustering around S20, S10 (granite) and S22 to S24 (granodiorite) testifying different magma affinity. Compositional and isotopic characteristics indicate that the granites and granodiorites were coeval melts, but not differentiates of a single parent magma. The granodiorites were derived from a source with higher time-integrated 87Rb/86Sr and lower 147Sm/144Nd ratios than the granites. One granite body is transected by the shear zone but the main mass of the granite is largely undeformed. This finding suggests that granite intrusion predates the final stage of ductile deformation along the Pfahl shear zone.  相似文献   

8.
Idiomorphic quartz crystals in topaz-bearing granite from the Salmi batholith contain primary inclusions of silicate melt and abundant mostly secondary aqueous fluid inclusions. Microthermometric measurements on melt inclusions give estimates for the granite solidus and liquidus of 640–680°C and 770–830°C, respectively. Using published solubility models for H2O in granitic melts and the obtained solidus/liquidus temperatures from melt inclusions, the initial water concentration of the magma is deduced to have been approximately 3 wt.% and the minimum pressure about 2 kbar. At this initial stage, volatile-undersaturation conditions of magma were assumed. These results indicate that the idiomorphic quartz crystals are magmatic in origin and thus real phenocrysts. During subsolidus cooling and fracturing of the granite, several generations of aqueous fluid inclusions were trapped into the quartz phenocrysts. The H2O inclusions have salinities and densities of 1–41 wt.% NaCl eq. and 0.53–1.18 g/cm3, respectively.  相似文献   

9.
An investigation has been made of the relationships between tectonic processes and fluid inclusions in quartz from variably deformed and syntectonically recrystallized granitic rocks from the Lachlan Fold Belt, eastern Australia. The quartz contains many fluid inclusions which decorate healed fractures introduced as a result of late-stage brittle deformation. The majority of small inclusions however, are associated with deformation band boundaries and deformation lamellae showing that they have been introduced during or subsequent to ductile deformation. Fluid inclusions disappear from the cores of sub-grains during recovery and before recrystallization, and new inclusions which form along sub-grain boundaries coalesce into stringers. Inclusions are eliminated from both sides of low angle boundaries showing that inclusions leak their contents either through the system of dislocations which accompanies grain interior slip, or by a dissolution-condensation process whereby inclusion contents move by lattice diffusion and condense on the boundaries.  相似文献   

10.
南岭中段骑田岭A型花岗岩与芙蓉超大型锡矿床具有密切的时间和空间关系。流体包裹体地球化学研究表明,骑田岭A型花岗岩石英斑晶中的流体包裹体类型主要有熔融包裹体、流体-熔融包裹体和流体包裹体。流体-熔融包裹体的显微测温学研究结果显示,骑田岭A花岗岩在岩浆演化过程中可以分异出流体,且岩浆分异出的流体与芙蓉超大型锡矿床流体包裹体所反映的高温和高盐度的CaCl2-NaCl-KCl-H2O流体体系的特征相吻合。综合分析表明,芙蓉超大型锡矿床成矿流体中的高盐度流体应为骑田岭黑云母二长花岗岩结晶过程中分异出的富含Cl等挥发份和成矿物质的高盐度热流体。  相似文献   

11.
Exsolution (unmixing) of the volatile element-rich phases from cooling and crystallising silicate magmas is critical for element transport from the Earth’s interior into the atmosphere, hydrosphere, crustal hydrothermal systems, and the formation of orthomagmatic ore deposits. Unmixing is an inherently fugitive phenomenon and melt inclusions (droplets of melt trapped by minerals) provide robust evidence of this process. In this study, melt inclusions in phenocrystic and miarolitic quartz were studied to better understand immiscibility in the final stages of cooling of, and volatile exsolution from, granitic magmas, using the tin-bearing Omsukchan Granite (NE Russia) as an example.

Primary magmatic inclusions in quartz phenocrysts demonstrate the coexistence of silicate melt and magma-derived Cl-rich fluids (brine and vapour), and emulsions of these, during crystallisation of the granite magma. Microthermometric experiments, in conjunction with PIXE and other analytical techniques, disclose extreme heterogeneity in the composition of the non-silicate phases, even in fluid globules within the same silicate melt inclusion. We suggest that the observed variability is a consequence of strong chemical heterogeneity in the residual silicate-melt/brine/vapour system on a local scale, owing to crystallisation, immiscibility and failure of individual phases to re-equilibrate. The possible evolution of non-silicate volatile magmatic phases into more typical “hydrothermal” chloride solutions was examined using inclusions in quartz from associated miarolitic cavities.  相似文献   


12.
The combination of scanning electron microscope–cathodoluminescence (CL), fluid inclusion analysis and high-resolution electron probe microanalysis of Al, Ti, K and Fe in vein quartz has yielded results permitting a greater understanding of the complex mineralisation of the Central Oyu Tolgoi and Zesen Uul porphyry-style deposits, southern Mongolia. These data demonstrate the relationship between quartz precipitation, dissolution and ore deposition as the mineralising fluid chemistry changed through time. Four major quartz generations are identified in the A-type veins from the stockworks of both the Central Oyu Tolgoi (OTi to OTiv) and Zesen Uul deposits (ZUi to ZUiv). Despite differences in the associated alteration and mineralisation style, the observed CL textures and trace element signatures of the quartz generations are comparable between deposits. The OTi and ZUi stage formed both the primary network of A-type veins and pervasive silicification of the host rock. Using the Ti-in-quartz geothermometer, crystallisation temperatures for OTi and ZUi of between 598°C and 880°C are indicated. The main stage of sulphide mineralisation was accompanied by the dissolution of pre-existing quartz (OTi and ZUi) and precipitation of a weakly luminescent generation of quartz (OTii and ZUii) with a low Ti content, reflected in a calculated temperature drop from approximately 700°C to 340°C in Central Oyu Tolgoi and 445°C in Zesen Uul. OTii and ZUii stage quartzes show high and variable Al concentrations. The next stage of quartz in both deposits (OTiii and ZUiii) forms a fine network of veins in cracks formed in pre-existing quartz. OTiii and ZUiii quartz contain measurable fluid inclusions of moderate salinity (3–17.1 wt.% NaCl eq.), entrapped in the temperature range 256°C to 385°C. OTiii and ZUiii are not related to any sulphide mineralisation. The final OTiv and ZUiv stages are characterised by quartz–calcite micro-breccias that penetrate the A-type veins. Based on the calculated entrapment temperatures, the OTiv/ZUiv stage crystallised between 212°C and 335°C, and the quartz is characterised by elevated but variable Al and Fe contents. The CL and trace element signatures of the OTi to OTiii and ZUi to ZUiii stages of the two Mongolian porphyries show similar features to those observed in porphyry-style deposits from other regions. This suggests that a common sequence of quartz crystallisation occurs during the formation of early veins in many porphyry copper systems.  相似文献   

13.
Mildly deformed granitoids exposed around Bilgi in the northernmost part of the eastern Dharwar craton are divided into two groups viz. granodiorites and monzogranites. The granodiorites contain microgranular enclaves and amphibolite xenoliths, and show low-Al TTG affinity with high SiO2 (71–74 %), Na2O, Y and Sr/Y, moderate to moderately high Mg#, Cr and Ni, low to moderate LILE, and low Nb and Ta. However, compared to similar TTGs from different cratons the Bilgi granodiorites have distinctly higher K2O, K2O/Na2O, Rb and lower REE and Th. The amphibolite xenoliths are characterized by variable enrichment of K2O, Rb, Ba and Th and depletion of Ti, Zr and P compared to MORB. The microgranular enclaves are quartz diorite to granodiorite in composition with high Mg, Ni and Cr, and compared to MORB, are enriched in LILE and depleted in Ti and Y. The monzogranites, compared to the granodiorites, display higher SiO2, K2O and Rb with lower Mg#, although still maintaining the high Na2O, Ni and Cr and low REE character. The Bilgi granodiorites are explained as transitional TTGs late synkinematic with respect to regional deformation. Geochemical signatures and regional geological set up suggest that they are probably derived from partial melting of a highly depleted slab material (metabasalt) followed by variable contamination or assimilation of intermediate crustal rocks in a subduction zone set up. Late stage fluid activity on the granodioritic magma is probably responsible for the generation of monzogranites. The amphibolite xenoliths predate the granodiorites and possibly represent fragments of a schist belt carried away by the granitic magma. They are probably island arc basalt derived from mantle source that has been metasomatized by slab-derived fluids. The microgranular enclaves are coeval with the Bilgi granodiorites and also likely to be island arc magmas derived from mantle variably enriched in slab-derived and within-plate components.  相似文献   

14.
Gold-bearing quartz veins of the Taihua Group consisting of Archean metavolcanic rocks are a main gold deposit type in the Xiao Qinling area,one of the three biggest gold production areas in China.The quartz veins experienced strong alteration characterized by a typical mesothermal hydrothermal altered mineral assemblage.The grade of gold is affected by the contents of sulphides,e.g.galena,pyrite and chalcopyrite.Results of minor elements analysis for the of gold-bearing quartz veins indicate higher contents of Au and high contents of Ag,Pb,Cu,Cd,W,and Mo.Abundant fluid inclusions were found in the gold-bearing quartz veins.Three types of fluid inclusions were identified:(1) aqueous inclusions;(2) CO 2-bearing inclusions;and(3) daughter crystal-bearing fluid inclusions.Homogenization temperatures ranged from 110 to 670℃ with low and high peaks appearing at 160 180℃ and 280 300℃,respectively.The salinity of aqueous inclusions varies between 1.8 wt% and 38.2 wt% NaCl.The homogenization temperature and salinity show a positive correlation.The H and O isotopes of fluid inclusions in the gold-bearing quartz veins indicate that magmatic solution and metamorphic hydrothermal solution,together with meteoric water,were involved in the formation of gold-bearing fluid.Mesozoic magma activities related to granite intrusions should be the main source of CO 2 fluid with higher temperature and salinity.  相似文献   

15.
Baerzhe Be–Nb–Zr–REE deposit is hosted in alkaline granite (125 Ma) which intrudes in the late Jurassic Baiyingaolao Formation in the middle of the Great Hinggan Metallogenic Belt in China. The ore‐forming granite consists of three lithological facies: arfvedsonite‐bearing alkaline granite at the bottom, aegirine‐bearing albite aplite in the middle and pegmatite crust on the top. The albite aplite is the main orebody. We recognized three magmatic‐hydrothermal stages: orthomagmatic stage, late‐magmatic stage and hydrothermal stage, with the late‐magmatic stage being divided into two substages, the pegmatite substage and the aplite substage. Petrographic study on the granite, the microthermometric study on fluid inclusions and in situ laser‐ablation inductively coupled plasma mass spectrometry analysis for quartz‐hosted melt inclusions reveal the process of magmatic‐hydrothermal evolution. The finding indicates that primary magma evolved to more peralkaline by fractional crystallization, with synchronously increasing high field strength elements. An extremely high content of Zr and Nb are in the melt inclusions from last stage albite aplite (Zr, min 52 548 ppm, and Nb, min 4104 ppm). This implies that the residual magma directly formed the orebody of rare metal elements. Meanwhile, volatility was increasing during the magma evolution process and F‐bearing aqueous fluid was oversaturated at temperatures higher than 800°C. The separation of fluid from magma caused Li‐REE enrichment in F‐bearing fluid and depletion in residual melt, and led to the difference of the Y/Ho ratio between whole rock compositions and melt inclusion data. Fluid separated into a high‐salinity liquid and a low density vapor phase above 697°C, and enriched REE in the high‐salinity liquid. The oxygen isotope data shows mixing between primary magmatic‐hydrothermal fluid and meteoric water. The ubiquitous pseudo‐secondary fluid inclusions have a wide range of salinity below 462°C, which is similar to the melting temperatures of REE‐bearing daughter minerals. A model involving the mixing by meteoric water could be a mechanism for precipitation of REE minerals.  相似文献   

16.
Petrographic observations on quartz crystals from the Mole Granite (Australia) and other localities shed new light on the mechanisms of post-entrapment modification of fluid inclusions. These modifications include migration away from pseudosecondary trails, changes in fluid salinity and density, shape distortion and the formation of “sweat-haloes” around strongly deformed inclusions. Increases in fluid salinity, which usually are associated with inclusion migration, indicate water-losses of up to 50%. However, LA-ICP-MS-analysis of unmobilized and mobilized inclusions of the same trail reveals basically unchanged ratios of major – and trace element cations, with the exception of Li, which seems to be incorporated into the crystal lattice during migration. Despite the fact that all these modifications are closely related to deformation processes, they occur not only in mechanically deformed quartz, but also in free-standing crystals. In the latter samples, stress has been generated internally as a result of brazil-twinned growth and compositional zonation. These observations and their interpretation leads to a list of practical criteria that should help in differentiating between reliable and suspect fluid inclusions in other samples. Received: 17 November 1998 / Accepted: 16 April 1999  相似文献   

17.
跃进山小型矽卡岩型铜金矿床位于完达山地体西南部,矿体主要赋存于矽卡岩、花岗斑岩及其构造裂隙中,呈扁豆状或脉状。本文对矿区花岗闪长岩和花岗斑岩进行锆石U-Pb年代学和岩石地球化学研究,以了解矿床形成时代、成岩（矿）构造背景及矿床成因。测年结果表明,花岗斑岩和花岗闪长岩成岩年龄分别为（115.8±1.0）Ma和（126.9±1.7）Ma,铜金矿化时代与花岗斑岩成岩时代基本一致,为早白垩世晚期。岩石地球化学研究表明,花岗闪长岩属过铝质钙碱性系列岩石,稀土配分模式图为轻稀土富集,重稀土亏损,具较强的铕负异常,无铈异常,岩浆主要来源于壳源物质;花岗斑岩属过铝质钙碱性系列岩石,轻稀土富集,重稀土亏损,具弱铕负异常,无铈异常,相对富集大离子亲石元素（Rb、Ba、K、Sr）和不相容元素（U、Th）,亏损高场强元素（Ta、Nb、P、Ti）和HREE,岩浆来源于壳幔物质混合源区,形成于碰撞后构造环境,成岩成矿作用与太平洋板块强烈俯冲作用后的伸展体制密切相关。  相似文献   

18.
We performed high strain (up to 47 %) axial compression experiments on natural quartz single crystals with added rutile powder (TiO2) and ~0.2 wt% H2O to investigate the effects of deformation on the titanium-in-quartz (TitaniQ) geothermobarometer. One of the objectives was to study the relationships between different deformation mechanisms and incorporation of Ti into recrystallized quartz grains. Experiments were performed in a Griggs-type solid-medium deformation apparatus at confining pressures of 1.0–1.5 GPa and temperatures of 800–1,000 °C, at constant strain rates of 1 × 10?6 or 1 × 10?7 s?1. Mobility of Ti in the fluid phase and saturation of rutile at grain boundaries during the deformation experiments are indicated by precipitation of secondary rutile in cracks and along the grain boundaries of newly recrystallized quartz grains. Microstructural analysis by light and scanning electron microscopy (the latter including electron backscatter diffraction mapping of grain misorientations) shows that the strongly deformed quartz single crystals contain a wide variety of deformation microstructures and shows evidence for subgrain rotation (SGR) and grain boundary migration recrystallization (GBMR). In addition, substantial grain growth occurred in annealing experiments after deformation. The GBMR and grain growth are evidence of moving grain boundaries, a microstructure favored by high temperatures. Electron microprobe analysis shows no significant increase in Ti content in recrystallized quartz grains formed by SGR or by GBMR, nor in grains grown by annealing. This result indicates that neither SGR nor moving grain boundaries during GBMR and grain growth are adequate processes to facilitate re-equilibration of the Ti content in experimentally deformed quartz crystals at the investigated conditions. More generally, our results suggest that exchange of Ti in quartz at low H2O contents (which may be realistic for natural deformation conditions) is still not fully understood. Thus, the application of the TitaniQ geothermobarometer to deformed metamorphic rocks at low fluid contents may not be as straightforward as previously thought and requires further research.  相似文献   

19.
Unidirectional solidification texture (UST) in an aplite body is recognized in the Neoproterozoic highly differentiated granitic rocks at Kharaatyagaan, central Mongolia. On the basis of crystal morphology, two main types of UST were identified in the aplite body: (i) thin crenulate UST layers; and (ii) thick intergrowth UST layers. Bulk geochemistry indicates that the Kharaatyagaan UST‐bearing aplite and aplite dike are alkaline, and are enriched in light rare‐earth elements. Scanning electron microscopy and cathadoluminescence imaging of UST quartz from Kharaatyagaan show four types of quartz: euhedral quartz phenocrysts with well‐developed concentric growth zoning (Qa1) in the aplite; euhedral quartz with weak growth zoning in the aplite (Qa2); UST quartz exhibiting distinct growth zones (Qu1); and UST quartz showing mosaic texture (Qu2). Crystallization temperatures determined by the Ti‐in‐quartz geothermometer of Qa1 and Qu1 quartz range between around 500°C and 780°C and Qa2 and Qu2 range between about 490° and 630°C. The cathodoluminescence textures of quartz are predominantly caused by variations in the trace elements contents of quartz. The Qa1 and Qu1 quartz crystals are characterized by high Ti and Al concentrations in the quartz lattice, and are observed in the bottom of the Kharaatyagaan hill, which formed in the early, less evolved magmatic stage. The Qa2 and Qu2 UST quartz characterized by low Ti and variable Al concentrations are found at the top. The UST layers crystallized along the upper part of the magma chamber in the presence of fluid phases exsolved from felsic magma.  相似文献   

20.
The Xiaojiashan tungsten deposit is located about 200 km northwest of Hami City, the Eastern Tianshan orogenic belt, Xinjiang, northwestern China, and is a quartz vein‐type tungsten deposit. Combined fluid inclusion microthermometry, host rock geochemistry, and H–O isotopic compositions are used to constrain the ore genesis and tectonic setting of the Xiaojiashan tungsten deposit. The orebodies occur in granite intrusions adjacent to the metamorphic crystal tuff, which consists of the second lithological section of the first Sub‐Formation of the Dananhu Formation (D2d 12). Biotite granite is the most widely distributed intrusive bodies in the Xiaojiashan tungsten deposit. Altered diorite and metamorphic crystal tuff are the main surrounding rocks. The granite belongs to peraluminous A‐type granite with high potassic calc‐alkaline series, and all rocks show light Rare Earth Element (REE)‐enriched patterns. The trace element characters suggest that crystallization differentiation might even occur in the diagenetic process. The granite belongs to postcollisional extension granite, and the rocks formed in an extensional tectonic environment, which might result from magma activity in such an extensional tectonic environment. Tungsten‐bearing quartz veins are divided into gray quartz vein and white quartz veins. Based on petrography observation, fluid inclusions in both kinds of vein quartz are mainly aqueous inclusions. Microthermometry shows that gray quartz veins have 143–354°C of Th, and white quartz veins have 154–312°C of Th. The laser‐Raman test shows that CO2 is found in fluid inclusions of the tungsten‐bearing quartz veins. Quadrupole mass spectrometry reveals that fluid inclusions contain major vapor‐phase contents of CO2, H2O. Meanwhile, fluid inclusions contain major liquid‐phase contents of Cl?, Na+. It can be speculated that the ore‐forming fluid of the Xiaojiashan tungsten deposit is characterized by an H2O–CO2, low salinity, and H2O–CO2–NaCl system. The range of hydrogen and oxygen isotope compositions indicated that the ore‐forming fluids of the tungsten deposit were mainly magmatic water. The ore‐forming age of the Xiaojiashan deposit should to be ~227 Ma. During the ore‐forming process, the magmatic water had separated from magmatic intrusions, and the ore‐bearing complex was taken to a portion where tungsten‐bearing ores could be mineralized. The magmatic fluid was mixed by meteoric water in the late stage.  相似文献   

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