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1.
Within the framework of Pitzer's specific interaction model, interaction parameters for aqueous silica in concentrated electrolyte solutions have been derived from Marshall and co-authors amorphous silica solubility measurements. The values, at 25°C, of the Pitzer interaction parameter (λ SiO2(aq)−i) determined in this study are the following: 0.092 (i = Na +), 0.032 (K +), 0.165 (Li +), 0.292 (Ca 2+, Mg 2+), −0.139 (SO 42−), and −0.009 (NO 3−). A set of polynomial equations has been derived which can be used to calculate λ SiO2(aq)−i for these ions at any temperature up to 250°C. A linear relationship between the aqueous silica-ion interaction parameters (λ SiO2(aq)−i) and the surface electrostatic field ( Zi/ re,i) of ions was obtained. This empirical equation can be used to estimate, in first approximation, λ SiO2(aq)−i if no measurements are available. From this parameterisation, the calculated activity coefficient of aqueous silica is 2.52 at 25°C and 1.45 at 250°C in 5 m NaCl solution. At lower concentrations, e.g. 2 m NaCl, the activity coefficient of silica is 1.45 at 25°C and 1.2 at 250°C. Hence, in practice, it is necessary to take into account the activity coefficient of aqueous silica (λ SiO2(aq)≠1) in hydrothermal solutions and basinal brines where the ionic strength exceeds 1. A comparison of measured [Marshall, W.L., Chen, C.-T.A., 1982. Amorphous silica solubilities, V. Prediction of solubility behaviour in aqueous mixed electrolyte solutions to 300°C. Geochim. Cosmochim. Acta 46, 289–291.] and computed amorphous silica solubility, using this parameterisation, shows a good agreement. Because the effect of individual ions on silicate and silica polymorph solubilities are additive, the present study has permitted to derive Pitzer interaction parameters that allow a precise computation of γ SiO2(aq) in the Na---K---Ca---Mg---Cl---SO 4---HCO 3---SiO 2---H 2O system, over a large range of salt concentrations and up to temperatures of 250°C. 相似文献
2.
Vicksburg loess is characterized by preferred orientation of constituent grains, which on the average dip 4° toward the west (N 80–85°W). This investigation was undertaken to study, quantitatively, the relationship between natural fabric anisotropies of Vicksburg loess and the orientation of applied stress distribution Results of the study indicate the fabric anisotropies in Vicksburg loess are reflected by definite variation in triaxial shear strength of dry and moist specimens. In two series of triaxial tests, ultimate strength of the loess is maximum where σ1 is perpendicular to grain orientation, and it is reduced where the principal stresses are 45° to the fabric plane. In this respect, Vicksburg loess may serve as a structural model for granular earth materials in illustrating the influence of fabric on ultimate strength. Moreover, the Mohr-Coulomb fracture line consists of two line segments, with an increase in slope at higher confining pressure. This characteristic suggests that poorly-cemented sands, or sandstones, and silts, or siltstones, may undergo two failures: one at small strains where cement bonds are disrupted and the other at larger strains where internal shearing resistance of granular components is exceeded. 相似文献
3.
Feda, J., 1988. Collapse of loess upon wetting. Eng. Geol., 25: 263–269. The results of a series of tests conducted on loess samples from one locality, tested under the condition of confined and hydrostatic compression are presented and analyzed. The samples are of different water content and saturation and display different degrees of collapse upon wetting. Based on the experimental results, a collapse surface is depicted and the phenomenon hypothetically generalized for other types of collapse. The structural collapse causes the mechanical behaviour of samples to be more uniform. The effect of the hydrostatic stress conditions is reflected in the tendency of samples to deform isotropically, although, originally, they are anisotropic. The phenomenon of collapse cannot be explained by the principle of effective stresses. 相似文献
4.
Milovic, D., 1988. Stress deformation properties of macroporous loess soils. Eng. Geol., 25: 283–302. Herein are presented the results of laboratory and field tests which were carried out on loess in Yugoslavia. Experience gained during recent decades show that the loess soil in some cases undergoes structural collapse and subsidence due to inundation. In order to find the explanation of such behaviour, numerous laboratory and field load tests on loess soil have been performed. Using the obtained results, several correlations have been established. On the basis of the unconfined test results, a correlation between the initial dry density, initial water content and unconfined compression strength has been established. A relatively large number of the consolidation subsidence tests (about 550), carried out on undisturbed loess samples, made possible the determination of the degree of subsidence and the corresponding values of the dimensionless coefficients of subsidence. These coefficients have been determined for several values of the initial dry density, for various degrees of saturation and for several stress levels upon wetting. Using these coefficients, the values of the additional settlement caused by flooding of loess under the foundation can easily be calculated. It is of particular interest to note that, in general, water penetrates under one part of the building, producing differential settlements, which are in most cases very dangerous. By the comparative laboratory investigation of the undisturbed loess samples obtained by thin walled sampler and samples obtained from pits, it has been shown that the mechanical disturbance is an extremely important factor which governs the shear and deformation parameters of loess soils. The laboratory test results obtained on undisturbed loess samples, cut from blocks in the vertical and horizontal direction, have shown that this soil exhibits anisotropic properties. For this reason a stress deformation problem in an anisotropic medium has been treated by the finite element method. Static penetration tests and field load tests in loess soils with natural water content and also after saturation have been performed and are described. The results of the observed settlements for two statically identical multi-storey buildings are also presented. Using the coefficients of subsidence for the undisturbed samples cut from blocks, very good agreement between the calculated and the observed settlements has been obtained. 相似文献
5.
Rendell, H.M., 1988. Comparison between naturally consolidated and laboratory consolidated loess. Eng. Geol., 25: 229–233. Preliminary results of a comparison between naturally consolidated and laboratory consolidated loess are presented. Mercury intrusion porosimetry was used to compare nominal pore size distributions of loess before and after laboratory consolidation with those for samples that had undergone “natural” compaction. Although changes in density appear to be modelled well by the oedometer tests, the pore size distributions approach, they do not mirror exactly those for naturally consolidated loess. 相似文献
6.
Lateral stresses existing in soil deposits are important clues to recent stress history because they tend to remain “locked in” following adjustments in the overburden load: Thus a high lateral stress is partly retained following a reduction in vertical stress, as by glacial melting or erosion. Conversely, during loess deposition a low lateral stress should be retained if the soil structure is preserved under increasing vertical stress. This has not previously been verified in the field because of the difficulty of measuring lateral stresses in situ in an hydrocollapsible material. Tests were conducted at two sites in Missouri river valley loess using theKo Stepped Blade, which uses data extrapolation to give stress on a zero thickness blade. In basal loess where the moisture content was at or above the liquid limit,Ko = 1.0 ± 0.02. In the upper to middle loess zoneKo is as low as 0.2 to 0.4, lower than the values of 0.4 to 0.5 that would be expected if the soil were normally consolidated. Near the ground surface, lateral stresses are higher soKo > 1, attributed to post-depositional weathering and the presence of smectite clay minerals. The vertical sequence of lateral stress from high to low to high again should contribute a tension-induced cleavage if lateral confinement is removed by excavation or erosion. This stress condition is most pronounced in loess close to its source, where the potential tension zone was found to extend to a depth of about 7 m compared to 4 m at the other site. Loess cleavage appears to result from stress relief and is not a unique directional property of this material. 相似文献
7.
为了研究陕西省杨凌示范区黄土边坡的稳定性,采用改进的应力型三轴蠕变仪对所取黄土试样进行了一系列室内三轴固结不排水蠕变试验。试验结果表明：含水率、干密度、偏应力水平对黄土的蠕变特性均有较大的影响,表现为含水率一定,偏应力愈大时,黄土的蠕变变形量较小;偏应力水平一定时,含水率愈大,蠕变现象愈明显,产生的蠕变应变量愈大;其他条件相同时,干密度愈大,黄土试样的蠕变变形愈小。在黄土边坡治理工程中可通过改善边坡排水和增加边坡土体压实情况减小蠕变破坏的可能性。通过对试验数据分析得出了适合杨凌地区黄土的经验蠕变模型,通过与Singh-Mitchell模型和Mesri模型的比较发现,该模型具有精度高、参数少且易获取的优点,并能很好地描述黄土的蠕变特性。 相似文献
8.
Trace element partition coefficients ( D's) for up to 13 REE, Nb, Ta, Zr, Hf, Sr and Y have been determined by SIMS analysis of seven garnets, four clinopyroxenes, one orthopyroxene and one phlogopite crystallized from an undoped basanite and a lightly doped (200 ppm Nb, Ta and Hf) quartz tholeiite. Experiments were conducted at 2–7.5 GPa, achieving near-liquidus crystallization at relatively low temperatures of 1080–1200°C under strongly hydrous conditions (5–27 wt.% added water). Garnet and pyroxene DREE show a parabolic pattern when plotted against ionic radius, and conform closely to the lattice strain model of Blundy and Wood (Blundy, J.D., Wood, B.J., 1994. Prediction of crystal–melt partition coefficients from elastic moduli. Nature 372, 452–454). Comparison, at constant pressure, between hydrous and anhydrous values of the strain-free partition coefficient ( D0) for the large cation sites of garnet and clinopyroxene reveals the relative importance of temperature and melt water content on partitioning. In the case of garnet, the effect of lower temperature, which serves to increase D0, and higher water content, which serves to decrease D0, counteract each other to the extent that water has little effect on garnet–melt D0 values. In contrast, the effect of water on clinopyroxene–melt D0 overwhelms the effect of temperature, such that D0 is significantly lower under hydrous conditions. For both minerals, however, the lower temperature of the hydrous experiments tends to tighten the partitioning parabolas, increasing fractionation of light from heavy REE compared to anhydrous experiments. Three sets of near-liquidus clinopyroxene–garnet two-mineral D values increase the range of published experimental determinations, but show significant differences from natural two-mineral D's determined for subsolidus mineral pairs. Similar behaviour is observed for the first experimental data for orthopyroxene–clinopyroxene two-mineral D's when compared with natural data. These differences are in large part of a consequence of the subsolidus equilibration temperatures and compositions of natural mineral pairs. Great care should therefore be taken when using natural mineral–mineral partition coefficients to interpret magmatic processes. The new data for strongly hydrous compositions suggest that fractionation of Zr–Hf–Sm by garnet decreases with increasing depth. Thus, melts leaving a garnet-dominated residuum at depths of about 200 km or greater may preserve source Zr/Hf and Hf/Sm. This contrasts with melting at shallower depths where both garnet and clinopyroxene will cause Zr–Hf–Sm fractionation. Also, at shallower depths, clinopyroxene-dominated fractionation may produce a positive Sr spike in melts from spinel lherzolite, but for garnet lherzolite melting, no Sr spike will result. Conversely, clinopyroxene megacrysts with negative Sr spikes may crystallize from magmas without anomalous Sr contents when plotted on mantle compatibility diagrams. Because the characteristics of strongly hydrous silicate melt and solute-rich aqueous fluid converge at high pressure, the hydrous data presented here are particularly pertinent to modelling processes in subduction zones, where aqueous fluids may have an important metasomatic role. 相似文献
9.
Saye, S.R., Nass, K.H. and Easton, C.N., 1988. Performance of heavy structures founded upon loess at varying moisture conditions. Eng. Geol., 25: 325–339. The site preparation for foundations and records of performance of three storage structures founded on loess are presented to illustrate the engineering problems and the range in compressibility of loess associated with different moisture conditions. The sites are located in western Iowa and eastern Nebraska. The structures are a 7500 m3 capacity steel water storage reservoir founded on dry collapsible loess along the bluff line of the Missouri River; a 7200 m3 capacity concrete grain elevator supported by a rigid mat founded on saturated and partially saturated loess; and a 10 m high soil preload for a 54 m diameter ammonia storage tank underlain by saturated and partially saturated loess. The foundation design, the site preparation and the observed settlements are presented for each structure. The settlement behavior varies markedly with the individual moisture conditions and the apparent preconsolidation of the loess. The apparent preconsolidation is attributed to desiccation and appears to vary systematically. 相似文献
10.
The potential of marble dust as a stabilizing additive to red tropical soils was evaluated. The evaluation involved the determination of the geotechnical properties of three different red tropical soils in their natural state as well as when mixed with varying proportions of marble dust. The parameters tested included the particle size distribution, specific gravity, Atterberg limits, the standard compaction characteristics, the compressive strength and the California bearing ratio (CBR). The strength tests were repeated after normal 28 day curing of the treated samples and also after accelerated 24 h curing at temperatures of 40°C, 60°C and 80°C. Results showed that the geotechnical parameters of red tropical soils are improved substantially by the addition of marble dust; plasticity was reduced by 20 to 33% and strength and CBR increased by 30 to 46% and 27 to 55% respectively. The highest strength and CBR values were achieved at 8% marble dust. Results also showed that normal 28 day curing improved the strength of the marble dust-treated soil with over 80% strength gain achieved after 7 to 10 days of normal curing. Higher strength development was realised following accelerated 24 h curing at 60°C. Although these results imply marked improvement in the geotechnical parameters of red tropical soils, the higher strength developed is not enough for the improved soil to be used as a base material in the construction of heavily trafficked flexible pavements. The improved material may, however, be successfully used as base material for lightly trafficked roads and as a sub-base material for heavily trafficked roads. 相似文献
11.
We conducted a series of melting experiments in the join forsterite–diopside–leucite under 0.1 and 2.3 GPa and in the join forsterite–leucite–åkermanite under 2.3 GPa to understand paragenetic relationships amongst different types of lamproitic and lamprophyric magmas with K-rich mafic and ultramafic volcanic (kamafugitic) rocks. Both the joins were studied in the presence of excess water. The experimental results of the join forsterite–diopside–leucite at 0.1 GPa show that the five-phase point of forsterite (Fo) ss + diopside (Di) ss + leucite (Lc) ss + liquid (Liq) + vapour (V) (equivalent to ugandite lava) occurs at Fo 2Di 50Lc 48 at 880 ± 5 °C. Phlogopite appears as the last phase at 830 ± 15 °C. The final crystalline assemblage of forsterite ss + diopside ss + leucite ss + phlogopite is similar to the phenocryst assemblage of missourite lava. Present study suggests that an olivine leucitite (ugandite) can be derived from an olivine italite, a slightly potassic peridotite and a leucitite magma. A study of the join Fo–Di–Lc [P(H2O) = P(Total)] at 2.3 GPa shows that liquid compositions penetrate the primary phase volumes of forsteritess, phlogopitess, kalsilitess, K-feldsparss and diopsidess. It has the following three five-phase points: 1) one occurring at Fo9Di49Lc42 and 1005 ± 5 °C, where liquid and vapour coexists with forsteritess, phlogopitess and diopsidess (phlogopite-bearing madupite), 2) the second one at Fo4Di50Lc46 and 990 ± 10 °C, where diopsidess, K-feldsparss and phlogopitess coexist with liquid and vapour (pyroxene-bearing minette), and 3) the third one at Fo3Di21Lc76 and 775 ± 5 °C, where phlogopitess, kalsilitess and K-feldsparss are in equilibrium with liquid plus vapour (kalsilite-bearing minette). The experimental results of the join Fo–Lc–åkermanite (Ak) show that the join 40 penetrates the primary phase volumes of forsteritess, phlogopitess, kalsilite, K-feldsparss, diopsidess and merwinitess. The data indicate the presence of four five-phase points: 1) one occurring at Fo7Lc42Ak51 and 1165 ± 5 °C, where phlogopitess, forsteritess, diopsidess coexists with liquid and vapour (olivine-bearing madupite), 2) the second one at Fo3Lc49Ak48 and 1140 ± 10 °C, where a liquid is in equilibrium with phlogopitess, K-feldsparss, diopsidess and vapour (pyroxene-bearing minette), 3) the third one at Fo18Lc21Ak61 and 1255 ± 10 °C, where merwinitess, forsteritess and diopsidess are in equilibrium with liquid and vapour (merwinite-bearing wherlite), and 4) the fourth one at Fo5Lc73.5Ak21.5 and 770 ± 5 °C, where kalsilitess, phlogopitess and K-feldspar coexist with liquid and vapour (kalsilite-bearing minette). The present data suggest that high pressure heteromorphic equivalent of a katungite magma is represented by a kalsilite-bearing minette, a pyroxene-bearing minette, or an olivine-bearing madupite. 相似文献
12.
In low-temperature aqueous solutions (< 100°C, pH 2–4.5), chalcopyrite (CuFeS 2) does not form through direct precipitation from solution. The pathway is exclusively via precursor iron sulphides and dissolved Cu salts. The reaction of dissolved Cu (II) salts with natural hexagonal pyrrhotite (Fe 0.9S) is diffusion controlled. The initial stage has an apparent activation energy of 11.4 ± 1.8 kJ mol −1 and the rate (in units of mol dm −3s −1 cm −2) is independent of the solid reactant surface area. The reaction proceeds through a series of metastable Cu-Fe-sulphide intermediaries. These phases form a series of ephemeral layers penetrating into the pyrrhotite surface. The first phase formed has the stoichiometry Cu 0.1Fe 0.9S. No Fe is released into the solution during its formation and this, together with the extremely low apparent activation energy and the stoichiometry, suggest that it is formed by stuffing of electron holes in the pyrrhotite structure with Cu ions. The transformation from the hexagonal close-packed arrangement of the pyrrhotite structure to the essentially cubic packing in chalcopyrite proceeds through a series of intermediaries, approximating in composition to members of the cubanite group. The rate of formation of these phases is controlled by the coupled diffusion of Fe (II), Fe (III), Cu (I) and Cu (II) species through the surface reaction zone, although the process as a whole can be approximated by steady-state diffusion of total Cu into a semi-infinite medium. Experiments with metastable precursor iron monosulphide phases, including amorphous FeS and synthetic mackinawite indicate similar reaction pathways. The results suggest that chalcopyrite formation in low-temperature natural systems may be significantly constrained by kinetic factors. Chalcopyrite is, at least, a diagenetic mineral since its formation requires the prior formation of iron sulphides. However, at ambient temperatures its formation is probably limited to very early diagenesis. 相似文献
13.
Loess as a typically subaerial, loess deposit has long been regarded a Pleistocene sediment and its date of formation has been put to ca 600 ka BP. Recently, the beginning of the Pleistocene is identified in the official concord reached — at 1.6 Ma BP, while not infrequently others propose 2.4 Ma BP. Until the fifties the whole loess (loess-paleosol-sand) sequence could be referred into the shorter Pleistocene period, which —according to the climatic claendar by Milankovitch — consisted of nine cold and eight warm intervals. Some supporters of the longer Pleistocene chronology hold that the beginning of loess formation can be put as far back as 1.6 – 2.4 Ma BP. Loess formation intervals are usually correlated with the cold stages (nos 2, 4, 6 etc.) of the Emiliani oxygen isotope timescale, while soil formation is believed to correspond to the warm stages (nos 1, 3, 5, 7 etc.). The typical loess, i. e. loess proper, are not older than stage no 23 (Jaramillo event — 0.96 Ma BP). Previous to this date climatic conditions had not generally favoured loess formation and paleosols formed one above the other with clay, loam or carbonate intercalations. 相似文献
14.
Peridotitic clinopyroxene (cpx) and pyrope garnet xenocrysts from four kimberlite pipes in the Kaavi–Kuopio area of Eastern Finland have been studied using major and trace element geochemistry to obtain information on the vertical compositional variability of the underlying mantle. The xenocryst data, when combined with the petrological constraints provided by peridotite xenoliths, yield a relatively complete section through the lithospheric mantle. Single-grain cpx thermobarometry fits with a 36-mW/m 2 geotherm calculated using heat flow constraints and xenolith modes and geophysical properties. Ni thermometry on pyrope xenocrysts gives 700–1350 °C and, based on the cpx xenocryst/xenolith geotherm, indicates a wide sampling interval, ca. 80–230 km. Plotting pyrope major and trace element compositions as a function of temperature shows there are three distinct layers in the local lithospheric mantle: - (1) A low-temperature (<850 °C) harzburgite layer distinguished by Ca-rich but Ti-, Y- and Zr-depleted pyropes. The xenoliths originating from this layer are all fine-grained garnet-spinel harzburgites with secondary cpx.
- (2) A variably depleted lherzolitic, harzburgitic and wehrlitic horizon from 950 to 1150 °C or 130 to 180 km.
- (3) A deep layer from 180 to 240 km composed largely of fertile material.
The peridotitic diamond window at Kaavi–Kuopio stretches from the top of the diamond stability field at 140 km to the base of the harzburgite-bearing mantle at about 180 km, implying a roughly 40-km-wide prospective zone. 相似文献
15.
Experiments in which cleavage nepheline samples were reacted with aqueous solutions at fixed pH's and temperature were carried out in the laboratory. The chemistry of the solution as a function of time was monitored, as well as the chemistry of the nepheline surfaces. At 25°C, Al derived from the nepheline stays in solution due to slow precipitation kinetics of Al(OH)3. At 60° and 80°C, precipitation of Al(OH)3 is so rapid that Al concentration in solution is below 0.05 ppm. This indicates that precipitation kinetics favour the formation of bauxite deposits in tropical regions (i.e. T25°C), but not in temperate regions. Precipitation products on the surface of the nepheline fragments at 60° and 80°C depend on the pH. At pH 3.0, an amorphous aluminium silicate (proto-kaolinite?) is formed. At pH>7.0, the precipitated phase contains, in addition to Al and Si, high amounts of Na and K (proto-muscovite?). The optimum pH for the formation of bauxite is in the range 5–7. These results are in agreement with thermodynamic calculations. 相似文献
16.
Lutenegger, A.J. and Hallberg, G.R., 1988. Stability of loess. Eng. Geol., 25: 247–261. The natural stability of loess soils can be related to fundamental geotechnical properties such as Atterberg limits, water content and void ratio. Field observations of unstable conditions in loess deposits in the upper midwest, U.S.A. show relationships between instability and the in situ moisture content and the liquidity index of the loess. Unstable loess can attain natural moisture contents equal to, or greater than, its liquid limit. Implications of these observations for applied engineering works are described. 相似文献
17.
A brief review is presented of my efforts to improve the accuracy of dating unheated sediments by TL and of the development of a new tephrochronometer. Specific applications to known-age deposits are outlined, as are studies of the depositional environment of subaqueous sediments. Removal of anomalous fading in loess by storage at 75°C for 8 days is demostrated.Throughout, for unheated sediments the preferential use of the partial bleach (R-gamma or R-beta) technique is emphasized, especially in situations where the growth curves are sublinear. Contrary to a widespread misconception, sublinearity does not invalidate the partial bleach method. Furthermore, examples are given of TL ‘sensitivity’ (or ‘efficiency’) changes occurring with the regeneration technique — changes that are variable and seemingly sample dependent. 相似文献
18.
Four stratigraphic sections in the southern part of the Columbia Basin preserve a sequence of aeolian and non-aeolian sediments ranging in age from 9·43 to >47·0 14C ka based on accelerator mass spectrometry radiocarbon dating of fossil molluscs, geochemistry of Cascade Mountain-sourced tephra and association with formally recognized pedostratigraphic units (the Washtucna and Old Maid Coulee soils). Study sections are interpreted as representing concurrent deposition of loess and distal Missoula Flood rhythmites in valleys tributary to main drainages backflooded during the Missoula Floods, and formation of carbonate and iron-rich soils. Sediments belong to the formally recognized L-1 and L-2 loess units established for the Palouse loess, which were deposited in the Columbia Basin subsequent to events of glacial outburst flooding. Sediments associated with the Mount Saint Helens set S and set C tephras in the study sections preserve a fauna of five species of gastropod mollusc which have not been reported previously from sediments of late Pleistocene age in the Palouse region. The fossils comprise two distinct faunules stratigraphically separated by the Mount Saint Helens So tephra. Accelerator mass spectrometry radiocarbon dating of the fossils collected above the tephra in two of the sections yielded ages of 12·48 ± 0·06 and 9·43 ± 0·05 14C kyr. These ages suggest that independent determinations of the 13·35 14C kyr age of the So tephra in other areas where Missoula Flood sediments are preserved are probably accurate, and help to refine the age of the latest events in the most recent sequence of catastrophic glacial outburst flooding. 相似文献
19.
We investigate the use of a ductile material with temperature-sensitive viscosity for thermomechanical modelling of the lithosphere. First, we consider the scaling of mechanical and thermal properties. For a normal field of gravity, the balance of stresses and body forces sets the stress scale, in proportion to the linear dimensions and the densities. The equation of thermal conduction sets the time scale. The activation enthalpy for creep sets the temperature scale; but the thermal expansivity provides an additional constraint on this temperature scale. Gum rosin appears to be a suitable material for lithospheric modelling. We have measured its flow properties, at various temperatures, in a specially designed rotary viscometer with unusually low machine friction. The rosin is almost Newtonian. Strain rate depends upon stress to the power n, where 1.0 <n < 1.14. The viscosity varies over 5 orders of magnitude, from about 102 Pa s at 80°C, to about 107 Pa s at 40°C. The activation enthalphy is thus about 250 kJ/mol. Measured with a needle probe, the thermal conductivity is 0.113 ± 0.001 W m−1K−1; the thermal diffusivity, (6±3) ×10−7 m2 s−1. Calculated from X-ray profiles, the thermal expansivity is about 3 × 10−4 K−1. These thermal and mechanical properties make gum rosin suitable for thermomechanical models, where linear dimensions scale down by a factor of 106; time, by 1011; viscosity, by 1017; and temperature change, by 101. 相似文献
20.
We have determined cooling rates of orthopyroxene crystals from two Mg-suite lunar samples (gabbronorite 76255 and troctolite 76535) and one terrestrial sample (orthopyroxenite SC-936 from the Stillwater Complex), on the basis of their Fe–Mg ordering states. In addition, a cooling rate of 76255 was determined by modeling the formation of exsolution lamellae in pyroxenes. The M1–M2 site occupancies of the orthopyroxene crystals were determined by single crystal X-ray diffraction and the rate constant for the ordering reaction was used along with calibrations of the equilibrium intracrystalline fractionation of Fe and Mg as a function of temperature to calculate cooling rates. The closure temperatures ( TC) of cation ordering are 525 °C for 76255, 500 °C for 76535 and 350 °C for SC-936 corresponding to cooling rates of 4 × 10 −2 °C/year at the closure temperature for the lunar samples and 10 −6 °C/year for the Stillwater sample. A cooling rate for 76255, determined by simulating the exsolution process, is 1.7 × 10 −2 °C/year at a closure temperature for exsolution of 700 °C. The Fe–Mg ordering cooling rate determined for 76535 reflects a complex thermal history superimposed on the initial plutonic provenance established for this sample [McCallum, I.S., Schwartz, J.M., 2001. Lunar Mg suite: thermobarometry and petrogenesis of parental magmas. J. Geophys. Res. 106, 27969–27983]. The preservation of a crystallization age of 4.51 Ga and a metamorphic age of 4.25 Ga for 76535 is consistent with a model in which excavation of this sample from the lower lunar crust took place while the sample was at a temperature above the closure temperatures for the Sm–Nd, U–Pb and Ar–Ar isotopic systems. Temperatures in excess of the isotopic closure temperatures (i.e., >600 °C) in the lower lunar crust were maintained by heat diffusing from concentrations of U- and Th-rich KREEP material at the base of the crust. On the other hand, 76255 formed at a much shallower depth in the lunar crust (2 km) and was well below its isotopic closure temperatures at the time of excavation, most likely during the Serenitatis basin-forming impact event. Both lunar samples were reheated during transport to the surface and deposition in hot ejecta blankets. The reheating was short lived but apparently sufficient to redistribute Fe and Mg in M sites in orthopyroxenes. For the lunar samples, the cooling rates based on Fe–Mg ordering represent final stage cooling within an ejecta blanket. 相似文献
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