Temperature and solar zenith angle control of D-region positive ion chemistry     

Jeffrey M. Forbes 《Planetary and Space Science》1982,30(10):1065-1072

A numerical model is utilized to investigate the temperature (T) and solar zenith angle (χ) control of D-region positive ion chemistry between 75 and 90 km. It is assumed that NO^? is the precursor ion in a chain which involves three-body formation of the intermediary cluster ions NO⁺(H₂O)_m?1(X) (m = 1–3), where X can be N₂,O₂, H₂O, or CO₂, switching reactions which convert these weakly bound clusters to hydrates of NO⁺ and reaction of the third hydrate of NO⁺ with H₂O to initiate the chain to form H⁺(H₂O)_n (n = 1–7). Zonal mean and tidal temperatures from rocket observations and theory are synthesized to obtain the best available estimate of mean latitudinal, seasonal and local time variations of temperature in this height region. Relative compositions of NO⁺(H₂O)_m and H⁺(H₂O)_n are found to vary widely over the complete range of realistic conditions; however, the relative ion populations are entirely explicable in terms of the effects of χ and T on the relative life-times of the intermediary ion clusters with respect to recombination, switching and thermal decomposition. For instance, as χ increases (and electron production decreases) beyond 60° for a given temperature, the recombination times of the intermediate ion cluster species lengthen with respect to the formation time of the H⁺ water clusters, causing the relative H⁺ water cluster population to increase and thus raise the level where the cluster ion and NO⁺ concentrations are equal from about 85 km (normal midday) to 90 km. For a given χ the concentrations of NO⁺H₂O and H⁺(H₂O)₄ increase (decrease) for temperatures less than (greater than) 190 and 205 K, respectively. The transition occurs when the temperature becomes sufficiently high that the lifetimes of intermediary ion clusters with respect to thermal decomposition become less than their lifetimes with respect to H₂O switching (which ultimately leads to the third hydrate of NO⁺ and entry into the water chain). At this point, the formation time of H⁺(H₂O)₄ becomes long compared with its lifetime with respect to thermal decomposition and its relative concentration decreases also. Implications of these results with respect to studies of the D-region are discussed.  相似文献   

Electronic Sputtering Analysis of Astrophysical Ices     

L. S. Farenzena  P. Iza  R. Martinez  F. A. Fernandez-Lima  E. Seperuelo Duarte  G. S. Faraudo  C. R. Ponciano  M. G. P. Homem  A. Naves de Brito  K. Wien  E. F. da Silveira 《Earth, Moon, and Planets》2005,97(3-4):311-329

Experimental results on fast ion collision with icy surfaces having astrophysical interest are presented. ²⁵²Cf fission fragments projectiles were used to induce ejection of ionized material from H₂O, CO₂, CO, NH₃, N₂, O₂ and Ar ices; the secondary ions were identified by time-of-flight mass spectrometry. It is observed that all the bombarded frozen gas targets emit cluster ions which have the structure X_nR^±, where X is the neutral ice molecule and R^± is either an atomic or a molecular ion. The shape of the positive or negative ion mass spectra is characterized by a decreasing yield as the emitted ion mass increases and is generally described by the sum of two exponential functions. The positive ion water ice spectrum is dominated by the series (H₂O)_nH₃O⁺ and the negative ion spectrum by the series (H₂O)_nOH⁻ and (H₂O)_nO⁻. The positive ion CO₂ ice spectrum is characterized by R⁺ = C⁺, O⁺, CO⁺, O₂⁺ or CO₂⁺ and the negative one by R⁻ = CO₃⁻. The dominant series for ammonia ice correspond to R⁺ = NH₄⁺ and to R⁻ = NH₂⁻. The oxygen series are better described by (O₃)_nO_m⁺ secondary ions where m = 1, 2 or 3. Two positive ion series exist for N₂ ice: (N₂)_nN₂⁺ and (N₂)_nN⁺. For argon positive secondary ions, only the (Ar)_nAr⁺ series was observed. Most of the detected molecular ions were formed by one-step reactions. Ice temperature was varied from ∼20 K to complete sublimation.  相似文献   

Time dependent studies of the aurora—I. Ion density and composition     

R.A. Jones  M.H. Rees 《Planetary and Space Science》1973,21(4):537-557

Ion densities and composition are investigated in a time varying model aurora. There is a time lag between turning on the source of ionization and the resulting increase in ion densities that depends on the species and the height level in the ionsophere, so that altitude profiles of auroral electron densities evolve with time. Characteristic buildup times for the ionization are a few seconds at the altitude of maximum energy deposition, increasing to tens of seconds above and below this level. A wide range of composition ratios, n(NO⁺/n(O₂⁺ and n(NO⁺/n(O⁺), can be expected, depending on the time an observation is made during buildup or decay of ionization. The concentrations of atomic nitrogen and nitric oxide increase as a result of auroral ionization, but the associated characteristic times are long compared to the average duration of ‘auroral event’. Thus, intermittent auroral bombardment could result in a gradual buildup of these minor neutral constituents in the auroral atmosphere. Variations in the electron density during pulsating, fluctuating or coruscating aurora lag the source function variations by a few seconds in a typical aurora.  相似文献   

Radial distribution of production rates, loss rates and densities corresponding to ion masses ?40 amu in the inner coma of Comet Halley: Composition and chemistry     

S.A. Haider 《Icarus》2005,177(1):196-216

In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH₃OH⁺₂, H₃CO⁺, NH⁺₄, H₃S⁺, H₂CN⁺, H₂O⁺, NH⁺₃, CO⁺, C₃H⁺₃, OH⁺, H₃O⁺, CH₃OH⁺, C₃H⁺₄, C₂H⁺₂, C₂H⁺, HCO⁺, S⁺, CH⁺₃, H₂S⁺, O⁺, C⁺, CH⁺₄, C⁺₂, and O⁺₂) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH⁺₄, H₃O⁺, CH₃OH⁺₂, H₃S⁺, H₂CN⁺, and H₂O⁺, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H₃O⁺, CH₃OH⁺₂, H₂O⁺, H₃CO⁺, C₂H⁺₂, and NH⁺₄; along with ions CO⁺, OH⁺, and HCO⁺, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models.  相似文献   

Decrease of ozone and atomic oxygen in the lower mesosphere during a PCA event     

W. Swider  T.J. Keneshea 《Planetary and Space Science》1973,21(11):1969-1973

It is argued that ozone measurements made by Weeks et al. (1972) can be interpreted in terms of the enhanced ionization present. The conversion of O₂⁺ ions to oxonium, H₃O⁺ · (H₂O)_n, ions plus the dissociative recombination of these ions provides for an increased OH and/or H formation rate. The resulting enhanced OH and HO₂ concentrations reduce the ambient atomic oxygen and hence ozone populations. The net excess H + OH formation rate is found to lie between one and two times the ionization production rate at altitudes where oxonium ions are the dominant positive ion species.  相似文献   

The production of water-cluster positive ions in the quiet daytime D region     

George C. Reid 《Planetary and Space Science》1977,25(3):275-290

In the quiet daytime D region, the primary positive-ion species is thought to be NO⁺, produced by solar Lyman-alpha ionization of NO. Below the altitude of the mesopause, however, the dominant ambient species observed are water-cluster ions of the general type H⁺(H₂O)_n. No satisfactory reaction scheme for producing these cluster ions from NO⁺ has yet been proposed. Following earlier suggestions, a model calculation has been carried out in which successive hydrations of NO⁺ take place through clustering with N₂ and CO₂, followed by “switching” reactions with H₂O. The third hydrate of NO⁺ is then converted into the water-cluster species H⁺(H₂O)₃, and the other water-cluster species are produced by successive clustering and thermal breakup reactions. Many of the reactions involved have not been measured in the laboratory, but reasonable estimates of their rates can be made on the basis of existing measurements of other species. Since both temperature and water-vapor content are of major importance in the model, calculations were carried out for two temperature profiles and two water-vapor profiles. It is shown that the results are in reasonably good agreement with observations as far as the water-cluster species are concerned. Under low-temperature conditions, the model predicts relatively large concentrations of various clusters of NO⁺, in agreement with some observations but in disagreement with others. The importance of sampling breakup of these weakly bound clusters, and their relevance to the free electron concentrations are discussed.  相似文献   

Models of the cometary coma in which abundances are calculated for various heliocentric distances     

Michael B. Swift  George F. Mitchell 《Icarus》1981,47(3):412-430

One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H₂O, OH, O, CN, C₂, C₃, CH, and NH₂. Whole-coma abundances are presented for NH₂, CH, C₂, C₃, CN, OH, CO⁺, H₂O⁺, CH⁺, N₂⁺, and CO₂⁺.  相似文献   

Collisional vibrational quenching of O2+(v) and other molecular ions in planetary atmospheres     

H. Böhringer  M. Durup-Ferguson  E.E. Ferguson  D.W. Fahey 《Planetary and Space Science》1983,31(4):483-487

New experimental techniques have yielded several thermal energy vibrational quenching rate constants for O₂⁺(v). Rates for quenching of O₂⁺(v = 1) by O₂, N₂, Ar, CO₂, H₂, and CH₄ are 3(?10), 2(?12), 1(?12), 1(?10), 2.5(?12), and 6(?10) cm³s^?1 at 300 K. The quenching is somewhat faster for O₂⁺(v = 2). The triatomic ions CO₂⁺, NO₂⁺, N₂O⁺, SO₂⁺, and H₂O⁺ are all vibrationally deexcited with an efficiency greater than 10^?3 in Ar or Ne collisions. A theoretical rationalization of the experimental results leads to the prediction that vibrational quenching in planetary atmospheres will generally be efficient, k > 1(?12) cm³s^?1 for almost all ion and neutral gas pairs.  相似文献   

Changes in thermospheric composition inferred from twilight O⁺(²P) emission     

J.F. Noxon  R.B. Norton 《Planetary and Space Science》1979,27(5):653-663

Measurements of the twilight enhancement of airglow emission from O⁺(²P) near 7325 Å reveal major changes which accompany geomagnetic activity, no significant distance between evening and morning and an increase in brightness paralleling the approach to solar maximum. The principal source for O⁺(²P) is direct photoionization from O(³P) but at low solar activity there appears to be a contribution from another source in early twilight which may be local photoelectron ionization into O⁺(²P). The geomagnetic and solar effects appear to reflect changes in the O and N₂ density in the thermosphere; ground based twilight measurements of O⁺ emissions thus provide a simple means for monitoring thermospheric structure from 300 km to ～ 500 km at solar minimum and to ～600 km at solar maximum.  相似文献   

Effects of ion excitation on charge transfer reactions of the Mars, Venus, and Earth ionospheres   总被引：1，自引：0，他引：1  

C. Nicolas  C. Alcaraz  R. ThissenJ. Zabka  O. Dutuit 《Planetary and Space Science》2002,50(9):877-887

The absolute reaction cross sections and reaction rate coefficients as a function of photoionisation energy for 25 ion-molecule reactions (charge transfer reactions except for one) have been measured between the most abundant species present as ions or neutral in the Mars, Venus and Earth ionospheres: O₂, N₂, NO, CO, Ar and CO₂.This study shows the strong influence of electronic as well as vibrational internal energy on most ion-molecule reactions. In particular endothermic charge transfer reactions are driven by electronic excitation of O₂⁺ and NO⁺ ions in their a⁴Π_u and a³Σ⁺ metastable states, respectively. Moreover, it is shown that lifetimes of these metastable states are sufficient to survive the mean free path in the lowest part of ionospheres and therefore express their enhanced reactivity. The reactions of O₂⁺ with NO as well as the reactions of CO₂⁺ with NO, O₂, CO and to a less extent N₂ are driven by vibrational excitation. N₂⁺ and CO⁺ reactions vary much less with photon energy than the other ones, except for the case of reactions with Ar. The effects of the molecular ion internal energy content on their reactivity must be included in the ionospheric models for most of the reactions investigated in the present work. It is also the case for the effect of collision energy on the CO⁺+M reactions as we expect that a significant proportion of these CO⁺ could be produced with translational energy by dissociation of doubly charged CO₂²⁺, in particular in the Mars ionosphere. Recommended effective rate constant values are given as a function of VUV photon energy.  相似文献   

Photochemistry of the stratosphere of Venus: Implications for atmospheric evolution     

Yuk L. Yung  W.B. Demore 《Icarus》1982,51(2):199-247

The photochemistry of the stratosphere of Venus was modeled using an updated and expanded chemical scheme, combined with the results of recent observations and laboratory studies. We examined three models, with H₂ mixing ratio equal to 2 × 10^?5, 5 × 10^?7, and 1 × 10^?13, respectively. All models satisfactorily account for the observations of CO, O₂, O₂(¹Δ), and SO₂ in the stratosphere, but only the last one may be able to account for the diurnal behavior of mesospheric CO and the uv albedo. Oxygen, derived from CO₂ photolysis, is primarily consumed by CO₂ recombination and oxidation of SO₂ to H₂SO₄. Photolysis of HCl in the upper stratosphere provides a major source of odd hydrogen and free chlorine radicals, essential for the catalytic oxidation of CO. Oxidation of SO₂ by O occurs in the lower stratosphere. In the high-H₂ model (model A) the OO bond is broken mainly by S + O₂ and SO + HO₂. In the low-H₂ models additional reactions for breaking the OO bond must be invoked: NO + HO₂ in model B and ClCO + O₂ in model C. It is shown that lightning in the lower atmosphere could provide as much as 30 ppb of NO_x in the stratosphere. Our modeling reveals a number of intriguing similarities, previously unsuspected, between the chemistry of the stratosphere of Venus and that of the Earth. Photochemistry may have played a major role in the evolution of the atmosphere. The current atmosphere, as described by our preferred model, is characterized by an extreme deficiency of hydrogen species, having probably lost the equivalent of 10²–10³ times the present hydrogen content.  相似文献   

Effects of low concentrations of O2 and CO on the ion-clustering reactions in the lower ionosphere of Mars     

L.W. Sieck  R. Gorden  P. Ausloos 《Planetary and Space Science》1973,21(11):2039-2041

It is demonstrated that under conditions which approximate those of the Martian ionosphere traces of CO and O₂ can be effectively incorporated in ion clusters via ion-molecule reaction schemes initiated by the CO₂⁺ ion. For example, when 0.3 % CO is added to CO₂, (CO)₂⁺ and [(CO)₂CO₂]⁺ appear as the major cations (584 Å radiation, 300°K). In mixtures containing O₂ in addition to CO₂ (CO₂. O₂)⁺ and [(CO₂)₂O₂]⁺ are important species. A recently proposed mechanism to account for the low abundance of CO and O₂ in the Martian atmosphere is discussed in the light of these observations.  相似文献   

Ion composition and chemistry in the coma of Comet 1P/Halley—A comparison between Giotto's Ion Mass Spectrometer and our ion-chemical network     

Martin Rubin  Kenneth C. Hansen  Michael R. Combi  Hans Balsiger 《Icarus》2009,199(2):505-519

In order to understand the cometary plasma environment it is important to track the closely linked chemical reactions that dominate ion evolution. We used a coupled MHD ion-chemistry model to analyze previously unpublished Giotto High Intensity Ion Mass Spectrometer (HIS-IMS) data. In this way we study the major species, but we also try to match some minor species like the CH_x and the NH_x groups. Crucial for this match is the model used for the electrons since they are important for ion-electron recombination. To further improve our results we included an enhanced density of supersonic electrons in the ion pile-up region which increases the local electron impact ionization. In this paper we discuss the results for the following important ions: C⁺, CH⁺, CH⁺₂, CH⁺₃, N⁺, NH⁺, NH⁺₂, NH⁺₃, NH⁺₄, O⁺, OH⁺, H₂O⁺, H₃O⁺, CO⁺, HCO⁺, H₃CO⁺, and CH₃OH⁺₂. We also address the inner shock which is very distinctive in our MHD model as well as in the IMS data. It is located just inside the contact surface at approximately 4550 km. Comparisons of the ion bulk flow directions and velocities from our MHD model with the data measured by the HIS-IMS give indication for a solar wind magnetic field direction different from the standard Parker angle at Halley's position. Our ion-chemical network model results are in a good agreement with the experimental data. In order to achieve the presented results we included an additional short lived inner source for the C⁺, CH⁺, and CH⁺₂ ions. Furthermore we performed our simulations with two different production rates to better match the measurements which is an indication for a change and/or an asymmetric pattern (e.g. jets) in the production rate during Giotto's fly-by at Halley's comet.  相似文献   

Recombination rates of O and CO on solid CO2: Implications for the composition of the martian atmosphere     

Dhanwant S. Sethi  Allan L. Smith 《Planetary and Space Science》1975,23(4):661-669

An atomic oxygen flow system and a C¹⁴ radiochemical technique have been used to show that the reactions O + CO → CO₂ and O + O → O₂, are heterogeneously catalysed by solid CO₂ at 77 K.The O-CO recombination is first order in CO and inhibited by O, whereas the O-O recombination is first order in O and weakly inhibited by CO. Assuming simple first order kinetics, recombination coefficients γ_co = 1.3(±0.9) × 10^?5 and γ_O = 0.05± 0.02 are determined. A recombination mechanism involving an intermediate adsorbed CO₃ is proposed. If the kinetic results are assumed to apply under Martian surface conditions, then conversion of CO to CO₂ by reaction on the solid CO₂ at the polar caps occurs at ~10 times the total column recombination rates for homogeneous reactions previously proposed; night-side CO₂ ice clouds would also constitute an important recombination surface.  相似文献   

Mass spectrometric measurements of fractional ion abundances in the stratosphere—Positive ions     

F. Arnold  G. Henschen  E.E. Ferguson 《Planetary and Space Science》1981,29(2):185-193

Measured fractional abundances for stratospheric positive ions are reported for the first time. The measurements which were obtained from balloon-borne ion mass spectrometer experiments relied on recent simulation studies of electric field induced cluster ion dissociation conducted at our laboratory.The ion abundance data provide strong support for identifications of the observed ions as H⁺(H₂O)_n and Hx⁺x_L(H₂O)_m proposed previously. Moreover, it is found that x most likely cannot be identified as NaOH or MgOH which implies that gaseous metal compounds do not exist in the middle stratosphere in significant abundances.Implications of the present findings for the composition and chemistry of stratospheric ions as well as for stratospheric aerosols are discussed.  相似文献   

Representative abundances of a few positive ions in the innermost coma of comet Halley     

P. P. Saxena  Alka Misra 《Earth, Moon, and Planets》1993,60(1):59-68

The production rate of H₂O molecules at a heliocentric distance of 1 AU for comet Halley and the abundance ratio with respect to water (H₂O) of parent molecules at the cometary nucleus from the paper of Yamamoto (1987) have been used to compute the number densities of positive ions viz. H₃O⁺, H₃S⁺, H₂CN⁺, H₃CO⁺, CH₃OH ₂ ⁺ and NH ₄ ⁺ at various cometocentric distances within 600 kms from the nucleus.The role of proton transfer reactions in producing major ionic species is discussed. A major finding of the present investigation is that NH ₄ ⁺ ion which may be produced through proton transfer reactions is the most abundant ion near the nucleus of a comet unless the abundance of NH₃ as a parent is abnormally low. Using the quoted value of Q(NH₃)/Q(H₂O) for comet Halley and the life times of NH₃ and H₂O molecules, the abundance ratio N(NH₃)/N(H₂O) is found to be one-third of that used in the present paper. The consequent proportionate decrease in the NH ₄ ⁺ ions does not, however, affect its superiority in number density over other ions near the nucleus.The number density of the next most abundant ion viz. H₃O⁺ is found to be 4 × 10⁴ cm^-3 at the nucleus of comet Halley and decreases by a factor of two only upto a distance of 600 K ms from the nucleus. The ionic mass peak recorded by VEGA and GIOTTO spacecrafts atm/q = 18 is most probably composite of the minor ionic species H₂O⁺, as its number density = 10² cm^-3 remains virtually constant in the inner coma and of NH ₄ ⁺ , the number density of which at large cometocentric distances may add to the recorded peak atmlq = 18. The number densities of other major ions produced through proton transfer from H₃O⁺ are also discussed in the region within 600 K ms from the nucleus of comet Halley.  相似文献   

The Gas Production Rate and Coma Structure of Comet C/1995 O1 (Hale–Bopp)     

Morgenthaler  Jeffrey P.  Harris  Walter M.  Roesler  Frederick L.  Scherb  Frank  Anderson  Christopher M.  Doane  Nathaniel E.  Oliversen  Ronald J. 《Earth, Moon, and Planets》2002,90(1-4):77-87

The University of Wisconsin–Madison and NASA–Goddard conducted acomprehensive multi-wavelength observing campaign of coma emissionsfrom comet Hale–Bopp, including OH 3080 Å, [O I] 6300 Å H₂O⁺ 6158 Å, H Balmer-α 6563 Å, NH₂ 6330 Å, [C I] 9850 ÅCN 3879 Å, C₂ 5141 Å, C₃ 4062 Å,C I 1657 Å, and the UV and optical continua. In thiswork, we concentrate on the results of the H₂O daughter studies.Our wide-field OH 3080 Å measured flux agrees with other, similarobservations and the expected value calculated from published waterproduction rates using standard H₂O and OH photochemistry.However, the total [O I] 6300 Å flux determined spectroscopically overa similar field-of-view was a factor of 3-4 higher than expected.Narrow-band [O I] images show this excess came from beyond theH₂O scale length, suggesting either a previously unknown source of[O I] or an error in the standard OH + ν→ O(¹ D) + H branching ratio. The Hale–Bopp OH and[O I] distributions, both of which were imaged tocometocentric distances >1 × 10⁶ km, were more spatiallyextended than those of comet Halley (after correcting for brightnessdifferences), suggesting a higher bulk outflow velocity. Evidence ofthe driving mechanism for this outflow is found in the Hα lineprofile, which was narrower than in comet Halley (though likelybecause of opacity effects, not as narrow as predicted by Monte-Carlomodels). This is consistent with greater collisional coupling betweenthe suprathermal H photodissociation products and Hale–Bopp's densecoma. Presumably because of mass loading of the solar wind by ionsand ions by the neutrals, the measured acceleration of H₂O⁺ downthe ion tail was much smaller than in comet Halley. Tailwardextensions in the azimuthal distributions of OH 3080 Å,[O I], and [C I] , as well as a Doppler asymmetry in the[O I] line profile, suggest ion-neutral coupling. While thetailward extension in the OH can be explained by increased neutralacceleration, the [O I] 6300 Å and [C I] 9850 Å emissions show 13%and >200% excesses in this direction (respectively), suggesting anon-negligible contribution from dissociative recombination of CO⁺and/or electron collisional excitation. Thus, models including theeffects of photo- and collisional chemistry are necessary for the fullinterpretation of these data.  相似文献   

Airglow from the inner comas of comets     

T.E. Cravens  A.E.S. Green 《Icarus》1978,33(3):612-623

The intensities of radiation from the inner comas of comets which are composed primarily of water and carbon monoxide have been calculated. Only “airglow” emissions initiated by the absorption of extreme ultraviolet radiation have been considered. The photoionizations of H₂O, CO, CO₂, and N₂ are the most important emission sources, although photoelectron excitation is also considered. Among the emission features for which intensities were calculated are H₂O⁺ ($\text{A}\text{?}{}^2\text{A}{}_{\mathrm{1?}}\text{X}\text{?}{}^2\text{B}{}_1$), CO⁺ (first negative), CO (fourth positive), CO (Cameron), CO₂⁺ ($\text{B}\text{?}{}^2\text{?}{}_{\mathrm{u}}\text{?}\text{X}\text{?}{}^2\text{II}{}_{\mathrm{g}}$), N₂ (Vegard-Kaplan), N₂⁺ (first negative), and OI (1304 Å). In the inner coma (collision region) these airglow mechanisms are shown to be possible competitors with the usually assumed resonance scattering and flourescence excitation mechanisms which are appropriate for the outer coma and tail.  相似文献   

Implications of mass spectrometric measurements on space shuttle     

Edmond Murad 《Planetary and Space Science》1985,33(4):421-423

Mass spectrometric measurements of the neutrals and positive ions in the Space Shuttle environment have indicated the presence of large amounts of contaminants, particularly CO₂⁺ and H₂O⁺. The ionic abundances are analyzed in terms of known ion-neutral kinetics and from this analysis absolute abundances of CO₂ and H₂O are calculated. The implication of these results for optical measurements is considered.  相似文献   

The Origin of Water Vapor and Carbon Dioxide in Jupiter's Stratosphere     

E. LellouchB. Bézard  J.I. MosesG.R. Davis  P. DrossartH. Feuchtgruber  E.A. BerginR. Moreno  T. Encrenaz 《Icarus》2002,159(1):112-131

Observations of H₂O rotational lines from the Infrared Space Observatory (ISO) and the Submillimeter Wave Astronomy Satellite (SWAS) and of the CO₂ ν₂ band by ISO are analyzed jointly to determine the origin of water vapor and carbon dioxide in Jupiter's stratosphere. Simultaneous modelling of ISO/LWS and ISO/SWS observations acquired in 1997 indicates that most of the stratospheric jovian water is restricted to pressures less than 0.5±0.2 mbar, with a disk-averaged column density of (2.0±0.5)×10¹⁵ cm⁻². Disk-resolved observations of CO₂ by ISO/SWS reveal latitudinal variations of the CO₂ abundance, with a decrease of at least a factor of 7 from mid-southern to mid-northern latitudes, and a disk-center column density of (3.4±0.7)×10¹⁴ cm⁻². These results strongly suggest that the observed H₂O and CO₂ primarily result from the production, at midsouthern latitudes, of oxygenated material in the form of CO and H₂O by the Shoemaker-Levy 9 (SL9) impacts in July 1994 and subsequent chemical and transport evolution, rather than from a permanent interplanetary dust particle or satellite source. This conclusion is supported by quantitative evolution model calculations. Given the characteristic vertical mixing times in Jupiter's stratosphere, material deposited at ∼0.1 mbar by the SL9 impacts is indeed expected to diffuse down to the ∼0.5 mbar level after 3 years. A coupled chemical-horizontal transport model indicates that the stability of water vapor against photolysis and conversion to CO₂ is maintained over typically ∼50 years by the decrease of the local CO mixing ratio associated with horizontal spreading. A model with an initial (i.e., SL9-produced) H₂O/CO mass mixing ratio of 0.07, not inconsistent with immediate post-impact observations, matches the observed H₂O abunda nce and CO₂ horizontal distribution 3 years after the impacts. In contrast, the production of CO₂ from SL9-produced CO and a water component deriving from an interplanetary dust component is insufficient to account for the observed CO₂ amounts. The observations can further be used to place a stringent upper limit (8×10⁴ cm⁻² s⁻¹) on the permanent water influx into Jupiter. This may indicate that the much larger flux observed at Saturn derives dominantly from a ring source, or that the ablation of micrometeoroids leads dominantly to different species at Saturn (H₂O) and Jupiter (CO). Finally, the SWAS H₂O spectra do not appear fully consistent with the ISO data and should be confirmed by future ODIN and Herschel observations.  相似文献