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1.
The University of Wisconsin–Madison and NASA–Goddard conducted acomprehensive multi-wavelength observing campaign of coma emissionsfrom comet Hale–Bopp, including OH 3080 Å, [O I] 6300 Å H2O+ 6158 Å, H Balmer-α 6563 Å, NH2 6330 Å, [C I] 9850 ÅCN 3879 Å, C2 5141 Å, C3 4062 Å,C I 1657 Å, and the UV and optical continua. In thiswork, we concentrate on the results of the H2O daughter studies.Our wide-field OH 3080 Å measured flux agrees with other, similarobservations and the expected value calculated from published waterproduction rates using standard H2O and OH photochemistry.However, the total [O I] 6300 Å flux determined spectroscopically overa similar field-of-view was a factor of 3-4 higher than expected.Narrow-band [O I] images show this excess came from beyond theH2O scale length, suggesting either a previously unknown source of[O I] or an error in the standard OH + ν→ O(1 D) + H branching ratio. The Hale–Bopp OH and[O I] distributions, both of which were imaged tocometocentric distances >1 × 106 km, were more spatiallyextended than those of comet Halley (after correcting for brightnessdifferences), suggesting a higher bulk outflow velocity. Evidence ofthe driving mechanism for this outflow is found in the Hα lineprofile, which was narrower than in comet Halley (though likelybecause of opacity effects, not as narrow as predicted by Monte-Carlomodels). This is consistent with greater collisional coupling betweenthe suprathermal H photodissociation products and Hale–Bopp's densecoma. Presumably because of mass loading of the solar wind by ionsand ions by the neutrals, the measured acceleration of H2O+ downthe ion tail was much smaller than in comet Halley. Tailwardextensions in the azimuthal distributions of OH 3080 Å,[O I], and [C I] , as well as a Doppler asymmetry in the[O I] line profile, suggest ion-neutral coupling. While thetailward extension in the OH can be explained by increased neutralacceleration, the [O I] 6300 Å and [C I] 9850 Å emissions show 13%and >200% excesses in this direction (respectively), suggesting anon-negligible contribution from dissociative recombination of CO+and/or electron collisional excitation. Thus, models including theeffects of photo- and collisional chemistry are necessary for the fullinterpretation of these data.  相似文献   

2.
S.A. Haider 《Icarus》2005,177(1):196-216
In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH3OH+2, H3CO+, NH+4, H3S+, H2CN+, H2O+, NH+3, CO+, C3H+3, OH+, H3O+, CH3OH+, C3H+4, C2H+2, C2H+, HCO+, S+, CH+3, H2S+, O+, C+, CH+4, C+2, and O+2) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH+4, H3O+, CH3OH+2, H3S+, H2CN+, and H2O+, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H3O+, CH3OH+2, H2O+, H3CO+, C2H+2, and NH+4; along with ions CO+, OH+, and HCO+, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models.  相似文献   

3.
Lis  D. C.  Mehringer  D. M.  Benford  D.  Gardner  M.  Phillips  T. G.  Bockelée-Morvan  D.  Biver  N.  Colom  P.  Crovisier  J.  Despois  D.  Rauer  H. 《Earth, Moon, and Planets》1997,78(1-3):13-20
We present millimeter-wave observations of HNCO, HC3N, SO, NH2CHO, H13CN, and H3O+ in comet C/1995 O1 (Hale-Bopp)obtained in February–April, 1997 with the Caltech Submillimeter Observatory (CSO). HNCO, first detected at the CSO in comet C/1996B2 (Hyakutake), is securely confirmed in comet Hale-Bopp via observations of three rotational transitions. The derived abundance with respect to H2O is (4-13) × 10-4. HC3N, SO, and NH2CHO are detected for the first time in a comet. The fractional abundance of HC3N based on observations of three rotational lines is (1.9 ± 0.2) × 10-4. Four transitions of SO are detected and the derived fractional abundance, (2-8) ×10-3, is higher than the upper limits derived from UV observations of previous comets. Observations of NH2CHO imply a fractional abundance of (1-8) × 10-4. H3O is detected for the first time from the ground. The H13CN (3-2)transition is also detected and the derived HCN/H13CN abundance ratio is 90 ± 15, consistent with the terrestrial12C/13C ratio. In addition, a number of other molecular species are detected, including HNC, OCS, HCO+, CO+, and CN(the last two are first detections in a comet at radio wavelengths). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

4.
《Planetary and Space Science》1999,47(6-7):745-763
An improved magnetohydrodynamic (MHD) model with chemistry is presented. The analysis of the source and sink terms for H2O + shows that for small comets up to 11% of water molecules are finally ionized. For large comets (such as Halley) this fraction decreases to less than 3%. From the MHD scaling laws a similarity law for the individual ion densities is deduced which takes into account that the mother molecules are depleted by dissociation. This is applied to H2O + ions. Radial density profiles from model calculations, observations by Giotto near comet Halley, and ground based observations of three comets confirm this scaling law for H2O + ions. From the similarity law for the density a scaling law for the column density is derived which is more convenient to apply for ground based observations. From these scaling laws methods are derived which allow the determination of the water production rate from the ground based images of the H2O + ions. Finally, the two dimensional images of model column densities are compared with observations.  相似文献   

5.
Dirty ice of a second kind (major components, H2O, CO, and N2; minor components less than several percents, NH3, CH4, and other organic substances such as HCN, CH3CN etc.) is assumed for the composition of volatiles in the cometary nucleus. The consistency with the observations of molecular ions and daughter molecules in the cometary atmosphere is argued by taking into account various ion-molecular reactions and dissociative recombinations. There is a satisfactory agreement for the second kind of dirty-ice model, but the presence of large amounts of CH4 and NH3 is found to be rather in contradiction with observational evidence. A velocity of 8 km s?1 for the hydrogen atoms, derived from analysis of the hydrogen Lyman-alpha corona around comets, is found from the dissociative recombination of H3O+, the dominant constituent of cometary ionosphere, in accordance with H3O++e ?→OH+H+H.  相似文献   

6.
We obtained spectra of comet C/1999 S4 (LINEAR) with the UAGS spectrograph(long slit and CCD) installed on the 1-m Zeiss reflector of the SAO of the RAS(Northern Caucuses, Nizhny Arkhyz) on July 23/24, 26/27 and 27/28, 2000. OnJuly 22/23, before the splitting of the cometary nucleus, several emission lines,such as C2, C3, CN, NH, CH, NH2, CO+, H2O+ wereclearly identified in the spectra. The inspections of the CCD spectra obtainedon July 27/28, 2000 reveals only very weak emission lines superimposed on thesolar reflection spectrum. From analyzing the surface brightness profile of C2 along the slit the velocity of separation of two secondary fragments (V = 10 km/h) and the energy of the fragment separation (E = 8.7 × 1015 erg) were estimated. A luminescence cometary continuum of 26% of the total continuum level is detected in the spectra of the comet at 5000 Å. Possible mechanisms of nucleus splitting are discussed.  相似文献   

7.
Experimental results on fast ion collision with icy surfaces having astrophysical interest are presented. 252Cf fission fragments projectiles were used to induce ejection of ionized material from H2O, CO2, CO, NH3, N2, O2 and Ar ices; the secondary ions were identified by time-of-flight mass spectrometry. It is observed that all the bombarded frozen gas targets emit cluster ions which have the structure XnR±, where X is the neutral ice molecule and R± is either an atomic or a molecular ion. The shape of the positive or negative ion mass spectra is characterized by a decreasing yield as the emitted ion mass increases and is generally described by the sum of two exponential functions. The positive ion water ice spectrum is dominated by the series (H2O)nH3O+ and the negative ion spectrum by the series (H2O)nOH and (H2O)nO. The positive ion CO2 ice spectrum is characterized by R+ = C+, O+, CO+, O2+ or CO2+ and the negative one by R = CO3. The dominant series for ammonia ice correspond to R+ = NH4+ and to R = NH2. The oxygen series are better described by (O3)nOm+ secondary ions where m = 1, 2 or 3. Two positive ion series exist for N2 ice: (N2)nN2+ and (N2)nN+. For argon positive secondary ions, only the (Ar)nAr+ series was observed. Most of the detected molecular ions were formed by one-step reactions. Ice temperature was varied from ∼20 K to complete sublimation.  相似文献   

8.
In order to understand the cometary plasma environment it is important to track the closely linked chemical reactions that dominate ion evolution. We used a coupled MHD ion-chemistry model to analyze previously unpublished Giotto High Intensity Ion Mass Spectrometer (HIS-IMS) data. In this way we study the major species, but we also try to match some minor species like the CHx and the NHx groups. Crucial for this match is the model used for the electrons since they are important for ion-electron recombination. To further improve our results we included an enhanced density of supersonic electrons in the ion pile-up region which increases the local electron impact ionization. In this paper we discuss the results for the following important ions: C+, CH+, CH+2, CH+3, N+, NH+, NH+2, NH+3, NH+4, O+, OH+, H2O+, H3O+, CO+, HCO+, H3CO+, and CH3OH+2. We also address the inner shock which is very distinctive in our MHD model as well as in the IMS data. It is located just inside the contact surface at approximately 4550 km. Comparisons of the ion bulk flow directions and velocities from our MHD model with the data measured by the HIS-IMS give indication for a solar wind magnetic field direction different from the standard Parker angle at Halley's position. Our ion-chemical network model results are in a good agreement with the experimental data. In order to achieve the presented results we included an additional short lived inner source for the C+, CH+, and CH+2 ions. Furthermore we performed our simulations with two different production rates to better match the measurements which is an indication for a change and/or an asymmetric pattern (e.g. jets) in the production rate during Giotto's fly-by at Halley's comet.  相似文献   

9.
10.
The neutral gas environment of a comet is largely influenced by dissociation of parent molecules created at the surface of the comet and collisions of all the involved species. We compare the results from a kinetic model of the neutral cometary environment with measurements from the Neutral Mass Spectrometer and the Dust Impact Detection System onboard the Giotto spacecraft taken during the fly-by at Comet 1P/Halley in 1986. We also show that our model is in good agreement with contemporaneous measurements obtained by the International Ultraviolet Explorer, sounding rocket experiments, and various ground based observations.The model solves the Boltzmann equation with a Direct Simulation Monte Carlo technique (Tenishev, V., Combi, M., Davidsson, B. [2008]. Astrophys. J. 685, 659-677) by tracking trajectories of gas molecules and dust grains under the influence of the comet’s weak gravity field with momentum exchange among particles modeled in a probabilistic manner. The cometary nucleus is considered to be the source of dust and the parent species (in our model: H2O, CO, H2CO, CO2, CH3OH, C2H6, C2H4, C2H2, HCN, NH3, and CH4) in the coma. Subsequently our model also tracks the corresponding dissociation products (H, H2, O, OH, C, CH, CH2, CH3, N, NH, NH2, C2, C2H, C2H5, CN, and HCO) from the comet’s surface all the way out to 106 km.As a result we are able to further constrain cometary the gas production rates of CO (13%), CO2 (2.5%), and H2CO (1.5%) relative to water without invoking unknown extended sources.  相似文献   

11.
The paper presents the results of the spectral observations of comet C/2001 Q4 (NEAT) acquired with the Zeiss-600 telescope of the Andrushevka astronomical observatory in May 2004. The spectrum of the comet was obtained in the range of 3600–8200 Å. We identified a number of emission features in the spectrum of comet C/2001 Q4 (NEAT). The emission bands of C2, C3, CN, CH, NH2, H2O+ were detected in the spectrum of the comet, and their intensities were determined. The ratios of gas-production rates Q(C2)/Q(CN) = 0.23, Q(C3)/Q(CN) = ?0.79, and Q(NH2)/Q(CN) = ?0.029 were determined with the Haser model.  相似文献   

12.
Negative ions (anions) were identified in the coma of comet 1P/Halley during in situ Electron Electrostatic Analyzer measurements performed by the Giotto spacecraft in 1986. These anions were detected with masses in the range 7–110 amu, but with insufficient mass resolution to permit unambiguous identification. We present details of a new chemical‐hydrodynamic model for the coma of comet Halley that includes—for the first time—atomic and molecular anions, in addition to a comprehensive hydrocarbon chemistry. Anion number densities are calculated as a function of radius in the coma, and compared with the Giotto results. Important anion production mechanisms are found to include radiative electron attachment, polar photodissociation, dissociative electron attachment, and proton transfer. The polyyne anions C4H? and C6H? are found to be likely candidates to explain the Giotto anion mass spectrum in the range 49–73 amu. The CN? anion probably makes a significant contribution to the mass spectrum at 26 amu. Larger carbon‐chain anions such as C8H? can explain the peak near 100 amu provided there is a source of large carbon‐chain‐bearing molecules from the cometary nucleus.  相似文献   

13.
One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H2O, OH, O, CN, C2, C3, CH, and NH2. Whole-coma abundances are presented for NH2, CH, C2, C3, CN, OH, CO+, H2O+, CH+, N2+, and CO2+.  相似文献   

14.
The quadrupole mass spectrometer flown by the Air Force Geophysics Laboratory on STS-4 in 1982 detected large intensities of several ions, primarily O+, H2O+ and H3O+, with energies less than 1.5 e V with respect to the Shuttle Orbiter. Ion-molecule reactions and non-reactive scattering between the outgassing neutral flux from the Orbiter surfaces and the ambient ionic species are identified as the primary source of these low energy ions.  相似文献   

15.
During the recent apparition of Comet Halley in 1985-86 a transient ionic event in the form of a blob of H2 O+ emission was recorded in thecoma at ~ 0h UT on 1986 March 13. Observations were carried out using a special IHW filter for H2 O+ emission at 7000 å/175 å, a 35 cm telescope, a Fabry-Perot interferometer and an image intensifier camera from Gurushikhar, Mt Abu. (24?39’N,72? 47’E). A Fabry-Perot inter-ferogram in Ha taken a few minutes later at the same location reveals strong hydrogen emission (Hα) associated with the blob. The velocity field in the blob is structured with relative velocities upto ~ 35km s?1. The event is interpreted as arising due to the sector boundary crossing of the interplanetary magnetic field by the comet  相似文献   

16.
C/2006 P1 McNaught is a dynamically new comet from the Oort cloud that passed very close to the Sun, driving overall volatile production rates up to about 1031 molecules s−1. Post-perihelion observations were obtained in a target-of-opportunity campaign using the CSHELL instrument at the NASA Infrared Telescope Facility atop Mauna Kea, Hawaii, on UT 2007 January 27 and 28. Eight parent volatiles (H2O, CH4, C2H2, C2H6, HCN, CO, NH3, H2CO) and two daughter fragments (OH and NH2) were detected, enabling the determination of a rotational temperature and production rate for H2O on UT January 27 and absolute and relative production rates for all the detected parent species on UT January 28. The chemical composition measured in the coma suggests that this close perihelion passage stripped off processed outer surface layers, likely exposing relatively fresh primordial material during these observations. The post-perihelion abundances we measure for CO and CH4 (relative to H2O) are slightly depleted while C2H2, NH2 and possibly NH3 are enhanced when compared to the overall comet population. Measured abundances for other detected molecular species were within the range typically observed in comets.  相似文献   

17.
We report on simultaneous optical and infrared observations of the Halley Family comet 8P/Tuttle performed with the ESO Very Large Telescope. Such multi-wavelength and coordinated observations are a good example of what can be done to support space missions. From high resolution optical spectroscopy of the CN (0,0) 388 nm and NH2 (0,9,0) 610 nm bands using UVES at UT2 we determined 12C/13C = 90 ± 10 and 14N/15N = 150 ± 20 in CN and we derived a nuclear spin temperature of NH3 of 29 ± 1 K. These values are similar to those found in Oort-Cloud and Jupiter Family comets. From low resolution long slit spectroscopy with FORS1 at UT2 we determined the CN, C3 and C2 production rates and the parent and daughter scale lengths up to 5.2 105 km tailward. From high resolution IR spectroscopy with CRIRES at UT1 we measured simultaneously the production rates and mixing ratios of H2O, HCN, C2H2, CH4, C2H6, and CH3OH.  相似文献   

18.
We measured the chemical composition of Comet C/2007 W1 (Boattini) using the long-slit echelle grating spectrograph at Keck-2 (NIRSPEC) on 2008 July 9 and 10. We sampled 11 volatile species (H2O, OH, C2H6, CH3OH, H2CO, CH4, HCN, C2H2, NH3, NH2, and CO), and retrieved three important cosmogonic indicators: the ortho-para ratios of H2O and CH4, and an upper-limit for the D/H ratio in water. The abundance ratios of almost all trace volatiles (relative to water) are among the highest ever observed in a comet. The comet also revealed a complex outgassing pattern, with some volatiles (the polar species H2O and CH3OH) presenting very asymmetric spatial profiles (extended in the anti-sunward hemisphere), while others (e.g., C2H6 and HCN) showed particularly symmetric profiles. We present emission profiles measured along the Sun-comet line for all observed volatiles, and discuss different production scenarios needed to explain them. We interpret the emission profiles in terms of release from two distinct moieties of ice, the first being clumps of mixed ice and dust released from the nucleus into the sunward hemisphere. The second moiety considered is very small grains of nearly pure polar ice (water and methanol, without dark material or apolar volatiles). Such grains would sublimate only very slowly, and could be swept into the anti-sunward hemisphere by radiation pressure and solar-actuated non-gravitational jet forces, thus providing an extended source in the anti-sunward hemisphere.  相似文献   

19.
The evolution of the charged particles are followed during contraction of a model of an interstellar cloud, with initial density number of n = 10 cm–3. The contraction is followed up to density increase by five orders of magnitude. Special care is given to the details of the negative ions. In addition, we have tested the ambipolar diffusion according to the results of the ion density.The results predict the importance of atomic ions in the diffuse regions. H+ and C+ are distinctly enhanced in the beginning of contraction but decrease as contraction proceeds. Molecular ions enhance as contraction proceeds and becomes important in dense regions. The most enhanced molecular ions are HCO+, O2 +, C2H3 +, H3O+ and SO+, H3 + is less abundant. The atomic ions (except metalic ions) decrease noticeably as density increases. In general the negative ions are of negligible fractional abundances. It has also been found that the time of ambipolar diffusion is shorter than the dynamical time, hence the magnetic field should be weakened in the central core as the central density increases to n = 104 cm–3.  相似文献   

20.
Rauer  H. 《Earth, Moon, and Planets》1997,79(1-3):161-178
The extraordinary brightness of comet Hale-Bopp (C/1995 O1) offered the rare opportunity to investigate its ion tail by observations over a wide range of wavelengths. For the first time, ion emission lines could be detected in the radio domain, originating from H3O+, HCO+ and CO+ ions. Observations in the extreme ultraviolet range showed O+ emissions. Optical imaging observations show a spectacular detail of structures in the ion tail. The combined measurements of the ion spatial distribution and dynamic provide a wealth of information which needs to be understood in terms of models of the comet-solar wind interaction and ion-neutral molecule reactions in the coma. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

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