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1.
In order to understand the cometary plasma environment it is important to track the closely linked chemical reactions that dominate ion evolution. We used a coupled MHD ion-chemistry model to analyze previously unpublished Giotto High Intensity Ion Mass Spectrometer (HIS-IMS) data. In this way we study the major species, but we also try to match some minor species like the CHx and the NHx groups. Crucial for this match is the model used for the electrons since they are important for ion-electron recombination. To further improve our results we included an enhanced density of supersonic electrons in the ion pile-up region which increases the local electron impact ionization. In this paper we discuss the results for the following important ions: C+, CH+, CH+2, CH+3, N+, NH+, NH+2, NH+3, NH+4, O+, OH+, H2O+, H3O+, CO+, HCO+, H3CO+, and CH3OH+2. We also address the inner shock which is very distinctive in our MHD model as well as in the IMS data. It is located just inside the contact surface at approximately 4550 km. Comparisons of the ion bulk flow directions and velocities from our MHD model with the data measured by the HIS-IMS give indication for a solar wind magnetic field direction different from the standard Parker angle at Halley's position. Our ion-chemical network model results are in a good agreement with the experimental data. In order to achieve the presented results we included an additional short lived inner source for the C+, CH+, and CH+2 ions. Furthermore we performed our simulations with two different production rates to better match the measurements which is an indication for a change and/or an asymmetric pattern (e.g. jets) in the production rate during Giotto's fly-by at Halley's comet.  相似文献   

2.
One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H2O, OH, O, CN, C2, C3, CH, and NH2. Whole-coma abundances are presented for NH2, CH, C2, C3, CN, OH, CO+, H2O+, CH+, N2+, and CO2+.  相似文献   

3.
Detections and upper limits to the continuum emission (1 ≤ λ ≤6 cm) and spectral line emission (OH, CO, CS, HCN, HCO+, CN, CH3CN, CH3C2H, NH3, H2O, HC3N, CH3CH2CN) are reported from radio observations of Comets 1983d and 1983e. Comparison is made with observations of CN at optical wavelengths. These results may be useful in planning future cometary observations.  相似文献   

4.
S.A. Haider 《Icarus》2005,177(1):196-216
In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH3OH+2, H3CO+, NH+4, H3S+, H2CN+, H2O+, NH+3, CO+, C3H+3, OH+, H3O+, CH3OH+, C3H+4, C2H+2, C2H+, HCO+, S+, CH+3, H2S+, O+, C+, CH+4, C+2, and O+2) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH+4, H3O+, CH3OH+2, H3S+, H2CN+, and H2O+, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H3O+, CH3OH+2, H2O+, H3CO+, C2H+2, and NH+4; along with ions CO+, OH+, and HCO+, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models.  相似文献   

5.
The formation of methylamine (CH3NH2) in the upper troposphere and lower stratosphere of Jupiter is investigated. Translationally hot hydrogen atoms are produced in the photolysis of ammonia, phosphine, and acetylene which react with methane to produce methyl (CH3) radicals; the latter recombine with NH2 to form CH3NH2. Also, methane is catalytically dissociated to CH3 + H by the species C2 and C2H produced in the photolysis of acetylene. It is shown that the combined production of CH3NH2 and subsequent photolysis to HCN is unlikely to account for the HCN observed near Jupiter's tropopause. Recombination of NH2 and C2H5N followed by photolysis to HCN is the preferred path. Production of C2H6 by these two processes is negligible in comparison to the downward flux of C2H6 from the Lyman α photolysis region of CH4. An upper limit column density on CH3PH2 is estimated to be ~1013 cm?2 as compared to 1015 cm?2 for CH3NH2. Hot H atoms account for a negligible fraction of the total ortho-para conversion by the reaction H + H2  相似文献   

6.
The production rate of H2O molecules at a heliocentric distance of 1 AU for comet Halley and the abundance ratio with respect to water (H2O) of parent molecules at the cometary nucleus from the paper of Yamamoto (1987) have been used to compute the number densities of positive ions viz. H3O+, H3S+, H2CN+, H3CO+, CH3OH 2 + and NH 4 + at various cometocentric distances within 600 kms from the nucleus.The role of proton transfer reactions in producing major ionic species is discussed. A major finding of the present investigation is that NH 4 + ion which may be produced through proton transfer reactions is the most abundant ion near the nucleus of a comet unless the abundance of NH3 as a parent is abnormally low. Using the quoted value of Q(NH3)/Q(H2O) for comet Halley and the life times of NH3 and H2O molecules, the abundance ratio N(NH3)/N(H2O) is found to be one-third of that used in the present paper. The consequent proportionate decrease in the NH 4 + ions does not, however, affect its superiority in number density over other ions near the nucleus.The number density of the next most abundant ion viz. H3O+ is found to be 4 × 104 cm-3 at the nucleus of comet Halley and decreases by a factor of two only upto a distance of 600 K ms from the nucleus. The ionic mass peak recorded by VEGA and GIOTTO spacecrafts atm/q = 18 is most probably composite of the minor ionic species H2O+, as its number density = 102 cm-3 remains virtually constant in the inner coma and of NH 4 + , the number density of which at large cometocentric distances may add to the recorded peak atmlq = 18. The number densities of other major ions produced through proton transfer from H3O+ are also discussed in the region within 600 K ms from the nucleus of comet Halley.  相似文献   

7.
A popular model of a cometary plasma is hydrogen (H+) with positively charged oxygen (O+) as a heavier ion component. However, the discovery of negatively charged oxygen (O?) ions enables one to model a cometary plasma as a pair-ion plasma (of O+ and O?) with hydrogen as a third ion constituent. We have, therefore, studied the stability of the ion-acoustic wave in such a pair-ion plasma with hydrogen and electrons streaming with velocities $V_{d\mathrm{H}^{+}}$ and V de , respectively, relative to the oxygen ions. We find the calculated frequency of the ion-acoustic wave with this model to be in good agreement with the observed frequencies. The ion-acoustic wave can also be driven unstable by the streaming velocity of the hydrogen ions. The growth rate increases with increasing hydrogen density $n_{\mathrm{H}^{+}}$ , and streaming velocities $V_{d\mathrm{H}^{+}}$ and V de . It, however, decreases with increasing oxygen ion densities $n_{\mathrm{O}^{+}}$ and $n_{\mathrm{O}^{-}}$ .  相似文献   

8.
Photoionization of the upper atmosphere of Titan by sunlight is expected to produce a substantial ionospheric layer. We have solved one-dimensional forms of the mass, momentum, and energy conservation equations for ions and electrons and have obtained electron number densities of about 103 cm?3, using various model atmospheres. The significant ions in a CH4H2 atmosphere are H+, H3+, CH5+, CH5+, CH3+, and C2H5+. Electron temperatures may be as high as 1000°K, depending on the abundance of hydrogen in the high atmosphere. Interaction of the solar wind with the ionosphere is also discussed.  相似文献   

9.
The neutral gas environment of a comet is largely influenced by dissociation of parent molecules created at the surface of the comet and collisions of all the involved species. We compare the results from a kinetic model of the neutral cometary environment with measurements from the Neutral Mass Spectrometer and the Dust Impact Detection System onboard the Giotto spacecraft taken during the fly-by at Comet 1P/Halley in 1986. We also show that our model is in good agreement with contemporaneous measurements obtained by the International Ultraviolet Explorer, sounding rocket experiments, and various ground based observations.The model solves the Boltzmann equation with a Direct Simulation Monte Carlo technique (Tenishev, V., Combi, M., Davidsson, B. [2008]. Astrophys. J. 685, 659-677) by tracking trajectories of gas molecules and dust grains under the influence of the comet’s weak gravity field with momentum exchange among particles modeled in a probabilistic manner. The cometary nucleus is considered to be the source of dust and the parent species (in our model: H2O, CO, H2CO, CO2, CH3OH, C2H6, C2H4, C2H2, HCN, NH3, and CH4) in the coma. Subsequently our model also tracks the corresponding dissociation products (H, H2, O, OH, C, CH, CH2, CH3, N, NH, NH2, C2, C2H, C2H5, CN, and HCO) from the comet’s surface all the way out to 106 km.As a result we are able to further constrain cometary the gas production rates of CO (13%), CO2 (2.5%), and H2CO (1.5%) relative to water without invoking unknown extended sources.  相似文献   

10.
Measured rates are presented for the reaction of He+ ions with H2 (and D2) molecules to form H+, H2+, and HeH+ ions, as well as for the subsequent reactions of H+ and HeH+ ions with H2 to form H3+. The neutralization of H3+ (and H5+) ions by dissociative recombination with electrons is shown to be fast. The reaction He+ + H2 is slow (k = 1.1 × 10?13 cm3/sec at300°K) and produces principally H+ by the dissociative charge transfer branch. It is concluded that there may be a serious bottleneck in the conversion of two of the primary ions of the upper Jovian ionosphere, H+ and He+ (which recombine slowly), to the rapidly recombining H3+ ion (α[H3+]?3.4 × 10?7 cm3/sec at 150°K).  相似文献   

11.
Spectral observations of Saturn from the far infrared spectrometer aboard the Cassini spacecraft [Flasar, F.M., et al., 2005. Temperatures, winds, and composition in the Saturnian system. Science 307, 1247-1251] have revealed that the C/H ratio in the planet is in fact about twice higher than previously derived from ground based observations and in agreement with the C/H value derived from Voyager IRIS by Courtin et al. [1984. The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH3, PH3, C2H2, C2H6, CH3D, CH4, and the Saturnian D/H isotopic ratio. Astrophys. J. 287, 899-916]. The implications of this measurement are reanalyzed in the present report on the basis that volatiles observed in cometary atmospheres, namely CO2, CH4, NH3 and H2S may have been trapped as solids in the feeding zone of the planet. CH4 and H2S may have been in the form of clathrate hydrates while CO2 presumably condensed in the cooling solar nebula. Carbon may also have been incorporated in organics. Conditions of temperature and pressure ease the hydratation of NH3. Such icy grains were included in planetesimals which subsequently collapsed into the hydrogen envelope of the planet, then resulting in C, N and S enrichments with respect to the solar abundance. Our calculations are consistent, within error bars, with observed elemental abundances on Saturn provided that the carbon trapped in planetesimals was mainly in the form of CH4 clathrate and CO2 ice (and maybe as organics) while nitrogen was in the form of NH3 hydrate. Our approach has implications on the possible pattern of noble gases in Saturn, since we predict that contrary to what is observed in Jupiter, Ar and Kr should be in solar abundance while Xe might be strongly oversolar. The only way to verify this scenario is to send a probe making in situ mass spectrometer measurements. Our scenario also predicts that the 14N/15N ratio should be somewhat smaller in Saturn than measured in Jupiter by Galileo.  相似文献   

12.
New experimental techniques have yielded several thermal energy vibrational quenching rate constants for O2+(v). Rates for quenching of O2+(v = 1) by O2, N2, Ar, CO2, H2, and CH4 are 3(?10), 2(?12), 1(?12), 1(?10), 2.5(?12), and 6(?10) cm3s?1 at 300 K. The quenching is somewhat faster for O2+(v = 2). The triatomic ions CO2+, NO2+, N2O+, SO2+, and H2O+ are all vibrationally deexcited with an efficiency greater than 10?3 in Ar or Ne collisions. A theoretical rationalization of the experimental results leads to the prediction that vibrational quenching in planetary atmospheres will generally be efficient, k > 1(?12) cm3s?1 for almost all ion and neutral gas pairs.  相似文献   

13.
Altitude profiles for the number densities of NO, NO2, NO3, N2O5, HNO2, CH3O, CH3O2, H2CO, OH, and HO2 are calculated as a function of time of day with a steady-state photochemical model in which the altitude profiles for the number densities of H2O, CH4, H2, CO, O3, and the sum of NO and NO2 are fixed at values appropriate to a summer latitude of 34°. Average daily profiles are calculated for the long-lived species, HNO3, H2O2, and CH3O2H.The major nitrogen compound HNO3 may have a number density approaching 5 × 1011 molecules cm?3 at the surface, although an effective loss path due to collisions with particulates could greatly reduce this value.The number density of OH remains relatively unchanged in the first 6 km and reaches 1 × 107 molecules cm?3 at noon, while the number density of HO2 decreases throughout the lower troposphere from its noontime value of 8 × 108 molecules cm?3 at the surface.H2O2 and H2CO both have number densities in the ppb range in the lower troposphere.Owing to decreasing temperature and water concentration, the production of radicals and their steady-state number densities decrease with altitude, reaching a noontime minimum of 1 × 108 molecules cm?3 for OH and 3 × 107 molecules cm?3 for HO2 at the tropopause. The related minor species show even sharper decreases with increasing altitude.The primary path for interconverting OH and HO2 serves as the major sink for CO and leads to a tropospheric lifetime for CO of ~0.1 yr.Another reaction cycle, the oxidation of CH4, is quite important in the lower troposphere and leads to the production of H2CO along with the destruction of CH4 for which a tropospheric lifetime of ~2 yr is estimated.The destruction of H2CO that was produced in the CH4 oxidation cycle provides the major source of CO and H2 in the atmosphere.  相似文献   

14.
Ionization of the atmosphere of Titan by galactic cosmic rays is a very significant process throughout the altitude range of 100 to 400 km. An approximate form of the Boltzmann equation for cosmic ray transport has been used to obtain local ionization rates. Models of both ion and neutral chemistry have been employed to compute electron and ion density profiles for three different values of the H2/CH4 abundance ratio. The peak electron density is of the order 103 cm?3. The most abundant positive ions are C2H9+ and C3H9+, while the predicted densities of the negative ions H? and CH3? are very small (<10?4 that of the positive ions). It is suggested that inclusion of the ion chemistry is important in the computation of the H and CH3 density profiles in the lower ionosphere.  相似文献   

15.
The observation of ions created by ionization of cometary gas, either by ground-based observations or byin situmeasurements can give us useful information about the gas production and composition of comets. However, due to the interaction of ions with the magnetized solar wind and their high chemical reactivity, it is not possible to relate measured ion densities (or column densities) directly to the parent gas densities. In order to quantitatively analyze measured ion abundances in cometary comae it is necessary to understand their dynamics and chemistry. We have developed a detailed ion–chemical network of cometary atmospheres. We include production of ions by photo- and electron impact-ionization of a background neutral atmosphere, charge exchange of solar wind ions with cometary atoms/molecules, reactions between ions and molecules, and dissociative recombination of molecular ions with thermal electrons. By combining the ion–chemical network with the three-dimensional plasma flow as computed by a new fully three-dimensional MHD model of cometary plasma environments (Gombosiet al.1996) we are able to compute the density of the major cometary ions everywhere in the coma. The input parameters for our model are the solar wind conditions (density, speed, temperature, magnetic field) and the composition and production rate of the gas. We applied our model to Comet P/Halley in early March 1986, for which the input parameters are reasonably well known. We compare the resulting column density of H2O+with ground-based observations of H2O+from DiSantiet al.(1990). The results of our model are in good agreement with both the spatial distribution and the absolute abundance of H2O+and with their variations with the changing overall water production rate between two days. The results are encouraging that it will be possible to obtain production rates of neutral cometary constituents from observations of their ion products.  相似文献   

16.
S.K. Atreya  T.M. Donahue 《Icarus》1975,24(3):358-362
Model ionospheres are calculated for Saturn, Uranus, and Neptune. Protons are the major ions above 150 km altitude measured from a reference level where the hydrogen density is 1 × 1016 molecules cm?3, while below 150 km quick conversion of protons to H3+ ions by a three-body association mechanism leads to a rapid removal of ionization in dissociative recombination of H3+. Electron density maxima are found at about 260 km for Saturn and Uranus and 200 km for Neptune. Present knowledge of the physical and chemical processes in the atmospheres of these planets suggests that their ionospheres probably will not be Jupiter-like.  相似文献   

17.
Following the recent mass spectrometric observations of the ambient stratospheric positive and negative ions we have carried out co-ordinated laboratory experiments using a selected ion flow tube apparatus and a flowing afterglow apparatus for the following purposes: (i) to consider whether CH3CN is a viable candidate molecule for the species X in the observed stratospheric ion series H+ (H2On (X)m and (ii) to determine the binary mutual neutralization rate coefficients αi for the reactions ofH+ (H2O4 and H+(H2O)(CH3CN)3 with several of the negative ion species observed in the stratosphere. We conclude from (i) that CH3CN is indeed a viable candidate for X and from (ii) that the αi for stratospheric ions are within the limited range (5–6) × 10?8 cm3 s?1.  相似文献   

18.
Models are developed to describe the photochemistry of ozone on Mars. Catalytic reactions involving H, OH and HO2 play a major role at low latitudes where they ensure a vertical column density for O3 of less than 2 × 10?4 cm atm. The source for odd hydrogen (H + OH + HO2) is relatively smaller at high latitudes in winter due to the small concentrations of H2O present there at that time. Odd hydrogen is also efficiently removed from the high-latitude winter atmosphere by condensation of H2O2. The role of catalytic chemistry is reduced accordingly and the vertical column density of O3 may be as large as 5.7 × 10?3 cm atm in accord with earlier observations carried out by Barth and co-workers with instruments on Mariner 9.  相似文献   

19.
It is argued that ozone measurements made by Weeks et al. (1972) can be interpreted in terms of the enhanced ionization present. The conversion of O2+ ions to oxonium, H3O+ · (H2O)n, ions plus the dissociative recombination of these ions provides for an increased OH and/or H formation rate. The resulting enhanced OH and HO2 concentrations reduce the ambient atomic oxygen and hence ozone populations. The net excess H + OH formation rate is found to lie between one and two times the ionization production rate at altitudes where oxonium ions are the dominant positive ion species.  相似文献   

20.
We obtained spectra of comet C/1999 S4 (LINEAR) with the UAGS spectrograph(long slit and CCD) installed on the 1-m Zeiss reflector of the SAO of the RAS(Northern Caucuses, Nizhny Arkhyz) on July 23/24, 26/27 and 27/28, 2000. OnJuly 22/23, before the splitting of the cometary nucleus, several emission lines,such as C2, C3, CN, NH, CH, NH2, CO+, H2O+ wereclearly identified in the spectra. The inspections of the CCD spectra obtainedon July 27/28, 2000 reveals only very weak emission lines superimposed on thesolar reflection spectrum. From analyzing the surface brightness profile of C2 along the slit the velocity of separation of two secondary fragments (V = 10 km/h) and the energy of the fragment separation (E = 8.7 × 1015 erg) were estimated. A luminescence cometary continuum of 26% of the total continuum level is detected in the spectra of the comet at 5000 Å. Possible mechanisms of nucleus splitting are discussed.  相似文献   

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