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1.
在温度为1130-1450℃,压力为0.4-2.0GPa条件下,实验研究了地幔橄榄岩部分熔融及相转变(尖晶石相→斜长石相)过程中的固相化学成分演变。在部分熔融中,随熔融度的增大,橄榄石的Mg/(Mg+Fe)^尖晶石和斜方辉石的Mg/(Mg+Fe)及Cr/(Cr+Al)逐渐增大;而橄榄石中的Ca含量增至单斜辉石消失后逐渐降低;尖晶石中的Ti以较低的含量(TiO2〈0.15%)保持不变或稍有降低;斜方  相似文献   

2.
本文用Mg-Cr2+做榄石、辉石、尖晶石的粉晶X射线衍射数据,采取“整体图谱最小二乘Rietveld”方法计算了上述矿物的晶胞参数和摩尔体积,并对Cr2+在各晶体结构中的占位情况进行了研究。结果显示,各矿物的晶胞参数随含Cr2+量的增大而增大。据Vegard定律,推算出各端元组分铬橄榄石(Cr2SiO1)、铬辉石(Cr2SiO2O6)及立方铬尖晶石(Cr3O4)的摩尔体积分别为47.7,68.0,44.9cm3。精化结构参数指示,在橄榄石中,Cr2+随机分配在两个八面体(M1,M2)位置;在辉石中,Cr2+优先选择八面体M2位置;在尖晶石中,Cr2+占置四面体位置。这种晶体内离子分配可从离子半径差别或晶体场稳定能大小得到解释。  相似文献   

3.
在t=1100-1500℃和P=0-2.88GPa条件下,实验确定了与金属Cr平衡的SiO_2-Cr-O及MgO-SiO_2-Cr-O体系中的亚固相相关系。结果显示,在SiO_2-Cr-O体系中,只发现绿铬矿-金属铬-石英(或鳞石英)组合;而在含MgO体系中,出现Mg-Cr~(2+)橄榄石、辉石及尖晶石固溶体。Cr~(3+)在橄榄石和辉石中的含量在可测定限度之下。当X_(Cr~(2+))=[Cr~(2+)/(Mg+Cr~(2+))]>0.2时,辉石的结构由斜方晶系转为单斜晶系;尖晶石的结构由立方变为四方。对实验数据进行热力学模拟,求得Mg-Cr~(2+)在橄榄石,辉石及尖晶石固溶体中的混合参数(W),以及铬橄榄石(Cr_2SiO_4)、铬辉石(Cr_2Si_2O_6)和铬尖晶石(Cr_3O_4)的形成自由能(△G°)与温度的关系。  相似文献   

4.
方同辉  马鸿文 《现代地质》1998,12(2):197-203
摘 要 利用穆斯堡尔谱仪对辽宁宽甸地幔岩包体中的矿物进行了三价铁的测定‚测试结果 与国内外已发表的数据接近。Fe 3+ /∑Fe 比值分别为:斜方辉石0∙066~0∙196‚单斜辉石 0∙216~0∙344‚尖晶石0∙283~0∙299‚石榴石0∙057~0∙223。依据电价平衡原理计算的 Fe 3+ 含量受 Si 4+ 、Al 3+ 和 Cr 3+ 的电子探针分析误差影响很大。根据地幔矿物的电子探针分析结果 计算平衡温度、压力和氧逸度时‚二辉石 En、Ca 转移反应温度计和石榴石 斜方辉石 Al 压力 计的计算结果不超过温压计的一般误差范围‚而石榴石 单斜辉石 Fe 2+ Mg 交换反应温度计 在忽略 Fe 3+ 时计算的温度值可偏高100℃以上;采用橄榄石/斜方辉石/尖晶石组合氧压力计 计算的氧逸度值‚误差一般约在±0∙7个对数单位。  相似文献   

5.
在温度为ll30─l450℃,压力为0.4─2.0GPa条件下,实验研究了地幔橄榄岩部分熔融及相转变(尖晶石相→斜长石相)过程中的固相化学成分演变。在部分熔融中,随熔融度的增大,橄榄石的Mg/(Mg+Fe)尖晶石和斜方辉石的Mg/(Mg+Fe)及Cr/(Cr+Al)逐渐增大;而橄榄石中的Ca含量增至单斜辉石消失后逐渐降低;尖晶石中的Ti以较低的含量(TiO2<0.15%)保持不变或稍有降低;斜方辉石中的Ti含量及单斜辉石的Na和Ti含量逐渐降低,直至非常小的值。在从尖晶石橄榄岩向斜长石橄榄岩的相转变过程中,尖晶石强烈富Ti,且其Cr/(Cr+Al)逐渐增大;斜方辉石中的Ti含量和Cr/(Cr+Al)同时逐渐增大;单斜辉石中的Na含量降低而Ti含量升高或保持不变。当斜长石橄榄岩经受了部分熔融(即使很微弱),其在相转变过程中引起的各矿物相的化学成分特征要全部消失,而表现部分熔融作用的特征。这可作为判别橄榄岩在斜长石相域内是否经历了部分熔融的标志。关键词  相似文献   

6.
分析了全球一些有代表性的上地幔尖晶石橄榄岩和斜长石橄榄岩中各矿物的化学成分变化特征。发现在斜长石橄榄岩中,尖晶石和斜方辉石富Ti,且Ti含量随Cr/(Cr+Al)的增大而增大;单斜辉石富Ti贫Na,其Ti含量随Na含量的增大而减少。据此,结合实验结果,可以肯定世界各地大多数斜长石二辉橄榄岩在斜长石相域内未经受部分熔融。岩体所曾经受的部分熔融只发生在尖晶石或石榴石相。它们的相对熔融度可以用下面两个指标来估计:(1)最贫Ti尖晶石的Cr/(Cr+Al);(2)单斜辉石的最高Na含量。对于尖晶石橄榄岩,从二辉橄榄岩、方辉橄榄岩到纯橄榄岩,其尖晶石和斜方辉石的Cr/(Cr+Al)逐渐增大,而含量很低的Ti或Na在尖晶石、斜方辉石及单斜辉石中保持不变或趋向逐渐减小。尖晶石橄榄岩的相对熔融度可据尖晶石的Cr/(Cr+Al)和单斜辉石的Na含量来判断。  相似文献   

7.
内蒙古集宁新生代玄武岩产于华北克拉通北缘,属于广义的“汉诺坝玄武岩”。首次在三义堂附近的碱性玄武岩中发现了大量的橄榄岩包体、辉石和长石以及少量的含钛磁铁矿巨晶。包体主要是尖晶石二辉橄榄岩,造岩矿物为橄榄石+斜方辉石+单斜辉石+尖晶石,辉石巨晶主要为透辉石和普通辉石,长石巨晶主要是歪长石和少量斜长石。1.5GPa条件下,尖晶石二辉橄榄岩样品所记录的平衡温度与汉诺坝相近,集中于950℃左右,大体上反映了华北克拉通北缘大陆岩石圈地幔尖晶石相部分的温度状态。单斜辉石巨晶的结晶温压大于幔源包体的平衡温压,表明巨晶的来源深度可能大于包体。包体的结构及矿物成分分析表明,这些包体是玄武质岩浆上升过程中偶然捕获岩石圈地幔的岩石碎块。二辉橄榄岩包体中橄榄石高Mg#值(89.5~91.7)和较高的NiO含量(0.29%~0.55%),暗示集宁玄武岩中的橄榄岩包体来自较高熔融程度的岩石圈地幔。  相似文献   

8.
前期研究认识到新疆东昆仑木孜塔格蛇绿岩形成在俯冲带环境.为了进一步研究该俯冲带的类型,对新疆东昆仑木孜塔格蛇绿岩变质橄榄岩的岩石学和矿物学特征进行了分析.薄片观察发现变质橄榄岩的橄榄石以变质残余、变质重结晶和斜方辉石熔融结晶3种结构存在,但探针分析发现它们具有稳定且低Fo值(87.8~89.5);斜方辉石发育变质残余和熔融残余结构,En较低(88~90),Al2O3含量变化大(2.90%~5.13%);尖晶石为他形一半自形结构,其Cr^#(=Cr/(Cr+Al))集中分布在0.508~0.723和0.100~0.118两个范围内.根据这些来自岩石学和矿物学的证据,并结合该蛇绿岩的构造背景与时代,认识到该蛇绿岩形成在大洋向具有厚陆壳的大陆弧俯冲的俯冲带环境,为新疆东昆仑地区古特提斯多岛洋洋一陆俯冲的结果.  相似文献   

9.
辽西阜新中生代碱性玄武岩的K-Ar同位素年龄为84.76±1.67Ma, 其中含有丰富的深源岩石捕虏体, 包括角闪尖晶二辉橄榄岩、尖晶石二辉橄榄岩、含长角闪二辉石岩、二辉麻粒岩和辉石斜长片麻岩等。与新生代玄武岩中的同类捕虏体相比, 橄榄岩类捕虏体中橄榄石的成分相似 (Fo= 86~91), 透辉石具有富Al、贫Cr 和Ca 的特点, 尖晶石的成分以MgAl2 O4 为主, 有的橄榄岩捕虏体中含少量韭闪石。二辉麻粒岩捕虏体中的斜方辉石为紫苏辉石, 单斜辉石为普通辉石, 斜长石属于更长石。橄榄岩类捕虏体的平衡温度为1012.6℃~1272.1℃; 压力为1.825~2.935GPa, 二辉麻粒岩和片麻岩的平衡温度为892℃~1157℃。该类深源岩石捕虏体的发现对中国东部中生代上地幔和下地壳的研究均具有重要意义。  相似文献   

10.
河北阳原新生代玄武岩中橄榄岩捕虏体的含水量研究   总被引:1,自引:0,他引:1  
为约束华北克拉通岩石圈的流变机制,使用傅立叶变换显微红外光谱仪(FTIR)测量了阳原玄武岩中尖晶石橄榄岩捕虏体的矿物含水量。FTIR光谱结果表明阳原橄榄岩捕虏体的橄榄石、斜方辉石和单斜辉石都有特征的OH吸收峰。橄榄石含有微量的水(4×10-6~9×10-6 H2O),斜方辉石含水量为(105~201)×10-6,单斜辉石含水量为(260~440)×10-6,计算得出的全岩含水量为(49~75)×10-6。值得注意的是,富流体交代以及后期蚀变作用使得含角闪石的方辉橄榄岩样品中单斜辉石的含水量显著增加。阳原橄榄岩中单斜辉石与斜方辉石的含水量存在明显的正相关关系,水在单斜辉石和斜方辉石中的分配系数D cpx/opxOH =2.4±0.9,与全球橄榄岩样品的平均值基本一致(D cpx/opx OH = 2.2±0.1)。与汉诺坝的橄榄岩捕虏体相比,阳原捕虏体中橄榄石和辉石的结构水含量都明显较高,这可能与阳原橄榄岩经历的上地幔交代作用有关。统计表明全球克拉通玄武岩携带的尖晶石橄榄岩捕虏体中橄榄石的含水量普遍较低(0~10×10-6),而斜方辉石和单斜辉石的含水量则存在明显的不均一性。金伯利岩携带的石榴石橄榄岩中橄榄石、斜方辉石和单斜辉石的含水量都明显高于玄武岩携带的尖晶石橄榄岩中相应矿物的含水量,这可能与金伯利岩来源深、富流体、上升快的性质相关。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

13.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

14.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

15.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

16.
17.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

18.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

19.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

20.
GEOCHEMISTRY     
正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861  相似文献   

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