The influence of macronitrogen (NO₃^- and NH₄⁺) addition with Ulva pertusa on dissolved inorganic carbon system     

ZHANG Naixing  SONG Jinming  CAO Conghu  REN Rongzhu  WU Fengcong  ZHANG Shaoping  SUN Xu 《海洋学报(英文版)》2012,31(1):73-82

The influence of macronitrogen (NO - 3 and NH + 4 ) addition with Ulva pertusa on dissolved inorganic carbon system in seawater was studied. The results indicate that p(CO 2 ) and HCO 3 concentration decrease significantly, while pH and CO 2- 3 concentration increase significantly. When the concentration of NO 3 was less than 71 μmol/dm 3 or NH + 4 was less than 49.7 μmol/dm 3 , dissolved inorganic carbon (DIC) absorption rates by Ulva pertusa generally increased with the increasing of nitrogen concentration. The DIC decreased 151 μmol/dm 3 with the addition of 71 μmol/dm 3 NO 3 and decreased 232 μmol/dm 3 with the addition of 49.7 μmol/dm 3 NH + 4 after the experiment compared with DIC measured without nitrogen addition. A significant negative-correlation was found between c(DIC) and growth rate (μ) of Ulva pertusa (r = -0.91, P <0.000 1, n=11). NH + 4 had more influence on the species of inorganic carbon system than NO 3 .  相似文献   

Comparison of carbonate parameters and air–sea CO<Subscript>2</Subscript> flux in the southern Yellow Sea and East China Sea during spring and summer of 2011     

Baoxiao Qu  Jinming Song  Huamao Yuan  Xuegang Li  Ning Li  Liqin Duan 《Journal of Oceanography》2017,73(3):365-382

In this work, we examined the carbonate parameters, i.e. total alkalinity (TA), pH, and partial pressure of CO₂ (pCO₂), and the air–sea CO₂ flux (FCO₂) in the continental shelves of the southern Yellow Sea (SYS) and East China Sea (ECS), based on two field surveys conducted in April and August of 2011. Surface pCO₂ showed significant spatial variations, ranging from 246 to 686 µatm in spring (average ± standard deviation = 379 ± 95 µatm) and from 178 to 680 µatm in summer (384 ± 114 µatm). During the spring cruise, the central SYS (pCO₂ < 240 µatm) and the Changjiang estuary (pCO₂ < 300 µatm) were under-saturated with CO₂, while the southern SYS and the southwestern ECS were supersaturated (pCO₂ = 420–680 µatm). In summer, however, the CO₂-supersaturated waters (pCO₂ = 380–680 µatm) occupied a relatively wide area, including the nearshore of the SYS and the Changjiang estuary, whereas pCO₂-deficient water (pCO₂ = 220–380 µatm) was observed only at the offshore ECS. In general, the entire SYS and ECS area behaved as a sustained CO₂ sink, with average FCO₂ of ?3.9 and ?2.1 mmol m^?2 d^?1 in spring and summer, respectively. Phytoplankton production was the driving force for CO₂ absorption, especially during the spring cruise. In addition, we found that typical water mixing processes and decomposition of terrestrial material were responsible for the release of CO₂ in three turbidity maximum regions.  相似文献   

2008年夏季加拿大海盆净二氧化碳吸收量评估     

孙恒  高众勇  修鹏  卢鹏  陈立奇 《海洋学报(英文版)》2017,36(8):94-100

The third Chinese National Arctic Research Expedition(CHINARE) was conducted in the summer of 2008.During the survey,the surface seawater partial pressure of CO_2(pCO_2) was measured,and sea water samples were collected for CO_2 measurement in the Canada Basin.The distribution of pCO_2 in the Canada Basin was determined,the influencing factors were addressed,and the air-sea CO_2 flux in the Canada Basin was evaluated.The Canada Basin was divided into three regions:the ice-free zone(south of 77°N),the partially ice-covered zone(77°–80°N),and the heavily ice-covered zone(north of 80°N).In the ice-free zone,pCO_2 was high(320 to 368μatm,1 μatm=0.101 325 Pa),primarily due to rapid equilibration with atmospheric CO_2 over a short time.In the partially ice-covered zone,the surface pCO_2 was relatively low(250 to 270 μatm) due to ice-edge blooms and icemelt water dilution.In the heavily ice-covered zone,the seawater pCO_2 varied between 270 and 300 μatm due to biological CO_2 removal,the transportation of low pCO_2 water northward,and heavy ice cover.The surface seawater pCO_2 during the survey was undersaturated with respect to the atmosphere in the Canada Basin,and it was a net sink for atmospheric CO_2.The summertime net CO_2 uptake of the ice-free zone,the partially ice-covered zone and the heavily ice-covered zone was(4.14±1.08),(1.79±0.19),and(0.57±0.03) Tg/a(calculated by carbon,1Tg=10~(12) g),respectively.Overall,the net CO_2 sink of the Canada Basin in the summer of 2008 was(6.5±1.3) Tg/a,which accounted for 4%–10% of the Arctic Ocean CO_2 sink.  相似文献   

Characterizing air–sea CO2 exchange dynamics during winter in the coastal water off the Hugli-Matla estuarine system in the northern Bay of Bengal, India     

Anirban Akhand  Abhra Chanda  Sachinandan Dutta  Sudip Manna  Sugata Hazra  Debasis Mitra  K. H. Rao  V. K. Dadhwal 《Journal of Oceanography》2013,69(6):687-697

The distribution of the fugacity of CO₂ ( $ f_{{{\text{CO}}_{ 2} }} $ ) and air–sea CO₂ exchange were comprehensively investigated in the outer estuary to offshore shallow water region (lying adjacent to the Sundarban mangrove forest) covering an area of ~2,000 km² in the northern Bay of Bengal during the winter. A total of ten sampling surveys were conducted between 1 December, 2011 and 21 February, 2012. Physico-chemical variables like sea surface temperature (SST), salinity, pH, total alkalinity (TAlk), dissolved inorganic carbon (DIC) and in vivo chlorophyll-a along with atmospheric variables were measured in order to study their role in controlling the CO₂ flux. Surface water $ f_{{{\text{CO}}_{ 2} }} $ ranged between 111 and 459 μatm which correlated significantly with the SST (r = 0.71, p < 0.001, n = 62). Neither DIC nor TAlk showed any linear relationship with varying salinity in the estuarine mixing zone, demonstrating the significant presence of non-carbonate alkalinity. An overall net biological control on the surface $ f_{{{\text{CO}}_{ 2} }} $ distribution was established during the study, although no significant correlation was found between chlorophyll-a and $ f_{{{\text{CO}}_{ 2} }} $ (water). The shallow water region studied was mostly under-saturated with CO₂ and acted as a sink for atmospheric CO₂. The difference between surface water and atmospheric $ f_{{{\text{CO}}_{ 2} }} $ ( $ \Updelta f_{{{\text{CO}}_{ 2} }} $ ) ranged from ?274 to 69 μatm, with an average seaward flux of ?10.5 ± 12.6 μmol m^?2 h^?1. The $ \Updelta f_{{{\text{CO}}_{ 2} }} $ and hence the air–sea CO₂ exchange was primarily regulated by the variation in sea surface $ f_{{{\text{CO}}_{ 2} }} $ , since atmospheric $ f_{{{\text{CO}}_{ 2} }} $ varied over a comparatively narrow range of 361.23–399.05 μatm.  相似文献   

Comparison of the results of determination of the carbonate system and the total alkalinity of seawater according to the data obtained by using different analytic methods     

D. S. Khoruzhii  E. I. Ovsyanyi  S. K. Konovalov 《Physical Oceanography》2011,21(3):182-194

On the basis of the data of hydrochemical investigations of waters of the Sevastopol Bay, we discuss the results of the analysis of the carbonate system and the total alkalinity of seawater obtained by using two methods. By using the linear method of least squares, we compare the results of the analysis of the carbonate system according to pH values and the total alkalinity and according to pH values and dissolved inorganic carbon. It is shown that, within the investigated range of pH values, Alk, and TCO₂, the mean relative deviations of values of the fugacity of CO₂ and the concentrations of dissolved CO₂ and CO₃²⁻ ions computed by using different input parameters are equal to 3.0, 1.0, and 9.6%, respectively.  相似文献   

Theoretical considerations about the reactions of calcification in sea water     

Claire Copin Montgut  Grard Copin Montgut 《Marine Chemistry》1999,63(3-4)

We examine the concentration variations of the different parameters X of the carbonate system in seawater when calcium carbonate precipitation occurs. Variations are expressed as ∂[X]/∂[Ca²⁺]. Four different cases are considered: spontaneous chemical precipitation; calcification combined with photosynthetic activity under a constant ΔCT/Δ[Ca²⁺] ratio; precipitation under constant p_CO2 and precipitation under constant [Ca²⁺]·[CO₃²⁻] ionic concentration product. The last condition should be maintained by an ecosystem which, thanks to the regulation of its calcifying and photosynthetic activity, would absorb 1 mol of carbon for organic tissue each time 1 mol of CaCO₃ is formed. This stoichiometric ratio would allow the activity of these biological communities to go on in practically closed systems during periods compatible with their growth or development cycles.  相似文献   

Biological organic carbon export estimated from the annual carbon budget observed in the surface waters of the western subarctic and subtropical North Pacific Ocean from 2004 to 2013     

Masahide Wakita  Makio C. Honda  Kazuhiko Matsumoto  Tetsuichi Fujiki  Hajime Kawakami  Sayaka Yasunaka  Yoshikazu Sasai  Chiho Sukigara  Mario Uchimiya  Minoru Kitamura  Toru Kobari  Yoshihisa Mino  Akira Nagano  Shuichi Watanabe  Toshiro Saino 《Journal of Oceanography》2016,72(5):665-685

The annual flux of biologically produced organic carbon from surface waters is equivalent to annual net community production (NCP) at a steady state and equals the export of particulate and dissolved organic carbon (POC and DOC, respectively) to the ocean interior. NCP was estimated from carbon budgets of salinity-normalized dissolved inorganic carbon (nDIC) inventories at two time-series stations in the western subarctic (K2) and subtropical (S1) North Pacific Ocean. By using quasi-monthly biogeochemical observations from 2004 to 2013, monthly mean nDIC inventories were integrated from the surface to the annual maximum mixed layer depth and corrected for changes due to net air–sea CO₂ exchange, net CaCO₃ production, vertical diffusion from the upper thermocline, and horizontal advection. The annual organic carbon flux at K2 (1.49 ± 0.42 mol m^?2 year^?1) was lower than S1 (2.81 ± 0.53 mol m^?2 year^?1) (p < 0.001 based on t test). These fluxes consist of three components: vertically exported POC fluxes (K2: 1.43 mol m^?2 year^?1; S1: 2.49 mol m^?2 year^?1), vertical diffusive DOC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.25 mol m^?2 year^?1), and suspended POC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.07 mol m^?2 year^?1). The estimated POC export flux at K2 was comparable to the sum of the POC flux observed with drifting sediment traps and active carbon flux exported by migrating zooplankton. The export fluxes at both stations were higher than those reported at other time-series sites (ALOHA, the Bermuda Atlantic Time-series Study, and Ocean Station Papa).  相似文献   

Gas flux and carbonate occurrence at a shallow seep of thermogenic natural gas   总被引：1，自引：1，他引：0  

Franklin S. Kinnaman  Justine B. Kimball  Luis Busso  Daniel Birgel  Haibing Ding  Kai-Uwe Hinrichs  David L. Valentine 《Geo-Marine Letters》2010,30(3-4):355-365

The Coal Oil Point seep field located offshore Santa Barbara, CA, consists of dozens of named seeps, including a peripheral ～200 m² area known as Brian Seep, located in 10 m water depth. A single comprehensive survey of gas flux at Brian Seep yielded a methane release rate of ～450 moles of CH₄ per day, originating from 68 persistent gas vents and 23 intermittent vents, with gas flux among persistent vents displaying a log normal frequency distribution. A subsequent series of 33 repeat surveys conducted over a period of 6 months tracked eight persistent vents, and revealed substantial temporal variability in gas venting, with flux from each individual vent varying by more than a factor of 4. During wintertime surveys sediment was largely absent from the site, and carbonate concretions were exposed at the seafloor. The presence of the carbonates was unexpected, as the thermogenic seep gas contains 6.7% CO₂, which should act to dissolve carbonates. The average δ¹³C of the carbonates was ?29.2?±?2.8‰ VPDB, compared to a range of ?1.0 to +7.8‰ for CO₂ in the seep gas, indicating that CO₂ from the seep gas is quantitatively not as important as ¹³C-depleted bicarbonate derived from methane oxidation. Methane, with a δ¹³C of approximately ?43‰, is oxidized and the resulting inorganic carbon precipitates as high-magnesium calcite and other carbonate minerals. This finding is supported by ¹³C-depleted biomarkers typically associated with anaerobic methanotrophic archaea and their bacterial syntrophic partners in the carbonates (lipid biomarker δ¹³C ranged from ?84 to ?25‰). The inconsistency in δ¹³C between the carbonates and the seeping CO₂ was resolved by discovering pockets of gas trapped near the base of the sediment column with δ¹³C-CO₂ values ranging from ?26.9 to ?11.6‰. A mechanism of carbonate formation is proposed in which carbonates form near the sediment–bedrock interface during times of sufficient sediment coverage, in which anaerobic oxidation of methane is favored. Precipitation occurs at a sufficient distance from active venting for the molecular and isotopic composition of seep gas to be masked by the generation of carbonate alkalinity from anaerobic methane oxidation.