Effects of CO<Subscript>2</Subscript> on Marine Fish: Larvae and Adults     

Atsushi Ishimatsu  Takashi Kikkawa  Masahiro Hayashi  Kyoung-Seon Lee  Jun Kita 《Journal of Oceanography》2004,60(4):731-741

CO₂-enriched seawater was far more toxic to eggs and larvae of a marine fish, silver seabream, Pagrus major, than HCl-acidified seawater when tested at the same seawater pH. Data on the effects of acidified seawater can therefore not be used to estimate the toxicity of CO₂, as has been done in earlier studies. Ontogenetic changes in CO₂ tolerance of two marine bony fishes (Pag. major and Japanese sillago, Sillago japonica) showed a similar, characteristic pattern: the cleavage and juvenile stages were most susceptible, whereas the preflexion and flexion stages were much more tolerant to CO₂. Adult Japanese amberjack, Seriola quinqueradiata, and bastard halibut, Paralichthys olivaceus, died within 8 and 48 h, respectively, during exposure to seawater equilibrated with 5% CO₂. Only 20% of a cartilaginous fish, starspotted smooth-hound, Mustelus manazo, died at 7% CO₂ within 72 h. Arterial pH initially decreased but completely recovered within 1-24 h for Ser. quinqueradiata and Par. olivaceus at 1 and 3% CO₂, but the recovery was slower and complete only at 1% for M. manazo. During exposure to 5% CO₂, Par. olivaceus died after arterial pH had been completely restored. Exposure to 5% CO₂ rapidly depressed the cardiac output of Ser. quinqueradiata, while 1% CO₂ had no effect. Both levels of ambient CO₂ had no effect on blood O₂ levels. We tentatively conclude that cardiac failure is important in the mechanisms by which CO₂ kills fish. High CO₂ levels near injection points during CO₂ ocean sequestration are likely to have acute deleterious effects on both larvae and adults of marine fishes. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Influence of Introduced CO<Subscript>2</Subscript> on Deep-Sea Metazoan Meiofauna     

Kevin R. Carman  David Thistle  John W. Fleeger  James P. Barry 《Journal of Oceanography》2004,60(4):767-772

An experiment was performed to determine the effect of injected CO₂ on the deep-sea (3200 m) meiofaunal community in the Monterey Canyon. Approximately 20 L of liquid CO₂ was added to each of three cylindrical corrals (PVC rings pushed into the seabed) that were arranged in a triangular array 10 m on a side. After a 30-day period, sediment cores were collected within an area exposed to the dissolution plume emanating from the CO₂ pools and from a reference site approximately 40 m away; cores were also collected from within two of the CO₂ corrals. Sediment cores were sectioned into 0–5, 5–10, and 10–20 mm layers. Abundances of major groups (harpacticoid copepods, nematodes, nauplii, kinorhynchs, polychaetes, and total meiofauna) were determined for each layer. CO₂ exposure did not significantly influence the abundances or vertical distributions of any of the major taxa. However, other evidence suggests that abundance alone did not accurately reflect the effect of CO₂ on meiofauna. We argue that slow decomposition rates of meiofaunal carcasses can mask adverse effects of CO₂ and that longer experiments and/or careful examination of meiofaunal condition are needed to accurately evaluate CO₂ effects on deep-sea meiofaunal communities. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Sub-Lethal Effects of Elevated Concentration of CO<Subscript>2</Subscript> on Planktonic Copepods and Sea Urchins   总被引：2，自引：0，他引：2  

Haruko Kurihara  Shinji Shimode  Yoshihisa Shirayama 《Journal of Oceanography》2004,60(4):743-750

Data concerning the effects of high CO₂ concentrations on marine organisms are essential for both predicting future impacts of the increasing atmospheric CO₂ concentration and assessing the effects of deep-sea CO₂sequestration. Here we review our recent studies evaluating the effects of elevated CO₂ concentrations in seawater on the mortality and egg production of the marine planktonic copepod, Acartia steueri, and on the fertilization rate and larval morphology of sea urchin embryos, Hemicentrotus pulcherrimus and Echinometra mathaei. Under conditions of +10,000 ppm CO₂ in seawater (pH 6.8), the egg production rates of copepods decreased significantly. The survival rates of adult copepods were not affected when reared under increased CO₂ for 8 days, however longer exposure times could have revealed toxic effects of elevated CO₂ concentrations. The fertilization rate of sea urchin eggs of both species decreased with increasing CO₂ concentration. Furthermore, the size of pluteus larvae decreased with increasing CO₂ concentration and malformed skeletogenesis was observed in both larvae. This suggests that calcification is affected by elevated CO₂ in the seawater. From these results, we conclude that increased CO₂ concentration in seawater will chronically affect several marine organisms and we discuss the effects of increased CO₂ on the marine carbon cycle and marine ecosystem. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Effects of Direct Ocean CO<Subscript>2</Subscript> Injection on Deep-Sea Meiofauna     

James P. Barry  Kurt R. Buck  Chris F. Lovera  Linda Kuhnz  Patrick J. Whaling  Edward T. Peltzer  Peter Walz  Peter G. Brewer 《Journal of Oceanography》2004,60(4):759-766

Purposeful deep-sea carbon dioxide sequestration by direct injection of liquid CO₂ into the deep waters of the ocean has the potential to mitigate the rapid rise in atmospheric levels of greenhouse gases. One issue of concern for this carbon sequestration option is the impact of changes in seawater chemistry caused by CO₂ injection on deep-sea ecosystems. The effects of deep-sea carbon dioxide injection on infaunal deep-sea organisms were evaluated during a field experiment in 3600 m depth off California, in which liquid CO₂ was released on the seafloor. Exposure to the dissolution plume emanating from the liquid CO₂ resulted in high rates of mortality for flagellates, amoebae, and nematodes inhabiting sediments in close proximity to sites of CO₂ release. Results from this study indicate that large changes in seawater chemistry (i.e. pH reductions of ∼0.5–1.0 pH units) near CO₂ release sites will cause high mortality rates for nearby infaunal deep-sea communities. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Perspectives on Biological Research for CO<Subscript>2</Subscript> Ocean Sequestration     

Jun Kita  Takashi Ohsumi 《Journal of Oceanography》2004,60(4):695-703

Feasibility studies recently suggest that sequestration of anthropogenic CO₂ in the deep ocean could help reduce the atmospheric CO₂ concentration. However, implementation of this strategy could have a significant environmental impact on marine organisms. This has highlighted the urgent need of further studies concerning the biological impact of CO₂ ocean sequestration. In this paper we summarize the recent literature reporting on the biological impact of CO₂ and discuss the research work required for the future. Although fundamental research of the effect of CO₂ on marine organisms before the practical consideration of CO₂ ocean sequestration was limited, laboratory and field studies concerning biological impacts have been increasing after the first international workshop in 1991 discussing CO₂ ocean sequestration. Acute impacts of CO₂ ocean sequestration could be determined by laboratory and field experiments and assessed by simulation models as described by the following papers in this section. On the other hand, chronic effects of CO₂ ocean sequestration, those directly related to the marine ecosystem, would be difficult to verify by means of experiments and to assess using ecosystem models. One of the practical solutions for this issue implies field experiments starting with controlled small scale and eventually to a large scale of CO₂ injection intended to determine ecosystem alteration. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Physiological effects of hypercapnia in the deep-sea bivalve Acesta excavata (Fabricius, 1779) (Bivalvia; Limidae)     

Hammer KM  Kristiansen E  Zachariassen KE 《Marine environmental research》2011,72(3):135-142

The option of storing CO₂ in subsea rock formations to mitigate future increases in atmospheric CO₂ may induce problems for animals in the deep sea. In the present study the deep-sea bivalve Acesta excavata was subjected to environmental hypercapnia (pHSW 6.35, PCO₂ = 33,000 μatm) corresponding to conditions reported from natural CO₂ seeps. Effects on acid–base status and metabolic rate were related to time of exposure and subsequent recovery. During exposure there was an uncompensated drop in both hemolymph and intracellular pH. Intracellular pH returned to control values, while extracellular pH remained significantly lower during recovery. Intracellular non-bicarbonate buffering capacity of the posterior adductor muscle of hypercapnic animals was significantly lower than control values, but this was not the case for the remaining tissues analyzed. Oxygen consumption initially dropped by 60%, but then increased during the final stages of exposure, which may suggest a higher tolerance to hypercapnia than expected for a deep-living species.  相似文献   

CO<Subscript>2</Subscript> Flux Measurements over the Sea Surface by Eddy Correlation and Aerodynamic Techniques     

Toru?Iwata  Keiko?Yoshikawa  Katsutoshi?Nishimura  Yoshihisa?Higuchi  Takao?Yamashita  Shigeru?Kato  Eiji?OhtakiEmail author 《Journal of Oceanography》2004,60(6):995-1000

The measurements of the vertical transport of CO₂ were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO₂ fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO₂ fluxes during sea breeze conditions: −0.001 to −0.08 mg m⁻²s⁻¹ with the mean of −0.05 mg m⁻²s⁻¹. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO₂ flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO₂ concentration difference of the order of 0.1 ppmv on the research vessels or the buoys.  相似文献   

Air-sea CO<Subscript>2</Subscript> flux by eddy covariance technique in the equatorial Indian Ocean     

Fumiyoshi Kondo  Osamu Tsukamoto 《Journal of Oceanography》2007,63(3):449-456

Direct measurements of the air-sea CO₂ flux by the eddy covariance technique were carried out in the equatorial Indian Ocean. The turbulent flux observation system was installed at the top of the foremast of the R/V MIRAI, thus minimizing dynamical and thermal effects of the ship body. During the turbulent flux runs around the two stations, the vessel was steered into the wind at constant speed. The power spectra of the temperature or water vapor density fluctuations followed the Kolmogorov −5/3 power law, although that of the CO₂ density fluctuation showed white noise in the high frequency range. However, the cospectrum of the vertical wind velocity and CO₂ density was well matched with those of the vertical velocity and temperature or water vapor density in this frequency range, and the CO₂ white noise did not influence the CO₂ flux. The raw CO₂ fluxes due to the turbulent transport showed a sink from the air to the ocean, and had almost the same value as the source CO₂ fluxes due to the mean vertical flow, corrected by the sensible and latent heat fluxes (called the Webb correction). The total CO₂ fluxes including the Webb correction terms showed a source from the ocean to the air, and were larger than the bulk CO₂ fluxes estimated using the gas transfer velocity by mass balance techniques.  相似文献   

Effects of CO<Subscript>2</Subscript> Enrichment on Marine Phytoplankton   总被引：1，自引：0，他引：1  

Ulf Riebesell 《Journal of Oceanography》2004,60(4):719-729

Rising atmospheric CO₂ and deliberate CO₂ sequestration in the ocean change seawater carbonate chemistry in a similar way, lowering seawater pH, carbonate ion concentration and carbonate saturation state and increasing dissolved CO₂ concentration. These changes affect marine plankton in various ways. On the organismal level, a moderate increase in CO₂ facilitates photosynthetic carbon fixation of some phytoplankton groups. It also enhances the release of dissolved carbohydrates, most notably during the decline of nutrient-limited phytoplankton blooms. A decrease in the carbonate saturation state represses biogenic calcification of the predominant marine calcifying organisms, foraminifera and coccolithophorids. On the ecosystem level these responses influence phytoplankton species composition and succession, favouring algal species which predominantly rely on CO₂ utilization. Increased phytoplankton exudation promotes particle aggregation and marine snow formation, enhancing the vertical flux of biogenic material. A decrease in calcification may affect the competitive advantage of calcifying organisms, with possible impacts on their distribution and abundance. On the biogeochemical level, biological responses to CO₂ enrichment and the related changes in carbonate chemistry can strongly alter the cycling of carbon and other bio-active elements in the ocean. Both decreasing calcification and enhanced carbon overproduction due to release of extracellular carbohydrates have the potential to increase the CO₂ storage capacity of the ocean. Although the significance of such biological responses to CO₂ enrichment becomes increasingly evident, our ability to make reliable predictions of their future developments and to quantify their potential ecological and biogeochemical impacts is still in its infancy. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Experiments on the ocean sequestration of fossil fuel CO₂: pH measurements and hydrate formation     

Peter G. Brewer  Edward T. Peltzer  Gernot Friederich  Izuo Aya  Kenji Yamane 《Marine Chemistry》2000,72(2-4)

We have carried out a series of in situ experiments to investigate the formation of a CO₂ hydrate (CO₂:5.75 H₂O) for the purpose of evaluating scenarios for ocean fossil fuel CO₂ disposal with a solid hydrate as the sequestered form. The experiments were carried out with a remotely operated vehicle in Monterey Bay at a depth of 619 m. pH measurements made in close proximity to the hydrate–seawater interface showed a wide range of values, depending upon the method of injection and the surface area of the hydrate formed. Rapid injection of liquid CO₂ into an inverted beaker to form a flocculant mass of hydrate resulted in pH initially as low as 4.5 within a few centimeters of the interface, decaying slowly over 1–2 h towards normal seawater values as dense CO₂ rich brine drained from the hydrate mass. In a second experiment, slower injection of the liquid CO₂ to produce a simple two-layer system with a near planar interface of liquid CO₂ with a thin hydrate film yielded pH values indistinguishable from the in situ ocean background level of 7.6. Both field and laboratory results now show that the dissolution rate of a mass of CO₂ hydrate in seawater is slow but finite.  相似文献   

2008年夏季加拿大海盆净二氧化碳吸收量评估     

孙恒  高众勇  修鹏  卢鹏  陈立奇 《海洋学报(英文版)》2017,36(8):94-100

The third Chinese National Arctic Research Expedition(CHINARE) was conducted in the summer of 2008.During the survey,the surface seawater partial pressure of CO_2(pCO_2) was measured,and sea water samples were collected for CO_2 measurement in the Canada Basin.The distribution of pCO_2 in the Canada Basin was determined,the influencing factors were addressed,and the air-sea CO_2 flux in the Canada Basin was evaluated.The Canada Basin was divided into three regions:the ice-free zone(south of 77°N),the partially ice-covered zone(77°–80°N),and the heavily ice-covered zone(north of 80°N).In the ice-free zone,pCO_2 was high(320 to 368μatm,1 μatm=0.101 325 Pa),primarily due to rapid equilibration with atmospheric CO_2 over a short time.In the partially ice-covered zone,the surface pCO_2 was relatively low(250 to 270 μatm) due to ice-edge blooms and icemelt water dilution.In the heavily ice-covered zone,the seawater pCO_2 varied between 270 and 300 μatm due to biological CO_2 removal,the transportation of low pCO_2 water northward,and heavy ice cover.The surface seawater pCO_2 during the survey was undersaturated with respect to the atmosphere in the Canada Basin,and it was a net sink for atmospheric CO_2.The summertime net CO_2 uptake of the ice-free zone,the partially ice-covered zone and the heavily ice-covered zone was(4.14±1.08),(1.79±0.19),and(0.57±0.03) Tg/a(calculated by carbon,1Tg=10~(12) g),respectively.Overall,the net CO_2 sink of the Canada Basin in the summer of 2008 was(6.5±1.3) Tg/a,which accounted for 4%–10% of the Arctic Ocean CO_2 sink.  相似文献   

A Eulerian-Eulerian Physical-Biological Impact Model of Zooplankton Injury Due to CO<Subscript>2</Subscript> Ocean Sequestration     

Baixin Chen  Yongchen Song  Masahiro Nishio  Makoto Akai 《Journal of Oceanography》2004,60(4):797-805

To study the biological impacts of CO₂ ocean sequestration on floating marine organisms, a full Eulerian-Eulerian scheme model has been developed in a large-eddy simulation (LES) version using one-way coupling of the equations of seawater flow to the transport equations of the bio-scalar variables. Special attention was paid to deriving the transport equation, involving non-conservative scalars to describe the degree of injury to floating organisms due to the change in the pH environment resulting from CO₂ dissolution. The source terms of the transport equations of bio-scalar variables are based on experimental data on zooplankton activities affected by lower pH seawater, allowing construction of empirical sub-models of three kinds of floating marine organisms: Gaidius variabilis, Paraeuchaeta Birostrata, and Multi-organisms. An example is given to show the applicability of the model to the assessment of the biological impact of CO₂ sequestration in the ocean. Given an initial CO₂ droplet diameter of 8.0 mm and an injection rate of 1.0 kg/sec, the model simulation predicts that the zooplanktons lose approximately 90% of their activity when the lowest pH inside the plume decreases from 7.57 to 5.61. These injured zooplanktons then recovered gradually to their normal state within two hours due to dilution of the plume. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Short-term variability of fCO₂ in seawater and air–sea CO₂ fluxes in a coastal upwelling system (Ría de Vigo, NW Spain)     

J. Gago  M. Gilcoto  F. F. Prez  A. F. Ríos 《Marine Chemistry》2003,80(4):247-264

Coastal upwelling systems are regions with highly variable physical processes and very high rates of primary production and very little is known about the effect of these factors on the short-term variations of CO₂ fugacity in seawater (fCO₂^w). This paper presents the effect of short-term variability (<1 week) of upwelling–downwelling events on CO₂ fugacity in seawater (fCO₂^w), oxygen, temperature and salinity fields in the Ría de Vigo (a coastal upwelling ecosystem). The magnitude of fCO₂^w values is physically and biologically modulated and ranges from 285 μatm in July to 615 μatm in October. There is a sharp gradient in fCO₂^w between the inner and the outer zone of the Ría during almost all the sampling dates, with a landward increase in fCO₂^w.CO₂ fluxes calculated from local wind speed and air–sea fCO₂ differences indicate that the inner zone is a sink for atmospheric CO₂ in December only (−0.30 mmol m⁻² day⁻¹). The middle zone absorbs CO₂ in December and July (−0.05 and −0.27 mmol·m⁻² day⁻¹, respectively). The oceanic zone only emits CO₂ in October (0.36 mmol·m⁻² day⁻¹) and absorbs at the highest rate in December (−1.53 mmol·m⁻² day⁻¹).  相似文献   

The Air-Sea Exchange of CO2 in the East Sea (Japan Sea)     

Dong-Chan Oh  Mi-Kyung Park  Sang-Hwa Choi  Dong-Jin Kang  Sun Young Park  Jeom Shik Hwang  Andrey Andreev  Gi Hoon Hong  Kyung-Ryul Kim 《Journal of Oceanography》1999,55(2):157-169

During CREAMS expeditions, fCO₂ for surface waters was measured continuously along the cruise tracks. The fCO₂ in surface waters in summer varied in the range 320–440 μatm, showing moderate supersaturation with respect to atmospheric CO₂. In winter, however, fCO₂ showed under-saturation of CO₂ in most of the area, while varying in a much wider range from 180 to 520 μatm. Some very high fCO₂ values observed in the northern East Sea (Japan Sea) appeared to be associated with the intensive convection system developed in the area. A gas-exchange model was developed for describing the annual variation of fCO₂ and for estimating the annual flux of CO₂ at the air-sea interface. The model incorporated annual variations in SST, the thickness of the mixed layer, gas exchange associated with wind velocity, biological activity and atmospheric concentration of CO₂. The model shows that the East Sea releases CO₂ into the atmosphere from June to September, and absorbs CO₂ during the rest of the year, from October through May. The net annual CO₂ flux at the air-sea interface was estimated to be 0.032 (±0.012) Gt-C per year from the atmosphere into the East Sea. Water column chemistry shows penetration of CO₂ into the whole water column, supporting a short turnover time for deep waters in the East Sea. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Time series of carbonate system variables off Otaru coast in Hokkaido, Japan     

Ai Sakamoto  Yutaka W. Watanabe  Masato Osawa  KazuoKido  Shinichiro Noriki 《Estuarine, Coastal and Shelf Science》2008,79(3):377-386

We report several biogeochemical parameters (dissolved inorganic carbon (DIC), total alkalinity (TA), dissolved oxygen (DO), phosphate (PO₄), nitrate + nitrite (NO₃ + NO₂), silicate (Si(OH)₄)) in a region off Otaru coast in Hokkaido, Japan on a “weekly” basis during the period of April 2002–May 2003. To better understand the long-term temporal variations of the main factors affecting CO₂ flux in this coastal region and its role as a sink/source of atmospheric CO₂, we constructed an algorithm of DIC and TA using other hydrographic properties. We estimated the CO₂ flux across the air–sea interface by using the classical bulk method. During 1998–2003 in our study region, the estimated fCO_2sea ranged about 185–335 μatm. The maximum of fCO_2sea in the summer was primarily due to the change of water temperature. The minimum of fCO_2sea in the early spring can be explained not only by the change of water temperature but also the change of nutrients and chlorophyll-a. To clarify the factors affecting fCO_2sea (water temperature, salinity, and biological activity), we carried out a sensitivity analysis of these effects on the variation of fCO_2sea. In spring, the biological effect had the largest effect for the minimum of fCO_2sea (40%). In summer, the water temperature effect had the largest effect for the maximum of fCO_2sea (25%). In fall, the water temperature effect had the largest effect for the minimum of fCO_2sea (53%). In winter, the biological effect had the largest effect for the minimum of fCO_2sea (35%).We found that our study region was a sink region of CO₂ throughout a year (−0.78 mol/m²/yr). Furthermore, we estimated that the increase of fCO_2sea was about 0.56 μatm/yr under equilibrium with the atmospheric CO₂ content for the period 1998–2003, with the temporal changes in the variables (T, S, PO₄) on fCO_2sea, thus as the maximum trend of each variable on fCO_2sea was 0.22 μatm/yr, and the trend of residual fCO₂ including gas exchange was 0.34 μatm/yr. This result suggests that interaction among variables would affect gas exchange between air and sea effects on fCO_2sea. We conclude that this study region as a representative coastal region of marginal seas of the North Pacific is special because it was measured, but there is no particular significance in comparison to any other area.  相似文献   

不同适温海洋富油微藻在富碳培养条件下的油脂积累特性研究   总被引：1，自引：0，他引：1  

王帅  郑立  韩笑天  李林  杨佰娟  刘晨光 《海洋学报》2014,36(12):41-52

本实验分别针对3株低温藻株:微拟球藻Nannochloropsis sp.ZL-12、四爿藻Tetraselmis chui ZL-33和小球藻Chlorellasp.ZL-45,3株中温藻株:球等鞭金藻Isochrysis galbana CCMM5001、等鞭金藻Isochrysis sp.CCMM5002和微拟球藻Nannochloropsis sp.CCMM7001,3株高温藻株:微拟球藻Nannochloropsis sp.JN1、绿色巴夫藻Pavlova viridis JN2和海洋小球藻Chlorellasp.JN3,研究了在通入0.03%(空气)、5%、10%3个CO2浓度梯度条件下的生长特性,同时考察了其总酯及中性脂的累积情况。结果显示,富碳培养有利于不同温度条件下9株藻株的生长,除微拟球藻Nannochloropsis sp.CCMM7001最适生长的CO2浓度为5%外,其余8株藻株最适生长的CO2浓度均为10%。在低温和高温条件下,6株海洋富油微藻在通入10%CO2时具有最大生物量产率,在中温条件下球等鞭金藻和等鞭金藻在通入10%CO2时获得最大生物量产率,而微拟球藻在通入5%时获得最大生物量产率,随着CO2浓度的增加,9株藻株的总脂含量和中性脂含量有明显提高。低温和中温藻株的总脂含量高于高温藻株的总脂含量,从中性脂的累积规律来看,9株藻株均在平台期的累积达到最大值,GC-MS分析结果表明,9株微藻适合制备生物柴油的C14~C18系脂肪酸相对含量在不同CO2条件下基本保持不变,维持在90%左右。实验结果显示,所研究的藻株作为富油高固碳优良藻株,具备用于海洋生物质能耦合CO2减排开发的潜力。  相似文献   

淡水和海水环境下沉积物搬运过程碳释放通量的模拟研究     

彭峰  唐梅  刘昱恒 《海洋科学》2013,37(9):77-81

基于室内物理模拟实验, 对长江沉积物进行淡水和海水环境下沉积物搬运过程碳释放通量实验模拟。结果表明, 模拟实验初期, 淡水和海水均为大气CO₂的源, 但淡水CO₂释放通量略高于海水;淡水、海水两种环境下, CH₄释放通量均较小, 为弱释放-弱吸收过程。对两种环境下碳通量对比研究发现,Eh 值可能是造成淡水和海水环境下CO₂通量差别的主要原因, 而pH 值可能对CO₂通量差别的影响较小。两种环境下温室气体通量差别的具体原因仍需进一步研究。通过模拟对比试验, 旨在为系统地认识长江流域水库的温室效应与减排提供科学依据, 为我国清洁水电能源发展提供理论参考。  相似文献   

An improved model for the calculation of CO₂ solubility in aqueous solutions containing Na, K, Ca, Mg, Cl, and SO₄     

Zhenhao Duan  Rui Sun  Chen Zhu  I-Ming Chou 《Marine Chemistry》2006,98(2-4):131-139

An improved model is presented for the calculation of the solubility of carbon dioxide in aqueous solutions containing Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻, and SO₄²⁻ in a wide temperature–pressure–ionic strength range (from 273 to 533 K, from 0 to 2000 bar, and from 0 to 4.5 molality of salts) with experimental accuracy. The improvements over the previous model [Duan, Z. and Sun, R., 2003. An improved model calculating CO₂ solubility in pure water and aqueous NaCl solutions from 273 to 533K and from 0 to 2000 bar. Chemical Geology, 193: 257–271] include: (1) By developing a non-iterative equation to replace the original equation of state in the calculation of CO₂ fugacity coefficients, the new model is at least twenty times computationally faster and can be easily adapted to numerical reaction-flow simulator for such applications as CO₂ sequestration and (2) By fitting to the new solubility data, the new model improved the accuracy below 288 K from 6% to about 3% of uncertainty but still retains the high accuracy of the original model above 288 K. We comprehensively evaluate all experimental CO₂ solubility data. Compared with these data, this model not only reproduces all the reliable data used for the parameterization but also predicts the data that were not used in the parameterization. In order to facilitate the application to CO₂ sequestration, we also predicted CO₂ solubility in seawater at two-phase coexistence (vapor–liquid or liquid–liquid) and at three-phase coexistence (CO₂ hydrate–liquid water–vapor CO₂ [or liquid CO₂]). The improved model is programmed and can be downloaded from the website http://www.geochem-model.org/programs.htm.  相似文献   

考洲洋牡蛎养殖海域海-气界面CO₂交换通量的时空变化     

彭鹏飞  马媛  史荣君  王迪  许欣  颜彬 《海洋科学》2022,46(10):140-149

根据2018年7月、11月和2019年1月、4月对广东考洲洋牡蛎养殖海域进行4个季节调查获得的pH、溶解无机碳(DIC)、水温、盐度、溶解氧(DO)及叶绿素a(Chla)等数据,估算该区域表层海水溶解无机碳体系各分量的浓度、初级生产力(P_P)、表层海水CO₂分压[p(CO₂)]和海-气界面CO₂交换通量(F_CO2),分析牡蛎养殖活动对养殖区碳循环的影响。结果表明:牡蛎养殖区表层海水中Chla、DIC、HCO₃^–和P_P显著低于非养殖区;养殖淡季表层海水中pH、DO、DIC、HCO₃^–、和CO₃^2–显著大于养殖旺季,养殖旺季的p(CO₂)和F_CO2显著大于养殖淡季。牡蛎养殖区表层海水夏季、秋季、冬季和春季的海-气界面CO₂交换通量F_CO2平均值分别是(42.04±9.56)、(276.14±52.55)、(–11.59±18.15)和(–13.02±6.71)mmol/(m²·d),冬季各站位F_CO2值离散度较大,其中位数是–10.73mmol/(m²·d)。在全年尺度,表层海水p(CO₂)及F_CO2与水温呈显著正相关,与盐度呈显著负相关。在非养殖区,浮游植物光合作用可能对影响表层海水p(CO₂)及F_CO2起主导作用。养殖牡蛎钙化、呼吸作用等生理因素释放的CO₂对表层海水p(CO₂)及F_CO2未产生显著影响。考洲洋养殖海域养殖旺季为CO₂的源,养殖淡季整体为CO₂的弱汇。  相似文献   

海水二氧化碳分压测量用水-气平衡器          下载免费PDF全文

李权龙  刘文静  江坤善  袁东星 《应用海洋学学报》2022,41(2):185-192

水-气平衡法被广泛地应用于海水CO₂分压（partial pressure,pCO₂）的测定。该方法采用水-气平衡器,使海水与平衡器上部顶空中的空气进行CO₂交换,达到平衡后测定该顶空空气中CO₂的浓度,再换算成海水pCO₂。水-气平衡器是海水pCO₂测量仪器的关键部件,其性能在很大程度上决定所获得的pCO₂数据的准确度和可靠性。本文介绍了水-气平衡器的平衡原理、平衡器时间常数的测量方法及影响因素,归纳了现有的4种用于海水pCO₂测量的水-气平衡器即喷淋式、鼓泡式、层流式及混合式平衡器的结构与特点,着重介绍了两种新型的水 气平衡器即基于射流器的鼓泡式平衡器和基于球形降膜的层流式平衡器,比较了不同水-气平衡器的尺寸、运行参数及时间常数,分析了设计和应用水-气平衡器时需考虑的因素。本文可为使用水-气平衡器测定海水pCO₂的技术人员提供技术参考。  相似文献