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1.
Most of the methods currently used for pore pressure prediction in sedimentary basins assume one-dimensional compaction based on relationships between vertical effective stress and porosity. These methods may be inaccurate in complex tectonic regimes where stress tensors are variable. Modelling approaches for compaction adopted within the geotechnical field account for both the full three-dimensional stress tensor and the stress history. In this paper a coupled geomechanical-fluid flow model is used, along with an advanced version of the Cam-Clay constitutive model, to investigate stress, pore pressure and porosity in a Gulf of Mexico style mini-basin bounded by salt subjected to lateral deformation. The modelled structure consists of two depocentres separated by a salt diapir. 20% of horizontal shortening synchronous to basin sedimentation is imposed. An additional model accounting solely for the overpressure generated due to 1D disequilibrium compaction is also defined. The predicted deformation regime in the two depocentres of the mini-basin is one of tectonic lateral compression, in which the horizontal effective stress is higher than the vertical effective stress. In contrast, sediments above the central salt diapir show lateral extension and tectonic vertical compaction due to the rise of the diapir. Compared to the 1D model, the horizontal shortening in the mini-basin increases the predicted present-day overpressure by 50%, from 20 MPa to 30 MPa. The porosities predicted by the mini-basin models are used to perform 1D, porosity-based pore pressure predictions. The 1D method underestimated overpressure by up to 6 MPa at 3400 m depth (26% of the total overpressure) in the well located at the basin depocentre and up to 3 MPa at 1900 m depth (34% of the total overpressure) in the well located above the salt diapir. The results show how 2D/3D methods are required to accurately predict overpressure in regions in which tectonic stresses are important. 相似文献
2.
Ever since a breakthrough of marine shales in China, lacustrine shales have been attracting by the policy makers and scientists. Organic-rich shales of the Middle Jurassic strata are widely distributed in the Yuqia Coalfield of northern Qaidam Basin. In this paper, a total of 42 shale samples with a burial depth ranging from 475.5 m to 658.5 m were collected from the Shimengou Formation in the YQ-1 shale gas borehole of the study area, including 16 samples from the Lower Member and 26 samples from the Upper Member. Geochemistry, reservoir characteristics and hydrocarbon generation potential of the lacustrine shales in YQ-1 well were preliminarily investigated using the experiments of vitrinite reflectance measurement, maceral identification, mineralogical composition, carbon stable isotope, low-temperature nitrogen adsorption, methane isothermal adsorption and rock eval pyrolysis. The results show that the Shimengou shales have rich organic carbon (averaged 3.83%), which belong to a low thermal maturity stage with a mean vitrinite reflectance (Ro) of 0.49% and an average pyrolytic temperature of the generated maximum remaining hydrocarbon (Tmax) of 432.8 °C. Relative to marine shales, the lacustrine shales show low brittleness index (averaged 34.9) but high clay contents (averaged 55.1%), high total porosities (averaged 13.71%) and great Langmuir volumes (averaged 4.73 cm−3 g). Unlike the marine and marine-transitional shales, the quartz contents and brittleness index (BI) values of the lacustrine shales first decrease then increase with the rising TOC contents. The kerogens from the Upper Member shales are dominant by the oil-prone types, whereas the kerogens from the Lower Member shales by the gas-prone types. The sedimentary environment of the shales influences the TOC contents, thus has a close connection with the hydrocarbon potential, mineralogical composition, kerogen types and pore structure. Additionally, in terms of the hydrocarbon generation potential, the Upper Member shales are regarded as very good and excellent rocks whereas the Lower Member shales mainly as poor and fair rocks. In overall, the shales in the top of the Upper Member can be explored for shale oil due to the higher free hydrocarbon amount (S1), whereas the shales in the Lower Member and the Upper Member, with the depths greater than 1000 m, can be suggested to explore shale gas. 相似文献
3.
The Mississippian Barnett Shale (Texas, USA), consisting of organic-rich shales and limestones, hosts the largest gas fields of North America. This study examines sealed fractures from core and outcrop samples of the Barnett Shale of the Fort Worth Basin and aims to: 1) characterize the phases occurring in the fractures from samples having experienced different burial histories; 2) establish a paragenetic sequence to relate the timing of fracture origin and sealing with the burial history of the basin; and 3) contribute to the understanding of the mechanisms of fracture formation in shales, including overpressure origin.Four fracture generations were distinguished in the most deeply buried core samples by characterizing the sealing minerals petrographically and geochemically. The generations were inserted into the framework of a reconstructed burial history for the Fort Worth Basin, which allowed a time sequence for fracture development to be established. This in turn allowed inference of conditions of fracture development, and consideration of fracture mechanisms as well as the origin of the parent fluids of sealing minerals.Type 1 fractures formed during early mechanical compaction (at a few 10 s to 100 m of depth) of still not fully cemented sediments. Type 2 fractures formed during moderate burial (∼2 km), from slightly modified seawater. Their timing is consistent with overpressure generated during rapid deposition and differential compaction of Pennsylvanian lithologies during the onset of the Ouachita compressional event. Type 3 fractures formed during deep burial (>3 km) from silica-rich basinal brines possibly derived from clay diagenesis. Type 4 fractures formed at very deep burial (>4 km), from hot and 18O-rich fluids, carrying light oil (20-30 API) and record the opening of the fluid system after hydrocarbon migration.Differences are highlighted between the timing and thermal regimes under which fractures formed in Barnett lithologies from different areas of the basin, this suggesting that extrapolation of outcrop observations to subsurface must be used with due care. 相似文献
4.
Geological evidence for overpressure is common worldwide, especially in petroleum-rich sedimentary basins. As a result of an increasing emphasis on unconventional resources, new data are becoming available for source rocks. Abnormally high values of pore fluid pressure are especially common within mature source rock, probably as a result of chemical compaction and increases in volume during hydrocarbon generation. To investigate processes of chemical compaction, overpressure development and hydraulic fracturing, we have developed new techniques of physical modelling in a closed system. During the early stages of our work, we built and deformed models in a small rectangular box (40 × 40 × 10 cm), which rested on an electric flatbed heater; but more recently, in order to accommodate large amounts of horizontal shortening, we used a wider box (77 × 75 × 10 cm). Models consisted of horizontal layers of two materials: (1) a mixture of equal initial volumes of silica powder and beeswax micro-spheres, representing source rock, and (2) pure silica powder, representing overburden. By submerging these materials in water, we avoided the high surface tensions, which otherwise develop within pores containing both air and liquids. Also we were able to measure pore fluid pressure in a model well. During heating, the basal temperature of the model surpassed the melting point of beeswax (∼62 °C), reaching a maximum of 90 °C. To investigate tectonic contexts of compression or extension, we used a piston to apply horizontal displacements.In experiments where the piston was static, rapid melting led to vertical compaction of the source layer, under the weight of overburden, and to high fluid overpressure (lithostatic or greater). Cross-sections of the models, after cooling, revealed that molten wax had migrated through pore space and into open hydraulic fractures (sills). Most of these sills were horizontal and their roofs bulged upwards, as far as the free surface, presumably in response to internal overpressure and loss of strength of the mixture. We also found that sills were less numerous towards the sides of the box, presumably as a result of boundary effects. In other experiments, in which the piston moved inward, causing compression of the model, sills also formed. However, these were thicker than in static models and some of them were subject to folding or faulting. For experiments, in which we imposed some horizontal shortening, before the wax had started to melt, fore-thrusts and back-thrusts developed across all of the layers near the piston, producing a high-angle prism. In contrast, as soon as the wax melted, overpressure developed within the source layer and a basal detachment appeared beneath it. As a result, thin-skinned thrusts propagated further into the model, producing a low-angle prism. In some experiments, bodies of wax formed imbricate zones within the source layer.Thus, in these experiments, it was the transformation, from solid wax to liquid wax, which led to chemical compaction, overpressure development and hydraulic fracturing, all within a closed system. According to the measurements of overpressure, load transfer was the main mechanism, but volume changes also contributed, producing supra-lithostatic overpressure and therefore tensile failure of the mixture. 相似文献
5.
The Wufeng-Longmaxi organic-rich shales host the largest shale gas fields of China. This study examines sealed fractures within core samples of the Wufeng-Longmaxi shales in the Jiaoshiba shale gas field in order to understand the development of overpressures (in terms of magnitude, timing and burial) in Wufeng-Longmaxi shales and thus the causes of present-day overpressure in these Paleozoic shale formations as well as in all gas shales. Quartz and calcite fracture cements from the Wufeng-Longmaxi shale intervals in four wells at depth intervals between 2253.89 m and 3046.60 m were investigated, and the fluid composition, temperature, and pressure during natural fracture cementation determined using an integrated approach consisting of petrography, Raman spectroscopy and microthermometry. Many crystals in fracture cements were found to contain methane inclusions only, and aqueous two-phase inclusions were consistently observed alongside methane inclusions in all cement samples, indicating that fluid inclusions trapped during fracture cementation are saturated with a methane hydrocarbon fluid. Homogenization temperatures of methane-saturated aqueous inclusions provide trends in trapping temperatures that Th values concentrate in the range of 198.5 °C–229.9 °C, 196.2 °C-221.7 °C for quartz and calcite, respectively. Pore-fluid pressures of 91.8–139.4 MPa for methane inclusions, calculated using the Raman shift of C-H symmetric stretching (v1) band of methane and equations of state for supercritical methane, indicate fluid inclusions trapped at near-lithostatic pressures. High trapping temperature and overpressure conditions in fluid inclusions represent a state of temperature and overpressure of Wufeng-Longmaxi shales at maximum burial and the early stage of the Yanshanian uplift, which can provide a key evidence for understanding the formation and evolution of overpressure. Our results demonstrate that the main cause of present-day overpressure in shale gas deposits is actually the preservation of moderate-high overpressure developed as a result of gas generation at maximum burial depths. 相似文献
6.
The influence of oil-expulsion efficiency on nanopore development in highly mature shale was investigated by using anhydrous pyrolysis (425–600 °C) on solvent-extracted and non-extracted shales at a pressure of 50 MPa. Additional pyrolysis studies were conducted using non-extracted shales at pressures of 25 and 80 MPa to further characterize the impact of pressure on pore evolution at high maturity. The pore structures of the original shale and relevant artificially matured samples after pyrolysis were characterized by using low-pressure nitrogen and carbon-dioxide adsorption techniques, and gas yields during pyrolysis were measured. The results show that oil-expulsion efficiency can strongly influence gas generation and nanopore development in highly mature shales, as bitumen remained in shales with low oil expulsion efficiency significantly promotes gaseous hydrocarbon generation and nanopore (diameter < 10 nm) development. The evolution of micropores and fine mesopores at high maturity can be divided into two main stages: Stage I, corresponding to wet gas generation (EasyRo 1.2%–2.4%), and Stage II, corresponding to dry gas generation (EasyRo 2.4%–4.5%). For shales with low oil expulsion efficiency, nanopore (diameter < 10 nm) evolution increases rapidly in Stage I, whereas slowly in Stage II, and such difference between two stages may be attributed to the changes of the organic matter (OM)’s mechanical properties. Comparatively, for shales with high oil expulsion efficiency, the evolution grows slightly in Stage I, not as rapidly as shales with low efficiency, and decays in Stage II. The different pore evolution behaviors of these two types of shales are attributed to the contribution of bitumen. However, the evolution of medium–coarse mesopores and macropores (diameter >10 nm) remains flat at high maturation. In addition, high pressure can promote the development of micropores and fine mesopores in highly mature shales. 相似文献
7.
Pore pressure prediction is needed for drilling deepwater wildcats in the Sea of Japan because it is known from past experience that there can be drilling problems can arise due to overpressure at shallow depths. The “Joetsu Basin” area is located offshore to the southwest of Sado Island on the eastern margin of the Sea of Japan. The sedimentary succession of the Neogene is mainly composed of turbidite sediments which contained smectite-rich mudstones. The cause of overpressure in the study area is expected to be a combination of mechanical disequilibrium compaction and chemical compaction, especially from the illitization of smectite.We have constructed basin models and performed numerical simulations by using 1D and 3D PetroMod to understand clearly the history of fluid flow and overpressure development in the lower Pliocene Shiya Formation and Middle to Upper Miocene Teradomari Formations. A compaction model coupled with both mechanical and chemical compaction for smectite-rich sediments is used for pore pressure calibration. We have examined three key relationships: porosity-effective stress, porosity-permeability, and the kinetics of smectite-illite transformation. We determined the ranges for the parameter values in those relationships that allow a good fit between measured and modelled pore pressures to be obtained. Results showed that for the most likely case, high pore pressure in the Lower and Upper Teradomari developed since 8.5 Ma and 5.5 Ma, respectively. Pore pressures in studied structures have approximately doubled since 1 Ma due to the high deposition rate of the Pleistocene Haizume Formation and smectite-illite transformation in the lower Pliocene-Shiya and Middle to Upper Miocene- Lower and Upperr Teradomari formations. In three cases (high case, most likely case and low case), the overpressures in the Shiya, Upper and Lower Teradomari Formations are less than 1 MPa, 15 and 30 Ma, respectively.The results provide a basis for planning future wells in the “Joetsu Basin” area and in other basins where geological conditions are similar, i.e., deepwater, high sedimentation rate, high geothermal gradient and smectite-rich sediments. 相似文献
8.
The development of expulsion fractures in organic-rich shale is closely related to hydrocarbon generation and expulsion from kerogen. Organic-rich shales from the upper part of the fourth member and the lower part of the third member of the Paleogene Shahejie Formation in the Jiyang Depression, Bohai Bay Basin, East China, are used as an example. Based on thin sections, SEM and thermal simulation experiments, the characteristics of hydrocarbon generation and the conditions supporting the development of expulsion fractures were explored. The key factors influencing these fractures include the presence of kerogens, their distribution along laminae and around particle boundaries, their exposure to heat and the build-up in pressure due to confinement by low permeability. The development of excess pore fluid pressures and intrinsic low rock fracture strength are the main influencing factors. Pressurization by rapid generation of hydrocarbon provides impetus for fracture initiation and cause bitumen to migrate quickly. The shale laminae results in distinctly lower fracture strength laminae-parallel than laminae-normal and this directs the formation of new fractures in the direction of weakness. When pore fluid pressure increases, maximum and minimum principal effective stresses decrease by different proportions with a larger reduction in the maximum principal effective stress. This increases the deviatoric stress and reduces the mean stress, thus driving the rock towards failure. Moreover, the tabular shape of the kerogen aids the generation of hydrocarbon and the initiation of expulsion fractures from the tip and edge. The resulting fractures extend along the laminae when the tensile strength is lower in the vertical direction than in the horizontal direction. Particle contact boundaries are weak and allow fractures to expand around particles and to curve as the stress/strength regime changes. When pore fluid pressure fields at different fracture tips overlap, fractures will propagate and interconnect, forming a network. This paper could provide us more detailed understanding of the forming processes of expulsion fractures and better comprehension about hydrocarbon expulsion (primary migration) in source rocks. 相似文献
9.
《Marine and Petroleum Geology》2012,32(1):125-136
As a result of a long-lasting and complex geological history, organic-matter-rich fine-grained rocks (black shales) with widely varying ages can be found on Ukrainian territory. Several of them are proven hydrocarbon source rocks and may hold a significant shale gas potential.Thick Silurian black shales accumulated along the western margin of the East European Craton in a foreland-type basin. By analogy with coeval organic-matter-rich rocks in Poland, high TOC contents and gas window maturity can be expected. However, to date information on organic richness is largely missing and maturity patterns remain to be refined.Visean black shales with TOC contents as high as 8% and a Type III-II kerogen accumulated along the axis of the Dniepr-Donets rift basin (DDB). They are the likely source for conventional oil and gas. Oil-prone Serpukhovian black shales accumulated in the shallow northwestern part of the DDB. Similar black shales probably may be present in the Lviv-Volyn Basin (western Ukraine).Middle Jurassic black shales up to 500 m thick occur beneath the Carpathian Foredeep. They are the likely source for some heavy oil deposits. TOC contents up to 12% (Type II) have been recorded, but additional investigations are needed to study the vertical and lateral variability of organic matter richness and maturity.Lower Cretaceous black shales with a Type III(-II) kerogen (TOC > 2%) are widespread at the base of the Carpathian flysch nappes, but Oligocene black shales (Menilite Fm.) rich in organic matter (4–8% TOC) and containing a Type II kerogen are the main source rock for oil in the Carpathians. Their thermal maturity increases from the external to the internal nappes.Oligocene black shales are also present in Crimea (Maykop Fm.). These rocks typically contain high TOC contents, but data from Ukraine are missing. 相似文献
10.
The pore size classification (micropore <2 nm, mesopore 2–50 nm and macropore >50 nm) of IUPAC (1972) has been commonly used in chemical products and shale gas reservoirs; however, it may be insufficient for shale oil reservoirs. To establish a suitable pore size classification for shale oil reservoirs, the open pore systems of 142 Chinese shales (from Jianghan basin) were studied using mercury intrusion capillary pressure analyses. A quantitative evaluation method for I-micropores (0–25 nm in diameter), II-micropores (25–100 nm), mesopores (100–1000 nm) and macropores (>1000 nm) within shales was established from mercury intrusion curves. This method was verified using fractal geometry theory and argon-ion milling scanning electron microscopy images. Based on the combination of pore size distribution with permeability and average pore radius, six types (I-VI) shale open pore systems were analyzed. Moreover, six types open pore systems were graded as good, medium and poor reservoirs. The controlling factors of pore systems were also investigated according to shale compositions and scanning electron microscopy images. The results show that good reservoirs are composed of shales with type I, II and III pore systems characterized by dominant mesopores (mean 68.12 vol %), a few macropores (mean 7.20 vol %), large porosity (mean 16.83%), an average permeability of 0.823 mD and an average pore radius (ra) of 88 nm. Type IV pore system shales are medium reservoirs, which have a low oil reservoir potential due to the developed II-micropores (mean 57.67 vol %) and a few of mesopores (mean 20.19 vol %). Poor reservoirs (composed of type V and VI pore systems) are inadequate reservoirs for shale oil due to the high percentage of I-micropores (mean 69.16 vol %), which is unfavorable for the flow of oil in shale. Pore size is controlled by shale compositions (including minerals and organic matter), and arrangement and morphology of mineral particles, resulting in the developments of shale pore systems. High content of siliceous mineral and dolomite with regular morphology are advantage for the development of macro- and mesopores, while high content of clay minerals results in a high content of micropores. 相似文献
11.
The Kuqa Foreland Basin (KFB) immediately south of the South Tianshan Mountains is a major hydrocarbon producing basin in west China. The Kelasu Thrust Belt in the basin is the most favorable zone for hydrocarbon accumulations. Widespread overpressures are present in both the Cretaceous and Paleogene reservoirs with pressure coefficients up to 2.1. The tectonic compression process in KFB resulted from the South Tianshan Mountains uplift is examined from the viewpoint of the overpressure generation and evolution in the Kelasu Thrust Belt. The overpressure evolution in the reservoir sandstones were reconstructed through fluid inclusion analysis combined with PVT and basin modeling. Overpressures at present day in the mudstone units in the Kelasu Thrust Belt and reservoir sandstones of the Dabei Gas Field and the Keshen zone are believed to have been generated by horizontal tectonic compression. Both disequilibrium compaction and horizontal tectonic compression are thought to contribute to the overpressure development at present day in the reservoir of the Kela-2 Gas Field with the reservoir sandstones showing anomalously high primary porosities and low densities from wireline log and core data. The overpressure evolution for the Cretaceous reservoir sandstone in the Kelasu Thrust Belt evolved through four stages: a normal hydrostatic pressure (>12–5 Ma), a rapidly increasing overpressure (∼5–3 Ma), an overpressure release (∼3–1.64 Ma) and overpressure preservation (∼1.64–0 Ma). Overpressure developed in the second stage (∼5–3 Ma) was generated by disequilibrium compaction as tectonic compression due to the uplift of the Tianshan Mountains acted at the northern monocline of KFB from 5 Ma to 3 Ma, which provided abundant sediments for the KFB and caused the anomalously high sedimentation rate during the N2k deposition. From 3 Ma to 1.64 Ma, the action of tectonic compression extended from the northern monocline to the Kelasu Thrust Belt and returned to the northern monocline of KFB from 1.64 Ma to present day. Therefore, the horizontal tectonic compression was the dominant overpressure mechanism for the overpressure generation in the third stage (∼3–1.64 Ma) and overpressure caused by disequilibrium compaction from 5 Ma to 3 Ma was only preserved in the Kela-2 Gas Field until present day. 相似文献
12.
Fractures not only control the distribution of oil and gas reservoirs, but also are key points in the research of oil and gas reservoir development programmes. The tectonic fractures in the Lower Cambrian shale reservoirs in the Feng'gang No. 3 block are effective reservoir spaces for hydrocarbon accumulation, and these fractures are controlled by palaeotectonic stress fields. Therefore, quantitatively predicting the development and distribution of tectonic fractures in the Lower Cambrian shale reservoir is important for the exploration and exploitation of shale gas in the Feng'gang No. 3 block. In the present study, a reasonable geological, mechanical and mathematical model of the study area was established based on the faults systems interpreted from seismic data, fracture characteristics from drilling data, uniaxial and triaxial compression tests and experiments on the acoustic emissions (AE) of rocks. Then, a three-dimensional (3-D) finite element method is applied to simulate the palaeotectonic stress field with the superposition of the Yanshan and Himalayan movements and used to predict the fracture distribution. The simulation results indicate that the maximum principal stress value within the study area ranged from 269.97 MPa to 281.18 MPa, the minimum principal stress ranged from 58.29 MPa to 79.64 MPa, and the shear stress value ranged from 91.05 MPa to 106.21 MPa. The palaeotectonic stress field is controlled by the fault zone locations. The fracture development zones are mainly controlled by the tectonic stress fields and are located around the faults, at the end of the fault zones, at the inflection point and at the intersection of the fault zones. 相似文献
13.
The geochemical and petrographic characteristics of saline lacustrine shales from the Qianjiang Formation, Jianghan Basin were investigated by organic geochemical analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and low pressure nitrogen adsorption analysis. The results indicate that: the saline lacustrine shales of Eq3 member with high oil content are characterized by type I and type II oil-prone kerogen, variable TOC contents (1.0–10.0 wt%) and an early-maturity stage (Ro ranges between 0.41 and 0.76%). The mineral compositions of Eq3 saline shale show strong heterogeneity: brittle intervals with high contents of quartz and carbonate are frequently alternated with ductile intervals with high glauberite and clay contents. This combination might be beneficial for oil accumulation, but may cause significant challenges for the hydraulic stimulation strategy and long-term production of shale oil. The interparticle pores and intraparticle pores dominate the pore system of Eq3 shale, and organic matter hosted pores are absent. Widely distributed fractures, especially tectonic fractures, might play a key role in hydrocarbon migration and accumulation. The pore network is contributed to by both large size inorganic pores and abundant micro-factures, leading to a relatively high porosity (2.8–30.6%) and permeability (0.045–6.27 md) within the saline shale reservoir, which could enhance the flow ability and storage capacity of oil. The oil content (S1 × 100/TOC, mg HC/g TOC and S1, mg HC/g rock) and brittleness data demonstrate that the Eq33x section has both great potential for being a producible oil resource and hydraulic fracturing. Considering the hydrocarbon generation efficiency and properties of oil, the mature shale of Eq3 in the subsidence center of the Qianjiang Depression would be the most favorable zone for shale oil exploitation. 相似文献
14.
Geochemical characteristics and hydrocarbon generation modeling of the Jurassic source rocks in the Shoushan Basin, north Western Desert, Egypt 总被引：1，自引：0，他引：1
Mohamed Ragab ShalabyMohammed Hail Hakimi Wan Hasiah Abdullah 《Marine and Petroleum Geology》2011,28(9):1611-1624
The Shoushan Basin is an important hydrocarbon province in the Western Desert, Egypt, but the origin of the hydrocarbons is not fully understood. In this study, organic matter content, type and maturity of the Jurassic source rocks exposed in the Shoushan Basin have been evaluated and integrated with the results of basin modeling to improve our understanding of burial history and timing of hydrocarbon generation. The Jurassic source rock succession comprises the Ras Qattara and Khatatba Formations, which are composed mainly of shales and sandstones with coal seams. The TOC contents are high and reached a maximum up to 50%. The TOC values of the Ras Qattara Formation range from 2 to 54 wt.%, while Khatatba Formation has TOC values in the range 1-47 wt.%. The Ras Qattara and Khatatba Formations have HI values ranging from 90 to 261 mgHC/gTOC, suggesting Types II-III and III kerogen. Vitrinite reflectance values range between 0.79 and 1.12 VRr %. Rock−Eval Tmax values in the range 438-458 °C indicate a thermal maturity level sufficient for hydrocarbon generation. Thermal and burial history models indicate that the Jurassic source rocks entered the mature to late mature stage for hydrocarbon generation in the Late Cretaceous to Tertiary. Hydrocarbon generation began in the Late Cretaceous and maximum rates of oil with significant gas have been generated during the early Tertiary (Paleogene). The peak gas generation occurred during the late Tertiary (Neogene). 相似文献
15.
Potential source rocks on the Laminaria High, a region of the northern Bonaparte Basin on the North West Shelf of Australia, occur within the Middle Jurassic to Lower Cretaceous early to post-rift sequences. Twenty-two representative immature source rock samples from the Jurassic to Lower Cretaceous (Plover, Laminaria, Frigate, Flamingo and Echuca Shoals) sequences were analysed to define the hydrocarbon products that analogous mature source rocks could have generated during thermal maturation and filled the petroleum reservoirs in the Laminaria High region. Rock-Eval pyrolysis data indicate that all the source rocks contain type II–III organic matter and vary in organic richness and quality. Open system pyrolysis-gas chromatography on extracted rock samples show a dominance of aliphatic components in the pyrolysates. The Plover source rocks are the exception which exhibit high phenolic contents due to their predominant land-plant contribution. Most of the kerogens have the potential to generate Paraffinic–Naphthenic–Aromatic oils with low wax contents. Bulk kinetic analyses reveal a relatively broad distribution of activation energies that are directly related to the heterogeneity in the kerogens. These kinetic parameters suggest different degrees of thermal stability, with the predicted commencement of petroleum generation under geological heating conditions covering a relatively broad temperature range from 95 to 135 °C for the Upper Jurassic−Lower Cretaceous source rocks. Both shales and coals of the Middle Jurassic Plover Formation have the potential to generate oil at relatively higher temperatures (140–145 °C) than those measured for crude oils in previous studies. Hence, the Frigate and the Flamingo formations are the main potential sources of oils reservoired in the Laminaria and Corallina fields. Apart from being a reservoir, the Laminaria Formation also contains organic-rich layers, with the potential to generate oil. For the majority of samples analysed, the compositional kinetic model predictions indicate that 80% of the hydrocarbons were generated as oil and 20% as gas. The exception is the Lower Cretaceous Echuca Shoals Formation which shows the potential to generate a greater proportion (40%) of gas despite its marine source affinity, due to inertinite dominating the maceral assemblage. 相似文献
16.
Present-day stress and pore pressure fields in the Cuu Long and Nam Con Son Basins, offshore Vietnam 总被引：1，自引：0，他引：1
Nguyen Thi Thanh Binh Tomochika Tokunaga Hoang Phuoc Son Mai Van Binh 《Marine and Petroleum Geology》2007,24(10):607-615
Knowledge of the in situ, or contemporary stress field is vital for planning optimum orientations of deviated and horizontal wells, reservoir characterization and a better understanding of geodynamic processes and their effects on basin evolution.This study provides the first documented analysis of in situ stress and pore pressure fields in the sedimentary formations of the Cuu Long and Nam Con Son Basins, offshore Vietnam, based on data from petroleum exploration and production wells.In the Cuu Long Basin, the maximum horizontal stress is mainly oriented in NNW–SSE to N–S in the northern part and central high. In the Nam Con Son Basin, the maximum horizontal stress is mainly oriented in NE–SW in the northern part and to N–S in the central part of the basin.The magnitude of the vertical stress has a gradient of approximately 22.2 MPa/km at 3500 m depth. Minimum horizontal stress magnitude is approximately 61% of the vertical stress magnitude in normally pressured sequences.The effect of pore pressure change on horizontal stress magnitudes was estimated from pore pressure and fracture tests data in depleted zone caused by fluid production, and an average pore pressure–stress coupling ratio (ΔSh/ΔPp) obtained was 0.66. The minimum horizontal stress magnitude approaches the vertical stress magnitude in overpressured zones of the Nam Con Son Basin, suggesting that an isotropic or strike-slip faulting stress regime may exist in the deeper overpressured sequences. 相似文献
17.
Currently, the Upper Ordovician Wufeng (O3w) and Lower Silurian Longmaxi (S1l) Formations in southeast Sichuan Basin have been regarded as one of the most important target plays of shale gas in China. In this work, using a combination of low-pressure gas adsorption (N2 and CO2), mercury injection porosimetry (MIP) and high-pressure CH4 adsorption, we investigate the pore characteristics and methane sorption capacity of the over-mature shales, and discuss the main controlling factors for methane sorption capacity and distribution of methane gas in pore spaces.Low pressure CO2 gas adsorption shows that micropore volumes are characterized by three volumetric maxima (at about 0.35, 0.5 and 0.85 nm). The reversed S-shaped N2 adsorption isotherms are type Ⅱ with hysteresis being noticeable in all the samples. The shapes of hysteresis loop are similar to the H3 type, indicating the pores are slit- or plate-like. Mesopore size distributions are unimodal and pores with diameters of 2–16 nm account for the majority of mesopore volume, which is generally consistent with MIP results. The methane sorption capacities of O3w-S1l shales are in a range of 1.63–3.66 m3/t at 30 °C and 10 MPa. Methane sorption capacity increase with the TOC content, surface area and micropore volume, suggesting organic matter might provide abundant adsorption site and enhance the strong methane sorption capacity. Samples with higher quartz content and lower clay content have larger sorption capacity. Our data confirmed that the effects of temperature and pressure on methane sorption capacity of shale formation are opposite to some extent, suggesting that, during the burial or uplift stage, the gas sorption capacity of hydrocarbon reservoirs can be expressed as a function of burial depth. Based on the adsorption energy theory, when the pore diameter is larger than 2 nm, much methane molecular will be adsorbed in pores space with distance to pore wall less than 2 nm; while free gas is mainly stored in the pore space with distance to pore wall larger than 2 nm. Distributions of adsorption space decrease with the increasing pore size, while free gas volume increase gradually, assuming the pore are cylindrical or sphere. Particularly, when the pore size is larger than 30 nm, the content of adsorbed gas space volume is very low and its contribution to the all gas content is negligible. 相似文献
18.
The Central Graben of the North Sea is characterised by high levels of overpressure (up to 40 MPa overpressure at 4500 m depth). We present pressure data for Cenozoic and Mesozoic reservoirs. Palaeocene sandstones control pressures in Tertiary mudstones and Cretaceous Chalk by acting as a regional ‘drain’. We divide the Jurassic into 18 pressure cells. The rift structure of the Graben controls the magnitude of pressure in each cell. Lateral hydraulic communication exists over 10 km distance between deeply-buried terraces (> 5000 m depth) and shallow structural highs (< 4500 m depth). Lateral communication increases pressure in the structurally-elevated sandstones to the minimum stress. This dynamic process produces zones of vertical fluid flow on the Forties-Montrose High, termed Leak Points. Vertical flow at Leak Points produces a 20 MWm−2 heat flow anomaly and controls hydrocarbon retention. Leak Points are water-wet, while deep terraces in hydraulic communication with Leak Points are condensate-bearing. The Kimmeridge Clay Fm. forms the pressure seal in deep terraces. 相似文献
19.
The North Yellow Sea Basin ( NYSB ), which was developed on the basement of North China (Huabei) continental block, is a typical continental Mesozoic Cenozoic sedimentary basin in the sea area. Its Mesozoic basin is a residual basin, below which there is probably a larger Paleozoic sedimentary basin. The North Yellow Sea Basin comprises four sags and three uplifts. Of them, the eastern sag is a Mesozoic Cenozoic sedimentary sag in NYSB and has the biggest sediment thickness; the current Korean drilling wells are concentrated in the eastern sag. This sag is comparatively rich in oil and gas resources and thus has a relatively good petroleum prospect in the sea. The central sag has also accommodated thick Mesozoic-Cenozoic sediments. The latest research results show that there are three series of hydrocarbon source rocks in the North Yellow Sea Basin, namely, black shales of the Paleogene, Jurassic and Cretaceous. The principal hydrocarbon source rocks in NYSB are the Mesozoic black shale. According to the drilling data of Korea, the black shales of the Paleogene, Jurassic and Cretaceous have all come up to the standards of good and mature source rocks. The NYSB owns an intact system of oil generation, reservoir and capping rocks that can help hydrocarbon to form in the basin and thus it has the great potential of oil and gas. The vertical distribution of the hydrocarbon resources is mainly considered to be in the Cretaceous and then in the Jurassic. 相似文献
20.
Two sets of Lower Paleozoic organic-rich shales develop well in the Weiyuan area of the Sichuan Basin: the Lower Cambrian Jiulaodong shale and the Lower Silurian Longmaxi shale. The Weiyuan area underwent a strong subsidence during the Triassic to Early Cretaceous and followed by an extensive uplifting and erosion after the Late Cretaceous. This has brought about great changes to the temperature and pressure conditions of the shales, which is vitally important for the accumulation and preservation of shale gas. Based on the burial and thermal history, averaged TOC and porosity data, geological and geochemical models for the two sets of shales were established. Within each of the shale units, gas generation was modeled and the evolution of the free gas content was calculated using the PVTSim software. Results show that the free gas content in the Lower Cambrian and Lower Silurian shales in the studied area reached the maxima of 1.98–2.93 m3/t and 3.29–4.91 m3/t, respectively (under a pressure coefficient of 1.0–2.0) at their maximum burial. Subsequently, the free gas content continuously decreased as the shale was uplifted. At present, the free gas content in the two sets of shales is 1.52–2.43 m3/t and 1.94–3.42 m3/t, respectively (under a current pressure coefficient of 1.0–2.0). The results are roughly coincident with the gas content data obtained from in situ measurements in the Weiyuan area. We proposed that the Lower Cambrian and Lower Silurian shales have a shale gas potential, even though they have experienced a strong uplifting. 相似文献