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1.
Mafic volcanic rocks of the Mesozoic Kutch basin represent the earliest phase of Deccan volcanic activity. An olivine-clinopyroxene-plagioclase-phyric undersaturated basalt occurs as a sill near Sadara in the Pachham upland, Northern Kutch. The Sadara sill is deformed and emplaced along faults. The sill is alkaline in character and is transitional between basalt and basanite. Compared to primitive mantle, the Sadara sill is enriched in Sr, Ba, Pb and LREE but depleted in Nb, Cr, Y, Cs and Lu. Fractional crystallization of olivine and clinopyroxene from an alkaline mafic melt generated by low degree partial melting of mantle peridotite can explain the observed chemical variation in the sill.IRM and L-F test experiments and mineral analyses show titano-magnetite as the major remanence carrying magnetic mineral. AF and thermal demagnetizations of the Sadara sill yielded a mean ChRM direction as D=315.6°, I=−43.0° (α95=9.78; k=25.38) and the corresponding VGP at 25°S; 114.6°E (dp/dm=6.58°/11.6°). The Sadara sill pole is significantly different from those of the Deccan (65 Ma) and the Rajmahal Traps (118 Ma) but is close to the Cretaceous poles of 85–91 Ma rock units from southern India. This suggests a pre-Deccan age for the sill.  相似文献   

2.
《Chemical Geology》2007,236(1-2):42-64
Carboniferous volcanic rocks in the Alataw area, Northern Tianshan Range (Xinjiang), consist of early Carboniferous (ca. 320 Ma) adakites and Nb-enriched arc basalts and basaltic andesites (NEBs), and late Carboniferous (ca. 306–310 Ma) mainly high-K calc-alkaline andesites, dacites and rhyolites. The adakites are calc-alkaline, and characterized by high Na2O/K2O (1.52–3.32) ratios, negligible to positive Eu anomalies, strong depletion of heavy rare earth elements (e.g., Yb = 0.74–1.47 ppm) and Y (6.7–14.9 ppm), positive Sr and Ba but negative Nb and Ti anomalies, and relatively constant εNd(T) values (+ 3.4–+ 6.6) and (87Sr/86Sr)i ratios (0.7035–0.7042). Some andesitic and dacitic adakite samples exhibit high MgO contents similar to magnesian andesites. The NEBs are sodium-rich (Na2O/K2O = 2.03–8.06), and differ from the vast majority of arc basalts in their higher Nb, Zr, TiO2 and P2O5 contents and Nb/Th, Nb/La and Nb/U ratios, and minor negative to positive anomalies in Ba, Nb, Sr, Zr and Ti. They have the highest εNd(T) values (+ 6.4–+ 11.6) but varying (87Sr/86Sr)i ratios (0.7007–0.7063). The high-K calc-alkaline suite is similar to typical ‘normal’ arc volcanic rocks in terms of moderately fractionated rare earth abundance and distinctly negative Eu, Nb, Sr and Ti anomalies. They have εNd(T) values (+ 1.2–+ 6.4) and (87Sr/86Sr)i ratios (0.7018–0.7059). Geochemically, they are similar to coeval I-type granitoids in the Alataw area. Given the presence of early Carboniferous ophiolites in the Northern Tianshan Range, and the isotopically inappropriate compositions of Proterozoic metamorphic basement in the Alataw area, we argue that the Alataw adakites were most probably related to the melting of young subducted crust of the Northern Tianshan Ocean. The NEBs likely originated from mantle wedge peridotites metasomatized by adakites and minor slab-derived fluids. The later high-K calc alkaline suite was generated by AFC processes that acted on melts derived from a mantle wedge metasomatized by hydrous fluids. The larger range of isotopic compositions exhibited by both the NEB and high-K suite, relative to the adakites, suggests that the mantle wedge was heterogeneous prior to slab- or fluid-mediated metasomatism.Continental crustal growth of the Central Asian orogenic belt was dominated by contributions of the juvenile materials from the depleted mantle prior to 270 Ma and possibly afterwards. The results of this study suggest that other Carboniferous Nb-enriched basalts in the Tianshan Range were generated by subduction processes rather than by intraplate tectonics as previously proposed.  相似文献   

3.
The lava sequence of the central-western Deccan Traps (from Jalgaon towards Mumbai) is formed by basalts and basaltic andesites having a significant variation in TiO2 (from 1.2 to 3.3 wt%), Zr (from 84 to 253 ppm), Nb (from 5 to 16ppm) and Ba (from 63 to 407 ppm), at MgO ranging from 10 to 4.2 wt%. Most of these basalts follow a liquid line of descent dominated by low pressure fractionation of clinopyroxene, plagioclase and olivine, starting from the most mafic compositions, in a temperature range from 1220° to 1125°C. These rocks resemble those belonging to the lower-most formations of the Deccan Traps in the Western Ghats (Jawhar, Igatpuri and Thakurvadi) as well as those of the Poladpur formation. Samples analyzed for87Sr/86Sr give a range of initial ratios from 0.70558 to 0.70621. A group of flows of the Dhule area has low TiO2 (1.2–1.5 wt%) and Zr (84–105 ppm) at moderate MgO (5.2–6.2 wt%), matching the composition of low-Ti basalts of Gujarat, low-Ti dykes of the Tapti swarm and Toranmal basalts, just north of the study area. This allows chemical correlations between the lavas of central Deccan, the Tapti dykes and the north-western outcrops. The mildly enriched high field strength element contents of the samples with TiO2 > 1.5 wt% make them products of mantle sources broadly similar to those which generated the Ambenali basalts, but their high La/Nb and Ba/Nb, negative Nb anomalies in the mantle normalized diagrams, and relatively high87Sr/86Sr, make evident a crustal input with crustally derived materials at less differentiated stages than those represented in this sample set, or even within the sub-Indian lithospheric mantle.  相似文献   

4.
The Middle Cenozoic lava sequence of the Lake Kizi region was studied. It characterizes the activity of sources in the Northern zone of the eastern Sikhote Alin: a Middle Eocene pulse of slab-related magmatism and prolonged injection of magmas from the sublithospheric convecting mantle in the Late Oligocene. Low contents of high field strength elements (Nb and Ta) with low Nb/Ta, Ce/Pb, and Nb/La and high K/Nb ratios and a low (87Sr/86Sr)0 of 0.703399 were determined in a Middle Eocene dacite with an age of ∼43.5 Ma. Three phases of Late Oligocene volcanic eruptions were distinguished: (1) basaltic andesites (29–27 Ma), (2) basaltic trachyandesites and trachyandesites (27–24 Ma), and (3) andesites (∼23 Ma). The lavas of the first and third phases showed low Ce/Pb, Nb/La, and Ba/La and high K/Nb ratios, which are also characteristic of supraslab processes. The lavas of the second phase are shifted with respect to these ratios toward ocean island basalt compositions. The entire Late Oligocene volcanic sequence falls within a narrow range of the initial strontium isotope ratios, (87Sr/86Sr)0, from 0.703661 to 0.703853. Such ratios are characteristic of volcanic and subvolcanic rocks with ages of ∼37, 31–23, and ∼16 Ma over the whole region of the Tatar Strait coast.  相似文献   

5.
Crustal or mantle xenoliths are not common in evolved, tholeiitic flood basalts that cover huge areas of the Precambrian shields. Yet, the occasional occurrences provide the most direct and unequivocal evidence on basement composition. Few xenolith occurrences are known from the Deccan Traps, India, and inferences about the Deccan basement have necessarily depended on geophysical studies and geochemistry of Deccan lavas and intrusions. Here, we report two basalt dykes (Rajmane and Talwade dykes) from the central Deccan Traps that are extremely rich in crustal xenoliths of great lithological variety (gneisses, quartzites, granite mylonite, felsic granulite, carbonate rock, tuff). Because the dykes are parallel and only 4 km apart, and only a few kilometres long, the xenoliths provide clear evidence for high small-scale lithological heterogeneity and strong tectonic deformation in the Precambrian Indian crust beneath. Measured 87Sr/86Sr ratios in the xenoliths range from 0.70935 (carbonate) to 0.78479 (granite mylonite). The Rajmane dyke sampled away from any of the xenoliths shows a present-day 87Sr/86Sr ratio of 0.70465 and initial (at 66 Ma) ratio of 0.70445. The dyke is subalkalic and fairly evolved (Mg No. = 44.1) and broadly similar in its Sr-isotopic and elemental composition to some of the lavas of the Mahabaleshwar Formation. The xenoliths are comparable lithologically and geochemically to basement rocks from the Archaean Dharwar craton forming much of southern India. As several lines of evidence suggest, the Dharwar craton may extend at least 350–400 km north under the Deccan lava cover. This is significant for Precambrian crustal evolution of India besides continental reconstructions.  相似文献   

6.
The Mesoproterozoic (~1.23 Ga) Sudbury dyke swarm was emplaced at equatorial latitudes and cross-cuts the Grenville, Southern and Superior Provinces of the Canadian Shield. The dyke swarm has been linked to the break-up of the Mesoproterozoic supercontinent Columbia (1.8 to 1.3 Ga). The Sudbury dykes are alkaline olivine diabases that extend ~300 km to the W and NW from the Grenville Front. Major element trends and MELTS modeling indicate fractional crystallization of olivine and plagioclase. Detailed mineral chemical analyses across a 90-m-wide dyke shows a symmetric M-shaped pattern indicating vertical flow differentiation. The highest measured Fo value of olivine from the chilled margin of one dyke is 70, suggesting the parental magmas of the dykes were evolved. Unlike other dykes of the Canadian Shield, the Sudbury dykes do not show significant chemical variation across the length of the swarm. The Sudbury dykes have high Sr/Y (>10), La/YbN (>5) and Sm/YbPM (>2.4) values indicating they originated from a garnet-bearing source. The low Th/Nb (<1.5) values contrast with the low Nb/La (<0.6) and La/Ba (~0.4) values, suggesting a possible lithospheric mantle or subduction-modified mantle source. In the context of Grenvillian tectonics, the Sudbury dykes intruded the Laurentian craton and parautochthonous rocks. The dykes occupy pre-existing west to northwest trending faults, suggesting that they exploited regional structural heterogeneities during the closure of the Elzevir basin (i.e., 1,250 to 1,190 Ma). The alkaline composition, limited spatial-chemical variation, volume, geometry and regional geological context suggest that the dykes are not likely related to a mantle plume or the break-up of a supercontinent.  相似文献   

7.
《Gondwana Research》2011,19(4):596-610
There are large areas of Permian basaltic rocks in the Tarim basin (PBRT) in northwestern China. Precise Ar–Ar dating of these rocks revealed an eruption age span of 262 to 285 Ma. Most of the PBRT is composed of alkaline basaltic rocks with high TiO2 (2.43%–4.59%, weight percent), high Fe2O3 + FeO (12.63%–17.83%) and P2O5 (0.32%–1.38%) contents. Trace elements of these rocks have affinities with oceanic island basalts (OIB), as shown in chondrite normalized rare earth elements (REE) diagrams and primitive mantle normalized incompatible elements diagrams. The rocks show complex Sr–Nd isotopic character based on which they can be subdivided into two distinct groups: group 1 has relatively small initial (t = 280 Ma)87Sr/86Sr ratio (∼ 0.7048) and positive εNd(t) (3.42–4.66) values. Group 2 has relatively large initial 87Sr/86Sr ratio (0.7060–0.7083) and negative εNd(t) (from − 2.79 to − 2.16) values. Lead isotopes are even more complex with variations of (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t ranging from 17.9265 to 18.5778, 15.4789 to 15.6067 and 37.2922 to 38.1437, respectively. Moreover, these two groups have different trace elements ratios such as Nb/La, Ba/Nb, Zr/Nb, Nb/Ta and Zr/Hf, implying different magmatic processes. Based on the geochemistry of basaltic rocks and an evaluation of the tectonics, deformation, and the compositions of crust and lithospheric mantle in Tarim, we conclude that these basaltic rocks resulted from plume–lithosphere interaction. Permian mantle plume caused an upwelling of the Tarim lithosphere leading to melting of the asthenospheric mantle by decompression. The magma ascended rapidly to the base of lower crust, where different degrees of assimilation of OIB-like materials and fractionation occurred. Group 1 rocks formed where the upwelling is most pronounced and the assimilation was negligible. In other places, different degrees of assimilation and fractionation account for the geochemical traits of group 2.  相似文献   

8.
《地学前缘(英文版)》2018,9(6):1957-1980
The Paleoproterozoic basement of the northeastern part of the Leo-Man craton is intruded by generally NW-trending dikes. These regional scale dikes extend over 1000 km in Burkina Faso, Mali and Niger. We present chemical and Sr-Nd isotope compositions, as well as 40Ar/39Ar ages of these dikes with the following strikes N98°–N112°, and N114°–N124° in NE Burkina Faso. Field relationships show that the dikes are posterior to all other rock types dated between 2.26 Ga and 2.0 Ga. Chemical data indicate that the dikes are continental flood basalts and composed of low-Ti (TiO2 ≤ 2 wt.%) sub-alkaline basalts and andesites. They exhibit a minor negative Europium anomaly (0.86–0.99) and slightly fractionated REE patterns ((La/Yb)N = 2.5–9.1; YbN = 9.5–19.9). The ratios of Th/Ta (1.3–11.4) and Ce/Pb (5.2–58.5) suggest a varying crustal assimilation of the dike magmas during ascent in the continental crust for all studied samples. Calculated P-T conditions indicate that the magma reached temperatures of 1285 °C (calculated from olivine compositions) and pressures of 6.9 kbar (calculated for pyroxene minerals). Calculated initial 87Sr/86Sr (0.70040–0.70260) and ɛNd(t) = +2.1 to −3.5 at 1575 Ma, also point to a crustal contamination with the most primitive samples showing TDM values of 1946 Ma and 2154 Ma. The low values of La/Ba (<0.2) and Nb/La (<1.0), contrast with the low Th/Nb (<0.9), and suggest a lithospheric mantle or subduction-modified mantle as possible source for the dikes. Sr-Nd data, Mg# and Nb-Ta-Zr-Y-Th-Tb-Yb compositions further suggest that the most primitive samples were emplaced in a none orogenic setting and their magmas were subjected to variable crustal contaminations. Literature and the present whole rock 40Ar/39Ar age determinations show that the dikes were emplaced during a widespread Mesoproterozoic magmatism between 1.6 Ga and 1.2 Ga, and were affected by a thermal event causing the argon systematics resetting, best constrained by the date of sample KK1 (1236 ± 20 Ma, 40Ar/36Ar = 294 ± 13, MSWD = 2.2). Contemporaneous 1590–1570 Ma extensive magmatism is reported in other crustal blocks in Baltica (Sveconorw-Goth, svecofennian) NW Laurentia (Slave craton, Yukon), and Australia (Gawler craton), and together with the 1575 studied dikes, are related to the breakup of the supercontinent Nuna.  相似文献   

9.
Diabase dyke swarms are widespread in the East Tianshan and Beishan regions. LA-ICP-MS zircon U-Pb ages of these diabase vary from 305 Ma to 278 Ma, showing that these dykes were formed during Late Carboniferous-Early Permian magmatism. All diabase samples are subalkali calc-alkali, characterized by slight LREE and LILEs enrichment, and weak negative Ti, Nb and Ta anomalies. The diabase samples have positive εNd(t) values (>+3), high Sr isotopic compositions (initial 87Sr/86Sr values=0.7030-0.7097), and large variation of Pb isotopic compositions, indicating they were derived from a deplete mantle source. Regional geology and geochemistry evidences indicate that these diabase dyke swarms were generated in a lithosphere extensional setting and had the same magma sources. Initial magmas may be a mixture of depleted asthenosphere mantle and enriched lithospheric mantle during rapid magma ascending.  相似文献   

10.
Late Cenozoic intraplate basaltic rocks in northeastern China have been interpreted as being derived from a mantle source composed of DMM and EM1 components. To constrain the origin of the enriched mantle component, we have now determined the geochemical compositions of basaltic rocks from the active Baekdusan volcano on the border of China and North Korea. The samples show LREE-enriched patterns, with positive Eu and negative Ce anomalies. On a trace element distribution diagram, they show typical oceanic island basalt (OIB)-like LILE enrichments without significant Nb or Ta depletions. However, compared with OIB, they show enrichments in Ba, Rb, K, Pb, Sr, and P. The Nb/U ratios are generally within the range of OIB, but the Ce/Pb ratios are lower than those of OIB. Olivine phenocrysts are characterized by low Ca and high Ni contents. The radiogenic isotopic characteristics (87Sr/86Sr = 0.70449 to 0.70554; εNd = −2.0 to +1.8; εHf = −1.7 to +6.1; 206Pb/204Pb = 17.26 to 18.12) suggest derivation from an EM1-like source together with an Indian MORB-like depleted mantle. The Mg isotopic compositions (δ26Mg = −0.39 ± 0.17‰) are generally lower than the average upper mantle, indicating carbonates in the source. The 87Sr/86Sr ratios decrease with decreasing δ26Mg values whereas the 143Nd/144Nd and (Nb/La)N ratios increase. These observations suggest the mantle source of the Baekdusan basalts contained at least two components that resided in the mantle transition zone (MTZ): (1) recycled subducted ancient (∼2.2–1.6 Ga) terrigenous silicate sediments, possessing EM1-like Sr–Nd–Pb–Hf isotopic signatures and relatively high values of δ26Mg; and (2) carbonated eclogites with relatively MORB-like radiogenic isotopic compositions and low values of δ26Mg. These components might have acted as metasomatizing agents in refertilizing the asthenosphere, eventually influencing the composition of the MTZ-derived plume that produced the Baekdusan volcanism.  相似文献   

11.
A combined study of petrography, whole-rock major and trace elements as well as Rb?Sr and Sm?Nd isotopes, and mineral oxygen isotopes was carried out for two groups of low-T/UHP granitic gneiss in the Dabie orogen. The results demonstrate that metamorphic dehydration and partial melting occurred during exhumation of deeply subducted continent. Zircon δ18O values of ? 2.8 to + 4.7‰ for the gneiss are all lower than normal mantle values of 5.3 ± 0.3‰, consistent with 18O depletion of protolith due to high-T meteoric-hydrothermal alteration at mid-Neoproterozoic. Most samples have extremely low 87Sr/86Sr ratios at t1 = 780 Ma, but very high 87Sr/86Sr ratios at t2 = 230 Ma. This suggests intensive fluid disturbance due to the hydrothermal alteration of protoliths during Neoproterozoic magma emplacement and the metamorphic dehydration during Triassic continental collision. Rb–Sr isotopes, Th/Ta vs. La/Ta and Th/Hf vs. La/Nb relationships suggest that Group I gneiss experienced lower degrees of hydrothermal alteration, but higher degrees of dehydration, than Group II gneiss. The two groups of gneiss have similar patterns of REE and trace element partition. Group I gneiss displays good correlations between Nb and LREEs but no correlations between Nb and LILEs (Rb, Ba, Pb, Th and U), indicating differential mobilities of LILEs during the dehydration. Thus the correlation between Nb and LREEs is inherited from protolith rather than caused by metamorphic modification. Relative to Group I gneiss, Group II gneiss has stronger negative Eu anomaly, lower contents of Sr and Ba but higher contents of Rb, Th and U. In particular, Nb correlates with LILEs (e.g., Rb, Sr, Ba, Th and U), but not with LREEs (La and Ce). This may indicate decoupling between the dehydration and LILEs transport during continental collision. Furthermore, dehydration melting may have occurred due to breakdown of muscovite during “hot” exhumation. Group II gneiss has extremely low contents of FeO + MgO + TiO2 (1.04 to 2.08 wt.%), high SiO2 contents of 75.33 to 78.23 wt%, and high total alkali (Na2O + K2O) contents (7.52 to 8.92 wt.%), comparable with compositions predicted from partial melting of felsic rocks by experimental studies. Almost no UHP metamorphic minerals survived; felsic veins of fine-grain minerals occurs locally between coarse-grain minerals, resulting in a kind of metatexite migmatites due to dehydration melting without considerable escape of felsic melts from the host gneiss. In contrast, Group I gneiss only shows metamorphic dehydration. Therefore, the two groups of gneiss show contrasting behaviors of fluid–rock interaction during the continental collision.  相似文献   

12.
 Agali–Coimbatore dolerite dykes constitute an important Proterozoic magmatic event that affected the south Indian shield. Rb-Sr whole rock isotope data yield an “errorchron” of 2369±400 Ma (2σ error) which is within error of the reported 2030±65 Ma K-Ar age. The dyke magmas were evolved Fe-rich tholeiitic melts produced by fractionation of clinopyroxene, orthopyroxene and olivine in the initial stages. Plagioclase became a fractionation phase during the latter stages of crystallization. The dykes characteristically have high 87Sr/86Sri (0.703–0.706) and are enriched in large-ion lithophile and light rare earth elements relative to primordial mantle values and show negative Nb anomalies. These compositional characteristics are interpreted as source mantle characteristics whereas some crustal effects are visible in some samples with high initial 87Sr/86Sr. Peridotite with minor hydrous metasomatic phases like amphibole (and phlogopite) within the shallow lithospheric mantle could be a potential source material for the dykes. However, at this stage we cannot convincingly differentiate whether the source of the parent magmas is solely lithospheric or a product of asthenosphere-lithosphere mixing. The δ18O values of the dykes range from +5.2 to +7.2 per mil (vs standard mean oceanic water). Initial Nd isotope values at the time of dyke intrusion (ɛNd at t=2.0 Ga) range from −2.3 to −4.8. Whole rocks define a correlation on an Sm-Nd isochron plot with a slope equivalent to an age of 3.15±0.53 Ga (2σ error); Sm-Nd crustal residence ages average at 2.87 Ga. The isochron age does not appear to be the result of systematic mixing with an older crustal component. These results together with trace element geochemistry suggest that the south Indian mantle lithosphere developed by addition of enriched melts/fluids at about 3.0 Ga synchronously with major crustal gene- ration in the south Indian shield. Received 20 June 1994/Accepted: 17 May 1995  相似文献   

13.
A comparison of geochemical and Sr–Nd–Pb isotopic compositions for Deccan Continental Flood Basalts (CFBs) and Central Indian Ridge (CIR) Basalts is presented: these data permit assessment of possible parental linkages between the two regions, and comparison of their respective magmatic evolutionary trends in relation to rift-related tectonic events during Gondwana break-up. The present study reveals that Mid-Ocean Ridge Basalt (MORB) from the northern CIR and basalts of Deccan CFB are geochemically dissimilar because of: (1) the Deccan CFB basalts typically show a greater iron-enrichment as compared to the northern CIR MORB, (2) a multi-element spiderdiagram reveals that the Deccan CFBs reveal a more fractionated slope (Ba/YbN > 1), as compared to relatively flat northern CIR MORB (Ba/YbN < 1), (3) there is greater REE fractionation for Deccan CFB than for the northern CIR MORB (i.e., La/YbN  2.3 and 1 respectively) and (4) substantial variation of compatible–incompatible trace elements and their ratios among the two basalt groups suggests that partial melting is a dominant process for northern CIR MORB, while fractional crystallization was a more important control to the geochemical variation for Deccan CFB. Further, incompatible trace element ratios (Nb/U and Nb/Pb) and radiogenic isotopic data (Sr–Pb–Nd) indicate that the northern CIR MORBs are similar to depleted mantle [and/or normal (N)-MORB], and often lie on a mixing line between depleted mantle and upper continental crust. By contrast, Deccan CFB compositions lie between the lower continental crust and Ocean island basalt. Accordingly, we conclude that the basaltic suites of the northern CIR MORB and Deccan CFB do not share common parentage, and are therefore genetically unrelated to each other. Instead, we infer that the northern CIR MORB were derived from a depleted mantle source contaminated by upper continental crust, probably during the break up of Gondwanaland; the Deccan CFB are more similar to Ocean island basalt (Reunion-like) composition, and perhaps contaminated by lower continental crust during their evolution.  相似文献   

14.
New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na2O/K2O (12–49) ratios, high Al2O3 (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and εND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive εND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.  相似文献   

15.
Major and trace element and isotopic ratios (Sr, Nd and Pb) are presented for mafic lavas (MgO > 4 wt%) from the southwestern Yabello region (southern Ethiopia) in the vicinity of the East African Rift System (EARS). New K/Ar dating results confirm three magmatic periods of activity in the region: (1) Miocene (12.3–10.5 Ma) alkali basalts and hawaiites, (2) Pliocene (4.7–3.6 Ma) tholeiitic basalts, and (3) Recent (1.9–0.3 Ma) basanite-dominant alkaline lavas. Trace element and isotopic characteristics of the Miocene and Quaternary lavas bear a close similarity to ocean island basalts that derived from HIMU-type sublithospheric source. The Pliocene basalts have higher Ba/Nb, La/Nb, Zr/Nb and 87Sr/86Sr (0.70395–0.70417) and less radiogenic Pb isotopic ratios (206Pb/204Pb = 18.12–18.27) relative to the Miocene and Quaternary lavas, indicative of significant contribution from enriched subcontinental lithospheric mantle in their sources. Intermittent upwelling of hot mantle plume in at least two cycles can explain the magmatic evolution in the southern Ethiopian region. Although plumes have been originated from a common and deeper superplume extending from the core–mantle boundary, the diversity of plume components during the Miocene and Quaternary reflects heterogeneity of secondary plumes at shallower levels connected to the African superplume, which have evolved to more homogeneous source.  相似文献   

16.
In this paper we report zircon U–Pb age, chemical compositions of rock-forming minerals, and whole-rock elemental and Sr–Nd isotopic data for the No. II mafic-ultramafic intrusive complex (N2MC) in the Quruqtagh area at the northeastern margin of the Tarim Block, northwestern China to evaluate its petrogenesis and tectonic significance. The N2MC with an exposure area of ca. 12 km2 has a funnel-shaped cross-section and intruded the Paleoproterozoic basement. U–Pb zircon dating gives a crystallization age of 760 ± 6 Ma. Rock types of the N2MC include lherzolite, pyroxenite, gabbro and minor diorite. Major elements geochemistry of these rocks exhibits a tholeiitic trend with a wide range of SiO2 contents (38.8–60 wt.%). On the other hand, they are systematically enriched in LILE, LREE and depleted in HFSE and HREE, thus leading to low HFSE/LREE ratios (e.g., Nb/La  0.3). Isotopically, the studied rocks are characterized by negative whole-rock εNd(t) values (? 7.6 to ? 2.8) and variable high (87Sr/86Sr)i (0.7095–0.7059). These features, together with chemical compositions of the rock-forming minerals and the presence of the primary phlogopite and hornblende, suggest that N2MC was likely formed via crystal fractionation/cumulation (with negligible crustal contamination) of a tholeiitic magma derived from a metasomatized subcontinental lithosphere mantle (SCLM) in an extensional environment. The enrichment of the mantle source could be ascribed to the metasomatism by subducted-slab-released fluids before partial melting. Overall, reported Neoproterozoic igneous rocks throughout the Tarim Block constitute two major phases of Neoproterozoic igneous activities, i.e., ca. 825–800 Ma and ca. 780–745 Ma, respectively. Similar to that of many other Rodinian continents, this feature is interpreted to be related to the two phases of Neoproterozoic mantle plume activity under the Rodinia. Furthermore, there exist two types of mafic-ultramafic complex at Quruqtagh, i.e., the ca. 820 Ma carbonatite-bearing and the ca. 760 Ma tholeiitic, which could reflect the presence of two different mantle sources.  相似文献   

17.
 The Urach volcanic field is unique within the Tertiary–Quaternary European volcanic province (EVP) due to more than 350 tuffaceous diatremes and only sixteen localities with extremely undersaturated olivine melilitite. We report representative Pb-Sr-Nd isotopic compositions and incompatible trace element data for twenty-two pristine augite, Cr-diopside, hornblende, and phlogopite megacryst samples from the diatremes, and seven melilitite whole rocks. The Pb isotopic compositions for melilitites and comagmatic megacrysts have very radiogenic 206Pb/204Pb ratios of 19.4 to 19.9 and plot on the northern hemisphere mantle reference line (NHRL). The data indicate absence of an old crustal component as reflected in the high 207Pb/204Pb ratios of many basalts from the EVP. This inference is supported by 206Pb/204Pb ratios of ∼17.6 to 18.3 and ɛNd of ∼−7.8 to +1.6 for five phlogopite xenocryst samples reflecting a distinct and variably rejuvenated lower Hercynian basement. The 87Sr/86Sr ratios of 0.7033 to 0.7035 in the comagmatic megacrysts are low relative to their moderately radiogenic Nd isotopic compositions (ɛNd +2.2 to +5.1) and consistent with a long-term source evolution with a low Rb/Sr ratio and depletion in light rare-earth elements (LREE). The melilitite whole-rock data show a similar range in Nd isotopic ratios as determined for the megacrysts but their Sr isotopic compositions are often much more radiogenic due to surface alteration. The REE patterns and incompatible trace element ratios of the melilitites (e.g. Nb/Th, Nb/U, Sr/Nd, P/Nd, Ba/Th, Zr/Hf) are similar to those in ocean island basalts (OIB); negative anomalies for normalized K and Rb concentrations support a concept of melt evolution in the lithospheric mantle. Highly variable Ce/Pb ratios of 29 to 66 are positively correlated with La/Lu, La/K2O, and Ba/Nd and interpreted to reflect melting in the presence of residual amphibole and phlogopite. The data suggest an origin of the melilitites from a chemical boundary layer very recently enriched by melts from old OIB sources. We suggest that the OIB-like mantle domains represent low-temperature melting heterogeneities in an upwelling asthenosphere under western Europe. Received: 9 March 1995/Accepted: 24 July 1995  相似文献   

18.
Chen  Xiaoqing  Liu  Shen  Feng  Caixia  Coulson  Ian M.  Fan  Yan  Tai  Kairui  Gao  Tianjing  Zhang  Siyuan 《中国地球化学学报》2020,39(3):307-325

The mafic dykes (dolerites) during the Early Paleozoic are widely spread in Langao-Ziyang, southern Qiling Block, and the investigation on these dykes are very important. Previous studies have mainly focused on the Silurian mafic dykes; however, research on the Earlier Paleozoic mafic dykes is relatively weak at present. Therefore, the overall understanding of the mantle source and genetic dynamic setting during the Early Paleozoic in this area is lacking. To study the accurate age and origin of the Early Paleozoic mafic dykes in Ziyang, southern Shaanxi Province, the mafic dykes from dabacunand Qinmingzhai were selected and the petrology, zircon U–Pb chronology, geochemistry, and Sr–Nd–Hf isotopes were studied. Analysis indicates that the mafic dykes studied are mainly composed of dolerite, and they are the products of the Early Ordovician (475.8–480.7 Ma). Furthermore, the dolerites belong to alkaline rock series, and they are characterized by enrichment in LREE, Rb, Ba, Sr, Nb, (87Sr/86Sr)i = 0.7020–0.7050, εNd(t) = 3.0–4.0), εHf (t) = 4.5–12.1,176Hf/177Hf = 0.282681–0.282844. This suggests that the mafic dyke were derived from the partial melting of a depleted lithospheric mantle, and the genetic process is mainly controlled by the mantle plume based on the discussion of the genetic model. Furthermore, the genetic process experienced the separation and crystallization of olivine and clinopyroxene at the same time, with little crustal contamination.

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19.
The trace element compositions of melts and minerals from high-pressure experiments on hydrous pyroxenites containing K-richterite are presented. The experiments used mixtures of a third each of the natural minerals clinopyroxene, phlogopite and K-richterite, some with the addition of 5% of an accessory phase ilmenite, rutile or apatite. Although the major element compositions of melts resemble natural lamproites, the trace element contents of most trace elements from the three-mineral mixture are much lower than in lamproites. Apatite is required in the source to provide high abundances of the rare earth elements, and either rutile and/or ilmenite is required to provide the high field strength elements Ti, Nb, Ta, Zr and Hf. Phlogopite controls the high levels of Rb, Cs and Ba.Since abundances of trace elements in the various starting mixtures vary strongly because of the use of natural minerals, we calculated mineral/melt partition coefficients (DMin/melt) using mineral modes and melting reactions and present trace element patterns for different degrees of partial melting of hydrous pyroxenites. Rb, Cs and Ba are compatible in phlogopite and the partition coefficient ratio phlogopite/K-richterite is high for Ba (1 3 6) and Rb (12). All melts have low contents of most of the first row transition elements, particularly Ni and Cu ((0.1–0.01) × primitive mantle). Nickel has high DMin/melt for all the major minerals (12 for K-richterite, 9.2 for phlogopite and 5.6 for Cpx) and so behaves at least as compatibly as in melting of peridotites. Fluorine/chlorine ratios in melts are high and DMin/melt for fluorine decreases in the order apatite (2.2) > phlogopite (1.5) > K-richterite (0.87). The requirement for apatite and at least one Ti-oxide in the source of natural lamproites holds for mica pyroxenites that lack K-richterite. The results are used to model isotopic ageing in hydrous pyroxenite source rocks: phlogopite controls Sr isotopes, so that lamproites with relatively low 87Sr/86Sr must come from phlogopite-poor source rocks, probably dominated by Cpx and K-richterite. At high pressures (>4 GPa), peritectic Cpx holds back Na, explaining the high K2O/Na2O of lamproites.  相似文献   

20.
The Gondwana (Early Permian to Early Cretaceous) basins of eastern India have been intruded by ultramafic–ultrapotassic (minette, lamproite and orangeite) and mafic (dolerite) rocks. The Salma dike is the most prominent among mafic intrusives in the Raniganj basin. This dike is tholeiitic in composition; MgO varies from 5.4 to 6.3% and the mg number from 54 to 59. In general, the major and trace element abundances are uniform both along and across the strike. There is geochemical and mineralogical evidence for fractional crystallization. The chondrite normalized REE pattern of the Salma dike (La/Ybn=3.5) is similar to that of Deccan dikes of the Son–Narmada rift zone, western India. 87Sr/86Sr varies from 0.70552 to 0.70671 suggesting assimilation of crustal material. Some trace element abundances (e.g. Ti, Zr, Y) of the Salma dike are comparable to Group I Rajmahal basalts. The 40Ar–39Ar whole rock age of 65 Ma for the Salma dike is less than the ca. 114 Ma age for the Rajmahal basalt, but is similar to the generally accepted age for Deccan volcanic rocks. Despite geographical proximity with the Rajmahal basalt, the Salma dike is believed to be related to late phase of Deccan volcanic activity.  相似文献   

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