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1.
The results of 2-year (2010–2012) measurements of the concentrations of organic carbon (OC) and elemental carbon (EC), which were taken at the Zotino Tall Tower Observatory (ZOTTO) Siberian background station (61° N, 89° E), are given. Despite the fact that this station is located far from populated areas and industrial zones, the concentrations of OC and EC in the atmosphere over boreal forests in central Siberia significantly exceed their background values. In winter and fall, high concentrations of atmospheric carbonaceous aerosol particles are caused by the long-range transport (~1000 km) of air masses that accumulate pollutants from large cities located in both southern and southwestern regions of Siberia. In spring and summer, the pollution level is also high due to regional forest fires and agricultural burning in the steppe zone of western Siberia in the Russian–Kazakh border region. Background concentrations of carbonaceous aerosol particles were observed within relatively short time intervals whose total duration was no more than 20% of the entire observation period. In summer, variations in the background concentrations of OC closely correlated with air temperature, which implies that the biogenic sources of organic-particle formation are dominating.  相似文献   

2.
The emissions from fires in the boreal zone of northern Eurasia significantly contribute to the global emissions of greenhouse gases, their precursors, and aerosols. These emissions are an important component of the global carbon balance, and they significantly affect both seasonal and long-term variations in the chemical composition and radiation properties of the atmosphere on both regional and global scales. The atmospheric emissions of carbon monoxide (CO) from biomass burning have systematically been estimated for the entire territory of northern Eurasia over the period of 2000–2008 on the basis of satellite (MODIS MCD45A1) data on burned vegetation and the Seiler-Crutzen emission model with consideration for both regional and seasonal features. On the whole, for Russia, the annual emissions of CO from biomass burning ranged from 10.6 to 88.2 Mt/y over the indicated period. Depending on fire activity, the atmospheric emissions of CO from natural fires and agricultural work may yield from 25 to 200% of the total technogenic emissions according to the EDGAR-2000 model. In this case, the dominant contribution is made by boreal forest fires (8–57 Mt/y), whose portion amounts to 63–76% of the total emissions from biomass burning. This relatively short observational series does not allow one to reliably estimate long-term variations; however, on the whole, a stable increase in burned areas has been observed in forest, steppe, and agricultural regions over the last decade. Our analysis suggests significant spatial and seasonal variations in the large-scale fields of fire emissions, which are determined by the physical, geographic, and climatic features of individual regions. The calculated fields of emissions can be used in transport-chemical models, studies of the regional transport and quality of air, and climate models.  相似文献   

3.
Characterization of the proteinaceous matter in marine aerosols   总被引：1，自引：0，他引：1  
Marine aerosols play a dominant role in the transfer of oceanic material to the atmosphere. Most marine aerosol originates when air bubbles burst at the sea surface ejecting material from the sea surface microlayer and bubble surface layers into the air. Concentrations of chemical compounds in these surface layers often differ from their concentrations in bulk water. We examined the enrichment of aerosols with proteinaceous matter and attempted to characterize the physical nature and sources of this matter. We measured concentrations of dissolved free (DFAA), dissolved combined (DCAA), and particulate (PAA) amino acids, transparent stainable particles (TSP), and bacteria and virus-like particles as carriers of protein, in natural and simulated aerosols. We also evaluated D/L ratios certain amino acids in all amino acid fractions.DFAA and DCAA enriched the aerosols we sampled by 1.2–20 times compared to bulk seawater; PAA enrichment was usually higher (up to 50-fold). Aerosols contained particles typical of seawater, e.g., microorganisms, organic debris, inorganic particles with adsorbed organic matter, but also a large number of semitransparent gel-like particles, which all contained amino acids. Some of these particles were probably scavenged from bulk water, but new particles produced as bubbles burst at the surface comprised at least 10% of total proteinaceous matter in the aerosol. D/L ratios of certain amino acid suggested that the particles were most likely made from dissolved polymers secreted by phytoplankton that were concentrated on bubble surfaces and in the microlayer. Examination with Alcian Blue (a dye that targets carbohydrates) and Coomassie Blue (a dye that targets proteins) showed that most TSP in the aerosols contained both proteins and polysaccharides. Microorganisms enriched the aerosols by up to two orders of magnitude, but contributed less than 4% to the total protein pool.  相似文献   

4.
The microphysical characteristics of aerosol were measured in the atmospheric surface layer simultaneously over the center of Moscow and its vicinity (Zvenigorod Scientific Station, Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences) from June 15 to June 30, 2009, in order to compare the mass concentrations, particle-size distribution functions, and elemental compositions of aerosol over the megapolis and the background zone. During the fire peak of 2010, on August 8, aerosol samples were taken in the center of Moscow and their chemical composition was determined. Comparing results obtained from the simultaneous measurements of the concentrations of aerosol and its elemental composition made it possible to determine their interdiurnal variability, which suggests that the features of time variations are of a regional character and they are determined mainly by the dynamics of the synoptical processes of air-mass exchange. The chemical composition of obtained samples was determined using the method of atomic absorption spectrometry. The measurement results obtained in June 2009 revealed an increase in the content of anthropogenic elements in the atmosphere over Moscow when compared to their content in the atmosphere over the background zone. In Moscow, during the summer fires of 2010, the concentration of sulfur exceeded its concentration in June 2009 by an order of magnitude, and the concentrations of Na, Mg, Al, Si, K, Ca, and Fe increased several times. The mean mass concentration of aerosol amounted to 917 μg/m3 in August 2010 and 50–70 μg/m3 in June 2009.  相似文献   

5.
This is a study of the physical and chemical properties of carbonaceous aerosols emitted by transport systems (namely, by aircraft gas turbine engines and large ship diesel engines) into the atmosphere. A comparative analysis of the morphology, size, elemental composition, and surface chemistry between aviation and diesel soot particles reveals the general and characteristic features of emissions from each source. The high pollution rate of diesel soot particles, considerable fraction of metal admixtures, and availability of char particles characterize the specific features of the formation of particles of this type. The main characteristics characterizing the interaction between aviation and shipping emission aerosols in the moist atmosphere (the composition of organic and water-soluble fractions at the surface) have been obtained. Due to high hygroscopicity, the microparticles can generate cloud condensation nuclei and initiate contrails and additional tropospheric cloudiness.  相似文献   

6.
Monitoring data on the ion composition of aerosols and gas admixtures in the background and polluted atmosphere of the Lake Baikal region are presented. The ion composition and morphology of aerosols are affected by heterogeneous chemical reactions and variations in relative humidity. Two types of aerosol particles are revealed over this region. The fraction of solid particles recorded in most episodes includes primarily carbonates of alkaline and alkaline-earth metals. With increased atmospheric humidity, these particles are engaged in heterogeneous chemical reactions with gas-phase NH3 and H2SO4, proceeding through the phase of watering. As a result, the composition of these aerosols is changed, and a fraction of aqueous H2O/H2SO4/(NH4)2SO4 aerosol particles of a different composition is formed. On the basis of a physical and chemical analysis of monitoring data on the aerosol composition and concentrations of gas admixtures, the average aerosol-size distribution of different types is estimated. For the first time, the mean acidity of aqueous aerosol particles is estimated.  相似文献   

7.
Particulate matter from the atmosphere over the Atlantic Ocean along the South American and African Continents has been analyzed for organic tracers from natural and biomass burning emissions. The major biomarker compounds characterized are natural products from continental vegetation consisting primarily of epicuticular wax components. For example, n-alkanes ranged from C25 to C35, with an odd carbon number predominance and carbon maxima (Cmax) at 29 or 31. Concentrations of n-alkanes varied from 0.3 to 680 ng/m3. Nevertheless, n-alkanols are the dominant terrestrial tracers in almost all samples (concentrations from 0.1 to 780 ng/m3) and ranged from C22 to C34 with an even carbon number predominance. Despite the major presence of the natural tracers, organic components from biomass burning emissions are also present in the particulate matter. The major tracers from this source are thermal degradation products from the biopolymer cellulose, namely the dianhydromonosaccharide derivatives levoglucosan, galactosan, and mannosan. In general, the concentrations of levoglucosan, the major derivative from this source in all samples, varied from 0.0008 to 0.15 ng/m3 in atmospheric samples collected over the ocean and from 0.04 to 4860 ng/m3 in terrestrial particulate matter, used as reference in this study. Dehydroabietic acid, another marker compound emitted from burning of Gymnosperm fuel, is also detectable in most oceanic samples at concentrations ranging from 0.0001 to 0.4 ng/m3, whereas in terrestrial aerosol particulate matter, this component is present at much higher concentrations (0.23–440 ng/m3). The presence of these tracers in atmospheric particulate matter over the ocean confirms the long-range transport of smoke from biomass burning off the continents.  相似文献   

8.
Izvestiya, Atmospheric and Oceanic Physics - The results of 5-year (2013–2017) measurements of organic (OC) and elemental (EC) carbon aerosol fractions observed at the atmospheric monitoring...  相似文献   

9.
Marine aerosols in the western North Pacific were collected using a cascade impactor. Size-separated aerosols were analyzed for organic carbon, alkanes and polycyclic aromatic hydrocarbons (PAH). The results showed that the rate of decrease of the atmospheric concentrations of these organic components with increase in distance from Japan as well as from the coast of the Eurasian Continent was in the order PAHalkanes>organic carbon. The bulk of all these organic components occurred in the smallest size fraction of particles (<1m). Analysis of the alkanes and PAH indicated that the hydrocarbons in aerosols in Japanese coastal marine areas are primarily derived from terrestrial anthropogenic sources which also contribute to a lesser extent to aerosols in marine areas about 1,000 km off the coast of Japan. In remote marine areas the hydrocarbons on small particles (<1m) have principally a natural terrestrial origin while those on larger particles are marine in origin.  相似文献   

10.
A combined mathematical model has been developed to reproduce space and time variations in the concentrations of multicomponent gas constituents and aerosols in the atmosphere on both regional and urban scales. This model contains blocks of transport of gas constituents and aerosols in the atmosphere with consideration for homogeneous binary nucleation, the kinetic processes of condensation/evaporation and coagulation, chemical processes occurring in both gas and liquid phases, and the processes of mass exchange during the gas-droplet (particle) interaction. A nonhydrostatic model of atmospheric mesoscale processes is used to calculate the fields of meteorological elements and turbulent characteristics. The generation of new-phase particles from precursor gases by the mechanism of homogeneous binary nucleation and their interaction with background aerosol are considered. The results of numerical experiments are compared with the data obtained from field observations of both space and time variations in the concentrations of gas constituents and aerosols and in the ionic content of aerosol particles over the Baikal region under the influence of emissions from powerful industrial sources.  相似文献   

11.
Sediment samples were selected from 28 sites across the deep (212–3527 m) northern Gulf of Mexico (GOM) as part of the Deep Gulf of Mexico Benthos (DGoMB) program, and analyzed for geochemical parameters related to organic carbon (OC) distribution and characteristics. The results of this study indicate that the OC content of sediments in the deep northern GOM is controlled by several factors; including water depth, overlying water productivity, sediment carbonate content, sediment oxygen exposure time, OC sources, and regional influences. The best correlation between sediment OC content, on a CaCO3-free basis, and other parameters examined was an inverse correlation of OC with water depth. The OC/SA ratio had a wide range of values and, along with variable sources of sedimentary OC, indicated that the organism-available concentration of metabolizable organic matter may not be simply related to sedimentary OC content. This was perhaps reflected in the observation that benthic macrofaunal and meiofaunal biomass abundances were well correlated with sedimentary OC, but the abundance of bacteria in sediments was not.  相似文献   

12.
The spatial and temporal variabilities of the aerosol optical thickness (AOT) and the total carbon monoxide content (CO) in the period of development and weakening of mass forest and peatbog fires in the European Russia territory (ERT) in the summer of 2010 are investigated from data of the AOT and CO satellite observations. The intensities of aerosol and CO emissions in the period of mass fires and the ratio of the emission factors of aerosol particles and CO are estimated on the basis of calculations of the smoke and CO masses over the ERT. The interrelation between variations in the levels of the regional pollution by combustion products and the variability of meteorological parameters is investigated. Various aspects of the manifestation of radiation effects of aerosols are discussed. The synchronization of weekly signals of the AOT, CO, and meteorological parameters in the period of mass fires is noted.  相似文献   

13.
Naturally existing stable carbon and nitrogen isotopes are important in the study of sedimentary organic matter sources. To identify the sources of sedimentary organic matter in Sanggou Bay and its adjacent areas, which is characterized by high-density shellfish and seaweed aquaculture, the grain size, organic carbon(OC), total nitrogen(TN), carbon and nitrogen isotopic composition(δ13C and δ15N) of organic matter in the surface sediment were determined. The results showed that, in August, sedimentary OC and TN ranged from 0.17% to 0.76% and 0.04% to 0.14%, respectively. In November, OC and TN ranged from 0.23% to 0.87% and 0.05% to 0.14%, respectively. There was a significant positive correlation between OC and TN(R=0.98, P0.0001), indicating that OC and TN were homologous. In August, the δ13C and δ15N of organic matter varied from-23.06‰ to-21.59‰ and 5.10‰ to 6.31‰, respectively. In November, δ13C and δ15N ranged from-22.87‰ to-21.34‰ and 5.13‰ to 7.31‰, respectively. This study found that the major sources of sedimentary organic matter were marine shellfish biodeposition, seaweed farming, and soil organic matter. Using a three-end-member mixed model, we estimated that the dominant source of sedimentary organic matter was shellfish biodeposition, with an average contribution rate of 65.53% in August and 43.00% in November. Thus, shellfish farming had a significant influence on the coastal carbon cycle.  相似文献   

14.
Rock-magnetic measurements along with grain size, acid-insoluble residue (AIR), organic carbon (OC), CaCO3 and δ18O of the planktonic foraminifers of the sediments were determined for 15 gravity cores recovered from the western continental margin of India. Magnetic susceptibility (MS) values in the surficial sediments reflect the land-derived input and, in general, are the highest in terrigenous sediment-dominated sections of the cores off Saurashtra–Ratnagiri, followed by the sediments off Indus–Gulf of Kachchh and then Mangalore–Cape Comorin.

The down-core variations in mineral magnetic parameters reveal that the glacial sediments off the Indus are characterized by low MS values/S-ratios associated with high AIR-content, low OC/CaCO3 contents and relatively high δ18O values, while those off SW India are characterized by low MS values/high S-ratio% associated with low AIR content, and relatively high OC, CaCO3 and δ18O values. Conversely, the Early Holocene sediments of all cores are characterized by high MS values/S-ratio% associated with high AIR content, low OC, CaCO3 contents and gradually decreased δ18O values. These results imply that during the Last Glacial Maximum (LGM), the cores off northwestern India received abundant continental supply leading to the predominance of eolian/fluvial sedimentation. In the SW region the influence of hinterland flux is less evident during this period, but convective mixing associated with the NE monsoon resulted in increased productivity. During the early Holocene intense SW monsoon conditions resulted in high precipitation on land, which in turn contributed increased AIR content/MS values in the continental margin sediments. A shallow water core off Kochi further suggests that the intense SW monsoon conditions prevailed until about 5 ka. The late Holocene organic-rich sediments of the SW margin of India were, however, subjected to early diagenesis at different intervals in the cores. Therefore, caution is needed when interpreting regional climatic change from down-core changes in sediment magnetic properties.  相似文献   


15.
利用元素及同位素地球化学方法研究了冲绳海槽中部沉积物岩芯中有机碳及磷的地球化学特征及影响因素。结果表明,冲绳海槽沉积速率（16.5~32.5 cm/ka）变化小,不是沉积物中有机碳埋藏的重要影响因素。相对于全新世氧化性底水环境,末次盛冰期/冰消期冲绳海槽缺氧底水环境提高了沉积物对有机碳的埋藏效率。冲绳海槽沉积物中各形态磷的相对含量与其他边缘海沉积物中的相似。交换态磷（Ex-P）含量低、变化小。末次盛冰期/冰消期缺氧底水环境下铁氧化物的还原溶解导致铁结合磷（Fe-P）释放以及自生磷矿物（Au-P）的形成。全新世氧化性底水条件有利于铁氧化物的有效再生及对磷的再吸附,但不利于Au-P的保存。总有机碳（TOC）和有机磷（Org-P）之间良好的相关性表明TOC埋藏对Org-P含量的重要控制作用。冲绳海槽沉积物中碎屑磷（De-P）含量低于长江口及东海陆架沉积物中的含量,这与陆源碎屑向外海传输减弱有关。在约9.3 ka BP（岩芯200 cm深度）,TOC、Fe-P、Org-P、De-P以及FeHR均出现的极小值可能由物质坡移造成。  相似文献   

16.
The data on the content and composition of lipids and aliphatic hydrocarbons (HC) in aerosols and surface waters obtained during the spring-summer periods of 2001 and 2003 along the vessel route from the North Sea to the Antarctic and backwards are presented. It was shown that the distribution of organic compounds is caused by the influence of the zonal supply of eolian matter from land, anthropogenic, and marine autochtonous sources. The concentrations of organic compounds in the aerosols varied from 0.22 to 13.04 ng/m3 for the lipids and from 0.04 to 7.03 ng/m3 for the aliphatic HC; in the surface waters, it from 9 to 84 and from 1 to 53 μg/l, respectively. There is a correlation between the fluxes of the lithogenic fraction of the aerosols, HC, and lipids. The growth of the aquatic area productivity increases the levels of the HC in the surface waters but to a lower degree than the HC supply with oil contamination.  相似文献   

17.
Mangrove forests are vulnerably threatened by sea level rise (SLR). Vegetation organic carbon (OC) stocks are important for mangrove ecosystem carbon cycle. It is critical to understand how SLR affects vegetation OC stocks for evaluating mangrove blue carbon budget and global climate change. In this study, biomass accumulation and OC stocks of mangrove vegetation were compared among three 10 year-old Kandelia obovata (a common species in China) mangrove forests under three intertidal elevations through species-specific allometric equations. This study simulated mangrove forests with SLR values of 0 cm, 40 cm and 80 cm, respectively, representing for the current, future ~100 a and future ~200 a SLR of mangrove forests along the Jiulong River Estuary, China. SLR directly decreased mangrove individual density and inhibited the growth of mangrove vegetation. The total vegetation biomasses were (12.86±0.95) kg/m2, (7.97±0.90) kg/m2 and (3.89±0.63) kg/m2 at Sites SLR 0 cm, SLR 40 cm and SLR 80 cm, respectively. The total vegetation OC stock decreased by approximately 3.85 kg/m2 (in terms of C) from Site SLR 0 cm to Site SLR 80 cm. Significantly lower vegetation biomass and OC stock of various components (stem, branch, leaf and root) were found at Site SLR 80 cm. Annual increments of vegetation biomass and OC stock also decreased with SLR increase. Moreover, significant lower sedimentation rate was found at Site SLR 80 cm. These indicated that SLR will decrease mangrove vegetation biomass and OC stock, which may reduce global blue carbon sink by mangroves, exacerbate global warming and give positive feedback to SLR.  相似文献   

18.
In this paper the authors cite the aerosol samples collected with a KA-200 Anderson cascade Impactor and a KB-120 sampler during the first cruise of the Kuroshio investigation operated by the People's Republic of China and Japan cooperative program, from July 23 to August 21, 1987. The concentration size distributions and composition of marine aerosols over the Kuroshio area are analyzed. Neutron activation analysis is used to determine the elemental composition of the aerosols. The authors also discuss some characteristics of marine aerosols relating to long-range transport of crustal and anthropogenic elements from the continent to the remote ocean. Analytical results indicate that elements Al, Fe, Sc and Sb over this area are obviously influenced by the continent of Asia, and the size distributions are changed after long-range transport. The concentration of large particles increase. The concentrations of the elements C1 and Na are closely related to ocean conditions; the source of the elements Cl an  相似文献   

19.
It has been shown by numerical simulation that the rate of formation of secondary organic aerosols (SOAs) in smoke plumes caused by vegetation and peat fires under real conditions can significantly depend on the aerosol optical thickness (AOT). The AOT determines the photodissociation rate and hydroxyl radical concentration, which in turn determines the rate of SOA generation as a result of oxidation of semivolatile organic compounds. Quantitative analysis has been carried out for the situation that took place in European Russia during the 2010 Russian wildfires. The state-of-the-art 3D chemical transport model is used in this study; the simulations are optimized and validated using the data of monitoring of the particulate matter in the Moscow region and Finland. The findings indicate that it is important to allow for this effect in studies focused on the analysis and prediction of air pollution due to wildfires, as well as climate and weather studies, whose results may depend on the assumptions about the content and properties of atmospheric carbon-containing aerosol.  相似文献   

20.
We estimate the impact of sulfate aerosols on cloudiness formation over the sea in the middle troposphere and the involvement of these particles in the formation of polar stratospheric clouds (PSCs) in the lower stratosphere. The first of these problems is solved using a combined model of moist convection and the formation of cloudiness and sulfate aerosols in the troposphere and lower stratosphere over the sea, incorporating natural emissions of sulfur-containing compounds. We have found that a significant source of condensation nuclei in the troposphere is the photochemical transformation of biogenic dimethyl sulfide (in addition to NaCl). The results of numerical experiments indicate that the absence of sulfate aerosols hinders the cloudiness formation over the sea in the middle and upper troposphere. The problem of sulfate aerosol involvement in the formation of supercooled ternary solutions (STSs) (PSC Type Ib) in the lower stratosphere is solved using a mathematical model of global transport of multicomponent gas pollutants and aerosols in the atmosphere. Using the combined model, numerical experiments were performed for the winter season in both hemispheres. Sulfate aerosols were found to really participate in the formation of STS particles. Without their participation, the formation of STS particles in the lower stratosphere would be hindered. We present the results of numerical calculations and discuss the distribution of concentrations of gaseous nitric and sulfuric acids, as well as mass concentrations of these components in STS particles.  相似文献   

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