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1.
Hydraulic conductivity (K) for an alluvial system in a riverbank filtration area in Changwon City, South Korea, has been studied using grain-size distribution, pumping and slug tests, and numerical modeling. The alluvial system is composed of layers: upper fine sand, medium sand, lower fine sand, and a highly conductive sand/gravel layer at the base. The geometric mean of K for the sand/gravel layer (9.89?×?10?4 m s?1), as determined by grain-size analyses, was 3.33 times greater than the geometric mean obtained from pumping tests (2.97?×?10?4 m s?1). The geometric mean of K estimates obtained from slug tests (3.08?×?10?6 m s?1) was one to two orders of magnitude lower than that from pumping tests and grain-size analyses. K estimates derived from a numerical model were compared to those derived from the grain-size methods, slug tests and pumping tests in order to determine the degree of deviation from the numerical model. It is considered that the K estimates determined by the slug tests resemble the uppermost part of the alluvial deposit, whereas the K estimates obtained by grain-size analyses and pumping tests are similar to those from the numerical model for the sand/gravel layer of the riverside alluvial system.  相似文献   

2.
Uncertainties in paleoenvironmental interpretations for traditional chemical analysis of bulk samples result from different grain-size sub-populations of sediments containing variable distributions of elements and minerals. Therefore, it is important to understand the elemental and mineral distribution in different grain sizes in determining the quantitative relationship between chemical weathering and climatic change. We sieved a series of Xiashu loess samples into three sub-populations of different grain sizes (<2, 2–45 and >45 μm, respectively), and then analyzed each population for rubidium (Rb), strontium (Sr), rare earth elements and magnetic susceptibility. In comparison with elemental concentrations of bulk samples, clay mineralogy and illitic crystallinity, our results show that distinct elemental distributions and magnetic susceptibilities for different grain-size sub-populations are controlled by sorting and/or chemical weathering, although we also suggest that the Xiashu loess may have the same provenance as the Central Chinese Loess. Maximum concentrations of Rb and fine-grained magnetic minerals in the less than 2 μm sub-population, coupled with our finding of maximum Sr in the larger than 45 μm fraction, indicate that Sr was lost during chemical weathering. Grain-size sub-population analysis is, therefore, an effective method for extracting paleoenvironmental information, because individual sub-populations show minimal variations in initial Rb/Sr ratios compared to bulk analysis of all sizes together. Furthermore, a negative correlation between Rb/Sr ratios and Sr concentrations for the <2 μm fraction (R2 = 0.97) may indicate that clay is a sensitive indicator of intensity of chemical weathering and is an ideal sub-population for determining Rb/Sr ratios, but not for magnetic susceptibility.  相似文献   

3.
The Pichavaram mangrove ecosystem is located between the Vellar and Coleroon Estuaries in south-eastern India. To document the spatial-depth-based variabilities in organic matter (OM) input and cycling, five sediment cores were collected. A comparative study was carried out of grain-size composition, pore water salinity, dissolved organic C (DOC), loss-on-ignition (LOI), elemental ratios (C/N and H/C), pigments (Chl a, Chl b, and total carotenoids), and humification indices. Sand is the major fraction in these cores ranging from 60% to 99% followed by silt and clay; cores from the estuarine margin have high sand content. In mangrove forests, pore-water DOC concentrations are high (32 ± 14 mg L−1), whereas salinity levels are low (50 ± 5.5‰). Likewise, LOI, organic C and N, and pigment concentrations are high in mangroves. OM is mainly derived from upstream terrestrial matter and/or mangrove litter, and marine OM. The humification indices do not vary significantly with depth because of rapid OM turnover. The bulk parameters indicate that the Vellar and Coleroon Estuaries are more affected by anthropogenic processes than mangrove forests. Finally, greater variability and sometimes lack of specific trends in bulk parameters implies that the 2004 tsunami caused extensive mixing in sediments.  相似文献   

4.
《Applied Geochemistry》1991,6(6):653-664
An examination has been made of strategies to estimate kinetic parameters (activation energy and pre-exponential factor) for organic reactions from geological data. Least squares regression and a direct-search algorithm were applied to a set of sterane isomerization data from Volador 1, an oil exploration well in the Gippsland Basin, Australia. The best fit kinetic parameters depend on the number and quality of data points used, as well as the thermal history. Because both the data and thermal history have intrinsic uncertainties, a range of kinetic parameters can explain the data to a specified level of misfit. For reasonable variations in the thermal history, the effective kinetic parameters for the data from Volador 1 are E = 75–100kJ/mol and A = 10−1−10−5/s. It is observed that the range of acceptable parameter pairs has a linear relation of the form ln (A) = a + bE, and the slope b is dependent on the thermal history. Small departures of either parameter from this relation lead to significant variations in the predicted values for the reaction progress.  相似文献   

5.
Flow parameters (velocity and density) for turbidity currents in the Northwest Atlantic Mid-Ocean Channel (NAMOC) have been determined based on two different approaches, channel geometry and grain-size distributions of turbidites. Channel geometry has been obtained by a quantitative morphological analysis of the NAMOC which shows three genetically different segments in the upper 2000 km: (1) an upper 350 km-long ‘equilibrium channel’, (2) a middle 700 km-long ‘modified equilibrium channel’and (3) a lower ‘basement-controlled channel’which is more than 1000 km-long. In contrast to other meandering submarine channels the NAMOC has very low sinuosities and gradients. A consistently higher right-hand levee limits mean flow velocities to 3ms?1 and channel geometry indicates mean flow velocities of 0·86 m s?1 that decrease within the equilibrium channel to 0·05 m s?1. Grain-size distributions on the levees and in the channel suggest strong vertical velocity and density gradients for bank-full flows with velocities of up to 8 m s?1 and excess densities up to 87 kg m?3 at the base, and 0·45 m s?1 and 4 kg m?3 at the top. The internal shear produced by these strong vertical gradients results in a decoupling of the current head and body. Channel geometry appears to be mainly the result of the slowly moving dilute body of the current.  相似文献   

6.
Computation of the grain-size distribution of the suspended load above a sand bed must take into consideration: (1) sorting processes from the bed to the bed layer and (2) sorting between the bed layer and suspension. Grain-size distributions of the bed layers above sand beds of three different types have been computed in this work, both by the Einstein and the Gessler methods. Using these as references, suspended load distributions have been obtained in each case by the Rouse suspension equation. A new formula has also been developed in partial modification of Hunt's method for direct computation of bed load and suspended load from a bed's grain-size distribution and flow parameters. Comparison of the computed data with actual observations in laboratory flumes show that no one method is particularly superior to the others, but the present method is advantageous because it affords direct computation of the suspended load from a bed's grain-size distribution, without going through an intermediate stage (bed load). The possible sources of error in each of the methods have been discussed.  相似文献   

7.
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8.
Short and medium range order of silica and sodium silicate glasses have been investigated from a quantitative analysis of 29Si MAS NMR and 23Na, 17O MQMAS NMR spectra. The method described enables the extraction of the underlying 17O NMR parameter distributions of bridging oxygens (BOs) and non-bridging oxygens (NBOs), and yields site populations which are confirmed by 29Si NMR data. The extracted NMR parameter distributions and their variations with respect to the glass chemical composition can then be analyzed in terms of local structural features (bond angles and bond lengths, coordination numbers) with the help of molecular dynamics simulations combined with first-principles calculations of NMR parameters. Correlations of relevant structural parameters with 23Na, 29Si and 17O NMR interactions (isotropic chemical shift δiso, quadrupolar coupling constant CQ and quadrupolar asymmetry parameter ηQ) are re-examined and their applicability is discussed. These data offer better insights into the structural organization of the glass network, including both chemical and topological disorder. Adding sodium to pure silica significantly diminishes the Si-O-Si bond angles and leads to a longer mean Si-O bond length with a slight decrease of the mean Na-O bond length. Moreover, the present data are in favor of a homogeneous distribution of Na around both oxygen species in the silicate network. Finally, our approach was found to be sensitive enough to investigate the effect of addition of a small quantity of molybdenum oxide (about 1 mol%) on the 17O MAS spectrum, opening new possibilities for investigating the Mo environment in silicate glasses.  相似文献   

9.
Heap leaching is essentially a process in which metals are extracted from mine ores with lixiant. For a better understanding and modeling of this process, solute transport parameters are required to characterize the solute transport system of the leach heap. For porous media like leach ores, which contain substantial gravelly particles and have a broad range of particle size distributions, traditional small-scale laboratory experimental apparatus is not appropriate. In this paper, a 2.44 m long, 0.3 m inner diameter column was used for tracer test with boron as the tracer. Tracer tests were conducted for 2 bulk densities (1.92 and 1.62 g/cm3) and 2 irrigation rates (2 and 5 L/ (m2·h−1)). Inverse modeling with two-region transport model using computer code CXTFIT was conducted based on the measured breakthrough curves to estimate the transport parameters. Fitting was focused on three parameters: dispersion coefficient D, partition coefficient β, and mass transfer coefficient ω. The results turned out to fall within reasonable ranges. Sensitivity analysis was conducted for the three parameters and showed that the order of sensitivity is β > ω > D. In addition, scaling of these parameters was discussed and applied to a real scale heap leach to predict the tracer breakthrough.  相似文献   

10.
Particle-size analysis is a useful way to determine the source and deposition of sediments. However, there are inconsistencies when this method is used to constrain the origin of the red soils in south-eastern China. To address this problem, we performed a detailed grain-size analysis of two red soil sequences in Xuancheng and Qiliting located along the lower reaches of the Yangtze River. By comparing their particle-size characteristics with those of the loess on the Loess Plateau in northern China, we found that the aeolian samples plot in a particular zone in the C–M (grain size of the cumulative 1% versus median grain size) plot and cluster nearer the lower left corner of the plot as their degree of weathering increases. The grain-size features suggest that the onset of large-scale aeolian deposition along the lower reaches of the Yangtze River occurred at approximately 0.8 Ma. Although both sedimentary sorting and post-depositional weathering control the grain-size variations in the deposits, the extremely strong weathering due to the humid, warm climate along the lower reaches of the Yangtze River primarily modified the grain-size distributions of the primary red soil deposits. Strong weathering increased the very fine silt (2–5 μm) fraction and decreased the coarse (>63 μm) fraction. We also found that certain grain-size parameters of the red soils varied with the weathering intensity, which can be used as indicators of palaeoclimate variations. The grain size variations in both the Qiliting and Xuancheng sequences suggest that the mid-Pleistocene climate transition (MPT) may have affected the lower reaches of the Yangtze River at 0.9 Ma.  相似文献   

11.
Introduction and methods applied: some new DTA-methods (quantitative determination of gypsum, determination of grain-size of carbonates, analysis of small amounts of iron in the dolomite lattice and of magnesium in calcite) and improved DTA-data on some minerals (clay minerals, Fe- and Al-hydroxides, pyrite, quartz, fluorite), occuring in the residue of carbonate rocks and not admitting solution by acids, are given.

Meinem verehrten Lehrer, Herrn Prof. Dr. Dr. h. c. C. W. Correns, danke ich sehr für die Überlassung des Themas. Für viele Hinweise und Diskussionen bin ich weiterhin Frau Dr. P. Schneiderhöhn, Herrn Prof. Dr. K. H. Wedepohl und Herrn Dr. H. E. Usdowski zu Dank verpflichtet.  相似文献   

12.
Using the four-channel automatic photoelectric photometer of the Sternberg Astronomical Institute’s Tien Shan Mountain Observatory, we have acquired accurate (σobs≈0.004m) W BV R brightness measurements for the eclipsing binary AR Cas during selected phases before eclipse ingress and after egress, as well as at the center of minima. A joint analysis of these measurements with other published data has enabled us to derive for the first time a self-consistent set of physical and geometrical parameters for the star and the evolutionary age of its components, t=(60±3)×106 years. We have found the period of the apsidal motion (Uobs=1100±160 years, \(\dot \omega _{obs} = 0^\circ .327 \pm 0^\circ .049\) years?1) and the apsidal parameter of the primary, logk 2,1 obs =?2.41±0.08, with the apsidal parameter being in good agreement with current models of stellar evolution. There is an ultraviolet excess in the primary’s radiation, Δ(U?B)=?0.12m and Δ(B?V)=?0.06m, possibly due to a metal deficiency in the star’s atmosphere.  相似文献   

13.
Temporal changes of meteorological variables can affect reference evapotranspiration (ET0). The goal of the present research is to analyze the changes of ET0 and identify the impact of effective meteorological parameters to the changes of ET0. For this purpose, daily meteorological data recorded in 30 synoptic stations of Iran during 1960–2014 were used. The annual and seasonal values of ET0 were calculated by the recorded data. To calculate ET0, FAO56 Penman–Monteith method (standard method) was used. The annual and seasonal trends of ET0 and its eight effective parameters were analyzed. Then the contributions of effective parameters changes on ET0 were determined. To analyze ET0 trend at annual and seasonal scales, two common methods, Spearman’s Rho and Mann–Kendall tests, were used. The R 2 = 0.99 showed that the results of the mentioned methods were similar and on the basis of T-statistic <0.057, their difference was not significant (95% confidence level). Therefore, only one method’s results (Spearman’s Rho) were reported. On the basis of Spearman’s Rho results, the annual and seasonal values of ET0 had negative trend in most of arid and semi-arid stations while the trend of this parameter was positive in humid and very humid stations. At annual and seasonal scales, decreasing in wind speed (W), temperature (T), sunshine hours (n), minimum temperature (TN), dew point temperature (TD), maximum temperature (TX), saturation vapor pressure deficit (SVPD) and solar radiation (RS) was observed in 58, 54, 39, 43, 56, 65, 65 and 37% studied stations, respectively. In many scales, the results showed that TX and W were the most effective meteorological variables on ET0 changes and then SVPD was located in second step in arid and semi-arid stations. In humid and very humid stations, W was the first effective parameter at all scales, except autumn.  相似文献   

14.
Summary A new concept of feature size range of a roughness profile is introduced in the paper. It is shown that this feature size range plays an important role in estimating the fractal dimension,D, accurately using the divider method. Discussions are given to indicate the difficulty of using both the divider and the box methods in estimatingD accurately for self-affine profiles. The line scaling method's capability in quantifying roughness of natural rock joint profiles, which may be self-affine, is explored. Fractional Brownian profiles (self-affine profiles) with and without global trends were generated using known values ofD, input standard deviation, , and global trend angles. For different values of the input parameter of the line scaling method (step sizea 0),D and another associated fractal parameterC were calculated for the aforementioned profiles. Suitable ranges fora 0 were estimated to obtain computedD within ±10% of theD used for the generation. Minimum and maximum feature sizes of the profiles were defined and calculated. The feature size range was found to increase with increasingD and , in addition to being dependent on the total horizontal length of the profile and the total number of data points in the profile. The suitable range fora 0 was found to depend on bothD and , and then, in turn, on the feature size range, indicating the importance of calculating feature size range for roughness profiles to obtain accurate estimates for the fractal parameters. Procedures are given to estimate the suitablea 0 range for a given natural rock joint profile to use with the line scaling method in estimating fractal parameters within ±10% error. Results indicate the importance of removal of global trends of roughness profiles to obtain accurate estimates for the fractal parameters. The parametersC andD are recommended to use with the line scaling method in quantifying stationary roughness. In addition, one or more parameters should be used to quantify the non-stationary part of roughness, if it exists. The estimatedC was found to depend on bothD and and seems to have potential to capture the scale effect of roughness profiles.  相似文献   

15.
The classical aquitard-drainage model COMPAC has been modified to simulate the compaction process of a heterogeneous aquitard consisting of multiple sub-units (Multi-COMPAC). By coupling Multi-COMPAC with the parameter estimation code PEST++, the vertical hydraulic conductivity (K v) and elastic (S ske) and inelastic (S skp) skeletal specific-storage values of each sub-unit can be estimated using observed long-term multi-extensometer and groundwater level data. The approach was first tested through a synthetic case with known parameters. Results of the synthetic case revealed that it was possible to accurately estimate the three parameters for each sub-unit. Next, the methodology was applied to a field site located in Changzhou city, China. Based on the detailed stratigraphic information and extensometer data, the aquitard of interest was subdivided into three sub-units. Parameters K v, S ske and S skp of each sub-unit were estimated simultaneously and then were compared with laboratory results and with bulk values and geologic data from previous studies, demonstrating the reliability of parameter estimates. Estimated S skp values ranged within the magnitude of 10?4 m?1, while K v ranged over 10?10–10?8 m/s, suggesting moderately high heterogeneity of the aquitard. However, the elastic deformation of the third sub-unit, consisting of soft plastic silty clay, is masked by delayed drainage, and the inverse procedure leads to large uncertainty in the S ske estimate for this sub-unit.  相似文献   

16.
An evaluation of the spectral width parameter for wind-generated ocean waves is presented based on the analysis of wave data obtained through the ship-borne wave recorder fitted to RVGaveshani. The coverage of wave data includes deep as well as shallow waters on the east and west coasts of India. Considering that the spectral width parameter ?0 derived from Tucker's wave analysis provides a reasonably accurate estimate, a comparative study has been made for the other band-width definitions available in the literature. The results indicate some bias in the estimation of spectral width information using higher-order moments, e.g. ? S andv, and with the alteration of spectral forms that are usually associated with multiple- or single-peaked wave spectra. Such a bias is not seen in the case of Goda's peakedness parameterQ p with variation of spectral form. The effect of the ratio of the high-frequency cut-off to the spectral peak period on ? S ,v andQ p is also investigated.  相似文献   

17.
A sediment core from the Pearl River Estuary (PRE) was analyzed for grain size and organic geochemistry parameters (TOC and δ13Corg). The results showed that high mean grain-size value and increased sand content were correlated with the high TOC and negative δ13Corg. These results indicated high river runoff in the PRE area. Peak river discharge occurred during the periods 1900–1750, 1500–1600, 1400–1200, 1000–900 and 750–600 cal yr BP. The main changes recorded in grain-size distributions, TOC contents, and δ13Corg variations appear to be directly related to monsoon precipitation in the sediment source area. An increased East Asian summer monsoon rainfall (EASM) and/or an enhanced East Asian winter monsoon rainfall could result in the increasing of monsoon rainfall. Typhoon related rainfalls could act as positive influence on precipitation levels. The study of the correlations between the rainfall records and ENSO activities revealed a close relationship between the monsoon rainfall in the PRE and the tropical Pacific variations. The frequent occurrence of ENSO might result in the southern migration of the EASM rain belt and lead to more typhoon-derived rainfall in the PRD during the late Holocene.  相似文献   

18.
The Anita Peridotite, in southwestern New Zealand, is a ∼1 × 20 km ultramafic massif that was rapidly extruded from beneath a Cretaceous arc within the 4 km wide mylonitic Anita Shear Zone. The peridotitic body contains a spectacular array of textures that preserve evidence for changing temperature, stress, and deformation mechanisms during the exhumation process. Olivine and orthopyroxene microstructures and lattice-preferred orientations (LPO) record a three-phase deformation history. Dislocation glide on the C- and E-type slip systems is recorded by coarse pre-mylonitised olivine grains, and occurred under hydrous conditions at T ∼650 °C, stress ∼200–700 MPa and strain rate ∼10−15 s−1, probably within hydrated sub-arc mantle lithosphere. Rare protomylonite pods record deformation by dislocation creep in porphyroclasts and dislocation-accommodated grain boundary sliding in the matrix on {0kl}[100] in olivine and (100)[001] in orthopyroxene, under conditions of T ∼730–770 °C, stress ∼52–700 MPa and strain rate ∼10−15 s−1. The massif, however, is dominated by mylonite and ultramylonite that wrap the protomylonite pods, comprising mostly fine-grained olivine neoblasts that lack internal distortions and have uniform LPOs. These textures indicate deformation occurred by grain-size sensitive (GSS) creep at T ∼650 °C, stress ∼69–137 MPa and strain rate ∼10−15 s−1, and thus during conditions of cooling and decreasing stress. GSS creep became more dominant with time, as the proportion of randomly-oriented neoblasts increased and formed interlinked networks that accommodated much of the strain. Grain boundary pinning allowed GSS creep to be maintained in polyphase regions, following mixing of olivine and orthopyroxene, which may have occurred by grain boundary transport in a fluid phase during a “creep cavitation” process. The results indicate that the Anita Peridotite recrystallised and underwent rheological weakening at a constant strain rate, with strain distributed across the entire section. This widespread deformation caused rapid exhumation of the peridotite from the lithospheric mantle into the overlying arc crust. The massif therefore records multiple overprinting phases of deformation under mantle and crustal conditions associated with the rapid exhumation of a large orogenic peridotite.  相似文献   

19.
An attempt has been made to study the relief aspects from three different sources of Digital Elevation Models (DEMs) viz., Survey of India (SOI) topographic map (1:25,000), Shuttle Radar Topography Mission (SRTM-90 m and SRTM-30 m) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER-30 m). These aspects are evaluated to examine differences among them and their influence on time of concentration (TC) of runoff at Moolbari Experimental Watershed (MEW), Sub Himalayan region (Shimla, District of Himachal Pradesh) India. For detailed study of relief aspects, morphometry parameters, SOI topographic map (as base map) were used. The results show that the relief aspects morphometric parameters derived from the SRTM30m and ASTER30m lie between SOI topographic map, and SRTM90m. We estimated TC of 21 micro watersheds from different sources DEMs by using Kirpich, Johnstone, Témez, and Barnsby equation only. Témez and Barnsby equation demonstrate high potential for the identification of TC from SOI Topographic map, SRTM90m, ASTER and SRTM30m DEMs. TC_Topo has a positive relationship with TC_SRTM90m, TC_ASTER and TC_SRTM30m for both Témez, and Barnsby equation with R2=0.804Topo & SRTM90m, 0.810Topo & ASTER & 0.839Topo & SRTM30m and 0.712Topo & SRTM90m, 0.747 Topo & ASTER & 0.785 Topo & SRTM30m. Further statistical test of Témez, and Barnsby equation based TC, only Témez equation based TC qualify/satisfy the statistical test. by considering all freeware DEMs a Semi-empirical model (SEM) has been developed, where TC predicted in term of TC_Topo is a function of TC_SRTM90m, TC_ASTER and TC_SRTM30m. This SEM has R2=0.883 and adjusted R= 0.874, Multiple R=0.907 and with Standard Error =2.131 at 95% confidence level. Comparison of the TC derived from the multiple regressions among three DEMs with TC_Topo shows an RMSE of 3.803, R-RMSE of 0.169, NRMSE of 0.342, R2 of 0.89, and RMSE% of 3.296 for Témez equation.  相似文献   

20.
The 2001 Bhuj earthquake (Mw 7.6) source zone is examined in the light of crack density (ε), saturation rate (ξ) and porosity parameter (ψ) using new data set derived from a large aftershock sequence recorded by the Gujarat seismic network (GSNet) during November, 2006–December, 2009. Processes of rupture initiations of the mainshock and its aftershock sequence are better understood by synthesizing the dynamic snapshots of the source zone using the new dataset. Pattern of crustal heterogeneities associated with high-ε, high-ξ and high-ψ anomalies at depths varying from 20 km to 25 km is similar to those of earlier study by Mishra and Zhao (2003). The anomalous zone is found extended distinctly by 50–60 km in the lateral direction, indicating the reinforcement of cracks and fractured volume of rock matrix due to long aftershock sequence since 2001 Bhuj earthquake in the source area. It is inferred that the presence of a fluid-filled fractured rock matrix with super saturation may have affected the structural and seismogenic strengths of the source zone and is still contributing significantly to the geneses of earthquakes in and around the source zone. Anomalous pattern of high-ε with wider distribution of high-ξ indicates the existence of micro-cracks in the lower crust, while high-ψ suggests the cementation of cracks through permeation of residual magma/metamorphic fluids into the hypocenter zone. The results suggest that the existence of residual fluids in the fractured rock matrix in the mid to lower crust might have played a key role in triggering the 2001 mainshock and is still responsible for its continued long aftershock sequences.  相似文献   

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