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1.
A workflow is described to estimate specific storage (S s) and hydraulic conductivity (K) from a profile of vibrating wire piezometers embedded into a regional aquitard in Australia. The loading efficiency, compressibility and S s were estimated from pore pressure response to atmospheric pressure changes, and K was estimated from the earliest part of the measurement record following grouting. Results indicate that S s and K were, respectively, 8.8?×?10?6 to 1.2?×?10?5 m?1 and 2?×?10?12 m s?1 for a claystone/siltstone, and 4.3?×?10?6 to 9.6?×?10?6 m?1 and 1?×?10?12 to 5?×?10?12 m s?1 for a thick mudstone. K estimates from the pore pressure response are within one order of magnitude when compared to direct measurement in a laboratory and inverse modelled flux rates determined from natural tracer profiles. Further analysis of the evolution and longevity of the properties of borehole grout (e.g. thermal and chemical effects) may help refine the estimation of formation hydraulic properties using this workflow. However, the convergence of K values illustrates the benefit of multiple lines of evidence to support aquitard characterization. An additional benefit of in situ pore pressure measurement is the generation of long-term data to constrain groundwater flow models, which provides a link between laboratory scale data and the formation scale.  相似文献   

2.
The hydrogeologic and hydraulic characteristics of a lateritic terrain in West Bengal, India, were investigated. Test drilling was conducted at ten sites and grain-size distribution curves (GSDCs) were prepared for 275 geologic samples. Performance evaluation of eight grain-size-analysis (GSA) methods was carried out to estimate the hydraulic conductivity (K) of subsurface formations. Finally, the GSA results were validated against pumping-test data. The GSDCs indicated that shallow aquifer layers are coarser than the deeper aquifer layers (uniformity coefficient 0.19–11.4). Stratigraphy analysis revealed that both shallow and deep aquifers of varying thickness exist at depths 9–40 and 40–79 m, respectively. The mean K estimates by the GSA methods are 3.62–292.86 m/day for shallow aquifer layers and 0.97–209.93 m/day for the deeper aquifer layers, suggesting significant aquifer heterogeneity. Pumping-test data indicated that the deeper aquifers are leaky confined with transmissivity 122.69–693.79 m2/day, storage coefficient 1.01?×?10?7–2.13?×?10?4 and leakance 2.01?×?10?7–34.56?×?10?2 day?1. Although the K values yielded by the GSA methods are generally larger than those obtained from the pumping tests, the Slichter, Harleman and US Bureau Reclamation (USBR) GSA methods yielded reasonable values at most of the sites (1–3 times higher than K estimates by the pumping-test method). In conclusion, more reliable aquifers exist at deeper depths that can be tapped for dependable water supply. GSA methods such as Slichter, Harleman and USBR can be used for the preliminary assessment of K in lateritic terrains in the absence of reliable field methods.  相似文献   

3.
A characterization study was carried out in a 10-m-thick sandfill, formed by hydraulic filling with marine sand, in Singapore. Placement methods and compaction were found to influence hydrostratigraphy. The deepest part of the sandfill consists of a loose sand layer and is overlain by a medium sand layer extending to mean sea level (MSL). At certain locations, a thin silty-sand layer was found. The different layers within the saturated zone were found to have different values for hydraulic conductivity (K) and groundwater flow velocity. Estimates for K increase according to the following sequence of methods: repacked sand column, step-pumping test, grain-size analysis and slug test. Slug tests and grain-size analysis yielded comparable estimates of K. The freshwater lens in the older part of the sandfill is about 2 m thicker than in a recently completed area. Comparisons of Ca2+/Cl?, Mg2+/Cl?, K +/Cl? and \({\text{Cl}}^{{\text{ - }}} {\text{/}}{\left( {{\text{Cl}}^{{\text{ - }}} {\text{ + HCO}}^{{\text{ - }}}_{{\text{3}}} } \right)}\) ratios indicate that the chemical composition of the groundwater at shallower depths has probably been altered by mineral dissolution. Weathering of carbonate minerals was found to be a major contributor to the major ions at these depths. The molar ratios approach the value for seawater at greater depths. The groundwater is close to equilibrium with calcite.  相似文献   

4.
The River Gash Basin is filled by the Quaternary alluvial deposits, unconformably overlying the basement rocks. The alluvial deposits are composed mainly of unconsolidated layers of gravel, sand, silt, and clays. The aquifer is unconfined and is laterally bounded by the impermeable Neogene clays. The methods used in this study include the carry out of pumping tests and the analysis of well inventory data in addition to the river discharge rates and other meteorological data. The average annual discharge of the River Gash is estimated to be 1,056?×?106 m3 at El Gera gage station (upstream) and 587?×?106 m3 at Salam-Alikum gage station (downstream). The annual loss mounts up to 40% of the total discharge. The water loss is attributed to infiltration and evapotranspiration. The present study proofs that the hydraulic conductivity ranges from 36 to 105 m/day, whereas the transmissivity ranges from 328 to 1,677 m2/day. The monitoring of groundwater level measurements indicates that the water table rises during the rainy season by 9 m in the upstream and 6 m in the midstream areas. The storage capacity of the upper and middle parts of the River Gash Basin is calculated as 502?×?106 m3. The groundwater input reach 386.11?×?106 m3/year, while the groundwater output is calculated as 365.98?×?106 m3/year. The estimated difference between the input and output water quantities in the upper and middle parts of the River Gash Basin demonstrates a positive groundwater budget by about 20?×?106 m3/year  相似文献   

5.
Low-flow indices have been determined from long-term daily streamflow data for 13 catchments in Dongjiang Basin in southern China. The Brutsaert-Nieber method was applied to estimate catchment-scale effective groundwater parameters; representative values were 4.5?×?10?4 m2 s?1 for the hydraulic diffusivity; 3.19?×?10?5 m2 s?1/2 for the hydraulic desorptivity; 2.27?×?10?4 m s?1 for the hydraulic conductivity; and 0.2617 for the drainable porosity. The response constants correlate well with the total stream length and catchment area. Solutions of the linearised Boussinesq equation were used to guide the development of regional multivariate regression models for estimating low-flow indices from the catchment-scale effective parameters. Results showed that these catchments exhibit similar low-flow characteristics. The 7-day lowest average streamflows with return periods of 10 and 2 years (7Q10 and 7Q2) are highly correlated with the catchment-scale response constants. The low-flow ratio Q95/Q50 (ratio of daily streamflow exceeded 95 and 50% of the time, respectively) varied between 0.3 and 0.5, indicating a high proportion of groundwater in the streamflow. The advantage of the regional regression model is its conceptual basis and use of the catchment-scale effective parameters. The method has the potential to be applied to ungauged catchments for estimating low-flow statistics from stream length and catchment area.  相似文献   

6.
Leaky aquifers provide protected drinking water since the aquifer is overlain by an aquitard, and this study develops a method to estimate hydraulic properties of the latter deposit. Steady pumping, supply well shutdowns, and slug tests generate data in adjacent monitoring well clusters that characterize the aquitard. An existing steady model estimates a site-averaged value of the aquitard permeability k if its thickness is known, and this site-averaged estimate may be compared with local k estimates from conventional and extended slug tests. A shutdown attenuation model estimates a local value of the consolidation coefficient C V, which combines with the local k value to specify the compressibility α of the aquitard. The method is illustrated for the Fowl Meadow Aquifer, a stratified drift deposit used as a drinking water supply in eastern Massachusetts (USA), with an overlying silt aquitard of 10 m thickness. Steady data and theory suggest a site-averaged k of 2.3?×?10–17?m2 for the aquitard, while the shutdown attenuation model generates local C V values that vary from 10–5 to 10–3?m2/s. The slug tests yield a local k variation (10–17–10–13?m2) that brackets the site-averaged value, and an α range of 10–9–10–7?Pa–1.  相似文献   

7.
A numerical groundwater model of the weathered crystalline aquifer of Ursuya (a major water source for the north-western Pyrenees region, south-western France) has been computed based on monitoring of hydrological, hydrodynamic and meteorological parameters over 3 years. The equivalent porous media model was used to simulate groundwater flow in the different layers of the weathered profile: from surface to depth, the weathered layer (5?·?10?8?≤?K?≤?5?·? 10?7 m s?1), the transition layer (7?·?10?8?≤?K?≤?1?·? 10?5 m s?1, the highest values being along major discontinuities), two fissured layers (3.5?·?10?8?≤?K?≤?5?·?? 10?4 m s?1, depending on weathering profile conditions and on the existence of active fractures), and the hard-rock basement simulated with a negligible hydraulic conductivity (K = 1 10 ?9 ). Hydrodynamic properties of these five calculation layers demonstrate both the impact of the weathering degree and of the discontinuities on the groundwater flow. The great agreement between simulated and observed hydraulic conditions allowed for validation of the methodology and its proposed use for application on analogous aquifers. With the aim of long-term management of this strategic aquifer, the model was then used to evaluate the impact of climate change on the groundwater resource. The simulations performed according to the most pessimistic climatic scenario until 2050 show a low sensitivity of the aquifer. The decreasing trend of the natural discharge is estimated at about ?360 m3 y?1 for recharge decreasing at about ?5.6 mm y?1 (0.8 % of annual recharge).  相似文献   

8.
We have investigated the effect of undercooling and deformation on the evolution of the texture and the crystallization kinetics of remelted basaltic material from Stromboli (pumice from the March 15, 2007 paroxysmal eruption) and Etna (1992 lava flow). Isothermal crystallization experiments were conducted at different degrees of undercooling and different applied strain rate (T = 1,157–1,187 °C and $ \dot{\gamma }_{i} $ γ · i  = 4.26 s?1 for Stromboli; T = 1,131–1,182 °C and $ \dot{\gamma }_{i} $ γ · i  = 0.53 s?1 for Etna). Melt viscosity increased due to the decrease in temperature and the increase in crystal content. The mineralogical assemblage comprises Sp + Plg (dominant) ± Cpx with an overall crystal fraction (?) between 0.06 and 0.27, increasing with undercooling and flow conditions. Both degree of undercooling and deformation rate deeply affect the kinetics of the crystallization process. Plagioclase nucleation incubation time strongly decreases with increasing ΔT and flow, while slow diffusion-limited growth characterizes low ΔT—low deformation rate experiments. Both Stromboli (high strain rate) and Etna (low strain rate) plagioclase growth rates (G) display relative small variations with Stromboli showing higher values (4.8 ± 1.9 × 10?9 m s?1) compared to Etna (2.1 ± 1.6 × 10?9 m s?1). Plagioclase average nucleation rates J continuously increase with undercooling from 1.4 × 106 to 6.7 × 106 m?3 s?1 for Stromboli and from 3.6 × 104 to 4.0 × 106 m?3 s?1 for Etna. The extremely low value of 3.6 × 104 m?3 s?1 recorded at the lowest undercooling experiment for Etna (ΔT = 20 °C) indicates that the crystallization process is growth-dominated and that possible effects of textural coarsening occur. G values obtained in this paper are generally one or two orders of magnitude higher compared to those obtained in the literature for equivalent undercooling conditions. Stirring of the melt, simulating magma flow or convective conditions, facilitates nucleation and growth of crystals via mechanical transportation of matter, resulting in the higher J and G observed. Any modeling pertaining to magma dynamics in the conduit (e.g., ascent rate) and lava flow emplacement (e.g., flow rate, pāhoehoe–‘a‘ā transition) should therefore take the effects of dynamic crystallization into account.  相似文献   

9.
A multi-layered aquifer, typical of riverbank alluvial deposits in Korea, was studied to determine the hydrologic properties. The geologic logging showed that the subsurface of the study site was comprised of four distinctive hydrogeologic units: silt, sand, highly weathered and fresh bedrock layers. The electrical resistivity survey supplied information on lateral extension of hydrogeologic strata only partially identified by a limited number of the geologic loggings. The laboratory column tracer test for the recovered core of the sand layer resulted in a hydraulic conductivity of 5.00×10−2 cm/s. The slug tests performed in the weathered rock layer yielded hydraulic conductivities of 4.32–7.72×10−4 cm/s. Hydraulic conductivities for the sand layer calculated from the breakthrough curves of bromide ranged between 2.08×10−3 and 2.44×10−2 cm/s with a geometric mean of 6.89×10−3 cm/s, which is 7 times smaller than that from the laboratory column experiment. The trend of increasing hydraulic conductivity with an increase in tracer travel length is likely a result of the increased likelihood of encountering a high conductivity zone as more of the aquifer is tested. The combined hydrogeologic site characterization using hydraulic tests, tracer tests, and column test with geologic loggings and geophysical survey greatly enhanced the understanding of the hydrologic properties of the multi-layered alluvial aquifer.  相似文献   

10.
The current study aimed to evaluate hydrogeologically the Nubian sandstone aquifer in El-Bahariya Oasis. It represents the main water-bearing horizon in the study area and consists of continental elastic sediments, mainly sandstone alternating with shale and clays. The general flow lines are directed from SW to NE direction, as detected from the constructed potentiometric head contour map. The piezometric surface reaches 149 m in El-Heiz area at the southern part, while it reaches 90 m at the northern, reflecting higher pressure head of the aquifer in the southern part. The map also illustrates that the southern part is considered as the most promising location for development. The structural elements play an important role in the deposition and distribution of the sedimentary succession of the Nubian sandstone sediments. Consequently, this sedimentary pattern affects the occurrences and movements of the groundwater within the aquifer system. Along the structurally high areas, in the study area, the piezometric head increases, while the reverse is recorded along the structurally low areas. The step-drawdown tests data were carried out by calculating the aquifer loss coefficient (B) and the well loss constant (C). The B values are smaller compared with C values, indicating that the aquifer under pressure has a behavior of leaky aquifer; therefore, it shows hydraulic connection with surrounding formation. The values of well efficiency range from 78.50% to 87.76%. Analysis of 12 pumping test data (constant discharge tests) was carried out in order to calculate the Nubian aquifer hydraulic parameters (transmissivity, hydraulic conductivity, and storage coefficient). The transmissivity values decrease from 3,045 m2/day in the southern part (El-Heiz area) to 236 m2/day in the northeastern part (El-Harra area). Accordingly, the aquifer classified as a high to moderate potentiality. Transmissivity contour map observes gradual increase of transmissivity values from the southern to northeastern direction. This may be due to the increase of shale or clay content in the concerned aquifer in that direction. The storage coefficient values range between 1.04 × 10?4 and 5.22 × 10?3, as obtained from the results of pumping test analysis, which ensure that the Nubian sandstone aquifer is classified as semi-confined to confined aquifer type. The S values show a decrease from southwest to northeast direction as detected from S-map. The hydraulic conductivity values vary from to 0.46 m/day in the northern part to 10.88 m/day in the southern part with an average of 5.67 m/day. According to the classification based on K values, the aquifer is mainly composed of coarse sand.  相似文献   

11.
The Tabriz area is a densely populated area of northwestern Iran (more than 1.5 million in population) with a large proportion of its drinking, domestic, industrial and agricultural water supplied from groundwater resources. The average rate of drinking and industrial water use in the city of Tabriz is about 3.45 m3 s–1. The Plio-Pleistocene unconfined alluvial tuff aquifer (about 1,275 km2), the most important aquifer in the area, has been known for many years as a reliable resource. The greatest estimated thickness of the alluvial tuff lies in the Saidabad area, with 350 m thickness. There are 994 deep and 284 shallow active pumping wells and 83 qanats operate in the alluvial tuff aquifer. The total water withdrawal from all these artificial discharge points has been measured at 72, 3.8 and 17 million m3/year, respectively. Analytical and numerical methods have been applied to the constant rate pumping test data from the Saidabad wellfield (eight pumping and three observation wells). The values of electrical conductivity in the groundwater of alluvial tuff aquifer range from 203 to 960 μS cm–1 and bicarbonate type water dominates.  相似文献   

12.
The combined use of pumping and tracer test data enabled the derivation of equivalent average hydraulic conductivities (Kavg) for each test in a heterogeneous channelized alluvial aquifer, whereas K values of the preferential flow paths were two orders of magnitude higher. Greater and earlier drawdown was generally observed along preferential flow lines in a pumping test, within an array of 21 wells. The study aim was to characterize hydraulic properties of a channelized aquifer system in New Zealand by combining tracer and pumping test data. Estimates were able to be made of the percentage of highly permeable channels within the profile (～1.2%), effective porosity that reflected the maximum fraction of highly permeable channels within the aquifer (?eff–pc ～0.0038), and flows through highly permeable channels (～98%) and the sandy gravel matrix material (～2%). Using ?eff–pc, a tracer test Kavg value (～93 m/day) was estimated that was equivalent to pumping test values (～100 m/day), but two orders of magnitude smaller than K calculated solely from transport through permeable channels (Kpc ～8,400 m/day). Derived K values of permeable and matrix material were similar to values derived from grain size distribution using the Kozeny-Carman equation.  相似文献   

13.
The Guarani aquifer system (GAS) represents one of the biggest aquifers in the world and is the most relevant groundwater resource in South America. For the first time, by combining field and laboratory measurements, a high-resolution aquifer analog model of fluvial–aeolian sediments of the GAS in São Paulo State (Brazil) is constructed. Three parallel sections of frontal outcrops, 28 m × 5.8 m, and two parallel sections of lateral outcrops, 7 m × 5.8 m, are recorded during open-pit mining of sandy sediments and describe in detail the three-dimensional distribution of the local lithofacies and hydrofacies. Variations of hydraulic conductivity, K, and porosity, n, are resolved on the centimeter scale, and the most permeable units of the fluvial–aeolian facies association are identified. The constructed aquifer analog model shows moderate hydraulic heterogeneity and a mean K value of 1.36 × 10?4 m/s, which is greater than the reported range of K values for the entire GAS in São Paulo State. The results suggest that the examined sedimentary unit constitutes a relevant portion of the GAS in São Paulo State in the context of groundwater extraction and pollution. Moreover, the constructed aquifer analog is considered an ideal basis for future numerical model experiments, aiming at in-depth understanding of the groundwater flow and contaminant transport patterns at this GAS portion or at comparable fluvial–aeolian facies associations.  相似文献   

14.
The high-pressure response of the cell parameters of calcite, CaCO3, has been investigated by single crystal X-ray diffraction. The unit cell parameters have been refined from 0 to 1.435?GPa, and the linear and volume compressibilities have been measured as β a =2.62(2)?×?10?3?GPa?1,β c =7.94(7)?×?10?3?GPa?1, β v =13.12?×?10?3?GPa?1. The bulk modulus has been obtained from a fit to the Birch-Murnaghan equation of state, giving K 0=73.46?±?0.27?GPa and V 0=367.789 ±?0.004?Å3 with K′=4. Combined with earlier data for magnesite, ankerite and dolomite, these data suggest that K 0 V 0 is a constant for the Ca-Mg rhombohedral carbonates.  相似文献   

15.
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16.
A large number of valleys and basin systems are present in the northwestern part of the Himalayas in Pakistan which form significant aquifers in the region. Hydrogeophysical investigations in the western part of Nowshera District, a part of the intermontane Peshawar basin, were undertaken to help to determine the availability of groundwater resources in the region. Thirty vertical electrical resistivity soundings (VES) were acquired using a Schlumberger expanding array configuration with a maximum current electrode spacing (AB/2) of 150 m in delineating the groundwater potential in the study area. The results of the interpreted VES data using a combination of curve matching technique and computer iterative modeling methods suggest that the area is underlain by 3 to 5 geo-electric layers. The interpretation results showed that the geo-electrical succession consists of alluvium comprising of alternating layers of clay, silty clay, fine to coarse sands, sand with gravels and gravels of variable thickness. High subsurface resistivity values are correlated with gravel–sand units and low resistivity values with the presence of clays and silts. The modeled VES results were correlated with the pumping tests results and lithological logs of the existing wells. The pumping test suggests the transmissivity of the aquifer sediments is variable corresponding to different sediments within the area. The gravel–sand intervals having high resistivity value show high transmissivity values, whereas clay–silt sediments show low transmissivities. It is concluded that majority of the high resistive gravel–sand sediments belong to an alluvial fan environment. These gravel–sand zones are promising zones for groundwater abstraction which are concentrated in the central part of the study area.  相似文献   

17.
MgSiO3 akimotoite is stable relative to majorite-garnet under low-temperature geotherms within steeply or rapidly subducting slabs. Two compositions of Mg–akimotoite were synthesized under similar conditions: Z674 (containing about 550 ppm wt H2O) was synthesized at 22 GPa and 1,500 °C and SH1101 (nominally anhydrous) was synthesized at 22 GPa and 1,250 °C. Crystal structures of both samples differ significantly from previous studies to give slightly smaller Si sites and larger Mg sites. The bulk thermal expansion coefficients of Z674 are (153–839 K) of a 1 = 20(3) × 10?9 K?2 and a 0 = 17(2) × 10?6 K?1, with an average of α 0 = 27.1(6) × 10?6 K?1. Compressibility at ambient temperature of Z674 was measured up to 34.6 GPa at Sector 13 (GSECARS) at Advanced Photon Source Argonne National Laboratory. The second-order Birch–Murnaghan equation of state (BM2 EoS) fitting yields: V 0 = 263.7(2) Å3, K T0 = 217(3) GPa (K′ fixed at 4). The anisotropies of axial thermal expansivities and compressibilities are similar: α a  = 8.2(3) and α c  = 10.68(9) (10?6 K?1); β a  = 11.4(3) and β c  = 15.9(3) (10?4 GPa). Hydration increases both the bulk thermal expansivity and compressibility, but decreases the anisotropy of structural expansion and compression. Complementary Raman and Fourier transform infrared (FTIR) spectroscopy shows multiple structural hydration sites. Low-temperature and high-pressure FTIR spectroscopy (15–300 K and 0–28 GPa) confirms that the multiple sites are structurally unique, with zero-pressure intrinsic anharmonic mode parameters between ?1.02 × 10?5 and +1.7 × 10?5 K?1, indicating both weak hydrogen bonds (O–H···O) and strong OH bonding due to long O···O distances.  相似文献   

18.
The Khor Arbaat basin is the main source of potable water supply for the more than 750,000 inhabitants of Port Sudan, eastern Sudan. The variation in hydraulic conductivity and storage capacity is due to the heterogeneity of the sediments, which range from clay and silt to gravely sand and boulders. The water table rises during the summer and winter rainy seasons; it reaches its lowest level in the dry season. The storage capacity of the Khor Arbaat aquifer is estimated to be 21.75?×?106 m3. The annual recharge through the infiltration of flood water is about 1.93?×?106 m3. The groundwater recharge, calculated as underground inflow at the ‘upper gate’, is 1.33?×?105 m3/year. The total annual groundwater recharge is 2.06?×?106 m3. The annual discharge through underground outflow at the ‘lower gate’ (through which groundwater flows onto the coastal plain) is 3.29?×?105 m3/year. Groundwater discharge due to pumping from Khor Arbaat basin is 4.38?×?106 m3/year on average. The total annual groundwater discharge is about 4.7?×?106 m3. A deficit of 2.6?×?106 m3/year is calculated. Although the total annual discharge is twice the estimated annual recharge, additional groundwater flow from the fractured basement probably balances the annual groundwater budget since no decline is observed in the piezometric levels.  相似文献   

19.
Mid-shelf sediments off the Oregon coast are characterized as fine sands that trap and remineralize phytodetritus leading to the consumption of significant quantities of dissolved oxygen. Sediment oxygen consumption (SOC) can be delayed from seasonal organic matter inputs because of a transient buildup of reduced constituents during periods of quiescent physical processes. Between 2009 and 2013, benthic oxygen exchange rates were measured using the noninvasive eddy covariance (EC) method five separate times at a single 80-m station. Ancillary measurements included in situ microprofiles of oxygen at the sediment–water interface, and concentration profiles of pore water nutrients and trace metals, and solid-phase organic C and sulfide minerals from cores. Sediment cores were also incubated to derive anaerobic respiration rates. The EC measurements were made during spring, summer, and fall conditions, and they produced average benthic oxygen flux estimates that varied between ?2 and ?15 mmol m?2 d?1. The EC oxygen fluxes were most highly correlated with bottom-sensed, significant wave heights (H s). The relationship with H s was used with an annual record of deepwater swell heights to predict an integrated oxygen consumption rate for the mid-shelf of 1.5 mol m?2 for the upwelling season (May–September) and 6.8 mol m?2 y?1. The annual prediction requires that SOC rates are enhanced in the winter because of sand filtering and pore water advection under large waves, and it counters budgets that assume a dominance of organic matter export from the shelf. Refined budgets will require winter flux measurements and observations from cross-shelf transects over multiple years.  相似文献   

20.
This study highlights the distribution of hydraulic conductivity (K) in the regional aquiferous Ajali Formation of SE-Nigeria on one hand and assesses the possible influences of textural and geochemical characteristics on the hydraulic conductivity on the other hand. The investigation approach involved field sampling and collection of 12 sandstone samples from different outcrop locations, followed by laboratory studies such as grain-size analysis (GSA), constant head permeameter test and geochemical analysis of major and trace elements using X-ray fluorescence method. GSA and textural studies show that the sandstones range from fine to medium sands, constituting about <75–99% sand fraction, with graphic mean grain size of 0.23–0.53 mm. Other parameters such as coefficient of uniformity (Cu) range from 1.58 to 5.25 (av. 2.75), while standard deviation (sorting) values of 0.56Ø–1.24Ø imply moderately well sorted materials. In addition, the order of the estimated K values is Kpermeameter>KBeyer>KHazen>KKozeny-Carmen>KFair-Hatch with average values of 1.4×10?3, 4.4×10?4, 3.8×10?4, 2.2×10?4 and 8.1×10?5m/s, respectively. These values fall within the range of 10?5 and 10?3m/s for fine to medium sands. However, multivariate factor analysis of the data revealed significant positive dependence of the empirically determined K values on graphic mean grain size and percentage sand content and much less dependence on sorting and total porosity. Geochemical profiles of the fresh samples are dominated by quartz with corresponding SiO2 content of 76.1–98.2% (av. 89.7%) while other major oxides are generally below 1.0wt.% in the fresh samples. However, the ferruginized samples exhibited elevated concentrations of Al2O3 (3.50–11.60wt.%) and Fe2O3 (1.80–3.60wt.%), which are clear indications of weathering/ferruginization processes with attendant trace metal release/enrichment (2.5mg/l Cu, 7.5mg/l Pb, 6.5mg/l Zn, 3.9mg/l Ni and 19.6mg/l Cr) call for concern in respect of the chemical quality of the groundwater system. The associated groundwater is generally soft, slightly acidic, and with low dissolved solids (EC=14–134μs/cm) dominated by silica; implying water from clean sandy aquifer devoid of labile and weatherable minerals. Nonetheless, most of the metals (with exception of Si, Fe and Mn) exhibited higher degree of mobility (2–12 folds), which can be attributed to reduction of Fe-/Mn-oxyhydroxides as sinks/hosts for trace metals. Consequently, infiltration-induced geochemical reactions (redox, ferruginization and leaching processes) signify potential environmental impact in terms of groundwater quality as well as borehole/aquifer management, especially under humid tropical environment of the study area.  相似文献   

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