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1.
Element geochemistry of gold arsenic and mineralogical features of their sulfides in the Carlin-type gold depostis of the Qinling region are discussed in this paper.The initial contents of ore-forming elements such as glod and arsenic are high the ore-bearing rock series in the Qinling region.Furthermore,both the metals are concentrated mainly in the diagenetic pyrite.Study on the mineralogy of arsenic-bearing sulfide minerals in the ores demonstrated that there is a poistive correlation between gold and arsenic in the sulfide minerals.Available evidence suggests that gold in the As-bearing sulfide minerals in likely to be presented as a charge species(Au ),and it is most possible for it to replace the exxcess arsenic at the site of iron and war probably deposited together with arsenic as solid in the sulfide minerals. Pyrite is composed of(Aux^3 ,Fe1-2^2 )([AsS]x^3-[S2]1-x^2-),and arenopyrite of (Aux^3 ,Fe1-x^3 )([AsS]x^3-[AsS2]1-x^3-).The occurrence of glod in the As-sulfied minerals from the Carlin-type gold depostis in the Qinling region has been confirmed by electron probe and transmission electron microscopic studies.The results show that gold was probably depostied together with arsenicas coupled solid solutions in sulfide minerals in the early stage of mineralization.Metallogenic chemical reactions concerning gold deposition in the Carlin-type As-rich gold deposits would involve oxidation of glod and concurrent reduction of arsenic.Later,the deposited gold as solid was remobilized and redistributed as exsolutions,as a result of increasing hydrothermal alteration and crystallization,and decreasing resistance to refractoriness of the host minerals.Gold occurs as sub-microscopic grains(ranging from 0.04tp 0.16μm in diameter)of native gold along micro factures in and crystalline grains of the sulfiedes. 相似文献
2.
High-Al chromite from the Kudi chromitites contains a wide range of mineral inclusions. They include clinopyroxene, amphibole, phlogopite, olivine, orthopyroxene, apatite, base-metal sulfides, calcite and brucite. The modal abundance of inclusions vary greatly among different grains of chromite. The common inclusions are clinopyroxene and amphibole, which occur as monomineral or polymineral associated with other minerals. The shapes of these inclusions tend to follow the growth plane of host chromite. Mineral assemblages and textures demonstrate that some inclusions(olivine, clinopyroxene) are trapped during magmatic stage, and most of the inclusions(e.g., amphibole, phlogopite) are trapped during recrystallization of chromite. Sulfide inclusions are pentlandite, chalcopyrite and cubanite. They occur either as isolated grains or together with silicate minerals, and formed from the separation of sulfide-bearing liquid from silicate magma. The parental magma of chromitites contains Al_2O_3 15.0wt%–16.5wt%, TiO_20.30wt%–1.05wt% based on calculation with the composition of chromite, similar to parental magma of high-Al chromitites from elsewhere and the estimated melt composition is comparable with that of MORB. Considering the high-Mg olivine in disseminated chromitite and abundant hydrous inclusions, we propose that Kudi chromitites formed beneath a volcanic front during the subduction initiation of Proto-Tethys. 相似文献
3.
正Objective Sulfide inclusions within natural mineral phases play important roles in exploring the origin of magmatic sulfides ores,tracing the distribution of sulfur in mantle or crust and understanding continental mantle evolution(partial melting and metasomatism in upper mantle).Until now,varieties of sulfide inclusions have been extensively discovered in the ultramafic or mafic phenocrysts.However,previous studies 相似文献
4.
CAO Yangtong LIU Chenglin XUAN Zhiqiang JIAO Pengcheng CHEN Yongzhi WANG Chunlian 《《地质学报》英文版》2011,85(6):1448-1465
A large-scale evaporate series is developed in Paleogene-Neogene strata in the Kuqa basin. The series is composed mainly of evaporate with thin beds of clastic rock (mainly mudstone and siltstone). In grayish white medium- and coarse-grained sandstone in Miocene strata, the formation of copper minerals is in close connection with brine. In joint planes, which are developed in vertical strata, are filled with gypsum. Gypsum and copper-mineralized sandstone contains enormous copper minerals, mainly atacamite. According to the SEM analysis for salt rock, gypsum rock, limestone, grayish green siltstone, grayish white medium-coarse-grained sandstone, some minerals are composed of metallic elements including Au, Ag, Cu, Zn, Pb, Co, Ni and U etc., in which Au occurs in a native form, Cu occurs in a native form or as atacamite in salt rock, gypsum rock and limestone, Ag occurs as silver sulfide in gypsum, and Zn, Pb, Co, Ni, U occur as compounds along with the above metallic ions in evaporate or clastic rock. From SEM images, we can see that metallic elements or their compounds (oxides or sulfides) “take root” as grains in salt or gypsum crystals, which belong to primary chemical sedimentation along with evaporate, while some grains “float” on surface of salt or gypsum. In the former case, mineral grains were formed together with salt (gypsum) crystals; while in the latter case, minerals were enriched from internal metallic ions (Paleogene evaporate samples) or external metallic ions (Neogene gypsum samples) in the late stage of evaporate formation. The metallic ions in Paleogene evaporate samples might originate from weathered or denudated materials in the south Tianshan Mountains. The metallic ions in the Neogene evaporate samples might be from metal-bearing brine, which migrated upward to surface along fractures and leached into evaporate (gypsum). Occurrence of metallic minerals and their compounds (elementary substance) in Paleogene evaporate proves that diversified metallic minerals exist in evaporate. The source of metallic ions in the Neogene evaporate series shows that evaporate could provide materials for late-stage metallic mineralization. 相似文献
5.
中国山东昌乐地区碱性玄武岩刚玉中记录的岩浆不混溶作用 总被引：2，自引：0，他引：2
Abundant melt-and fluid inclusions occur in corundum megacrysts of alkaline basalt from the Changle area,Shandong province,eastern China.One type of melt inclusions,i.e.muhiphase melt inclusions(glass bubbles daughter minerals)were identified,which occur along growth zones of host corundum megacrysts.Microthermometry and laser Raman microprobe analysis were performed on the melt inclusions.The bubbles within the melt inclusions are confirmed to be CO_2-rich phase and the daughter minerals are probably silicates,such as augite and okenite.The results of high temperature homogenization experiment strongly suggest that two immiscible melts,i.e.a H_2O-and CO_2-rich melt and an anhydrous and CO_2-poor melt were trapped by melt inclusions in corundum megacryst. 相似文献
6.
Luobusaite： A New Mineral 总被引：6，自引：0，他引：6
BAI Wenji SHI Nicheng FANG Qingsong LI Guowu XIONG Ming YANG Jingsui RONG He 《《地质学报》英文版》2006,80(5):656-659
A group of mantle minerals including about 70-80 subtypes of minerals are discovered from a podiform chromitite in Tibet, China. Recovered minerals include diamond, coesite, moissanite, wustite, Fe-silides and a new mineral, luobusaite. All of these minerals were hand-picked from heavymineral separates of the podiform chromitite in the mantle peridotite of an ophiolite. The grains of luobusaite are as host mineral with inclusions of native silicon or as an intergrowth with native silicon and Fe-Si phase. Luobusaite occurs as irregular grains, with 0.1-0.2 mm in size, consisting of very finegrained aggregates. The mineral is steel-grey in color, metallic luster, and opaque. The empirical formula （based on 2 for Si） is Fe0.83Si2, according to the chemical compositions of luobusaite. X-ray powder-diffraction data： orthorhombic system, space group Cmca, a = 9.874 （14） A, b = 7.784 （5） A, c= 7.829（7） A, Z=16. 相似文献
7.
IrinaP.Solovova Theodoros Ntaflos Andrei Girnis Natalya N.Kononkova Vyacheslav V.Akinin 《岩石学报》2007,23(1):83-92
Melt and fluid inclusions were studied in the minerals of Cenozoic olivine melanephelinites from the Chukchi Peninsula, Russia.The rock contain several generations of olivine phenocrysts varying in composition at mg=0.88～0.77.The phenocrysts bear fluid and melt inclusions recording various stages of melt crystallization in volcanic conduits and shallow magma chambers.Primary fluid inclusions are CO_2-dominated with a density of up to O.93 g/cm~3.All fluid inclusions are partially leaked,which is indicated by haloes of tiny fluid bubbles around large fluid inclusions in minerals.Melt inclusions contain various daughter crystals,which were completely resorbed in thermometric experiments at about 1230℃.Assuming that this temperature corresponds to the entrapment conditions of the CO_2 fluid inclusions,the minimum pressure of the beginning of magma degassing is estimated as 800MPa.Variations in the compositions of homogenized silicate melt inclusions indicate that olivine was the earliest crystalline phase followed by clinopyroxene,nepheline and orthoclase.This sequence is in agreement with the mineralogy of the rocks.The melts are strongly enriched in incompatible trace elements and volatiles(in addition to CO_2,high C1,F,and S contents were detected).There are some differences between the compositions of melts trapped in minerals from different samples.Variations in SiO_2,FeO,and incompatible element contents are probably related to melt generations at various levels in a homogeneous mantle reservoir. 相似文献
8.
Sequential core sediments from northwestern Taihu Lake in China were analyzed for grain size, organic carbon and heavy metal content. The sediments are composed of organic-poor clayey-fine silts. The chemical speciations of Cu, Fe, Mn, Ni, Pb, and Zn were also analyzed using the BCR sequential extraction procedure. Cu, Fe, Ni, and Zn are mainly associated with the residue fraction; Mn is concentrated mainly in exchangeable/carbonate fraction and residue fraction; and Pb mainly in Fe/Mn oxide fraction and organic/sulfide fraction. The exchangeable/carbonate fractions of Cu, Fe, Ni, Zn and Pb are lower. The fractions of Ni, Pb and Zn bound to the Fe/Mn oxide have significant correlations with reducible Mn; the organic/sulfide fractions of Cu, Mn, Ni, Pb, and Zn have significant correlations with TOC. The extractable fractions of Cu, Mn, Ni, Pb, and Zn are high at the top 4 cm of the core sediments as compared to those in the deeper layers, showing the anthropogenic input of heavy metals is due to rapid industrial development. The heavy metal pollution history of the sediments has been recorded since the late 1970s, determined by the result of ^137Cs dating. 相似文献
9.
SONG Huanbin HE Mingqin ZHANG Shangzhong YI Fenghuang 《中国地球化学学报》2008,27(1):104-108
The Jingbaoshan platinum-palladium deposit is China＇s largest independent PGM （platinum-group metals） deposit so far discovered. There are eleven kinds of useful components in the ore： Pt, Pd, Os, Ir, Ru, Rh, Au, Ag, Cu, Ni, and Co. The platinum-group elements, gold and silver occur in the form of minerals in ores. twenty-five kinds of precious metal minerals have been found, of which twenty one belong to the platinum-group minerals. The minerals are very small in grain size. Copper occurs mainly as copper sulfide with a small amount of free copper oxide, and the beneficiated copper accounts for 95.21%. Nickel occurs mainly as nickel sulfide, and some nickel silicate and nickel oxide occur in the ore. The beneficiated nickel accounts for 72.03%. Cobalt occurs mainly as cobalt sulfide, and there are some cobalt oxide and other kinds of cobalt. The beneficiated cobalt accounts for 77.58%. 相似文献
10.
Fluids and Melts in the Upper Mantle 总被引：3，自引：0，他引：3
XIA Linqi XIA Zuchun XU XueyiXi''an Institute of Geology Mineral Resources Chinese Academy of Geological Sciences East Youyi Rd. Xi ''an Zhu Xiling 《《地质学报》英文版》1999,73(3):330-340
This paper presents a direct study of the fluids and melts in the upper mantle by examining the fluid inclusions, melt inclusions and glasses trapped in the mantle lherzolite xenoliths entrained by Cenozoic alkali basalts (basanite, olivine-nephelinite and alkali-olivine basalt) from eastern China. The study indicates that the volatile components, which are dissolved in high-pressure solid mineral phases of mantle peridotite at depths, may be exsolved under decompressive conditions of mantle plume upwelling to produce the initial free fluid phases in the upper mantle. The free fluid phases migrating in the upper mantle may result in lowering of the mantle solidus (and liquidus), thereby initiating partial melting of the upper mantle, and in the meantime, producing metasomatic effects on the latter. 相似文献
11.
江苏六合新生代玄武岩中地幔捕虏体的硫化物相研究 总被引：13，自引：3，他引：10
江苏六合一带碱性玄武岩中的出露有以尖晶石二辉橄榄岩为主的地幔捕虏体,这些地幔矿物中普遍有硫化物相出现：（１）被寄主矿物捕获的早期硫化物颗粒。（２）产于矿物晶粒边界或次生裂隙充填物,（３）硫化物包裹体,包括单相硫的包裹体、硫化物－玻璃两相熔体包裹体和ＣＯ／２－硫化物－玻璃（含硅酸盐子矿物）的多相包裹体,电子探针分析表明,硫化物包裹体比例隙中硫化物具有更高的相对Ｆｅ和Ｓ含量,较低的Ｎｉ含量。硫化物包裹 相似文献
12.
浙江新昌地幔岩捕虏体中的硫化物包裹体初步研究 总被引：8，自引：1，他引：7
浙江新昌一带晚第三纪碱性玄武岩中地幔岩（二辉橄榄岩）捕虏体内存在大量硫化物熔体包裹体。电子探针分析表明,硫化物相成分主要为镍黄铁矿,次为磁共铁矿。硫化物包裹体的Ｎｉ／Ｆｅ值与寄主地幔岩的橄榄石含量呈正相关。同一包裹体的硫化物相成分不均一,自中心至边缘硫化物的Ｎｉ／Ｆｅ、（Ｆｅ＋Ｎｉ）／Ｓ值和Ｎｉ呈均呈增加趋势。通过与中国汉诺坝、德国ＷｅｓｔＥｉｆｅｌ东欧Ｎｏｇｒａｄ－Ｇｏｍｏｒ地区资料的综合分析, 相似文献
13.
福建牛头山新近纪碱性玄武岩中地幔岩包体内硫化物研究 总被引：3，自引：0，他引：3
福建牛头山一带新近纪碱性玄武岩中含有尖晶石二辉橄榄岩包体。这些地幔岩包体内普遍存在有硫化物。硫化物按产状和成因分为两类:1)分布于寄主矿物内部,未与裂隙相连,是地幔岩浆作用的产物;2)分布于颗粒内或颗粒边部,在裂隙上或与裂隙相连,是地幔流体交代作用的产物。电子探针分析表明,15个硫化物测点中,除2个黄铜矿、1个硫铜铁矿外,其余为不同Ni/Fe(mol比)比值的铁镍硫化物:6个测点为富镍镍黄铁矿,其Ni/Fe=0.98～2.79,(Fe+Ni)/S=1.03～1.08;2个为针镍矿,其Ni/Fe=5.5,(Fe+Ni)/S=1.01;4个测点为富镍磁黄铁矿,其Ni/Fe=0.29～0.49,(Fe+Ni)/S=0.79～0.94。4粒单一硫化物矿物的成份是不均一的,多数表现为自中心到边部Ni含量和Ni/Fe值呈增加趋势,而Fe和Cu含量呈减少趋势。本研究还发现单一硫化物中由中心到边部金与镍大致有相同的变化趋势。 相似文献
14.
Djerfisherite, a Cl-bearing potassium sulfide (K6Na(Fe,Ni,Cu)24S26Cl), is a widespread accessory mineral in kimberlite-hosted mantle xenoliths. Nevertheless, the origin of this sulfide in nodules remains disputable. It is usually attributed to the replacement of primary Fe–Ni–Cu sulfides when xenoliths interact with a K-and Cl-enriched hypothetical melt/fluid. The paper is devoted to a detailed study of the composition and morphology of djerfisherite from a representative collection (22 samples) of the deepest mantle xenoliths—sheared garnet peridotite, taken from the Udachnaya-East kimberlite pipe (Yakutia). Four types of djerfisherite were distinguished in the mantle rocks on the basis of morphology, spatial distribution, and relationships with the rock-forming and accessory minerals in the nodules. Type 1 was found in the rims of polysulfide inclusions in the rock-forming minerals of the xenoliths; there, it was younger than the primary sulfide assemblage pyrrhotite + pentlandite ± chalcopyrite. Type 2 formed rims around large polysulfide segregations (pyrrhotite+ pentlandite) in the xenolith interstices. Type 3 formed individual grains in the xenolith interstices together with other sulfides, silicates, oxides, phosphates, and carbonates. Type 4 was present as a daughter phase in the secondary melt inclusions which occurred in healed cracks in the rock-forming minerals of the xenoliths. Along with djerfisherite, the inclusions contained silicates, oxides, phosphates, carbonates, alkaline sulfates, chlorides, and sulfides. The results indicate that djerfisherite from the xenoliths is consanguine with kimberlite. Djerfisherite both in the sheared-peridotite xenoliths from the Udachnaya-East pipe and in different xenoliths from other kimberlite pipes worldwide formed owing to the interaction between the nodules and kimberlitic melts. Djerfisherite forming individual grains in the melt inclusions and xenolith interstices crystallized directly from the infiltrating kimberlitic melt. Djerfisherite bounding the primary Fe–Ni ± Cu sulfides formed by their replacement as a result of a reaction with the kimberlitic melt. 相似文献
15.
J. P. Lorand 《Lithos》1989,23(4):281-298
The orogenic-type spinel peridotite massifs of Lherz and Freychinède (Northeastern Pyrenees, Ariège, France) were tectonically emplaced along the North Pyrenean fault. They have been cross-cut by Cretaceous alkali basalts, a few kilometres below the Moho. These magmas crystallized at about 1.0–1.5 GPa as veins of amphibole-rich pyroxenites, containing garnet, and also occasionally as phlogopite hornblendites. In spite of the low volume of trapped silicate liquid, the veins contain up to 1900 ppm S, up to 140 ppm Cu and up to 10 ppb Pd. Under the microscope, the sulfides occur as isolated inclusions within magmatic phases (orthopyroxene, clinopyroxene, amphibole, garnet, spinel, ilmenite), irrespective of parting, cleavage or exsolution planes, or as interstitial grains among the major phases, showing signs of textural equilibration. The sulfide inclusions are interpreted as resulting from entrapment of an immiscible sulfide liquid during magmatic crystallization of the veins. However, a detailed comparison with sulfide inclusions from Cpx- and Al-augite megacrysts entrained in continental basalts shows that post-trapping structural and compositional rearrangements have probaly occurred, in response to cooling, deformation and recrystallization of the veins in the lithospheric mantle.
Except in the thinnest veins where subsolidus re-equilibration of the Ni partitioning has occurred between the veins and their host peridotites, the sulfide inclusions are predominantly composed of slightly nickeliferous pyrrhotite, coexisting with subordinate amounts of pentlandite and chalcopyrite. Bulk chemistry recomputed from modal proportions and microprobe analyses of each individual sulfide in 500 inclusions is as follows: 54% Fe, 5.5% Ni, 2.0% Cu and 38.0% S. A calculation combining this composition and the experimentally determined distribution coefficients for Ni and Cu between sulfide melt and silicate melt leads to < 200 ppm Ni and > 85 ppm Cu in the silicate melt at the time at which the sulfide liquid became immiscible. It is concluded that the alkalic basaltic magma parent to the amphibole-rich veins reached sulfide saturation at depth of 30–40 km, i.e. after some differentiation occurred in the uppermost lithospheric mantle. 相似文献
16.
捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物。电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳。 相似文献
17.
地幔捕虏体中的流体-熔体包裹体 总被引：3，自引：0，他引：3
地幔流体的研究现已成为国内外前沿课题。地幔岩捕虏体中的流体-熔体包裹体是地幔流体的直接证据,通过对它们的研究可以直接获取地授流体的信息。包裹体按相态特征主要有三类：二氧化碳流体包裹体、二氧化碳-硅酸盐熔体包裹体、硫化物-熔体流体包裹体。本总结了地幔岩中流体-熔体包裹体的基本特征、微量元素地球化学、硫化物-熔体包裹体和二氧化碳流体包裹体稳定同位素特征的研究进展状况。讨论认为：地幔流体是由C、H、O、S等元素的挥发份和硅酸盐熔体组成;上地幔流体在化学成分上明显富含CO2、硫化物、LILE和BEE,它引起地幔交代作用和地授部分熔融;上地授流体的分布存在不均匀性,其组成也存在地区性差异。 相似文献
18.
Pyroxenite layers in the orogenic spinel lherzolite massifsof Ari?ge are porphyroclastic textured and range in compositionfrom spinel websterite to garnet clinopyroxenite. Each pyroxenitetype forms individual layers or occurs as part of compositelayers in which the Opx/Cpx and Sp/Gt ratios decrease from marginsto core. They are interpreted as crystalline segregations separatedby flow crystallization from continental tholeiites en routeto the surface. The primary magmatic phases consist of Al-richpyroxenes, together with a minor amount of spinel, which startedto crystallize at 1400?C and 20–22 kb pressure; the pyroxeneshave locally survived plastic strains and subsolidus rccrystallizationsand now occur in the form of clinopyroxene and orthopyroxenemegacrysts displaying unmixing features. Although the differentiated silicate liquid was fully expelledduring the flow crystallization process, the layered pyroxeniteshave concentrated the highly incompatible elements S and Cuand locally display significant chalcophile platinum-group elementenrichment (Pd, Pt). Cu and S behave coherently over the wholerange of pyroxenite composition; their highest concentrationsare found in the thinnest websterite layers or at the marginof composite layers. Microscopic investigation of 214 polishedthin sections shows these elements to be present as accessoryCu-Fe-Ni sulfides interstitial among the silicate phase or formingdiscrete bodies included in the relic pyroxene megacrysts. Allthese features indicate the presence of a sulfide liquid, immisciblewith the silicate magma, during the crystallization of the layeredpyroxenites. Sulfide liquid immiscibility probably occurredin response to thermal contrast between the pyroxenites andthe cooler surrounding peridotites. It is proposed that the megacryst-hosted sulfide inclusionswere trapped as linear arrays arranged on host megacryst growthplanes. Due to the slow cooling and complex unmixing historyof the megacrysts, these arrays have been transformed into coarse,isolated sulfide inclusions by subsolidus migration and spheroidizationprocesses. They started to crystallize at T = 1200?C as monosulfidesolid solution (MSS), probably coexisting with a minor amountof Ni- and Cu-rich sulfide liquid down to r=900?C. The reconstructionof the bulk chemistry of each individual inclusion reveals significantbetween-inclusion variations of Cu/Ni+ Fe and Ni/Fe ratios,which would result from strain-induced immobilization of theseliquids. On cooling, the high-temperature MSS has decomposedbelow 230?C into Ni-rich pyrrhotite, nickeliferous pentlandite,chalcopyrite and minor pyrite. The post-magmatic history ofthe interstitial sulfide grains was not unlike that of the inclusions,except at near-surface temperatures where the primary sulfidesresulting from unmixing of MSS have been partly altered intosecondary sulfides by serpentinizing aqueous fluids. In spite of these post-magmatic alterations, the inclusionsand the interstitial sulfide phases are remarkably homogeneousas regards their bulk Ni/Cu ratio, which is close to 3. Thisvalue is characteristic of sulfide separated from primary ratherthan partially differentiated tholeiitic melts. It is thus concludedthat the continental tholeiite parent to the layered pyroxeniteswas saturated with sulfides when it left its mantle source regioaIn this aspect, it would not be different from MORBs which containsimilar sulfide compositions. In both cases, sulfide fractionationcannot be ignored in models for chalcophile trace element fractionationduring initial evolution of these magmas. 相似文献
19.
地幔岩中不同产状的流体-熔体包裹体及地幔流体交代作用 总被引：1，自引：0，他引：1
地幔捕虏体中存在不同产状的熔体包裹体和各种硅酸盐玻璃相,包括主矿物内部的蠕虫状、长圆形、圆形、不规则状包裹体(I型)、边部的连通的管状包裹体(T型)、主矿物边部和粒间的片状熔融体——“浆胞”(C型),三者可见明显过渡关系,它们是地幔流体交代地幔岩石过程中由交代重熔形成的,是研究地幔流体的特征和地幔交代作用的对象之一,从I型、T型到C型,其成分呈规律变化,其中S、Cu、Ni,K、Na含量呈明显的降低趋势．包裹体中玻璃相的成分较主矿物富Si、Al、S、Cu、Ni、K和Na,再加上C02包裹体的发现,表明地幔流体的成分富碱金属、Si、Al、S、Cu、Ni和CO2,地幔交代作用可以使交代产物中Si、Al含量升高而形成中酸性岩浆,也可由于硫化物熔体聚集而形成矿浆．不同地区的地幔流体性质可能存在差异,这些不同性质的地幔流体町能与不同类型的地幔成矿作用有关． 相似文献
20.
Spinel lherzolite xenoliths from Tertiary basaltic host magmas at Allyn River, eastern Australia reveal two distinct petrographic and geochemical types. One group is distinguished by xenoliths with undeformed, equilibrated microstructures and interstitial melt patches; The second group shows deformation and contains abundant fluid inclusions but no melt patches. Trace-element signatures of clinopyroxene in these xenoliths provide evidence for metasomatism by a silicate agent with hydrous component and by a carbonate-rich agent respectively.
Melt patches in the undeformed xenoliths contain secondary minerals including clinopyroxene, olivine, feldspar, Mg- and Ca-rich carbonate, apatite, ilmenite and spinel. They are interpreted to represent volatile-rich melt captured shortly prior to entrainment in the host basalt. Sulfide globules, now recrystallised to discrete sulfide phases but inferred to be molten at lithospheric mantle T and P, are closely associated with the melt patches. The close association between sulfide and highly mobile, volatile-bearing fluid has important implications for the mobility of Re and Os, the use of their isotopes in dating mantle events, and the possible effect of volatile-bearing metasomatic agents on their composition. 相似文献