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1.
Geochemical characteristics of the Chagande’ersi molybdenum deposit in Inner Mongolia and its genesis were analyzed in this study using rock mineralography and rock geochemical testing. The mineralized country rocks of the Chagande’ersi molybdenum deposit consist mainly of medium-to fine-grained monzogranite,medium-to fine-grained rich-K granite,with minor fine-grained K-feldspar granite veins and quartz veins.The rocks are characterized by high silica,rich alkali,high potassium,which are favorable factors for molybdenum mineralization.The rocks have the Rittmann index ranging from 1.329 to 1.961,an average Na2O+K2O value of 7.41,and Al2O3/（CaO+Na2O+K2O）>1,suggesting that the rocks belong to the high-K calc-alkaline peraluminous granite.The typical rock samples are enriched in Rb,Th,K and light rare earth elements,depleted in Sr,Ba,Nb,P and Ti, and these features are similar to that of the melt granite resulting from collision of plate margins.TheδEu of the rocks falls the zone between the crust granite and crust-mantle granite,and are close to that of the crust granite;（La/Lu）N indicates the formation environment of granite is a continental margin setting.The Nb/Ta ratios are close to that of the average crust（10）;the Zr/Hf ratios of monzogranite are partly below the mean mantle（34-60）,while the Zr/Hf ratio of K-feldspar granite are close to the mean value in the crust.Comprehensive analyses show that the granite in this area formed during the transition period between tectonic collision and post-collision.During the plate collision and orogeny,the crust and mantle material were mixed physically,remelting into lava and then crystal fractionation,finally gave rise to the formation of the rock body in this area.This has close spatial and temporal relation with the molybdenum mineralization.  相似文献   

2.
The mechanism that controls regional mineralization must be governed by a series of geochemical reactions in relation to the source system of magmatism.In this respect,the geological bodies must have been overprinted by various kinds of tracers in terms of either chemical elements or isotopes.For this reason,the problem may be better approached by treating the lithosphere as a whole with due considerations given to the various tracer elements and isotopes and the various media of the magmatism(magmatic as well as sedimentary rocks).Presented in this paper are the results of this attempt based on a great wealth of available data concerning the source system of Mesozoic magmatism in the Middle and Lower Yangtze Valleys and adjacent areas.  相似文献   

3.
Abstract：In this study, whole-rock geochemical and Nd isotopic data, as well as detrital zircon Hf isotopes of Palaeoproterozoic metasedimentary rocks from the Jiangxian Group are presented to evaluate the characteristics of their provenance and the tectonic history. The major and trace element compositions are comparable to Post-Archean upper continental crust (PA-UCC), but have slight enrichment in the LILE, with the exception of Cs and Sr, and a slight depletion in ferromagnesian elements, HFS elements, such as Nb and Ta, and some major elements, such as CaO and Na2O. The geochemical data reveal that the collected metasedimentary rocks have experienced intermediate source weathering with chemical index of alteration values ranging from 72 to 78, varying degrees of K-metasomatism, and post-depositional loss of Na, as well as negligible sorting, and are derived from the weathering of mostly felsic and non-mafic rocks. The selected Lu–Hf isotopic analysis on detrital zircon points to both the Trans-North China Orogen and Eastern Block of the north China craton as the most likely sources for the metasedimentary rocks of the Jiangxian Group. However, a contribution of detritus from the Western Block of the north China craton can be ruled out. The sediments were probably deposited in a back-arc basin within an active continental margin setting.  相似文献   

4.
The Helegangnaren feldspar granite exposed in the eastern part of East Kunlun, is characterized by high concentrations of SiO2 and alkaline, low abundances of Fe, Mg and Ca, metaluminous-weak peraluminous. Trace elements analysis shows that the granite is depleted extremely in Ba, Sr and Eu, and rich in some large-ion lithophile elements and high field strength elements. Besides, the granite has high Ga contents, the values of 104(Ga/Al) vary from 2.50 to 2.77, which is mainly greater than the lower limit of A-type granites (2.6), and is higher than the I- and S-type granites’ average (2.1 and 2.28, respectively). Rare earth element (REE) is characterized by relatively high fractionations of light REE (LREE) and heavy REE (HREE) (LREE/HREE=9.3–13.60, (La/Yb)N=10.92–18.02), pronounced negative Eu anomalies (δEu=0.08–0.13), and exhibits right-dipping gull pattern. Major elements, rare elements and trace elements features show the granite is ascribed to A-type granite and A2 subtype in tectonic genetic type. They are plotted into post-collision or within-plate area in a variety of tectonic discriminations. Geological and geochemical data comprehensively suggest that the granite is formed in a post-collision extensive tectonic setting. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U-Pb dating yields a weighted mean age of 425?Ma, belonging to Middle Silurian, which is similar to the age of the post-collision geological events in the region. The differences of magmatic rocks in formation age, rocks assemblage and rocks series systematically indicate that the regional tectonic stress regime in the East Kunlun orogenic belt experienced a major transformation from compress to extension in Middle Silurianin, and the Helegangnaren feldspar granite intruded in the early stage of tectonic transformation.  相似文献   

5.
Based on a review of the available petrological and petrochemical data on magmarie rocks in a certain district in China, the average chemical composition of magmarie rocks has been calculated, and the frequenee distribution of elements in rocks,mineralization of rock bodies and regional geochemical characteristics have been discussed. In response to the temporal and. spatiai variations during the evolutionary process of magmatie activity, a systematic variation is obvious from this study in the chemical compositions of magmatie rocks, the frequence distribution patterns of elements, the concentration levels of various elements, the calc-alkaline index of the rocks as well as in the average atomic weight and average atomie valence. Particularly,different geochemical indicators have been observed for mineralized and barren rock bodies respectively. Crystallization-differentiation and postmagmatic metasomatism constitute the most important mechanisms controlling mineralization.  相似文献   

6.
个旧含Sn花岗岩的Sr同位素特征及找矿标志的研究   总被引：30，自引：0，他引：30  
Whole-reck Rb-Sr isochron dating of Sb-bearing granites and alkaline rocks at Gejiu, Yunan Province has been conducted for their emplacement ages and initial ^87Sr/^84Sr ratios. The Sr isotopic compositions of apatites from some basic rocks in Jiasha and granite bodies have also been studied in decal, The genesis and evolution of Gejiu Snbearing granites as well as ore-search indicators are discussed on the basis of the available data in conjunction with the geochemical data on trace elements, such as Rb and Sr, Sr isotopic characteristics of the volcanie rocks, meta-diabase and host rocks, and isotopic features of ore leads.  相似文献   

7.
The Longbohe Cu deposit, which is located in the southern part of the Honghe ore-forming zone, Yunnan Province, China, belongs to a typical ore field where volcanic rocks are of wide distribution and are associated with Cu mineralization in time and space. The volcanic rocks in the ore field, which have experienced varying degree of alteration or regional metamorphism, can be divided into three types, i.e., meta-andesite, meta-subvolcanic rock and meta-basic volcanic rock in accordance with their mineral assemblages. These three types of volcanic rocks in the ore field are relatively rich in Na and the main samples plot in the area of alkali basalts in the geochemical classification diagram. With the exception of very few elements, these three types of volcanic rocks are similar in the content of trace elements. In comparison to the basalts of different tectonic settings, the meta-volcanic rocks in the ore field are rich in high field strength elements (HFSE) such as Th, Nb, etc. and depleted in large ion lithophile elements (LILE) such as Sr, Ba, etc. and their primary mantle-normalized trace element patterns show remarkable negative Th and Nb anomalies and negative Sr and Ba anomalies. These three types of volcanic rocks are similar in REE content range and chondrite-normalized REE patterns with the exception of Eu anomaly. Various lines of evidence show that these three types of volcanic rocks in the ore field have the same source but are the products of different stages of magmatic evolution, their original magma is a product of partial melting of the metasomatically enriched mantle in the tensional tectonic setting within the continent plate, and the crystallization differentiation plays an important role in the process of magmatic evolution.  相似文献   

8.
The Lanhualing tungsten-molybdenum deposit is a skarn-type deposit located in Ningguo county, Anhui province. This deposit is mainly hosted in the Yinzhubu Formation and the Yanwashan Formation of Ordovician, and genetically related to the Lanhualing granite. The Lanhualing granite belongs to high-K calc-alkaline series with high alkali (Na2O+K2O=4.00%-7.03%), SiO2 (67.87%-74.92%) and MgO (0.62%-1.23%) contents. The granitic rocks show right-dipping chondrite normalized REE patterns with weak δEu anomalies. The granitic rocks are relatively enriched in large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE). The ore-bearing granite was dated at 148.17±0.94 Ma by LA-ICP-MS zircon U-Pb method. The late Yanshanian is the main tungsten mineralization epoch in the South Anhui-north Jiangxi area; and indeed, the Dongyuan, Zhuxi, Yangchuling, Dahutang and other large and super-large tungsten deposits were formed in this period. Geochemical Characteristics of the Lanhualing granite indicate a crustal source but with mantle input under tectonic regime of compression thickening. ©, 2015, Science Press. All right reserved.  相似文献   

9.
Discriminations in a local chemical,fluidal,mechanical and thermal processes in a shear zone will lead to metallogenic differentiation in a local section.This paper,based on the general geological setting of the Shibangou gold deposit in Xixia,Henan,deals with petrological and petrochemical samples of altered rocks in the metallogenic section and of mylonites in the non-metallogenic section of a selected shear zone.The discriminations in fluid-rock interaction and petrological mass balance between altered rocks near the orebody and mylonites in the shear zone are discussed as well.The results show that the petrological volume of altered rocks in the metallogenic section of the shear zone is almost always dilatant and the mylonite volume in the non-metallogenic section is almost always lost.Major elements in altered rocks from the metallogenic section and in mylonites from the non-metallogenic section always show a tendency of being enriched and depleted,respectively.Fluid-rock ratios in the mylonites(Nu=93.68-468.40)are larger than those of the altered rocks(NC(Ⅳ）^s=36.11-216.67).The gain and loss of major and trace elements from the altered rocks and mylonites in the shear zone are a composite process to be imported and exported by percolating fluids as well as of the loss and dilatancy of rock volume.  相似文献   

10.
Many igneous rocks distribute in Gejiu tin polymetallic ore-field at Yunnan province, rocks including basalt, gabbro, mafic microgranular enclaves, granites (porphyritic granite and equigranular granite) and akaline rocks. The ages of the granites and akaline rocks which are considered to have genetic connecting with the mineralization have been comfirmed, but the gabbro-mafic microgranular enclaves-granite assemblage’s ages are still unknown. By means of LA-ICP-MS zircon U-Pb dating, the data of Shenxianshui equigranular granite, the mafic microgranular enclave in Jiasha area, the host rock of the mafic microgranular enclaves and the Jiasha gabbro are around ~80 Ma. Besides the above mentioned data, a group of new ages at ~30 Ma were discovered in this study, which is from gabbro and mafic microgranular enclaves. Based on the previous data and the new data gained this time, we suggest the major geochronology framework of the magmatism and mineralization events in Gejiu area is ~80 Ma, which is consistent with the Late Cretaceous magmatism and mineralization events in the whole southeast Yunnan and west Guangxi area and they were suggested to belong to the same geotectonic setting in late Yenshannian. And the new ages of the ~30 Ma obtained in this study is considered to represent a responding to the complicate tectonic evolution history of the Tibetan orogenic events in Cenozoic.  相似文献   

11.
Recently discovered intermediate-basic volcanic rocks in the Devonian strata at Dachang, Guangxi Zhuang Autonomous Region are dominated by basalts and andesites. Most of them belong to the calc-alkali and alkali series. Petrology and geochemistry data indicate that the volcanic rocks may be formed in a continental rift environment. The volcanic rocks are in conformable contact with the overlying and underlying wall rocks, with such typical sedimentary structures as laminated and striped ones, and the host rocks of the volcanic rocks contain lots of marine fossils such as tentaculite. Many pieces of evidence indicate that the eruption environment of the volcanic rocks is a sea-facies one. The volcanic rocks are of the LREE-enrichment type, with high ratios of light rare-earth elements to heavy rare-earth elements. In addition, they display moderately negative δEu anomalies and moderately negative δCe anomalies with a higher degree of LREE and HREE fractionation. Through the Q-cluster analysis of the REE samples, it is indicated that the ores have a closer relation with the layered volcanic rocks, and also possess a certain inheritance-consistency relationship with the layered volcanic rocks. The source of ore-forming materials may be related with volcanism. It is proposed that the ore deposit in the study area should be genetically explained as the result of marine volcano-sedimentary exhalation of hot water and late superposition-reworking.  相似文献   

12.
Geochemical studies on REE, trace elements and oxygen isotopes from metamorphic veins and their host metasedimentary rocks in the Zhoutan Group at two localities, Xiangshan and Yihuang, in central Jiangxi Province have been conducted in this paper. The results show that the metamorphic quartz veins inherited the REE and oxygen isotope geochemical characteristics from their host rocks, suggesting that the vein-forming fluids were derived from the host rocks. Additionally, fractionation degrees of the trace element pairs Zr-Hf, Nb-Ta, Y-Ho and U-Th in the veins are different from those of their host rocks. It is also indicated that the veins are the products of the fluids. The metamorphic veins within the Zhoutan Group metasedimentary rocks were formed principally as a result of lateral diffusion of the metamorphic fluids.  相似文献   

13.
The xenoliths in host rocks of hydrothermal gold deposits can generally provide much geochemical information of the deep rocks, which may have an implication for the sources of ore-forming materials. Geochronology and geochemical characteristics are reported for a granite xenolith, which is enclosed by the lamprophyre in the Zhenyuan gold deposit (Yunnan Province, SW China). This granite xenolith mainly consists of K-feldspar, quartz, and plagioclase with trace amounts of magnetite, titanite, apatite, zircon, and sulfides. Zircons from the granite xenolith yield a weighted average U-Pb age of 281.1 ± 1.3 Ma (MSWD = 2.1), which could represent the crystallization age of this granite xenolith. The Ti-in-zircon geothermometer and the Mn concentration in apatite calculate that this granite xenolith formed at 685 ± 43°C with the logfO2 values ranging from NNO + 3.7 to NNO + 6.4. The zircons in the granite xenolith have a restricted range of positive εHf(t) values ranging from +9.4 to +10.8, and the corresponding Hf TDM2 model ages range from 588 to 678 Ma. The zircon U-Pb age and the Hf isotopic compositions indicate this granite xenolith within the lamprophyre is mainly derived from partial melting of juvenile crustal rocks before the completed closure of the Ailaoshan Ocean. The pyrites in the granite xenolith have higher Bi concentrations, and lower As, Sb, and Tl concentrations than the gold-bearing pyrites of the ores in the Zhenyuan gold deposit. The low Au concentrations of the pyrites together with the ore-forming age of the Zhenyuan gold deposit (Oligocene) indicate the granite xenolith may have limited contribution to the gold mineralization of the Zhenyuan gold deposit.  相似文献   

14.
The Pulang (普朗) porphyry copper deposit, located in the southern segment of the Yidun-Zhongdian (义敦-为中甸) island arc ore-forming belt of the Tethys-Himalaya ore-forming domain, is a recently discovered large copper deposit. Compared with the composition of granodiorite in China, the porphyry rocks in this area are enriched in W, Mo, Cu, Au, As, Sb, F, V, and Na2O (K1≥1.2). Compared with the composition of fresh porphyry rocks in this district, the mineralized rocks are enriched in Cn, Au, Ag, Mo, Pb, Zn, W, As, Sb, and K2O (K≥1.2). Some elements show clear anomalies, such as Zn, Ag, Cu, Au, W, and Mo, and can be regarded as pathfinders for prospecting new ore bodies in depth. It has been inferred from factor analysis that the Pulang porphyry copper deposit may have undergone the multiple stages of alteration and mineralization: (a) Cu-Au mineralization; (b) W-Mo mineralization; and (c) silicification and potassic metasomatism in the whole ore-forming process. A detailed zonation sequence of indicator elements is obtained using the variability index of indicator elements as follows: Zn→Ag→Cu→Au→W→Mo. According to this zonation, an index such as (Ag×Zn) D/(Mo×W) D can be constructed and regarded as a significant criterion for predicting the Cu potential at a particular depth.  相似文献   

15.
Neogene volcanic rocks in the Belog Co area, Qiangtang, northern Tibet, are represented by a typical intermediate-basic and intermediate alkaline rock association, with latite-trachyte as the main rock type. The results of chemical analysis are: SiO2=52%–62%, Al2O3>15%, Na2O/K2O>1 and MgO<3.30%. In addition, the volcanic rocks are LREE-enriched with LREE/HREE=10–13, (La/Yb)N=15–19, and show a weak negative Eu anomaly with δEu=0.71–0.89. The close relationship between Mg# and SiO2 and the co-variation of the magmatophile elements and ultra-magmatophile elements such as La/Sm-La and Cr-Tb indicate that this association of volcanic rocks is the product of comagmatic fractional crystallization. The rock association type and lower Sm/Yb values (Sm/Yb=3.23–3.97) imply that this association of volcanic rocks should have originated from partial melting of spinel lherzolite in the lithospheric mantle. On the other hand, the weak negative Eu anomaly and relative depletion in Nb, Ta and Ti reflect the features of terrigenous magma. So the Neogene Belog Co alkaline volcanic rocks should be the result of partial melting of the special crust-mantle transition zone on the Qinghai-Tibet Plateau.  相似文献   

16.
The Cenozoic volcanic rock of Shandong Province are mainly alkalic and strongly alkalic basaltic rocks.The Contents of major and trace elements including transitional,incompatible and rare-earth elements were determined.The chemical characterisitics of major and trace elements indicate that these basaltic rocks were derived from a mantle source and probably represent a primary magma,I,e.,unmodifiecd partical melts of mantle peridotite in terms of Mg values,correlatione between P2O5 and Ce,Sr,Ni and Rb concentrations,mantle xenoliths,etc.The abundances of trace elements vary systematically from west to east.The compatible transition elements such as Co,Ni,and Cr show a remarkable depletion,whereas the incompatible and rare-earth elements are abundant as viewed from the chondrite-nor-malized patterns.The chemical composition and correlation are consistent with the tectonic setting.According to the batch and fractional partial melting theory,the trace element contents of Shandong volcanic rocks can be calculated from the two-component mixing model.  相似文献   

17.
The properties of feldspar and quartze are studied in this article from a fractal point of view using gray-scale micro-images of granite samples collected at the Fangshan (房山) granite body in Hebei (河北) Province, China, which can be regarded as an ideal granite in the sense of Vistelius. We found that there exist power-law relationships between the eigenvalues of the gray-scale matrices and their ranks for the feldspar and quartz. The fractal model used here is a λ-R model similar to the N-λ model proposed by Qiuming Cheng in 2005. Meanwhile, we found that average variances for the gray-scale matrices of feldspar are larger than those of quartz on the same sections, and this may be useful for auto-identification of feldspar and quartz as well as other minerals.  相似文献   

18.
斑岩铜（钼）矿成矿作用的地球化学特征   总被引：1，自引：0，他引：1  
Dealt with in this paper are some geochemical characteristics of mineralization of porphyry copper deposits, especially those observed in intrusive bodies, wa11 rocks, alteration zones, ores and individual pyrites. Productive intrusions have been correlated with barre nones from such aspects as major and trace elements, copper contents of biotite and pyrite,and distribution pattern of copper. In the mineralized rocks, trace elements show apparent zoning surrounding ore bodies; major and trace dements seem to show some reguIarity of variation in the process of alteration, and as a result each alteration zone displays its own peculiar element combination. Trace dements in ores can provide information on the genesis of ore deposits, thus of great help in distinguishing ore types while those in pyrites may be indicative of mineralization, provide dues for distinguishing orebearing from barren rocks,and reflect the degree of erosion of ore bodies.  相似文献   

19.
This paper re-describes the characteristics of pre-Ordovician (Pt3) metamorphic volcanic rocks in the Huimin-Manlai region of Yunnan Province from the aspects of petrographic characteristics, rock assemblage, petrochemistry, REE, trace elements, lead isotopes and geotectonic setting. The metamorphic volcanic rocks maintain blasto-intergranular and blasto-andesitic textures; the volcanic rocks are characterized by a basalt-andesite-dacite assemblage; the volcanic rocks are basic-intermediate-intermediate-acid in chemical composition, belonging to semi-alkaline rocks, with calc-alkaline series and tholeiite series coexisting, and they are characterized by low TiO2 contents; their REE distribution patterns are of the LREE-enrichment right-inclined type; the volcanic rocks are enriched in large cation elements and commonly enriched in Th and partly depleted in Ti, Cr and P, belonging to the Gondwana type as viewed from their Pb isotopic composition; petrochemically the data points fall mostly within the field of island-arc volcanic rocks. All these characteristics provided new evidence for the existence of original Tethysan island-arc volcanic rocks in the region studied.  相似文献   

20.
<正>The Muchang composite intrusion is located about 14 km southeast of the Fengwei town and south of the Baoshan-Zhenkang block.The rift-related intrusion consists of the early-stage riebeckite nordmarkite in the east and west sides and the discontinuous marginal zone,the late-stage main body of dominant riebeckite granite,and minor aegirine granite.Studies on petrological geochemistry and LA-ICP-MS zircon U-Pb dating of the late-stage riebeckite granite,origin and evolution of the Muchang alkali granite and the relationship between the granite and the associated skarn-type Luziyuan Pb-Zn deposit are discussed in this paper.The results show that the Muchang alkali granites belong to A-type granites,which are characterized by enrichment in Al_2O_3,SiO_2,total alkali and Fe, depletion in MgO and CaO contents with high FeO_T/MgO ratios.The REE concentrations are relatively high,exhibiting highly fractionated LREE patterns with significantly Eu negative anomaly. The Muchang granites are obviously enriched in lithophile elements(e.g.,Rb,K,U and Th) and high field strength elements(e.g.,Zr,Hf,Nb,Y and Ga) with high 10000×Ga/Al ratios and depleted in Sr, Ba,Ti,Cr and Ni,which are similar to those of the A-type granites and quite different from those of S-type andⅠ-type granites.The LA-ICP-MS zircon dating results of the Muchang granite gave a weighted mean age of 266.2±5.4 Ma(2σ),suggesting that they were formed in the stage of extension at the end of post-collision at Middle Permian and the consumption of Paleo-Tethys ocean took place before 266 Ma. It is suggested that the unexposed intermediate-acid intrusive rocks in the Luziyuan ore district,which is the "sister" rocks material of the Muchang granites and related closely to Luziyuan Pb-Zn mineralization,were the product of Middle Permian.  相似文献   

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